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1. 发明授权

US07049356B2 Low fogging thermoplastic elastomer composition and manufacturing method and use of same composition 有权
标题翻译：低雾热塑性弹性体组合物及其制造方法和用途相同
公开(公告)号：US07049356B2
公开(公告)日：2006-05-23
申请号：US09779558
申请日：2001-02-09
申请人： Yuichi Itoh , Kunihiko Mizumoto , Hiroyasu Yamaoka , Akira Uchiyama
发明人： Yuichi Itoh , Kunihiko Mizumoto , Hiroyasu Yamaoka , Akira Uchiyama
IPC分类号： C08L91/00 , C08L9/00 , C08J3/24
CPC分类号： C08L23/04 , C08L23/0815 , C08L23/10 , C08L23/16 , C08L2207/04 , C08L2312/00 , C08L2666/04
摘要： This invention relates to a perfectly or partially crosslinked olefinic thermoplastic elastomer composition which comprises 10 to 90 parts by weight of a crystalline polyolefin (a), 90 to 10 parts by weight of an olefin-based copolymer rubber (b) (the total amount of the components (a) and (b) being 100 parts by weight) and 3 to 100 parts by weight of a paraffinic mineral oil softening agent (c) having an evaporation loss of 0.4% by weight or less at a condition of 200° C., atmospheric pressure and 1 hour and having a kinetic viscosity (40° C.) of 50 to 250 cSt; an olefinic thermoplastic elastomer composition which is obtainable by subjecting a mixture including 40 to 85 parts by weight of an ethylene-based copolymer rubber (A), 60 to 15 parts by weight of an olefinic resin (B) and 45 parts by weight or less of a softening agent (C) [the total amount of the components (A), (B) and (C) being 100 parts by weight] to dynamic heat treatment in the presence of a crossliking agent and which has a gloss value of 80% or more and a haze value of 10% or less on glass plate when subjected to the fogging test at a condition of 100° C. and 3 hours according to the prescription of A method of DIN 75201; and a manufacturing method and use of the compositions.
摘要翻译：本发明涉及一种完全或部分交联的烯烃热塑性弹性体组合物，其包含10至90重量份的结晶聚烯烃（a），90至10重量份的烯烃基共聚物橡胶（b）（总计组分（a）和（b）为100重量份）和3至100重量份在200℃条件下蒸发损失为0.4重量％以下的石蜡矿物油软化剂（c）大气压和1小时，动力粘度（40℃）为50〜250cSt; 烯烃类热塑性弹性体组合物，其通过使含有乙烯系共聚物橡胶（A）40〜85重量份，烯烃系树脂（B）60〜15重量份和45重量份以下的混合物的软化剂（C）[组分（A），（B）和（C）的总量为100重量份]在光泽剂存在下进行动态热处理，其光泽值为80 ％以上，雾度值为10％以下时，在100℃，3小时的条件下进行雾化试验时，根据DIN75201A法的处方，以及组合物的制造方法和用途。

2. 发明授权

US07094828B2 Olefin thermoplastic elastomer composition 有权
标题翻译：烯烃热塑性弹性体组合物
公开(公告)号：US07094828B2
公开(公告)日：2006-08-22
申请号：US10199066
申请日：2002-07-22
申请人： Kyoko Kobayashi , Hiroyasu Yamaoka , Yuichi Itoh , Akira Uchiyama
发明人： Kyoko Kobayashi , Hiroyasu Yamaoka , Yuichi Itoh , Akira Uchiyama
IPC分类号： C08J3/22
CPC分类号： C08L53/00 , C08L23/10 , C08L23/12 , C08L23/16 , C08L53/02 , C08L91/00 , C08L2207/04 , C08L2312/00 , C08L2666/24 , C08L2666/04 , C08L2666/02
摘要： An olefin thermoplastic elastomer composition which is superior in the resistance to oils, heat resistance, formability and flexibility is provided, said elestomer composition comprising the components(A) 40–90 parts by weight of a polypropylene resin having a melt flow rate (determined at 230 ° C. under a load of 2.16 kg according to ASTM D 1238) of 0.1–5 g/10 minutes,(B) 10–60 parts by weight of a copolymer rubber based on olefin, the contents of the components (A) and (B) summing up to 100 parts by weight, and(C) 20–150 parts by weight of a softener,wherein the composition is in such a cross-linked state that the gel content thereof amounts to 97% by weight or higher.
摘要翻译：提供了耐油性，耐热性，成形性和柔软性优异的烯烃热塑性弹性体组合物，所述组分（A）包含40-90重量份的具有熔体流动速率的聚丙烯树脂（在 230℃，根据ASTM D 1238的2.16kg负荷）为0.1-5g / 10分钟，（B）10-60重量份基于烯烃的共聚物橡胶，组分（A）的含量和（B）总计100重量份，和（C）20-150重量份的软化剂，其中组合物处于交联状态，其凝胶含量为97重量％以上。

