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1. 发明授权

US08339770B2 Capacitor and method for producing thereof 有权
标题翻译：电容器及其制造方法
公开(公告)号：US08339770B2
公开(公告)日：2012-12-25
申请号：US12280003
申请日：2007-02-21
申请人： Kazuyoshi Yoshida , Tailu Ning , Hironao Fujiki , Mitsuaki Negishi
发明人： Kazuyoshi Yoshida , Tailu Ning , Hironao Fujiki , Mitsuaki Negishi
IPC分类号： H01G9/02 , H01G9/04
CPC分类号： H01G9/0036 , H01G9/028 , H01G9/042 , H01G11/48 , H01G11/52 , H01G11/56 , Y02E60/13 , Y10T29/417
摘要： A capacitor having a high degree of electric strength, a high electrostatic capacity, and a low ESR, which can be readily downsized, is provided. The capacitor according to the present invention includes an anode made of porous valve metal, a dielectric layer formed by oxidizing the surface of the anode, and a solid electrolyte layer formed on the surface of the dielectric layer. The solid electrolyte layer includes a π conjugated conductive polymer, a polyanion, and an ion-conductive compound.
摘要翻译：提供了可以容易地小型化的具有高电力强度，高静电电容和低ESR的电容器。根据本发明的电容器包括由多孔阀金属制成的阳极，通过氧化阳极表面形成的电介质层和形成在电介质层的表面上的固体电解质层。固体电解质层包括：共轭导电聚合物，聚阴离子和离子导电化合物。

2. 发明授权

US06875534B2 Polymer electrolyte fuel-cell separator sealing rubber composition 失效
标题翻译：聚合物电解质燃料电池隔板密封胶组成
公开(公告)号：US06875534B2
公开(公告)日：2005-04-05
申请号：US10175048
申请日：2002-06-20
申请人： Tsutomu Nakamura , Noriyuki Meguriya , Hironao Fujiki
发明人： Tsutomu Nakamura , Noriyuki Meguriya , Hironao Fujiki
IPC分类号： C08K3/00 , C08K5/5419 , C08L23/22 , C08L23/26 , C08L83/04 , C08L83/05 , H01M8/02 , H01M8/10 , H01M2/08 , B32B9/04 , B32B15/06 , B32B25/20
CPC分类号： C08L83/04 , C08G77/12 , C08G77/70 , C08K5/5419 , C08L23/22 , C08L83/00 , C08L2666/04
摘要： A rubber composition comprising (A) a polyisobutylene polymer having an allyl radical at an end, (B) an optional organpolysiloxane, (C) an organohydrogenpolysiloxane having at least two SiH radicals per molecule, and (D) a platinum group metal catalyst forms a seal member on a periphery of one side of a polymer electrolyte fuel-cell separator. Due to improved acid resistance, weather resistance, creep resistance and gas permeability, the seal member remains effective for a long period of time.
摘要翻译：一种橡胶组合物，其包含（A）末端具有烯丙基的聚异丁烯聚合物，（B）任选的有机聚硅氧烷，（C）每分子具有至少两个SiH基团的有机氢聚硅氧烷和（D）铂族金属催化剂形成密封件在聚合物电解质燃料电池隔板的一侧的周边。由于耐酸性，耐候性，抗蠕变性和气体渗透性的改善，密封件长时间保持有效。

