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1. 发明授权

US5962083A Methods of depositing films on polymer substrates 失效
标题翻译：在聚合物基材上沉积膜的方法
公开(公告)号：US5962083A
公开(公告)日：1999-10-05
申请号：US664959
申请日：1996-06-13
申请人： Yoshinori Hatanaka , Yoichiro Nakanishi , Sunil Wickramanayaka , Keiichiro Sano , Masaya Nomura , Shigekazu Hayashi
发明人： Yoshinori Hatanaka , Yoichiro Nakanishi , Sunil Wickramanayaka , Keiichiro Sano , Masaya Nomura , Shigekazu Hayashi
IPC分类号： C08J7/00 , C08J7/06 , C08J7/18 , C23C16/40 , C23C16/511 , H01J37/32 , H05H1/18
CPC分类号： H01J37/32192 , C23C16/402 , C23C16/511 , H01J37/32678
摘要： A method of depositing a thin film on a polymer substrate by plasma CVD comprises applying a magnetic field to a plasma generating chamber by activating a magnetic coil placed in the circumference of the plasma generating chamber, the plasma generating chamber having an inlet; introducing a microwave into the plasma generating chamber; introducing an upstream gas into the plasma generating chamber wherein an ECR plasma is generated; vaporizing a feed gas wherein a supply gas is generated and carries the ECR plasma; passing said ECR plasma through a mesh provided between the inlet and a polymer substrate located downstream of the inlet; and depositing a film on the surface of the polymer substrate.
摘要翻译：通过等离子体CVD在聚合物基板上沉积薄膜的方法包括通过激活置于等离子体发生室周围的电磁线圈将等离子体产生室施加磁场，等离子体产生室具有入口; 将微波引入等离子体发生室; 将上游气体引入等离子体发生室，其中产生ECR等离子体; 蒸发进料气体，其中产生供应气体并携带ECR等离子体; 使所述ECR等离子体通过提供在入口和位于入口下游的聚合物基底之间的网格; 以及在所述聚合物基材的表面上沉积膜。

2. 发明授权

US06372304B1 Method and apparatus for forming SiC thin film on high polymer base material by plasma CVD 失效
标题翻译：通过等离子体CVD在高聚物基材上形成SiC薄膜的方法和装置
公开(公告)号：US06372304B1
公开(公告)日：2002-04-16
申请号：US08888954
申请日：1997-07-07
申请人： Keiichiro Sano , Masaya Nomura , Hiroaki Tamamaki , Yoshinori Hatanaka
发明人： Keiichiro Sano , Masaya Nomura , Hiroaki Tamamaki , Yoshinori Hatanaka
IPC分类号： C23C1632
CPC分类号： C23C16/325 , C23C16/511
摘要： A high quality transparent SiC thin film can be deposited on the surface of a plastic material at low temperature utilizing Electron Cyclotron Resonance (ECR) Plasma CVD techniques, thereby enhancing surfacial hardness without spoiling designability. A magnetic field is applied to a plasma generating chamber by means of a surrounding magnetic coil. Microwaves are then introduced into the plasma generating chamber. Further, an upstream gas is introduced into the plasma generating chamber. ECR plasma is thus generated. A downstream gas is then supplied to the chamber from an inlet. Furthermore, the ECR plasma is passed through a mesh placed between the inlet and a polymer base material or between the plasma generating chamber and the inlet. Accordingly, a SiC film is deposited on a surface of a polymer base material.
摘要翻译：使用电子回旋共振（ECR）等离子体CVD技术，可以在低温下在塑料材料的表面上沉积高质量的透明SiC薄膜，从而提高表面硬度，而不破坏可设计性。通过周围的电磁线圈将磁场施加到等离子体发生室。然后将微波引入等离子体发生室。此外，上游气体被引入到等离子体产生室中。从而产生ECR等离子体。然后从入口将下游气体供应到室。此外，ECR等离子体通过放置在入口和聚合物基材之间或者等离子体产生室和入口之间的网。因此，在聚合物基材的表面上沉积SiC膜。

