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    • 1. 发明授权
    • Room temperature-curable polymeric composition
    • 室温可固化聚合物组合物
    • US4675365A
    • 1987-06-23
    • US848986
    • 1986-04-07
    • Yoshio InoueMasatoshi AraiTakeo InoueAtsushi YaginumaTetsuo Tomizawa
    • Yoshio InoueMasatoshi AraiTakeo InoueAtsushi YaginumaTetsuo Tomizawa
    • C08L71/00C08G65/32C08G75/04C08G77/00C08G77/42C08G77/46C08L71/02C09K3/10
    • C08G75/04
    • The room temperature-curable polymeric composition is prepared by admixing (a) a polyether terminated at both molecular chain ends each with a mercapto group with (b) a 3-methacryloxypropyl silane having at least two hydrolyzable groups, e.g. alkoxy groups, in a molecule and (c) a 1,1,3,3-tetramethyl guanidino-containing organosilicon compound. The component (b) first reacts with the mercapto group of the component (a) to introduce silicon-bonded hydrolyzable groups to the molecular chain ends of the polyether and the silicon-bonded hydrolyzable groups pertain to the crosslinking reaction with the atmospheric moisture. The composition has good storability and workability and is capable of giving a cured rubbery elastomer without the addition of a toxic lead compound as a curing catalyst which is indispensable in the conventional polyether-based room temperature-curable polymeric compositions.
    • 室温可固化的聚合物组合物是通过将(a)在两个分子链端各自带有巯基的聚醚与(b)具有至少两个可水解基团的3-甲基丙烯酰氧基丙基硅烷混合来制备的。 烷氧基,和(c)含有1,1,3,3-四甲基胍基的有机硅化合物。 组分(b)首先与组分(a)的巯基反应以将导致硅键合的可水解基团引入到聚醚的分子链末端,硅键合的可水解基团涉及与大气湿气的交联反应。 该组合物具有良好的储存性和可加工性,并且能够在不添加有毒铅化合物作为固化催化剂的情况下得到固化的橡胶弹性体,其在常规的聚醚基室温可固化聚合物组合物中是必不可少的。
    • 6. 发明授权
    • Foamable organopolysiloxane composition
    • 可发泡有机聚硅氧烷组合物
    • US4987155A
    • 1991-01-22
    • US557824
    • 1990-07-26
    • Yoshio InoueMasatoshi AraiTsuneo Kimura
    • Yoshio InoueMasatoshi AraiTsuneo Kimura
    • C08J9/02C08L83/04
    • C08J9/02C08L83/04C08G77/045C08G77/12C08G77/16C08G77/62C08J2383/04
    • The invention provides a foamable organopolysiloxane composition capable of giving, by foaming and curing at room temperature, a silicone rubber foam of high foaming expansion having very uniform and dense cellular structure. The composition is prepared by a process comprising the steps of: (A) compounding an .alpha.,.omega.-dihydroxy dimethylpolysiloxane with a reinforcing silica filler, hexamethyl disilazane and water as the hydrolysis agent of the silazane to give a compound; (B) removing ammonia in the compound formed by the hydrolysis of the silazane compound as completely as possible; and (C) compounding the compound with a polyhydroxy methylpolysiloxane, an organohydrogenpolysiloxane and a platinum compound as a catalyst for the dehydrogenation reaction between the silanolic hydroxy groups and the silicon-bonded hydrogen atoms to produce hydrogen as the foaming gas.
