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    • 2. 发明授权
    • Method of preparing disilanol compound and method of storing disilanol compound
    • 制备二硅烷醇化合物的方法和二硅烷醇化合物的储存方法
    • US08247592B2
    • 2012-08-21
    • US13111647
    • 2011-05-19
    • Yasunori SakanoTakashi MatsudaNoriyuki Koike
    • Yasunori SakanoTakashi MatsudaNoriyuki Koike
    • C07F7/08
    • C07F7/0836C08G65/007C08G65/336
    • Disclosed is a method of storing a fluorine-containing disilanol compound represented by the following formula (3) in the presence of a tertiary amine in such an amount that a molar ratio of the tertiary amine to a silanol group of the fluorine-containing disilanol compound ranges from 0.001 to 20, HO—Z—R1—Rf—R1—Z—OH  (3) wherein Rf is a divalent fluorinated hydrocarbon group or a divalent fluorinated polyether group, R1 may be the same with or different from each other and is a substituted or unsubstituted divalent hydrocarbon group which may have at least one atom selected from the group consisting of oxygen, nitrogen, silicon, and sulfur atoms, and Z is a group represented by the following formula (2) —SiR2R3—  (2) wherein R2 and R3 may be the same with or different from each other and are monovalent organic groups.
    • 本发明公开了一种在叔胺存在下,使下式(3)表示的含氟二硅烷醇化合物的存在量使得含氟二硅烷醇化合物的叔胺与硅烷醇基的摩尔比 范围为0.001〜20,HO-Z-R1-Rf-R1-Z-OH(3)其中Rf为二价氟化烃基或二价氟化聚醚基,R 1可以相同或不同, 可以具有选自氧,氮,硅和硫原子中的至少一个原子的取代或未取代的二价烃基,Z是由下式(2)-SiR 2 R 3 - (2)表示的基团,其中 R2和R3可以彼此相同或不同,并且是一价有机基团。