3. 发明申请

US20100247700A1 COLLAPSIBLE MOLD AND METHOD OF MANUFACTURING THE SAME 有权
标题翻译：可塑模具及其制造方法
公开(公告)号：US20100247700A1
公开(公告)日：2010-09-30
申请号：US12722647
申请日：2010-03-12
申请人： Chitoshi Hayashi , Tomoaki Ishikuro , Taro Yamazaki , Mitsuru Wakisaka , Tatsunori Sakai , Masaya Nomura
发明人： Chitoshi Hayashi , Tomoaki Ishikuro , Taro Yamazaki , Mitsuru Wakisaka , Tatsunori Sakai , Masaya Nomura
IPC分类号： B28B1/14 , B29C33/52
CPC分类号： B22C9/105 , B22C9/04
摘要： In a collapsible mold and a method of manufacturing the same, the collapsible mold has extremely low moisture-absorption properties, does not change in surface properties thereof due to absorption of moisture and swelling, and is storable for a long time without absorbing moisture and swelling. Specifically, the method manufactures a collapsible mold containing at least any of calcium oxide and magnesium oxide. The method includes a step of bringing the collapsible mold into contact with carbon dioxide immediately after a step of burning the collapsible mold or a step of casting the collapsible mold.
摘要翻译：在可折叠模具及其制造方法中，可折叠模具具有极低的吸湿性，由于吸收水分和溶胀而不会改变其表面性质，并且可长期储存而不吸收水分和膨胀。具体地，该方法制造包含氧化钙和氧化镁中的至少一种的可折叠模具。该方法包括在可燃模具的燃烧步骤或铸造可折叠模具的步骤之后立即使可折叠模具与二氧化碳接触的步骤。

4. 发明授权

US06303232B1 Coated piston and surface-treating film 有权
标题翻译：涂层活塞和表面处理膜
公开(公告)号：US06303232B1
公开(公告)日：2001-10-16
申请号：US09169076
申请日：1998-10-09
申请人： Makoto Mihoya , Masaya Nomura , Shigehi Mitsuoka
发明人： Makoto Mihoya , Masaya Nomura , Shigehi Mitsuoka
IPC分类号： B32B900
CPC分类号： C23C22/34 , C23C22/68
摘要： This invention relates to a surface treatment method comprising the steps of soaking aluminum or an aluminum alloy in a treating solution containing a fluorine compound and ammonium silicofluoride, and treating the aluminum or aluminum alloy in the treating solution at a temperature in the range of 70 to 100° C.; a piston having undergone such a surface treatment; and a piston coated with a film consisting of an Al-OH-F compound, as well as a sliding member in which its sliding surface and the like are coated with a slide film consisting, for example, of a compound of aluminum, fluorine and the hydroxyl group; and a surface-treating film for an aluminum alloy which is formed on a surface of aluminum or an aluminum alloy and consists of an aluminum fluoride hydroxide compound and silicon particles dispersed therein. The present invention can provide a surface treatment method which requires simple equipment, can reduce treating costs, and can yield aluminum or an aluminum alloy having excellent abrasion resistance, corrosion resistance and other properties, as well as sliding members and pistons having excellent abrasion resistance and other properties.
摘要翻译：本发明涉及一种表面处理方法，包括以下步骤：将铝或铝合金浸入含氟化合物和氟化硅铵的处理溶液中，并将处理溶液中的铝或铝合金在70〜 100°C。经过这种表面处理的活塞; 以及涂覆有由Al-OH-F化合物组成的膜的活塞以及滑动构件，其中滑动构件的滑动表面等涂覆有例如由铝，氟化合物和羟基; 以及形成在铝或铝合金的表面上并由氟化铝氢氧化物化合物和分散在其中的硅颗粒组成的铝合金表面处理膜。本发明可以提供一种表面处理方法，其需要简单的设备，可以降低处理成本，并且可以产生具有优异耐磨性，耐腐蚀性等特性的铝或铝合金，以及具有优异耐磨性的滑动构件和活塞，其他属性。