3. 发明授权

US06803398B1 Thermoplastic olefin elastomer composition 失效
标题翻译：热塑性烯烃弹性体组合物
公开(公告)号：US06803398B1
公开(公告)日：2004-10-12
申请号：US09486368
申请日：2000-02-28
申请人： Yuichi Ito , Hiroyasu Yamaoka , Akira Uchiyama , Chika Kako , Hideo Nishimura , Junzo Ukai
发明人： Yuichi Ito , Hiroyasu Yamaoka , Akira Uchiyama , Chika Kako , Hideo Nishimura , Junzo Ukai
IPC分类号： C08K515
CPC分类号： C08L23/10 , C08L23/06 , C08L23/0807 , C08L23/0815 , C08L23/16 , C08L23/22 , C08L2666/04
摘要： An olefin-based thermoplastic elastomer composition comprising a thermoplastic elastomer blended with other resins and rubbers is provided. The thermoplastic elastomer contains polypropylene resin and an olefin-based copolymer rubber, and optionally, a linear polyethylene resin, and the thermoplastic elastomer has been crosslinked to a gel content of 95% or higher. A polyolefin resin, an olefin-based copolymer rubber and a softening agent are further blended with optional inorganic filler to provide the olefin-based thermoplastic elastomer composition. This composition is excellent in oil resistance and extrudability, and well-adapted for use as an energy-saving, resources-saving elastomer in applications including surface or skin material in autoparts, industrial mechanical parts, electric and electronic parts, and construction materials.
摘要翻译：提供了包含与其它树脂和橡胶共混的热塑性弹性体的烯烃类热塑性弹性体组合物。热塑性弹性体含有聚丙烯树脂和烯烃系共聚物橡胶，任意地为直链状聚乙烯树脂，热塑性弹性体的交联凝胶含量为95％以上。将聚烯烃树脂，烯烃类共聚物橡胶和软化剂进一步与任选的无机填料共混以提供烯烃系热塑性弹性体组合物。该组合物的耐油性和挤出性优异，适用于汽车零部件，工业机械部件，电气电子部件和建筑材料中的表面或表皮材料的节能，节省资源的弹性体。

