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1. 发明授权

US09920214B2 Solvent-based paint composition and fluorine-containing copolymer 有权
公开(公告)号：US09920214B2
公开(公告)日：2018-03-20
申请号：US14008259
申请日：2012-03-30
申请人： Yuji Imahori , Hirotoshi Yoshida , Mayumi Iida , Kengo Ito , Yoshito Tanaka , Katsuhiko Imoto , Takuma Kawabe , Akiko Ohya
发明人： Yuji Imahori , Hirotoshi Yoshida , Mayumi Iida , Kengo Ito , Yoshito Tanaka , Katsuhiko Imoto , Takuma Kawabe , Akiko Ohya
IPC分类号： C09D127/18 , C09D127/12 , C08F214/18 , C09D131/04 , C08F214/26 , C08F218/08 , C08F220/64 , C08F216/14
CPC分类号： C09D127/18 , C08F214/18 , C08F214/186 , C08F214/267 , C08F216/1416 , C08F218/08 , C08F220/64 , C09D127/12 , C09D131/04
摘要： Provided is a paint composition which can give a coating having excellent stretchability and further having excellent contamination resistance. A solvent-based paint composition comprises a fluorocopolymer (I), and an organic solvent (II), the fluorocopolymer (I) including: a perhaloolefin structural unit (a) that contains two carbon atoms, a vinyl acetate structural unit (b), a hydroxyl group-containing vinyl monomer structural unit (c) represented by the following formula (1): CH2═CH—O—(CH2)n—OH wherein n is an integer of 2 or more, and a carboxyl group-containing monomer structural unit (d) represented by the following formula (2): R1R2C═CR3—(CH2)m—COOH wherein R1, R2, and R3 are the same as or different from one another, and each a hydrogen atom or a C1-C10 linear or branched alkyl group; and m is an integer of 2 or more.

2. 发明申请

US20140018492A1 SOLVENT-BASED PAINT COMPOSITION AND FLUORINE-CONTAINING COPOLYMER 有权
标题翻译：溶剂型涂料组合物和含氟聚合物共聚物
公开(公告)号：US20140018492A1
公开(公告)日：2014-01-16
申请号：US14008259
申请日：2012-03-30
申请人： Yuji Imahori , Hirotoshi Yoshida , Mayumi Iida , Kengo Ito , Yoshito Tanaka , Katsuhiko Imoto , Takuma Kawabe , Akiko Ohya
发明人： Yuji Imahori , Hirotoshi Yoshida , Mayumi Iida , Kengo Ito , Yoshito Tanaka , Katsuhiko Imoto , Takuma Kawabe , Akiko Ohya
IPC分类号： C09D127/18 , C08F218/08 , C08F214/26 , C09D131/04
CPC分类号： C09D127/18 , C08F214/18 , C08F214/186 , C08F214/267 , C08F216/1416 , C08F218/08 , C08F220/64 , C09D127/12 , C09D131/04
摘要： Provided is a paint composition which can give a coating having excellent stretchability and further having excellent contamination resistance. A solvent-based paint composition comprises a fluorocopolymer (I), and an organic solvent (II), the fluorocopolymer (I) including: a perhaloolefin structural unit (a) that contains two carbon atoms, a vinyl acetate structural unit (b), a hydroxyl group-containing vinyl monomer structural unit (c) represented by the following formula (1): CH2═CH—O—(CH2)n—OH wherein n is an integer of 2 or more, and a carboxyl group-containing monomer structural unit (d) represented by the following formula (2): R1R2C═CR3—(CH2)m—COOH wherein R1, R2, and R3 are the same as or different from one another, and each a hydrogen atom or a C1-C10 linear or branched alkyl group; and m is an integer of 2 or more.
摘要翻译：提供一种涂料组合物，其能够赋予具有优异的拉伸性并且还具有优异的耐污染性的涂层。溶剂型涂料组合物包含含氟共聚物（I）和有机溶剂（II），含氟共聚物（I）包括：含有两个碳原子的全卤代烯烃结构单元（a），乙酸乙烯酯结构单元（b），由下式（1）表示的含羟基的乙烯基单体结构单元（c）：CH2 = CH-O-（CH2）n-OH其中n为2以上的整数，含羧基的单体由下式（2）表示的结构单元（d）：R1R2C = CR3-（CH2）m-COOH其中R1，R2和R3彼此相同或不同，并且各自为氢原子或C1- C10直链或支链烷基; m为2以上的整数。

