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1. 发明申请

US20120077041A1 FLUOROOXYALKYLENE GROUP-CONTAINING POLYMER COMPOSITION, A SURFACE TREATMENT AGENT COMPRISING THE SAME AND AN ARTICLE TREATED WITH THE AGENT 有权
标题翻译：包含含氟聚合物的含聚合物组合物，包含该聚合物组合物的表面处理剂和与该试剂一起处理的物品
公开(公告)号：US20120077041A1
公开(公告)日：2012-03-29
申请号：US13226987
申请日：2011-09-07
申请人： Yuji Yamane , Yasunori Sakano , Koichi Yamaguchi , Noriyuki Koike , Hirofumi Kishita
发明人： Yuji Yamane , Yasunori Sakano , Koichi Yamaguchi , Noriyuki Koike , Hirofumi Kishita
IPC分类号： C08L71/00 , C08L67/00 , B32B27/32 , C09D171/00
CPC分类号： C08G77/46 , C08G65/007 , C08G65/336 , C08G77/24 , C08G2650/48 , C09D171/02 , Y10T428/3154
摘要： A fluorooxyalkylene group-containing polymer composition including a liner fluorooxyalkylene group-containing polymer represented by the formula (1) which has a hydrolysable group at a terminal and is hereinafter called “one-terminal modified polymer”, and a liner fluorooxyalkylene group-containing polymer represented by the following formula (2) which has hydrolysable groups at the both terminals and is hereinafter called “both-terminal modified polymer”, wherein an amount of the both-terminal modified polymer is 0.1 mole % or more and less than 10 mole %, relative to a total mole of the one-terminal modified polymer and the both-terminal modified polymer.
摘要翻译：含有含氧代烯烃基的聚合物组合物，包含在末端具有可水解基团，以下称为“一端改性聚合物”的由式（1）表示的含有氧化烯烷基的聚合物的聚合物和含有氧化烯烃基的聚合物的聚合物由下式（2）表示，其在两末端具有可水解基团，以下称为“双末端改性聚合物”，其中两末端改性聚合物的量为0.1摩尔％以上且小于10摩尔％，相对于单末端改性聚合物和双末端改性聚合物的总摩尔数。

2. 发明授权

US08900711B2 Fluorooxyalkylene group-containing polymer composition, a surface treatment agent comprising the same and an article treated with the agent 有权
标题翻译：含有含氟氧化烯基的聚合物组合物，包含该组合物的表面处理剂和用该试剂处理的制品
公开(公告)号：US08900711B2
公开(公告)日：2014-12-02
申请号：US13226987
申请日：2011-09-07
申请人： Yuji Yamane , Yasunori Sakano , Koichi Yamaguchi , Noriyuki Koike , Hirofumi Kishita
发明人： Yuji Yamane , Yasunori Sakano , Koichi Yamaguchi , Noriyuki Koike , Hirofumi Kishita
IPC分类号： C08L71/00 , C08G65/336 , C08G65/00 , C08G77/24 , C08G77/46 , C09D171/02
CPC分类号： C08G77/46 , C08G65/007 , C08G65/336 , C08G77/24 , C08G2650/48 , C09D171/02 , Y10T428/3154
摘要： A fluorooxyalkylene group-containing polymer composition including a liner fluorooxyalkylene group-containing polymer represented by the formula (1) which has a hydrolysable group at a terminal and is hereinafter called “one-terminal modified polymer”, and a liner fluorooxyalkylene group-containing polymer represented by the following formula (2) which has hydrolysable groups at the both terminals and is hereinafter called “both-terminal modified polymer”, wherein an amount of the both-terminal modified polymer is 0.1 mole % or more and less than 10 mole %, relative to a total mole of the one-terminal modified polymer and the both-terminal modified polymer.
摘要翻译：含有含氧代烯烃基的聚合物组合物，包含在末端具有可水解基团，以下称为“一端改性聚合物”的由式（1）表示的含有氧化烯烷基的聚合物的聚合物和含有氧化烯烃基的聚合物的聚合物由下式（2）表示，其在两末端具有可水解基团，以下称为“双末端改性聚合物”，其中两末端改性聚合物的量为0.1摩尔％以上且小于10摩尔％，相对于单末端改性聚合物和双末端改性聚合物的总摩尔数。