4. 发明授权

US5786403A Foamable olefin thermoplastic elastomer compositions and foamed products thereof 失效
标题翻译：可发泡烯烃热塑性弹性体组合物及其发泡产品
公开(公告)号：US5786403A
公开(公告)日：1998-07-28
申请号：US807984
申请日：1997-03-03
申请人： Keiji Okada , Hiroyasu Yamaoka , Akira Uchiyama
发明人： Keiji Okada , Hiroyasu Yamaoka , Akira Uchiyama
IPC分类号： C08J9/00 , C08J9/06 , C08L23/16 , C08J9/08 , C08J9/10
CPC分类号： C08J9/06 , C08L23/16 , C08J2323/16 , C08L2203/14 , C08L2312/00
摘要： Disclosed is a foamable olefin thermoplastic elastomer composition comprising (A) a partially crosslinked thermoplastic elastomer composition, (B) long-chain branch-containing polypropylene and (C) a foaming agent. The partially crosslinked thermoplastic elastomer composition (A) is obtained by dynamically heat-treating a mixture in the presence of organic peroxide, said mixture comprising specific proportions of a peroxide-crosslinking type olefin copolymer rubber (a), which is an ethylene/.alpha.-olefin copolymer rubber composed of ethylene, an .alpha.-olefin of 3 to 20 carbon atoms and optionally a nonconjugated diene, and a peroxide-decomposition type olefin plastic (b), which is an .alpha.-olefin (co)polymer containing a specific amount of an .alpha.-olefin of 3 to 20 carbon atoms and having a specific MFR. Also disclosed is a foamed product obtained by heating the foamable olefin thermoplastic elastomer composition. From the foamable olefin thermoplastic elastomer composition, a foamed product having an expansion ratio of at least 2 times, being free from surface roughening caused by defoaming, being soft to the touch and showing excellent heat resistance and weathering resistance can be produced with high productivity through simplified steps.
摘要翻译：公开了一种可发泡烯烃热塑性弹性体组合物，其包含（A）部分交联的热塑性弹性体组合物，（B）长链支化聚丙烯和（C）发泡剂。部分交联的热塑性弹性体组合物（A）通过在有机过氧化物存在下动态热处理混合物而获得，所述混合物包含特定比例的过氧化物交联型烯烃共聚物橡胶（a），其是乙烯/ 由乙烯，3-20个碳原子的α-烯烃和任选的非共轭二烯构成的烯烃共聚物橡胶和作为含有特定量的α-烯烃的共聚物的过氧化物分解型烯烃塑料（b）具有3至20个碳原子并具有特定MFR的α-烯烃。还公开了通过加热可发泡烯烃热塑性弹性体组合物获得的发泡产品。从可发泡烯烃热塑性弹性体组合物中，可以以高生产率通过高生产率制造具有至少2倍膨胀率的泡沫产品，不发生由消泡引起的表面粗糙化，触感柔软并具有优异的耐热性和耐候性简化步骤。

5. 发明申请

US20110297230A1 RESIN COMPOSITION FOR SOLAR CELL PACKAGE 审中-公开
标题翻译：太阳能电池组件的树脂组合物
公开(公告)号：US20110297230A1
公开(公告)日：2011-12-08
申请号：US13209245
申请日：2011-08-12
申请人： Kazuyoshi Kaneko , Hiroyasu Yamaoka
发明人： Kazuyoshi Kaneko , Hiroyasu Yamaoka
IPC分类号： H01L31/0203
CPC分类号： H01G9/2068 , C08K5/005 , C08K5/34 , C08L23/0823 , C08L65/00 , H01G9/2031 , Y02E10/542
摘要： Provided is a resin composition for a solar cell package and a resin composition for a wet solar cell package which are excellent in transparency, moisture resistance, weather resistance and chemical resistance and are suitable as a material of a package for a solar cell, and a package for a wet solar cell and a transparent substrate for a wet solar cell which are obtained by molding the resin composition. The resin composition for a solar cell package of the present invention contains a cyclic olefin polymer having one kind or two or more kinds of structures represented by the following general formula (1)
摘要翻译：本发明提供一种透明性，耐湿性，耐候性和耐化学性优异的太阳能电池封装用树脂组合物和湿式太阳能电池组件用树脂组合物，适合作为太阳能电池组件的材料，用于湿太阳能电池的封装和通过模制树脂组合物获得的用于湿太阳能电池的透明基板。本发明的太阳能电池封装用树脂组合物含有具有以下通式（1）表示的一种或两种以上的结构的环状烯烃聚合物，