5. 发明授权

US6071625A Coated piston and surface-treating film 有权
公开(公告)号：US6071625A
公开(公告)日：2000-06-06
申请号：US169076
申请日：1998-10-09
申请人： Makoto Mihoya , Masaya Nomura , Shigehi Mitsuoka
发明人： Makoto Mihoya , Masaya Nomura , Shigehi Mitsuoka
摘要： This invention relates to a surface treatment method comprising the steps of soaking aluminum or an aluminum alloy in a treating solution containing a fluorine compound and ammonium silicofluoride, and treating the aluminum or aluminum alloy in the treating solution at a temperature in the range of 70 to 100.degree. C.; a piston having undergone such a surface treatment; and a piston coated with a film consisting of an Al--OH--F compound, as well as a sliding member in which its sliding surface and the like are coated with a slide film consisting, for example, of a compound of aluminum, fluorine and the hydroxyl group; and a surface-treating film for an aluminum alloy which is formed on a surface of aluminum or an aluminum alloy and consists of an aluminum fluoride hydroxide compound and silicon particles dispersed therein. The present invention can provide a surface treatment method which requires simple equipment, can reduce treating costs, and can yield aluminum or an aluminum alloy having excellent abrasion resistance, corrosion resistance and other properties, as well as sliding members and pistons having excellent abrasion resistance and other properties.

6. 发明授权

US06171706B2 Sliding members comprising aluminum or aluminum alloys 有权
标题翻译：滑动构件包括铝或铝合金
公开(公告)号：US06171706B2
公开(公告)日：2001-01-09
申请号：US09338829
申请日：1999-06-23
申请人： Makoto Mihoya , Masaya Nomura , Shigehi Mitsuoka
发明人： Makoto Mihoya , Masaya Nomura , Shigehi Mitsuoka
IPC分类号： B32B1504
CPC分类号： C23C22/34 , C23C22/68
摘要： This invention relates to a surface treatment method comprising the steps of soaking aluminum or an aluminum alloy in a treating solution containing a fluorine compound and ammonium silicofluoride, and treating the aluminum or aluminum alloy in the treating solution at a temperature in the range of 70 to 100° C.; a piston having undergone such a surface treatment; and a piston coated with a film consisting of an Al—OH—F compound, as well as a sliding member in which its sliding surface and the like are coated with a slide film consisting, for example, of a compound of aluminum, fluorine and the hydroxyl group; and a surface-treating film for an aluminum alloy which is formed on a surface of aluminum or an aluminum alloy and consists of an aluminum fluoride hydroxide compound and silicon particles dispersed therein. The present invention can provide a surface treatment method which requires simple equipment, can reduce treating costs, and can yield aluminum or an aluminum alloy having excellent abrasion resistance, corrosion resistance and other properties, as well as sliding members and pistons having excellent abrasion resistance and other properties.
摘要翻译：本发明涉及一种表面处理方法，包括以下步骤：将铝或铝合金浸入含氟化合物和氟化硅铵的处理溶液中，并将处理溶液中的铝或铝合金在70〜 100°C。经过这种表面处理的活塞; 以及涂覆有由Al-OH-F化合物组成的膜的活塞以及滑动构件，其中滑动构件的滑动表面等涂覆有例如由铝，氟化合物和羟基; 以及形成在铝或铝合金的表面上并由氟化铝氢氧化物化合物和分散在其中的硅颗粒组成的铝合金表面处理膜。本发明可以提供一种表面处理方法，其需要简单的设备，可以降低处理成本，并且可以产生具有优异耐磨性，耐腐蚀性等特性的铝或铝合金，以及具有优异耐磨性的滑动构件和活塞，其他属性。

