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    • 3. 发明申请
    • Supercapacitor with Hexacyanometallate Cathode, Activated Carbone Anode, and Aqueous Electrolyte
    • 超级电容器与六氰基金属阴极,活性炭骨阳极和水电解质
    • US20130257389A1
    • 2013-10-03
    • US13603322
    • 2012-09-04
    • Yuhao LuSean Andrew VailHidayat KisdarjonoJong-Jan Lee
    • Yuhao LuSean Andrew VailHidayat KisdarjonoJong-Jan Lee
    • H01G9/155H01G9/00H02J7/00
    • H01G11/30Y02E60/13Y10T29/417
    • A supercapacitor is provided with a method for fabricating the supercapacitor. The method provides dried hexacyanometallate particles having a chemical formula AmM1xM2y(CN)6.pH2O with a Prussian Blue hexacyanometallate, crystal structure, where A is an alkali or alkaline-earth cation, and M1 and M2 are metals with 2+ or 3+ valance positions. The variable m is in the range of 0.5 to 2, x is in the range of 0.5 to 1.5, y is in the range of 0.5 to 1.5, and p is in the range of 0 to 6. The hexacyanometallate particles are mixed with a binder and electronic conductor powder, to form a cathode comprising AmM1xM2y(CN)6.pH2O. The method also forms an activated carbon anode and a membrane separating the cathode from the anode, permeable to A and A′ cations. Finally, an electrolyte is added with a metal salt including A′ cations. The electrolyte may be aqueous.
    • 超级电容器具有制造超级电容器的方法。 该方法提供具有化学式AmM1xM2y(CN)6.pH2O的干燥的六氰基金属盐颗粒与普鲁士蓝六氰基金属酸盐晶体结构,其中A是碱金属或碱土金属阳离子,M1和M2是具有2+或3+价态的金属 职位 变量m在0.5至2的范围内,x在0.5至1.5的范围内,y在0.5至1.5的范围内,p在0至6的范围内。六氰基金属盐颗粒与 粘合剂和电子导体粉末,以形成包含AmM1xM2y(CN )6pH2O的阴极。 该方法还形成活性炭阳极和将阴极与阳极分开的膜,其可透过A和A'阳离子。 最后,向电解质中加入包含A'阳离子的金属盐。 电解质可以是水性的。
    • 4. 发明授权
    • Supercapacitor with hexacyanometallate cathode, activated carbon anode, and non-aqueous electrolyte
    • 具有六金属金属阴极,活性炭阳极和非水电解质的超级电容器
    • US09159502B2
    • 2015-10-13
    • US13603322
    • 2012-09-04
    • Yuhao LuSean Andrew VailHidayat KisdarjonoJong-Jan Lee
    • Yuhao LuSean Andrew VailHidayat KisdarjonoJong-Jan Lee
    • H01M2/16H01G11/30
    • H01G11/30Y02E60/13Y10T29/417
    • A supercapacitor is provided with a method for fabricating the supercapacitor. The method provides dried hexacyanometallate particles having a chemical formula AmM1xM2y(CN)6.pH2O with a Prussian Blue hexacyanometallate, crystal structure, where A is an alkali or alkaline-earth cation, and M1 and M2 are metals with 2+ or 3+ valance positions. The variable m is in the range of 0.5 to 2, x is in the range of 0.5 to 1.5, y is in the range of 0.5 to 1.5, and p is in the range of 0 to 6. The hexacyanometallate particles are mixed with a binder and electronic conductor powder, to form a cathode comprising AmM1xM2y(CN)6.pH2O. The method also forms an activated carbon anode and a membrane separating the cathode from the anode, permeable to A and A′ cations. Finally, an electrolyte is added with a metal salt including A′ cations. The electrolyte may be aqueous.