6. 发明申请

US20110060096A1 CYCLIC OLEFIN RESIN COMPOSITION, AND SUBSTRATE OBTAINED FROM SAID RESIN COMPOSITION 审中-公开
标题翻译：环烯烃树脂组合物和从树脂组合物获得的基材
公开(公告)号：US20110060096A1
公开(公告)日：2011-03-10
申请号：US12944334
申请日：2010-11-11
申请人： Kazuyoshi KANEKO , Toshiyuki Hirose , Hiroyasu Yamaoka , Kenichi Goto , Akira Hasegawa
发明人： Kazuyoshi KANEKO , Toshiyuki Hirose , Hiroyasu Yamaoka , Kenichi Goto , Akira Hasegawa
IPC分类号： C08L45/00
CPC分类号： H05K1/032 , C08L21/00 , C08L23/02 , C08L25/02 , C08L35/06 , C08L45/00 , C08L47/00 , C08L65/00 , H05K2201/0158 , C08L2666/02 , C08L2666/06 , C08L2666/04
摘要： A cyclic olefin resin composition which includes (A) 35 to 85 parts by weight of a cyclic olefin polymer having a glass transition temperature of 60 to 200° C., (B) 10 to 60 parts by weight of a flexible copolymer, prepared by polymerizing at least two monomers selected from the group consisting of an olefin compound, a diene compound and an aromatic vinyl hydrocarbon compound, and having a glass transition temperature of 0° C. or below, and (C) 5 to 55 parts by weight of a modified polyolefin. The cyclic olefin resin composition further includes, based on 100 parts by weight of total amount of the components (A), (B) and (C), (D) 0.01 to 5 parts by weight of a radical initiator and (E) 0 to 5 parts by weight of a polyfunctional compound having in its molecule two or more radically polymerizable functional groups. The composition can be used as a material for a substrate having low permittivity, low dielectric tangent, low water absorbability, and excellent heat resistance.
摘要翻译：一种环状烯烃树脂组合物，其包含（A）35〜85重量份的玻璃化转变温度为60〜200℃的环状烯烃聚合物，（B）10〜60重量份的柔性共聚物，由聚合至少两种选自烯烃化合物，二烯化合物和芳族乙烯基烃化合物的单体，并且玻璃化转变温度为0℃或更低，和（C）5至55重量份的改性聚烯烃。环状烯烃树脂组合物还包含基于100重量份的组分（A），（B）和（C）的总量，（D）0.01至5重量份的自由基引发剂和（E）0 至5重量份的在其分子中具有两个或更多个可自由基聚合的官能团的多官能化合物。该组合物可以用作具有低介电常数，低介电切线，低吸水性和优异的耐热性的基材的材料。

7. 发明申请

US20090050196A1 Resin Composition for Solar Cell Package 审中-公开
标题翻译：太阳能电池封装的树脂组合物
公开(公告)号：US20090050196A1
公开(公告)日：2009-02-26
申请号：US11886573
申请日：2006-03-15
申请人： Kazuyoshi Kaneko , Hiroyasu Yamaoka
发明人： Kazuyoshi Kaneko , Hiroyasu Yamaoka
IPC分类号： H01L31/00 , G02B5/22
CPC分类号： H01G9/2068 , C08K5/005 , C08K5/34 , C08L23/0823 , C08L65/00 , H01G9/2031 , Y02E10/542
摘要： The present invention provides a resin composition for a solar cell package and a resin composition for a wet solar cell package which are excellent in transparency, moisture resistance, weather resistance and chemical resistance and are suitable as a material of a package for a solar cell, and a package for a wet solar cell and a transparent substrate for a wet solar cell which are obtained by molding the resin composition. The resin composition for a solar cell package of the present invention contains a cyclic olefin polymer having one kind or two or more kinds of structures represented by the following general formula (1) (provided that, in the formula, x and y represent the copolymerization ratio and are a real number satisfying 0/100≦y/x≦95/5. n is the number of substitution of a substituent Q and an integer of 0≦n≦2. R1 is a 2+n valent group selected from the group consisting of hydrocarbon groups having 2 to 20 carbon atoms. R2 is a hydrogen atom, or a monovalent group selected from the group consisting of hydrocarbon groups having 1 to 10 carbon atoms containing carbon and hydrogen atoms. R3 is a tetravalent group selected from the group consisting of hydrocarbon groups having 2 to 10 carbon atoms. Q is COOR4 (R4 is a hydrogen atom, or a monovalent group selected from the group consisting of hydrocarbon groups having 1 to 10 carbon atoms containing carbon and hydrogen atoms)).
摘要翻译：本发明提供一种透明性，耐湿性，耐候性和耐化学性优异的太阳能电池封装用树脂组合物和湿式太阳能电池组件用树脂组合物，适合作为太阳能电池组件的材料，以及通过模塑树脂组合物获得的用于湿太阳能电池和湿太阳能电池的透明基板的包装。本发明的太阳能电池封装用树脂组合物含有具有以下通式（1）表示的一种或两种以上的结构的环状烯烃聚合物（式中，x和y表示共聚合并且是满足0/100 <= y / x <= 95/5的实数，n是取代基Q和0 <= n <= 2的整数的取代数，R1是2 + n价选自碳原子数为2〜20的烃基的基团，R2为氢原子或选自碳原子数为1〜10的碳原子的一价基团，R3为四价 Q为COOR 4（R4为氢原子，或选自碳原子数为1以上的碳原子数为1以上的一价基团，碳原子数为1〜10的烃基））。