3. 发明申请

US20150240012A1 METHOD FOR PRODUCING FLUORINE-CONTAINING COPOLYMER 审中-公开
标题翻译：生产含氟聚合物的方法
公开(公告)号：US20150240012A1
公开(公告)日：2015-08-27
申请号：US14008617
申请日：2012-03-28
申请人： Yuji Imahori , Hirotoshi Yoshida , Mayumi Iida , Kengo Ito , Yoshito Tanaka , Katsuhiko Imoto , Takuma Kawabe
发明人： Yuji Imahori , Hirotoshi Yoshida , Mayumi Iida , Kengo Ito , Yoshito Tanaka , Katsuhiko Imoto , Takuma Kawabe
IPC分类号： C08F218/08
CPC分类号： C08F218/08 , C08F2/26 , C08F14/18 , C08F214/00 , C08F214/182 , C08F214/186 , C08F214/188 , C08F214/24 , C08F214/245 , C08F214/26 , C08F214/265 , C08F14/26
摘要： The present invention provides a method for producing a copolymer containing a perhaloolefin and vinyl acetate by a novel emulsion polymerization method. The present invention relates to a method for producing a perhaloolefin-vinyl acetate copolymer by emulsion polymerization of at least a perhaloolefin having two carbon atoms and vinyl acetate in the presence of a hydrocarbon emulsifier or in the absence of an emulsifier, provided that the hydrocarbon emulsifier excludes a compound (1) represented by the formula (1): wherein R1 and R2 are the same as or different from each other and each represent a C4 to 12 unfluorinated saturated hydrocarbon group; M represents an alkali metal, an ammonium salt, or an amine salt.
摘要翻译：本发明提供一种通过新的乳液聚合法制备含有全卤代烯烃和乙酸乙烯酯的共聚物的方法。本发明涉及一种通过在烃类乳化剂的存在下或不存在乳化剂的情况下通过至少具有两个碳原子的全卤代烯烃和乙酸乙烯酯的乳液聚合制备全卤代烯烃 - 乙酸乙烯酯共聚物的方法，条件是烃类乳化剂不包括由式（1）表示的化合物（1）：其中R1和R2彼此相同或不同，并且各自表示C4至12个未氟饱和烃基; M表示碱金属，铵盐或胺盐。

4. 发明授权

US08143351B2 Fluororesin composition and covered electric wire 有权
标题翻译：氟树脂组成和覆盖电线
公开(公告)号：US08143351B2
公开(公告)日：2012-03-27
申请号：US12674070
申请日：2008-09-24
申请人： Keizo Shiotsuki , Hideki Kono , Kenji Ishii , Kengo Ito , Kenjiro Tanimoto , Takahiro Kitahara
发明人： Keizo Shiotsuki , Hideki Kono , Kenji Ishii , Kengo Ito , Kenjiro Tanimoto , Takahiro Kitahara
IPC分类号： C08L27/12
CPC分类号： C08J3/12 , C08F8/22 , C08J3/16 , C08J3/226 , C08J2327/18 , C08J2427/00 , C08L27/18 , C08L2205/02 , H01B3/445 , C08L2666/04
摘要： It is an object of the present invention to provide a fluororesin composition which hardly causes molding defects even when high-speed molding is performed in covering extrusion molding within a relatively broad molding temperature range and which can give covered electric wires, in particular foamed electric wires, excellent in surface smoothness.A fluororesin composition comprising a polytetrafluoroethylene [PTFE] having a standard specific gravity of 2.15 to 2.30 and a tetrafluoroethylene/hexafluoropropylene-based copolymer [FEP], the content of said PTFE being 0.01 to 3 parts by mass per 100 parts by mass of said FEP and the alkali metal content being not higher than 5 ppm on the resin composition solid matter basis, wherein said composition is obtained by a method comprising the step (1) of obtaining a cocoagulated fluororesin powder by mixing an aqueous dispersion containing said FEP and an aqueous dispersion containing said PTFE together, followed by coagulation, the step (2) of melt extruding the cocoagulated powder and the step (3) of subjecting the extrusion product to treatment for stabilizing unstable terminal groups in said PTFE and FEP.
摘要翻译：本发明的目的是提供即使在相对宽的成型温度范围内覆盖挤压成型进行高速成型时也难以引起成型缺陷的氟树脂组合物，其可以形成被覆电线，特别是发泡电线表面平滑度优异。一种含有标准比重为2.15〜2.30的聚四氟乙烯[PTFE]和四氟乙烯/六氟丙烯系共聚物[FEP]的氟树脂组合物，所述PTFE的含量相对于100质量份所述FEP为0.01〜3质量份碱性金属含量在树脂组合物固体物质上不高于5ppm，其中所述组合物通过包括步骤（1）的方法获得，所述方法包括通过将含有所述FEP的水性分散体和水溶液将所述PTFE分散在一起，然后凝固，熔融挤出可凝结粉末的步骤（2）和使挤出产物经受处理以稳定所述PTFE和FEP中的不稳定末端基团的步骤（3）。