3. 发明申请

US20100317875A1 PERFLUOROPOLYETHER GROUP-CONTAINING ACRYLATE COMPOUND 有权
标题翻译：全氟聚醚基团含丙烯酸酯化合物
公开(公告)号：US20100317875A1
公开(公告)日：2010-12-16
申请号：US12797103
申请日：2010-06-09
申请人： Yasunori Sakano , Yuji Yamane , Noriyuki Koike , Hirofumi Kishita
发明人： Yasunori Sakano , Yuji Yamane , Noriyuki Koike , Hirofumi Kishita
IPC分类号： C07D307/04 , C07F7/10
CPC分类号： C08G77/50 , C07F7/21 , C08F230/08 , C08G77/388 , C08G77/46 , C09D183/12 , C09D183/14
摘要： The present invention relates to a photo-curable perfluoropolyether group-containing acrylate compound represented by the following formula (1): X1—[Z—Rf—Z—X2]v—Z—Rf—Z—X1 (1) wherein Rf is a divalent perfluoropolyether group; X1 is a group represented by the following formula (2): R2 is a group represented by the following formula (4): X2 is a group represented by the following formula (5): and Z is a divalent organic group.
摘要翻译：本发明涉及由下式（1）表示的可光固化的全氟聚醚基丙烯酸酯化合物：X1- [Z-Rf-Z-X2] v-Z-Rf-Z-X1（1）其中Rf为二价全氟聚醚基团; X1是由下式（2）表示的基团：R2是由下式（4）表示的基团：X2是由下式（5）表示的基团：Z是二价有机基团。

4. 发明授权

US08283480B2 Perfluoropolyether group-containing acrylate compound 有权
标题翻译：含全氟聚醚基团的丙烯酸酯化合物
公开(公告)号：US08283480B2
公开(公告)日：2012-10-09
申请号：US12797103
申请日：2010-06-09
申请人： Yasunori Sakano , Yuji Yamane , Noriyuki Koike , Hirofumi Kishita
发明人： Yasunori Sakano , Yuji Yamane , Noriyuki Koike , Hirofumi Kishita
IPC分类号： C07F7/21 , C07F7/08 , C07F7/10
CPC分类号： C08G77/50 , C07F7/21 , C08F230/08 , C08G77/388 , C08G77/46 , C09D183/12 , C09D183/14
摘要： The present invention relates to a photo-curable perfluoropolyether group-containing acrylate compound represented by the following formula (1): X1—[Z—Rf—Z—X2]v—Z—Rf—Z—X1 (1) wherein Rf is a divalent perfluoropolyether group; X1 is a group represented by the following formula (2): R2 is a group represented by the following formula (4): X2 is a group represented by the following formula (5): and Z is a divalent organic group.
摘要翻译：本发明涉及由下式（1）表示的可光固化的全氟聚醚基丙烯酸酯化合物：X1- [Z-Rf-Z-X2] v-Z-Rf-Z-X1（1）其中Rf为二价全氟聚醚基团; X1是由下式（2）表示的基团：R2是由下式（4）表示的基团：X2是由下式（5）表示的基团：Z是二价有机基团。

5. 发明授权

US06552152B2 Curable fluoropolyether rubber compositions 有权
公开(公告)号：US06552152B2
公开(公告)日：2003-04-22
申请号：US09893603
申请日：2001-06-29
申请人： Yasunori Sakano , Shinichi Sato , Koichi Yamaguchi , Noriyuki Koike , Masatoshi Arai , Hirofumi Kishita
发明人： Yasunori Sakano , Shinichi Sato , Koichi Yamaguchi , Noriyuki Koike , Masatoshi Arai , Hirofumi Kishita
IPC分类号： C08G7712
CPC分类号： C08G65/336 , C08G65/007
摘要： A curable fluoropolyether rubber composition comprising (A) a straight-chain fluoropolyether compound having at least two alkenyl groups and a perfluoropolyether structure backbone, (B) an organosilicon compound having at least two silicon atom-bonded hydrogen atoms, which all form H—SiCH2— structures, and (C) a hydrosilylation catalyst cures into parts which have good heat resistance, chemical resistance, solvent resistance, parting property, water repellency, oil repellency and weather resistance as well as improved acid and alkali resistance and are useful as sealants.