8. 发明申请

US20080249235A1 Cyclic Olefin Resin Composition, and Substrate Obtained From Said Resin Composition 审中-公开
标题翻译：环状烯烃树脂组合物和由所述树脂组合物获得的基材
公开(公告)号：US20080249235A1
公开(公告)日：2008-10-09
申请号：US11885236
申请日：2006-01-31
申请人： Kazuyoshi Kaneko , Toshiyuki Hirose , Hiroyasu Yamaoka , Kenichi Goto , Akira Hasegawa
发明人： Kazuyoshi Kaneko , Toshiyuki Hirose , Hiroyasu Yamaoka , Kenichi Goto , Akira Hasegawa
IPC分类号： C08L53/02 , C08L23/08
CPC分类号： H05K1/032 , C08L21/00 , C08L23/02 , C08L25/02 , C08L35/06 , C08L45/00 , C08L47/00 , C08L65/00 , H05K2201/0158 , C08L2666/02 , C08L2666/06 , C08L2666/04
摘要： A cyclic olefin resin composition which can be suitably used as a material for a substrate having low permittivity, low dielectric tangent, low water absorbability, excellent heat resistance, and the like, and a substrate obtained from the resin composition are provided. In particular, there is provided a novel cyclic olefin resin composition that can be suitably used as a material for a substrate for high frequency circuit dealing with high frequency signal transmission. The cyclic olefin resin composition comprises (A) 5 to 95 parts by weight of a cyclic olefin polymer having a glass transition temperature of 60 to 200° C. and (B) 5 to 95 parts by weight of a flexible copolymer, prepared by polymerizing at least two monomers selected from the group consisting of an olefin compound, a diene compound and an aromatic vinyl hydrocarbon compound, and having a glass transition temperature of 0° C. or below. The cyclic olefin resin composition further comprises, based on 100 parts by weight of total amount of the components (A) and (B), (D) 0.01 to 5 parts by weight of a radical initiator and (E) 0 to 5 parts by weight of a polyfunctional compound having in its molecule two or more radically polymerizable functional groups.
摘要翻译：提供了可以适合用作具有低介电常数，低介电切线，低吸水性，优异的耐热性等的基材的材料的环烯烃树脂组合物和由该树脂组合物获得的基材。特别地，提供了一种新的环烯烃树脂组合物，其可以适合用作用于处理高频信号传输的高频电路的基板的材料。环状烯烃树脂组合物包含（A）5至95重量份的玻璃化转变温度为60至200℃的环烯烃聚合物和（B）5至95重量份的通过聚合制备的柔性共聚物选自烯烃化合物，二烯化合物和芳族乙烯基烃化合物中的至少两种单体，玻璃化转变温度为0℃以下。环状烯烃树脂组合物还包含基于100重量份的组分（A）和（B）的总量，（D）0.01至5重量份的自由基引发剂和（E）0至5重量份的其分子中具有两个或更多个可自由基聚合的官能团的多官能化合物的重量。

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