    • 超级电容器具有制造超级电容器的方法。 该方法提供具有化学式AmM1xM2y(CN)6.pH2O的干燥的六氰基金属盐颗粒与普鲁士蓝六氰基金属酸盐晶体结构,其中A是碱金属或碱土金属阳离子,M1和M2是具有2+或3+价态的金属 职位 变量m在0.5至2的范围内,x在0.5至1.5的范围内,y在0.5至1.5的范围内,p在0至6的范围内。六氰基金属盐颗粒与 粘合剂和电子导体粉末,以形成包含AmM1xM2y(CN )6pH2O的阴极。 该方法还形成活性炭阳极和将阴极与阳极分开的膜,其可透过A和A'阳离子。 最后,向电解质中加入包含A'阳离子的金属盐。 电解质可以是水性的。
    • 7. 发明申请
    • Electrode Forming Process for Metal-Ion Battery with Hexacyanometallate Electrode
    • 金属离子电池与六氰基金属电极的电极成型工艺
    • US20130260222A1
    • 2013-10-03
    • US13432993
    • 2012-03-28
    • Yuhao LuJong-Jan Lee
    • Yuhao LuJong-Jan Lee
    • H01M4/38H01M4/02H01M4/40H01M4/58H01M10/02
    • H01M4/58H01M4/0404H01M4/0438H01M4/0445H01M4/0459H01M4/139H01M4/587H01M10/054
    • A method is provided for forming a metal-ion battery electrode with large interstitial spacing. A working electrode with hexacyanometallate particles overlies a current collector. The hexacyanometallate particles have a chemical formula AmM1xM2y(CN)6·zH2O, and have a Prussian Blue hexacyanometallate crystal structure, where A is either alkali or alkaline-earth cations. M1 and M2 are metals with 2+ or 3+ valance positions. The working electrode is soaked in an organic first electrolyte including a salt including alkali or alkaline earth cations. A first electric field is created in the first electrolyte between the working electrode and a first counter electrode, causing A cations and water molecules to he simultaneously removed from interstitial spaces in the Prussian Blue hexacyanometallate crystal structure, forming hexacyanometallate particles having the chemical formula of Am′mM1xM2y(CN)6·z′H2O, where m′
    • 提供一种用于形成具有大间隙间距的金属离子电池电极的方法。 具有六氰基金属酸盐颗粒的工作电极覆盖集电器。 六氰基金属盐颗粒具有化学式AmM1xM2y(CN)6·zH2O,并具有普鲁士蓝六氰基金属酸盐晶体结构,其中A为碱金属或碱土金属阳离子。 M1和M2是具有2+或3+价位的金属。 将工作电极浸渍在包含碱​​金属或碱土金属阳离子的盐的有机第一电解质中。 在工作电极和第一对电极之间的第一电解质中产生第一电场,使得阳离子和水分子同时从普鲁士蓝六氰基金属酸盐晶体结构中的间隙中除去,形成化学式为Am的六氰基金属盐颗粒 'mM1xM2y(CN)6·z'H2O,其中m'
    • 8. 发明授权
    • Electrode forming process for metal-ion battery with hexacyanometallate electrode
    • 金属离子电池与六金属金属电极的电极形成工艺
    • US09269953B2
    • 2016-02-23
    • US13432993
    • 2012-03-28
    • Yuhao LuJong-Jan Lee
    • Yuhao LuJong-Jan Lee
    • H01M4/38H01M10/04H01M4/29H01M4/58H01M4/04H01M10/054
    • H01M4/58H01M4/0404H01M4/0438H01M4/0445H01M4/0459H01M4/139H01M4/587H01M10/054
    • A method is provided for forming a metal-ion battery electrode with large interstitial spacing. A working electrode with hexacyanometallate particles overlies a current collector. The hexacyanometallate particles have a chemical formula AmM1xM2y(CN)6.zH2O, and have a Prussian Blue hexacyanometallate crystal structure, where A is either alkali or alkaline-earth cations. M1 and M2 are metals with 2+ or 3+ valance positions. The working electrode is soaked in an organic first electrolyte including a salt including alkali or alkaline earth cations. A first electric field is created in the first electrolyte between the working electrode and a first counter electrode, causing A cations and water molecules to be simultaneously removed from interstitial spaces in the Prussian Blue hexacyanometallate crystal structure, forming hexacyanometallate particles having the chemical formula of Am′M1xM2y(CN)6.z′H2O, where m′
    • 提供一种用于形成具有大间隙间距的金属离子电池电极的方法。 具有六氰基金属酸盐颗粒的工作电极覆盖集电器。 六氰基金属盐颗粒具有化学式AmM1xM2y(CN)6.zH2O,并具有普鲁士蓝六氰基金属酸盐晶体结构,其中A为碱金属或碱土金属阳离子。 M1和M2是具有2+或3+价位的金属。 将工作电极浸渍在包含碱​​金属或碱土金属阳离子的盐的有机第一电解质中。 在工作电极和第一对电极之间的第一电解质中产生第一电场,从而在普鲁士蓝六氰基金属酸盐晶体结构中的间隙中同时去除阳离子和水分子,形成化学式为Am的六氰基金属盐颗粒 'M1xM2y(CN)6.z'H2O,其中m'