6. 发明授权

US07781604B2 Fluorine-containing acrylate 有权
标题翻译：含氟丙烯酸酯
公开(公告)号：US07781604B2
公开(公告)日：2010-08-24
申请号：US12619135
申请日：2009-11-16
申请人： Yasunori Sakano , Noriyuki Koike , Hirofumi Kishita
发明人： Yasunori Sakano , Noriyuki Koike , Hirofumi Kishita
IPC分类号： C07C7/10
CPC分类号： C08G77/045 , C07F7/21 , C08F220/22 , C08F220/24 , C08F230/08 , C08G18/61 , C08G18/8116 , C08G77/38 , C08G77/388 , C09D175/16
摘要： The present invention is a fluorine-containing acrylate or alpha-substituted, fluorine-containing acrylate, represented by the following formula (1): wherein a is an integer of from 1 to 4 and b is an integer of from 1 to 4, provided that a total of a and b is 3, 4, or 5; R1 is a group represented by the following formula (2): —(C4H8O)d(C3H6O)e(C2H4O)f(CH2O)g— (2) wherein d, e, f, and g are, independently of each other, an integer of from 0 to 4, provided that a molecular weight of R1 is in a range of 30 to 300, and these repeating units may be sequenced at random; R2 is an acryl group- or alpha-substituted acryl group-containing group having 4 to 20 carbon atoms and represented by the following formula (3): wherein R3 is, independently of each other, a hydrogen atom, a fluorine atom, a methyl group, or a trifluoromethyl group, R4 is a divalent or trivalent linking moiety having 1 to 18 carbon atoms, optionally having an ether bond and/or an ester bond, and n is 1 or 2; Rf is a perfluoropolyether residue represented by the following formula (4): wherein j, k, l, and m are, independently of each other, an integer of from 0 to 50, provided that a molecular weight of Rf is in a range of 200 to 6000, X is a fluorine atom or a trifluoromethyl group, and these repeating units may be sequenced at random; Z is a divalent organic group; and c is 0 or 1.
摘要翻译：本发明是由下式（1）表示的含氟丙烯酸酯或α-取代的含氟丙烯酸酯，其中a为1〜4的整数，b为1〜4的整数，总共a和b为3,4或5; R1是由下式（2）表示的基团： - （C4H8O）d（C3H6O）e（C2H4O）f（CH2O）g-（2）其中d，e，f和g彼此独立地是如果R1的分子量在30〜300的范围内，则0〜4的整数，这些重复单元可以随机排列; R2是具有4〜20个碳原子的丙烯酰基或α-取代的含丙烯酰基的基团，由下式（3）表示：其中R 3彼此独立地为氢原子，氟原子，甲基基团或三氟甲基，R 4是具有1至18个碳原子的二价或三价连接部分，任选具有醚键和/或酯键，n为1或2; Rf是由下式（4）表示的全氟聚醚残基：其中j，k，l和m彼此独立地为0至50的整数，条件是Rf的分子量在 200〜6000，X为氟原子或三氟甲基，这些重复单元可以随机排列; Z是二价有机基团; c为0或1。

7. 发明授权

US06521774B2 Organosilicon compounds 失效
标题翻译：有机硅化合物
公开(公告)号：US06521774B2
公开(公告)日：2003-02-18
申请号：US09841047
申请日：2001-04-25
申请人： Noriyuki Koike , Koichi Yamaguchi , Yasunori Sakano
发明人： Noriyuki Koike , Koichi Yamaguchi , Yasunori Sakano
IPC分类号： C07F704
CPC分类号： C07F7/0896
摘要： A novel organosilicon compound obtained by introducing an alkylene group or analogue instead of the oxygen atom in an Si—O—Si linkage is capable of hydrosilylation reaction with another compound having a vinyl group to form a hydrosilylated derivative which is less prone to decomposition under acidic or basic conditions.
摘要翻译：通过在Si-O-Si键中引入亚烷基或类似物而不是氧原子获得的新型有机硅化合物能够与具有乙烯基的另一种化合物进行氢化硅烷化反应以形成在酸性下不易分解的氢化硅烷基化衍生物或基本条件。