7. 发明授权

US08002017B2 Method of manufacturing a collapsible mold 有权
标题翻译：制造可折叠模具的方法
公开(公告)号：US08002017B2
公开(公告)日：2011-08-23
申请号：US12722647
申请日：2010-03-12
申请人： Chitoshi Hayashi , Tomoaki Ishikuro , Taro Yamazaki , Mitsuru Wakisaka , Tatsunori Sakai , Masaya Nomura
发明人： Chitoshi Hayashi , Tomoaki Ishikuro , Taro Yamazaki , Mitsuru Wakisaka , Tatsunori Sakai , Masaya Nomura
IPC分类号： B22C1/00
CPC分类号： B22C9/105 , B22C9/04
摘要： In a collapsible mold and a method of manufacturing the same, the collapsible mold has extremely low moisture-absorption properties, does not change in surface properties thereof due to absorption of moisture and swelling, and is storable for a long time without absorbing moisture and swelling. Specifically, the method manufactures a collapsible mold containing at least any of calcium oxide and magnesium oxide. The method includes a step of bringing the collapsible mold into contact with carbon dioxide immediately after a step of burning the collapsible mold or a step of casting the collapsible mold.
摘要翻译：在可折叠模具及其制造方法中，可折叠模具具有极低的吸湿性，由于吸收水分和溶胀而不会改变其表面性质，并且可长期储存而不吸收水分和膨胀。具体地，该方法制造包含氧化钙和氧化镁中的至少一种的可折叠模具。该方法包括在可燃模具的燃烧步骤或铸造可折叠模具的步骤之后立即使可折叠模具与二氧化碳接触的步骤。

8. 发明授权

US06607609B2 Surface treatment method 有权
标题翻译：表面处理方法
公开(公告)号：US06607609B2
公开(公告)日：2003-08-19
申请号：US10254282
申请日：2002-09-25
申请人： Masaya Nomura , Yoshinobu Ozaki
发明人： Masaya Nomura , Yoshinobu Ozaki
IPC分类号： C23C2200
CPC分类号： C23C22/66 , C23C22/68
摘要： This invention relates to a surface treatment method comprising the steps of providing a treating solution containing a specific ammonium compound or aqueous ammonia, and magnesium silicofluoride, heating the treating solution to a temperature of 70 to 100° C., and soaking aluminum or an aluminum alloy in the treating solution; a piston having a surface coated with a film consisting of a mixture of NH4MgAlF6 and MgAlF5. 1.5H2O or a mixture of NH4MgAlF6 and MgAl2F8.2H2O; and a sliding member made of aluminum or the like wherein the whole surface of the sliding member or the sliding surface thereof is coated with a film which consists of either of the aforesaid mixtures, has a cubic crystal structure, and shows no crystalline orientation. The present invention can provide a surface treatment method which requires simple equipment, can reduce treatment costs, and can yield aluminum or an aluminum alloy having excellent abrasion resistance, corrosion resistance and other properties, as well as sliding members and pistons having excellent abrasion resistance and other properties.
摘要翻译：本发明涉及一种表面处理方法，其包括以下步骤：提供含有特定的铵化合物或氨水的处理溶液和氟化硅镁，将处理溶液加热到70〜100℃的温度，将铝或铝处理溶液中的合金; 活塞具有涂覆有由NH 4 MgCl 4和MgAlF 5的混合物组成的膜的表面。 1.5H2O或NH4MgAlF6和MgAl2F8.2H2O的混合物; 以及由铝等制成的滑动构件，其中滑动构件的整个表面或其滑动表面涂覆有由上述混合物中的任一种构成的膜，具有立方晶体结构，并且不显示结晶取向。本发明可以提供一种表面处理方法，其需要简单的设备，可以降低处理成本，并且可以产生具有优异耐磨性，耐腐蚀性等特性的铝或铝合金，以及具有优异耐磨性的滑动构件和活塞，其他属性。