5. 发明申请

US20050117269A1 Ion generating unit 失效
标题翻译：离子发生单元
公开(公告)号：US20050117269A1
公开(公告)日：2005-06-02
申请号：US10879021
申请日：2004-06-30
申请人： Hidetoshi Nakasone , Itaru Saida , Kengo Ito
发明人： Hidetoshi Nakasone , Itaru Saida , Kengo Ito
IPC分类号： B03C3/02 , A61L9/22 , A61N1/44 , B03C3/40 , B03C3/41 , H01T19/04 , H01T23/00 , H05F3/04 , A46B15/00
CPC分类号： A61N1/44 , H01T23/00
摘要： An ion generating unit is made compact, yet avoids the undesired arc discharge for successfully generating the ions. The ion generating unit includes a dielectric base having a length and carrying a needle electrode and a ground electrode. The needle electrode has a pointed tip and is adapted to receive a high electric voltage relative to the ground electrode for electrically charging particles present in the surrounding air. The dielectric base being a polyhedron having multiple faces including a first face and a second face which are different from each other and have the length of the dielectric base. The needle electrode is mounted on or in a closely adjacent relation to the first face, and has its pointed tip directing forwardly along the length of the dielectric base with the pointed tip receded from the front end of the base. The ground electrode is mounted at the front end of the base in longitudinally spaced relation with the pointed tip. The ground electrode include anchor ends only by which the ground electrode is secured to the base. The anchor ends are fixed to the second face of the base, but not to the first face. Thus, the creepage distance between the electrodes extends over the first face and also the second face of the dielectric base, thereby being given an elongated distance relative to the air path between the electrodes for successfully generating the ions.
摘要翻译：离子发生单元紧凑，但避免了用于成功地产生离子的不期望的电弧放电。离子产生单元包括具有长度并携带针电极和接地电极的电介质基底。针状电极具有尖端，并且适于相对于接地电极接收高电压，用于对存在于周围空气中的颗粒进行充电。电介质基底是具有多个面的多面体，多面包括彼此不同的第一面和第二面，并具有电介质基底的长度。针状电极安装在第一面上或紧密相邻的第一面上，并且其尖端沿着电介质基底的长度向前引导，尖端从基座的前端退出。接地电极安装在基座的前端，与尖端呈纵向间隔的关系。接地电极仅包括锚固端，接地电极固定到基座上。锚固端部固定到基座的第二面，但不固定到第一面。因此，电极之间的爬电距离在第一面和电介质基底的第二面上延伸，从而相对于电极之间的空气路径给予较长的距离，以成功地产生离子。