    • 本发明提供一种可发泡的有机聚硅氧烷组合物,其能够通过在室温下发泡和固化得到具有非常均匀且致密的细胞结构的高发泡膨胀的硅橡胶泡沫。 通过包括以下步骤的方法制备组合物:(A)将α,ω-二羟基二甲基聚硅氧烷与增强二氧化硅填料,六甲基二硅氮烷和水混合,作为硅氮烷的水解试剂,得到化合物; (B)通过尽可能完全地水解硅氮烷化合物形成的化合物中除去氨; 和(C)将化合物与多羟基甲基聚硅氧烷,有机氢聚硅氧烷和铂化合物混合,作为硅烷醇羟基与硅键合的氢原子之间的脱氢反应的催化剂,以产生氢作为发泡气体。
    • 9. 发明授权
    • Room temperature-curable organopolysiloxane composition
    • 室温可固化的有机聚硅氧烷组合物
    • US4695617A
    • 1987-09-22
    • US837588
    • 1986-03-07
    • Yoshio InoueMasatoshi AraiShinichi SatoKoji Yokoo
    • Yoshio InoueMasatoshi AraiShinichi SatoKoji Yokoo
    • C08L83/00C08K5/5425C08K5/5465C08L83/04C08L83/06H01B3/46C08G77/20
    • C08K5/5465C08K5/54C08G77/14C08G77/16C08G77/20C08G77/26Y10S528/901
    • The room temperature-curable organopolysiloxane composition of the invention capable of giving a cured rubber can be used advantageously as an insulating material in electric and electronic instruments without causing troubles in contact points which is unavoidable with conventional compositions. The inventive composition is formulated with (a) a diorganopolysiloxane terminated at the molecule molecular chain ends each with a silanolic hydroxy group, (b) an alkenyloxy, e.g. isopropenyloxy, containing silane and (c) a guanidino-substituted organosilicon compound and these components are specified either by the upper limit of the content of low molecular constituents having a specified vapor pressure or higher or the upper limit of the vapor pressure of the compound per se so that the electric contact points near the insulation with the composition are free from exposure to the vapor of organosilicon compounds which may be deposited as an oxide of silicon by sparks.
    • 能够提供固化橡胶的本发明的室温可固化的有机基聚硅氧烷组合物可以有利地用作电气和电子仪器中的绝缘材料,而不会在常规组合物中不可避免地引起接触点的麻烦。 本发明的组合物配制成(a)在分子分子链处终止的二有机聚硅氧烷,每个末端具有硅烷醇羟基,(b)链烯氧基,例如, 含有硅烷的异丙烯氧基和(c)胍基取代的有机硅化合物,并且这些组分由具有特定蒸气压或更高的低分子量成分的含量的上限或化合物的蒸气压的上限规定 使得与组合物绝缘附近的电接触点不会暴露于有机硅化合物的蒸气中,有机硅化合物可以通过火花作为硅的氧化物沉积。
    • 10. 发明授权
    • Room temperature vulcanizable silicon rubber composition
    • 室温硫化硅橡胶组合物
    • US5112885A
    • 1992-05-12
    • US515028
    • 1990-04-26
    • Yoshio InoueMasatoshi AraiHironao Fujiki
    • Yoshio InoueMasatoshi AraiHironao Fujiki
    • C08K5/04C08K5/544C08K9/06C08L83/04C08L83/06
    • C08L83/04C08G77/14C08G77/16C08G77/18C08G77/20C08G77/24C08G77/70
    • A room temperature vulcanizable silicone rubber composition is described. The composition comprises an organopolysiloxane which is blocked with a hydroxyl group or hydrolyzable group at ends of the molecular chain thereof, fumed silica which is surface treated with a monoorganosilane of the general formula, R.sup.1 SiY.sub.3, or a monoorganopolysilazane of the general compositional formula, R.sup.1 Si(NH).sub.3/2, wherein R.sup.1 in each formula represents a monovalent hydrocarbon group and each Y represents a hydrolyzable group and which has a specific area of not less than 50 m.sup.2 /g, and an organosilicon compound of the general formula, R.sup.2.sub.1 SiZ.sub.4-1, wherein R.sup.2 represents an unsubstituted or substituted monovalent hydrocarbon group, Z represents a hydrolyzable group, and 1 is a value of 0 or 1, or its partially hydrolyzed product. The composition may further comprise a promoter for the vulcanization.
    • 描述室温硫化硅橡胶组合物。 该组合物包含在其分子链末端被羟基或可水解基团封闭的有机聚硅氧烷,用通式R 1 SiY 3或通用组成式的单有机硅氮烷表面处理的热解法二氧化硅,R 1 Si( NH)3/2,其中每个式中的R 1表示一价烃基,并且每个Y表示可水解基团,其比表面积不小于50m 2 / g,通式R 21 SiZ 4 -1的有机硅化合物 其中R2表示未取代或取代的一价烃基,Z表示可水解基团,1表示0或1的值,或其部分水解产物。 组合物还可以包含用于硫化的促进剂。