9. 发明授权

US06951691B2 Surface treatment method 失效
标题翻译：表面处理方法
公开(公告)号：US06951691B2
公开(公告)日：2005-10-04
申请号：US10600943
申请日：2003-06-20
申请人： Masaya Nomura , Yoshinobu Ozaki
发明人： Masaya Nomura , Yoshinobu Ozaki
IPC分类号： C23C22/66 , C23C22/68 , F16J1/01 , F16J1/08 , B32B9/00
CPC分类号： C23C22/66 , C23C22/68
摘要： This invention relates to a surface treatment method comprising the steps of providing a treating solution containing a specific ammonium compound or aqueous ammonia, and magnesium silicofluoride, heating the treating solution to a temperature of 70 to 100° C., and soaking aluminum or an aluminum alloy in the treating solution; a piston having a surface coated with a film consisting of a mixture of NH4MgAlF6 and MgAlF5.1.5H2O or a mixture of NH4MgAlF6 and MgAl2F8.2H2O; and a sliding member made of aluminum or the like wherein the whole surface of the sliding member or the sliding surface thereof is coated with a film which consists of either of the aforesaid mixtures, has a cubic crystal structure, and shows no crystalline orientation.The present invention can provide a surface treatment method which requires simple equipment, can reduce treatment costs, and can yield aluminum or an aluminum alloy having excellent abrasion resistance, corrosion resistance and other properties, as well as sliding members and pistons having excellent abrasion resistance and other properties.
摘要翻译：本发明涉及一种表面处理方法，其包括以下步骤：提供含有特定的铵化合物或氨水的处理溶液和氟化硅镁，将处理溶液加热到70〜100℃的温度，将铝或铝处理溶液中的合金; 具有涂覆有由NH 4 MgAlF 6和MgAlF 5 1.5 H 2的混合物构成的膜的表面的活塞，或者NH 4 N 2 NH 3 F 2的混合物或MgAl 2 H 2的混合物。 2 O; 以及由铝等制成的滑动构件，其中滑动构件的整个表面或其滑动表面涂覆有由上述混合物中的任一种构成的膜，具有立方晶体结构，并且不显示结晶取向。本发明可以提供一种表面处理方法，其需要简单的设备，可以降低处理成本，并且可以产生具有优异耐磨性，耐腐蚀性等特性的铝或铝合金，以及具有优异耐磨性的滑动构件和活塞，其他属性。

10. 发明授权

US06569537B1 Surface treatment method sliding member and piston 有权
标题翻译：表面处理方法滑动构件和活塞
公开(公告)号：US06569537B1
公开(公告)日：2003-05-27
申请号：US09553525
申请日：2000-04-20
申请人： Masaya Nomura , Yoshinobu Ozaki
发明人： Masaya Nomura , Yoshinobu Ozaki
IPC分类号： B32B1504
CPC分类号： C23C22/66 , C23C22/68
摘要： This invention relates to a surface treatment method comprising the steps of providing a treating solution containing a specific ammonium compound or aqueous ammonia, and magnesium silicofluoride, heating the treating solution to a temperature of 70 to 100° C., and soaking aluminum or an aluminum alloy in the treating solution; a piston having a surface coated with a film consisting of a mixture of NH4MgAlF6 and MgAlF5·1.5H2O or a mixture of NH4MgAlF6 and MgAl2F8·2H2O; and a sliding member made of aluminum or the like wherein the whole surface of the sliding member or the sliding surface thereof is coated with a film which consists of either of the aforesaid mixtures, has a cubic crystal structure, and shows no crystalline orientation. The present invention can provide a surface treatment method which requires simple equipment, can reduce treatment costs, and can yield aluminum or an aluminum alloy having excellent abrasion resistance, corrosion resistance and other properties, as well as sliding members and pistons having excellent abrasion resistance and other properties.
摘要翻译：本发明涉及一种表面处理方法，其包括以下步骤：提供含有特定的铵化合物或氨水的处理溶液和氟化硅镁，将处理溶液加热到70〜100℃的温度，将铝或铝处理溶液中的合金; 具有涂覆有由NH 4 MgClF 6和MgAlF 5.1.5H 2 O的混合物或NH4MgAlF6和MgAl2F8.2H2O的混合物构成的膜的表面活塞; 以及由铝等制成的滑动构件，其中滑动构件的整个表面或其滑动表面涂覆有由上述混合物中的任一种构成的膜，具有立方晶体结构，并且不显示结晶取向。本发明可以提供一种表面处理方法，其需要简单的设备，可以降低处理成本，并且可以产生具有优异耐磨性，耐腐蚀性等特性的铝或铝合金，以及具有优异耐磨性的滑动构件和活塞，其他属性。

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