6. 发明授权

US06468235B2 Facial aesthetic treatment apparatus 失效
标题翻译：面部美容治疗仪器
公开(公告)号：US06468235B2
公开(公告)日：2002-10-22
申请号：US09907765
申请日：2001-07-19
申请人： Kengo Ito , Kazuyasu Ikadai
发明人： Kengo Ito , Kazuyasu Ikadai
IPC分类号： A61H700
CPC分类号： A61M1/08 , A61M1/0047 , A61M1/0072 , A61M1/06 , A61M2210/0606
摘要： A facial aesthetic treatment apparatus includes a housing provided with a nozzle and a suction pump for developing a suction force. An attachment is mounted to the nozzle for applying the suction force to a facial skin for removal of sebum, dirt or the like debris from the facial skin. The apparatus is capable of regulating the suction force being applied to the skin, and particularly minimizing the suction force immediately in response to the user's action of ceasing the treatment, thereby making it easy to remove the attachment from the facial skin and therefore reducing a risk of causing a pain and leaving the purpuric mark as well. A regulator is incorporated to regulate the suction force being applied to the facial skin for easy and safe removal of the suction force.
摘要翻译：面部美容处理装置包括具有喷嘴的壳体和用于产生吸力的抽吸泵。将附件安装到喷嘴上以将吸力施加到面部皮肤上，以从面部皮肤去除皮脂，污垢或类似物体。该装置能够调节施加到皮肤的吸力，并且特别地最小化响应于用户停止治疗的动作的吸力，从而使得容易从面部皮肤移除附件并因此降低风险造成痛苦，并留下紫红色的痕迹。结合调节器以调节施加到面部皮肤的吸力，以便于和安全地去除吸力。

7. 发明授权

US5948149A Water-based ink composition 失效
标题翻译：水性油墨组合物
公开(公告)号：US5948149A
公开(公告)日：1999-09-07
申请号：US871379
申请日：1997-06-09
申请人： Kengo Ito , Hiroyuki Nakashinden
发明人： Kengo Ito , Hiroyuki Nakashinden
IPC分类号： C09D11/00
CPC分类号： C09D11/38
摘要： The present invention provides a water-based ink composition in which the wettability, surface tension, antibacterial properties, and other properties are controlled based on a simple formulation. The water-based ink composition of the present invention contains a semi-polar boron compound. Semi-polar boron compounds represented by diglycerin borate exhibit superior wettability in an ordinary environment, and addition of such a compound achieves a water-based ink composition well-balanced in surface tension, wettability, and drying property even if the composition is prepared according to a simple formulation. The optimum quantitative range for addition of the semi-polar boron compound depends on whether the coloring material contained in the watercolor ink composition is a dyestuff or a pigment. When the coloring material is a dyestuff, the quantitative range is preferably 0.5 to 3.0% by weight relative to the entire quantity of the water-based ink composition. When the coloring material is a pigment, the quantitative range is preferably 0.05 to 10% by weight relative to the same.
摘要翻译：本发明提供一种水性油墨组合物，其中基于简单的配方控制润湿性，表面张力，抗菌性能等特性。本发明的水性油墨组合物含有半极性的硼化合物。由二甘油硼酸盐代表的半极性硼化合物在普通环境中表现出优异的润湿性，并且添加这种化合物使表面张力，润湿性和干燥性能均匀的水性油墨组合物即使根据一个简单的表述。用于添加半极性硼化合物的最佳定量范围取决于水彩墨水组合物中包含的着色材料是染料还是颜料。当着色材料为染料时，相对于水性油墨组合物的总量，定量范围优选为0.5〜3.0重量％。当着色材料为颜料时，相对于该颜料，定量范围优选为0.05〜10重量％。

8. 发明授权

US5883232A Hydrophobic cationic dyes and thermal transfer ink ribbons using the same 失效
标题翻译：疏水性阳离子染料和热转印墨带使用相同
公开(公告)号：US5883232A
公开(公告)日：1999-03-16
申请号：US114980
申请日：1998-07-14
申请人： Masanobu Hida , Kengo Ito , Yoshio Fujiwara , Nobuo Suzuki , Hiroyoshi Yamaga , Junichi Hagiwara
发明人： Masanobu Hida , Kengo Ito , Yoshio Fujiwara , Nobuo Suzuki , Hiroyoshi Yamaga , Junichi Hagiwara
IPC分类号： B41J31/00 , B41M3/12 , B41M5/385 , B41M5/388 , B41M5/39 , C04B9/02 , C09B44/02 , C09B44/04 , C09B44/18 , C09B69/06 , D06P5/13 , G03C1/73 , G03C1/735
CPC分类号： B41M5/388 , C09B44/18 , C09B69/065 , Y10S534/02
摘要： Disclosed are diazahemicyanine hydrophobic cationic dyes represented by the formula (1): ##STR1## wherein R.sup.1, R.sup.2, R.sup.3 and R.sup.4 are lower alkyl groups having not more than 5 carbon atoms, R.sup.5 is a lower alkyl group having not more than 5 carbon atoms or a lower alkoxy lower alkyl group having not more than 6 carbon atoms, and Z.sup.- is a counter ion having a hydrophobic organic group, and a thermal transfer ink ribbon having a substrate and and ink layer laminated thereon containing said cationic dye.
摘要翻译：公开了由式（1）表示的二氮杂氨酸疏水性阳离子染料：其中R1，R2，R3和R4是不大于5个碳原子的低级烷基，R5是不大于 5个碳原子或具有不超过6个碳原子的低级烷氧基低级烷基，Z-是具有疏水性有机基团的抗衡离子，和具有基材的热转印墨带和层压在其上的含有所述阳离子染料的墨层。