3. 发明授权

US06831127B2 Non-staining silicone rubber compositions 有权
标题翻译：无污染的硅橡胶组合物
公开(公告)号：US06831127B2
公开(公告)日：2004-12-14
申请号：US10268981
申请日：2002-10-11
申请人： Hironao Fujiki , Tsuneo Kimura , Tadashi Araki
发明人： Hironao Fujiki , Tsuneo Kimura , Tadashi Araki
IPC分类号： C08L8306
CPC分类号： C08L83/04 , C08G77/16 , C08G77/20 , C08G77/50 , C08K5/54 , C08L83/14 , C08L2666/44
摘要： In a silicone rubber composition of the condensation curing type comprising a diorganopolysiloxane having at least two silicon-attached hydroxyl or hydrolyzable radicals as a base polymer, and a silane having at least two hydrolyzable radicals or a partial hydrolytic condensate thereof, at least 2 mol % of the entire substituent radicals attached to silicon atoms in the diorganopolysiloxane are monovalent hydrocarbon radicals having at least two carbon atoms. The cured composition has excellent non-staining and sealing properties, and when applied as a coating, filled into joints, or used as a solid gasket, it does not cause staining of the building, joints, or the area around joints.
摘要翻译：在包含具有至少两个具有硅的羟基或可水解基团的二有机聚硅氧烷作为基础聚合物的缩合固化型硅烷和具有至少两个可水解基团或其部分水解缩合物的硅烷中，至少2摩尔％与二有机聚硅氧烷中硅原子相连的整个取代基的全部是具有至少两个碳原子的一价烃基。固化的组合物具有优异的无污染和密封性能，并且当作为涂层涂覆，填充到接头中或用作固体垫圈时，不会造成建筑物，接头或接头周围的区域的污染。

4. 发明授权

US06425600B1 Silicone rubber composition for coating air bags 失效
标题翻译：用于涂装气囊的硅橡胶组合物
公开(公告)号：US06425600B1
公开(公告)日：2002-07-30
申请号：US09734743
申请日：2000-12-13
申请人： Hironao Fujiki , Yoshifumi Harada , Takeshi Miyao , Yoshifumi Inoue
发明人： Hironao Fujiki , Yoshifumi Harada , Takeshi Miyao , Yoshifumi Inoue
IPC分类号： B60R2116
CPC分类号： D06N3/128 , B60R2021/23514 , C09D183/04 , D06M15/643 , D06M15/693 , Y10T428/31663 , C08L83/00 , C08L2666/44 , C08L2666/54
摘要： Silicone rubber compositions comprising (A) an organopolysiloxane having at least two silicon-bonded alkenyl groups, (B) finely divided silica, (C) an adhesive component, (D) a silicone-soluble organopolysiloxane resin component bearing at least one alkenyl group, (E) an organohydrogenpolysiloxane containing SiH groups in a specific mole ratio to the alkenyl groups in components (A) and (D) combined, and (F) a platinum group catalyst, exhibit excellent adhesion to synthetic woven fabrics for air bags. When coated onto woven fabrics and cured, the compositions provide air bag base fabrics of outstanding flexibility, sealability and deployability which remain stable over time.
摘要翻译：硅橡胶组合物，其包含（A）具有至少两个与硅键合的烯基的有机聚硅氧烷，（B）细碎二氧化硅，（C）粘合剂组分，（D）含有至少一个烯基的硅氧烷可溶性有机聚硅氧烷树脂组分，（E）与组分（A）和（D）中的烯基相比具有特定摩尔比的SiH基的有机氢聚硅氧烷和（F）铂族催化剂对于气囊的合成织物表现出优异的粘合性。当涂布在机织织物上并固化时，组合物提供具有出色的柔性，密封性和展开性的气囊基织物，其随时间保持稳定。

5. 发明授权

US06403749B1 Preparation of organoxy-terminated organopolysiloxanes 失效
标题翻译：有机氧基封端的有机聚硅氧烷的制备
公开(公告)号：US06403749B1
公开(公告)日：2002-06-11
申请号：US09714142
申请日：2000-11-17
申请人： Masatoshi Miyake , Chinami Matsui , Kenichi Kimura , Hironao Fujiki
发明人： Masatoshi Miyake , Chinami Matsui , Kenichi Kimura , Hironao Fujiki
IPC分类号： C08G7706
CPC分类号： C08G77/08 , C08G77/18
摘要： An organoxy-terminated organopolysiloxane of the general formula (A): wherein R is a monovalent hydrocarbon group, R1 is a monovalent hydrocarbon group of 1-18 carbon atoms, and R2 is an organic group of 1-18 carbon atoms, and “a” is an integer of 0, 1 or 2, is prepared by reacting an organopolysiloxane of the formula: HO(R2SiO)nH having a viscosity of 10-100,000 centistokes at 25° C. with an organoxysilane of the formula: (R2O)4-a—Si—(R1)a or a partial hydrolyzate thereof in the presence of a tetraalkoxytitanium.
摘要翻译：通式（A）的有机氧基封端的有机聚硅氧烷：其中R是一价烃基，R1是1-18个碳原子的一价烃基，R2是1-18个碳原子的有机基团，“a “是0或1或2的整数，其通过在25℃下粘度为10-100,000厘沲的下式的有机聚硅氧烷（HO（R 2 SiO）nH）与下式的有机硅烷：（R 2 O）4 -a-Si-（R1）a或其部分水解产物在四烷氧基钛存在下进行。