8. 发明申请

US20080021233A1 Method of preparing disilanol compound and method of storing disilanol compound 有权
标题翻译：制备二硅烷醇化合物的方法和二硅烷醇化合物的储存方法
公开(公告)号：US20080021233A1
公开(公告)日：2008-01-24
申请号：US11826940
申请日：2007-07-19
申请人： Yasunori Sakano , Takashi Matsuda , Noriyuki Koike
发明人： Yasunori Sakano , Takashi Matsuda , Noriyuki Koike
IPC分类号： C07F7/10
CPC分类号： C07F7/0836 , C08G65/007 , C08G65/336
摘要： A method of preparing a disilanol compound by hydrolyzing a dichlorosilane compound having Si—Cl bonds at both ends, characterized in that the method comprises the step of hydrolyzing the dichlorosilane compound in the presence of a tertiary amine compound.
摘要翻译：通过在两端水解具有Si-Cl键的二氯硅烷化合物制备二硅烷醇化合物的方法，其特征在于该方法包括在叔胺化合物存在下水解二氯硅烷化合物的步骤。

9. 发明授权

US08247592B2 Method of preparing disilanol compound and method of storing disilanol compound 有权
标题翻译：制备二硅烷醇化合物的方法和二硅烷醇化合物的储存方法
公开(公告)号：US08247592B2
公开(公告)日：2012-08-21
申请号：US13111647
申请日：2011-05-19
申请人： Yasunori Sakano , Takashi Matsuda , Noriyuki Koike
发明人： Yasunori Sakano , Takashi Matsuda , Noriyuki Koike
IPC分类号： C07F7/08
CPC分类号： C07F7/0836 , C08G65/007 , C08G65/336
摘要： Disclosed is a method of storing a fluorine-containing disilanol compound represented by the following formula (3) in the presence of a tertiary amine in such an amount that a molar ratio of the tertiary amine to a silanol group of the fluorine-containing disilanol compound ranges from 0.001 to 20, HO—Z—R1—Rf—R1—Z—OH (3) wherein Rf is a divalent fluorinated hydrocarbon group or a divalent fluorinated polyether group, R1 may be the same with or different from each other and is a substituted or unsubstituted divalent hydrocarbon group which may have at least one atom selected from the group consisting of oxygen, nitrogen, silicon, and sulfur atoms, and Z is a group represented by the following formula (2) —SiR2R3— (2) wherein R2 and R3 may be the same with or different from each other and are monovalent organic groups.
摘要翻译：本发明公开了一种在叔胺存在下，使下式（3）表示的含氟二硅烷醇化合物的存在量使得含氟二硅烷醇化合物的叔胺与硅烷醇基的摩尔比范围为0.001〜20，HO-Z-R1-Rf-R1-Z-OH（3）其中Rf为二价氟化烃基或二价氟化聚醚基，R 1可以相同或不同，可以具有选自氧，氮，硅和硫原子中的至少一个原子的取代或未取代的二价烃基，Z是由下式（2）-SiR 2 R 3 - （2）表示的基团，其中 R2和R3可以彼此相同或不同，并且是一价有机基团。

10. 发明授权

US07087673B2 Fluororubber compositions and articles thereof 有权
标题翻译：氟橡胶组合物及其制品
公开(公告)号：US07087673B2
公开(公告)日：2006-08-08
申请号：US10337290
申请日：2003-01-07
申请人： Takashi Matsuda , Yasuhisa Osawa , Noriyuki Koike , Yasunori Sakano
发明人： Takashi Matsuda , Yasuhisa Osawa , Noriyuki Koike , Yasunori Sakano
IPC分类号： C08L27/12 , C08F114/18 , C08K5/14
CPC分类号： C08G65/336 , C08G65/007 , C08K9/06 , C08L71/00
摘要： A crosslinkable fluororubber composition comprising (A) a polymer of the formula: Z-(Rf-Q)n—Rf-Z wherein n is an integer of at least 1, Rf is a divalent perfluoroalkylene or perfluorooxyalkylene radical, Q is a divalent organic radical, and Z is a monovalent organic radical, having a viscosity of at least 1,000 Pa·s at 25° C., (B) a reinforcing filler, and (C) a peroxide crosslinking agent is effectively roll milled and experiences minimal changes of viscosity after milling. Molded parts can be produced on a mass scale.
摘要翻译：一种可交联氟橡胶组合物，其包含（A）下式的聚合物：Z-（R f -Q）n -R f-Z其中n是至少为1的整数，R f是二价全氟亚烷基或全氟氧化烯自由基，Q为二价有机基团，Z为单价有机基团，其在25℃下的粘度至少为1,000Pa.s，（B）增强填料，（C）过氧化物交联剂有效地辊磨，经过磨碎后粘度变化最小。模制件可以大规模生产。

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