9. 发明授权

US5589435A Sheet capable of releasing a thermal transfer image-receiving layer, a method for transferring a thermal transfer image-receiving layer from the sheet and a method for forming images 失效
标题翻译：能够释放热转印图像接收层的片材，从片材转印热转印图像接收层的方法和形成图像的方法
公开(公告)号：US5589435A
公开(公告)日：1996-12-31
申请号：US471767
申请日：1995-06-06
申请人： Kengo Ito , Kaori Isaji , Yoshio Fujiwara , Mitsuhiro Isogai , Masanobu Hida
发明人： Kengo Ito , Kaori Isaji , Yoshio Fujiwara , Mitsuhiro Isogai , Masanobu Hida
IPC分类号： B41M5/382 , B41M5/50 , B41M5/52 , B41M5/035 , B41M5/38
CPC分类号： B41M5/5218 , Y10S428/913 , Y10S428/914 , Y10T428/259
摘要： A sheet of the type which comprises a release base sheet and a thermal transfer image-receiving layer formed on the release base sheet and which is capable of releasing the thermal transfer image-receiving layer from the base sheet is described. The receiving layer is made of a dispersion, in a resin binder, of a layer compound capable of fixing cationic dyes through ion exchange reaction therewith. The receiving layer can be readily formed on a desired type of substrate by superposing the receiving layer on the substrate, after which the release base sheet is peeled off from the receiving layer. A thermal transfer image can be formed on the receiving layer by superposition with an ink ribbon containing a cationic dye and application of image information to the ink ribbon or by re-transfer of a cationic dye image from a printing paper. The thermal transfer image may be formed prior to the transfer of the receiving layer on the substrate. Owing to the fixing of the cationic dye through ion exchange reaction, the fixing properties of the dye in the receiving layer can be significantly improved.
摘要翻译：描述了一种包括释放基片和形成在释放基片上并且能够从基片释放热转印图像接收层的热转印图像接收层的类型。接收层由树脂粘合剂中的能够通过离子交换反应固定阳离子染料的层化合物的分散体制成。接收层可以通过将接收层叠置在基板上而容易地形成在期望类型的基板上，然后将释放基片从接收层剥离。可以通过与含有阳离子染料的墨带和向墨带施加图像信息或通过从印刷纸重新转移阳离子染料图像叠加在接收层上形成热转印图像。热转印图像可以在接收层在基板上传送之前形成。由于通过离子交换反应固定阳离子染料，染料在接收层中的定影性能可以显着提高。

10. 发明授权

US5324705A Printing sheet comprising an image-receiving layer made of an acidic resin 失效
标题翻译：包含由酸性树脂制成的图像接受层的印刷片
公开(公告)号：US5324705A
公开(公告)日：1994-06-28
申请号：US900269
申请日：1992-06-18
申请人： Kengo Ito
发明人： Kengo Ito
IPC分类号： B41J2/00 , B41M5/382 , B41M5/385 , B41M5/50 , B41M5/52 , D21H19/20 , B41M5/035 , B41M5/38
CPC分类号： B41M5/385 , B41M5/5254 , Y10S428/913 , Y10S428/914 , Y10T428/31855 , Y10T428/3192
摘要： A printing sheet which is used in combination with an ink ribbon containing a hydrophobic cationic dye is described. The printing sheet comprises on a support an image-accepting layer made of an acidic resin or resin composition whereby the transfer sensitivity and storage stability of the resultant image are significantly improved.
摘要翻译：描述了与含有疏水性阳离子染料的墨带组合使用的印刷片。印刷纸在载体上包含由酸性树脂或树脂组合物制成的图像接受层，由此显着提高所得图像的转印灵敏度和储存稳定性。

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