6. 发明授权

US5792723A Platinum catalyst, its preparation, and curable organopolysiloxane composition comprising the same 失效
标题翻译：铂催化剂，其制备方法和包含其的可固化的有机聚硅氧烷组合物
公开(公告)号：US5792723A
公开(公告)日：1998-08-11
申请号：US752938
申请日：1996-11-20
申请人： Masayuki Ikeno , Hideki Sugahara , Hironao Fujiki
发明人： Masayuki Ikeno , Hideki Sugahara , Hironao Fujiki
IPC分类号： A61K6/093 , B01J31/22 , B01J31/28 , C07B61/00 , C07F7/08 , C07F7/21 , C07F15/00 , C08G77/398 , C08L83/04 , C08L83/07 , B01J31/02
CPC分类号： B01J31/1608 , B01J31/2291 , C08G77/398 , C08L83/04 , B01J2231/14 , B01J2231/323 , B01J2531/828 , C08G77/08 , C08G77/12 , C08G77/20 , C08G77/24 , C08G77/70
摘要： A platinum catalyst containing (A) a platinum complex having a vinyl-containing organosiloxane ligand and (B) a vinyl-containing organopolysiloxane is prepared by mixing components (A) and (B) such that at least 2 mol of vinyl group in component (B) is available per mol of platinum atom in component (A) and heating the mixture at 40.degree.-100.degree. C. for at least 1 hour. When blended in an addition reaction curing type organosiloxane composition, the platinum catalyst has the advantage that even after long-term storage at elevated temperatures, it remains stable and active enough to cause the organosiloxane composition to cure.
摘要翻译：含有（A）具有含乙烯基的有机硅氧烷配体的铂络合物和（B）含乙烯基的有机聚硅氧烷的铂催化剂通过混合组分（A）和（B）制备，使得至少2摩尔组分（ B）可以在组分（A）中每摩尔铂原子获得并在40℃-100℃下加热该混合物至少1小时。当在加成反应固化型有机硅氧烷组合物中混合时，铂催化剂的优点在于，即使在高温下长期保存后，其仍保持稳定和足够活性以使有机硅氧烷组合物固化。

7. 发明授权

US5767193A Curable silicone elastomer composition and method of preparing the same 失效
标题翻译：可固化有机硅弹性体组合物及其制备方法
公开(公告)号：US5767193A
公开(公告)日：1998-06-16
申请号：US712388
申请日：1996-09-11
申请人： Hironao Fujiki , Kouichi Tanaka
发明人： Hironao Fujiki , Kouichi Tanaka
IPC分类号： C08K3/36 , C08K9/06 , C08L83/04 , C08L83/05 , C08L83/06 , C08L83/07 , C08K3/00
CPC分类号： C08K9/06 , C08L83/04 , C08G77/12 , C08G77/16 , C08G77/20 , C08G77/24
摘要： Provided are a non-foaming curable silicone elastomer composition and a method of preparing such a composition: with the composition comprising (A) 100 parts by weight of an organopolysiloxane mixture constituted at least of 90-10 parts by weight of organopolysiloxanes (i) containing, in a molecule, at least two alkenyl groups and substantially no silicon-attached hydroxyl group and having their kinematic viscosity in the range of 100 to 100,000 centistokes (cSt) at 25.degree. C. and 10-90 parts by weight of organopolysiloxanes (ii) containing, in a molecule, at least one hydroxyl group attached directly to a silicon atom and at least one alkenyl group attached directly to a silicon atom and having their kinematic viscosity in the range of 100 to 100,000 cSt at 25.degree. C.; (B) organohydrogenpolysiloxanes having in each molecule at least 3 hydrogen atoms attached directly to silicon atoms in an amount that the organohydrogenpolysiloxanes afford 0.4-10.0 moles of silicon-attached hydrogen atoms to 1 mole of alkenyl groups supplied from the organopolysiloxane mixture (A); (C) a platinum group metal catalyst; and (D) 10-60 parts by weight of finely powdered silica having a specific surface area of at least 50 m.sup.2 /g, measured by BET method.
摘要翻译：提供了一种不发泡的可固化的硅氧烷弹性体组合物和制备这种组合物的方法：该组合物包含（A）100重量份的构成至少90-10重量份的有机聚硅氧烷（i）的有机聚硅氧烷混合物，其包含在一个分子中，至少有两个烯基，基本上不含硅的羟基，其运动粘度在25℃为100至100,000厘沲（cSt），和10-90重量份的有机聚硅氧烷（ii ）在一个分子中含有至少一个直接连接到硅原子上的羟基和至少一个直接与硅原子连接的烯基，并且其运动粘度在25℃在100至100cSt的范围内; （B）在每个分子中具有至少3个氢原子的有机氢聚硅氧烷，其直接连接到硅原子上，其量为有机氢聚硅氧烷为从有机聚硅氧烷混合物（A）提供的1摩尔烯基中提供0.4-10.0摩尔与硅连接的氢原子; （C）铂族金属催化剂; 和（D）通过BET法测量10-60重量份比表面积为至少50m 2 / g的细粉状二氧化硅。

8. 发明授权

US5536803A Adhesive silicone compositions 失效
标题翻译：粘合硅胶组合物
公开(公告)号：US5536803A
公开(公告)日：1996-07-16
申请号：US461012
申请日：1995-06-05
申请人： Hironao Fujiki , Shigeki Shudo , Toshiaki Takahashi , Hiroyasu Hara , Takeshi Miyao
发明人： Hironao Fujiki , Shigeki Shudo , Toshiaki Takahashi , Hiroyasu Hara , Takeshi Miyao
IPC分类号： C08L83/07 , C09J183/04 , C09J183/07 , C08G77/08
CPC分类号： C09J183/04
摘要： An adhesive silicone composition comprising a diorganopolysiloxane, an organohydrogenpolysiloxane, and a platinum catalyst is blended with an organohydrogenpolysiloxane having at least two hydrogen atoms each bonded to a silicon atom in a molecule and containing an aromatic ring-bearing hydrocarbon radical in an amount of at least 12 mol % of the entire monovalent organic radicals bonded to silicon atoms, or a compound containing at least one hydrogen atom bonded to a silicon atom in a molecule and having a radical of two benzene rings separated by --R.sup.13 R.sup.14 Si--, --R.sup.13 R.sup.14 SiO--, --OR.sup.13 R.sup.14 SiO-- or --R.sup.13 R.sup.14 SiOR.sup.13 R.sup.14 Si-- wherein R.sup.13 and R.sup.14 are a monovalent hydrocarbon radical. The composition firmly adheres to organic resins, but is readily releasable from metal molds.
摘要翻译：将包含二有机聚硅氧烷，有机氢聚硅氧烷和铂催化剂的粘合性有机硅组合物与具有至少两个氢原子的有机氢聚硅氧烷共混，每个氢原子分子键合至硅原子并且含有至少含有芳环的烃基与硅原子键合的全部一价有机基团的12摩尔％，或分子中含有与硅原子键合的至少一个氢原子的化合物，其具有由-R 13 R 14 -Si，-R 13 R 14 SiO， - OR13R14SiO-或-R13R14SiOR13R14Si-，其中R13和R14是一价烃基。组合物牢固地粘附到有机树脂上，但是容易从金属模具中剥离。

9. 发明授权

US5506302A Organopolysiloxane composition and rubber substrate having a coating thereof 失效
标题翻译：有机聚硅氧烷组合物和具有其涂层的橡胶基材
公开(公告)号：US5506302A
公开(公告)日：1996-04-09
申请号：US493154
申请日：1995-06-21
申请人： Mikio Shiono , Kazumi Okada , Hironao Fujiki
发明人： Mikio Shiono , Kazumi Okada , Hironao Fujiki
IPC分类号： C08K7/16 , C08K13/02 , C09D183/04 , C08K5/54
CPC分类号： C08K13/02 , C08K7/16 , C09D183/04
摘要： An organopolysiloxane composition contains (A) a both end hydroxyl-blocked diorganopoly-siloxane, (B) a hydroxyl-free diorganopoly-siloxane having a degree of polymerization equal to or greater than that of (A), (C) an organo-hydrogenpolysiloxane having at least three hydrogen atoms in a molecule, (D) an organosilane containing at least two alkoxy groups and an amino group attached to a silicon atom through an alkylene group in a molecule and/or a partial hydrolyzate thereof, (E) a fatty acid metal salt, (F) polycarbonate powder having a mean particle size of up to 50 .mu.m, and optionally (G) an organo-silane containing at least two alkoxy groups and a mercapto group attached to a silicon atom through an alkylene group in a molecule and/or a partial hydrolyzate thereof. It is applied to a rubber substrate to form a wear resistance coating thereon.
摘要翻译：有机聚硅氧烷组合物含有（A）双端羟基封端的二有机硅氧烷，（B）聚合度等于或大于（A）的聚合度的无羟基的二有机聚硅氧烷，（C）有机氢聚硅氧烷在分子中具有至少三个氢原子，（D）含有至少两个烷氧基的有机硅烷和通过分子中的亚烷基与硅原子连接的氨基和/或其部分水解产物，（E）脂肪酸性金属盐，（F）平均粒径达50μm的聚碳酸酯粉末，以及任选地（G）含有至少两个烷氧基的有机硅烷和通过亚烷基连接到硅原子上的巯基，分子和/或部分水解产物。将其施加到橡胶基材上以在其上形成耐磨性涂层。

10. 发明授权

US5418065A Integrally molded article of silicone rubber and modified polypropylene resin 失效
标题翻译：硅橡胶和改性聚丙烯树脂的整体成型制品
公开(公告)号：US5418065A
公开(公告)日：1995-05-23
申请号：US163553
申请日：1993-12-09
申请人： Hironao Fujiki , Shigeki Shudo , Akira Matsuda , Yasushi Yamamoto , Noboru Shimamoto , Eiji Kuchiki , Yuji Fujita
发明人： Hironao Fujiki , Shigeki Shudo , Akira Matsuda , Yasushi Yamamoto , Noboru Shimamoto , Eiji Kuchiki , Yuji Fujita
IPC分类号： B29C45/16 , B32B37/00 , C08J5/12 , B32B7/04 , B32B25/20 , B32B27/32
CPC分类号： C08J5/12 , B29C45/1676 , B29K2023/12 , B29K2083/00 , B29K2083/005 , B29K2283/00 , B29L2009/00 , Y10T428/31663 , Y10T428/31667
摘要： In a polypropylene resin/silicone rubber integrally molded article, a polypropylene resin having an aliphatic unsaturated bond is integrally joined to an addition type silicone rubber at high bond strength. It is prepared by injection molding a modified polypropylene resin into a preform, injection molding a silicone rubber composition over the preform, and curing the composition at a temperature below the softening point of the polypropylene resin. Stronger bond is established when the silicone rubber contains a tackifier in the form of a compound containing in a molecule at least one hydrogen atom directly attached to a silicon atom and an alkoxysilyl, glycidyl or acid anhydride group or a --(CH.sub.2).sub.n -- linkage.
摘要翻译：在聚丙烯树脂/硅橡胶一体成型体中，具有脂肪族不饱和键的聚丙烯树脂以高粘合强度与加成型硅橡胶一体地接合。通过将改性聚丙烯树脂注塑成预成型体，在预成型体上注射成型硅橡胶组合物，并在低于聚丙烯树脂的软化点的温度下固化该组合物来制备。当硅橡胶含有在分子中含有至少一个直接连接到硅原子上的氢原子和烷氧基甲硅烷基，缩水甘油基或酸酐基团或 - （CH2）n-键的化合物形式的增粘剂时，形成更强的键。

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