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    • 4. 发明授权
    • Composition for sealing glass
    • 密封玻璃的组成
    • US07964523B2
    • 2011-06-21
    • US12214543
    • 2008-06-19
    • Yoshitaka MayumiHideyuki Kuribayashi
    • Yoshitaka MayumiHideyuki Kuribayashi
    • C03C3/064C03C3/068C03C3/066C03C8/14C03C8/20C03C8/02
    • C03C3/068C03C8/02C03C8/24H01M8/0282H01M2008/1293
    • A powder composition for forming a highly expansible crystallized glass substantially free of alkali metals is disclosed, which composition can provide, through its firing at a temperature of not more than 900° C., a seal between metal and ceramic. The powder composition is a powder composition for the formation of a sealing crystallized glass which is substantially free of alkali metals and consists of the powder of a glass containing, calculated as oxides, SiO2: 10-30% by mass, B2O3: 20-30% by mass, CaO: 10-40% by mass, MgO: 15-40% by mass, BaO+SrO+ZnO: 0-10% by mass, La2O3: 0-5% by mass, Al2O3: 0-5% by mass, and RO2: 0-3% by mass (wherein R represents Zr, Ti, or Sn), wherein the crystallized glass that is formed by firing the powder composition at 900±50° C. has a coefficient of thermal expansion of 90-120×10−7/° C. at 50-550 ° C.
    • 公开了一种用于形成基本上不含碱金属的高度可膨胀的结晶玻璃的粉末组合物,该组合物可以通过在不高于900℃的温度下烧制金属和陶瓷之间的密封来提供。 粉末组合物是用于形成密封结晶玻璃的粉末组合物,其基本上不含碱金属,并且由以氧化物计的SiO 2:10-30质量%,B 2 O 3:20-30的玻璃粉末组成 质量%CaO:10〜40质量%,MgO:15〜40质量%,BaO + SrO + ZnO:0〜10质量%,La2O3:0-5质量%,Al2O3:0-5% ,RO2:0〜3质量%(其中,R表示Zr,Ti或Sn),其中通过在900±50℃下烧成粉末组合物而形成的结晶化玻璃的热膨胀系数为 90-120×10-7 /℃,在50-550℃
    • 5. 发明申请
    • Composition for sealing glass
    • 密封玻璃的组成
    • US20090318278A1
    • 2009-12-24
    • US12214543
    • 2008-06-19
    • Yoshitaka MayumiHideyuki Kuribayashi
    • Yoshitaka MayumiHideyuki Kuribayashi
    • C03C14/00C03C3/068C03C3/064C03C3/066
    • C03C3/068C03C8/02C03C8/24H01M8/0282H01M2008/1293
    • A powder composition for forming a highly expansible crystallized glass substantially free of alkali metals is disclosed, which composition can provide, through its firing at a temperature of not more than 900° C., a seal between metal and ceramic. The powder composition is a powder composition for the formation of a sealing crystallized glass which is substantially free of alkali metals and consists of the powder of a glass containing, calculated as oxides, SiO2: 10-30% by mass, B2O3: 20-30% by mass, CaO: 10-40% by mass, MgO: 15-40% by mass, BaO+SrO+ZnO: 0-10% by mass, La2O3: 0-5% by mass, Al2O3: 0-5% by mass, and RO2: 0-3% by mass (wherein R represents Zr, Ti, or Sn), wherein the crystallized glass that is formed by firing the powder composition at 900±50° C. has a coefficient of thermal expansion of 90-120×10−7/° C. at 50-550 ° C.
    • 公开了一种用于形成基本上不含碱金属的高度可膨胀的结晶玻璃的粉末组合物,该组合物可以通过在不高于900℃的温度下烧制金属和陶瓷之间的密封来提供。 粉末组合物是用于形成密封结晶玻璃的粉末组合物,其基本上不含碱金属,并且由以氧化物计的SiO 2:10-30质量%,B 2 O 3:20-30的玻璃粉末组成 质量%CaO:10〜40质量%,MgO:15〜40质量%,BaO + SrO + ZnO:0〜10质量%,La2O3:0-5质量%,Al2O3:0-5% ,RO2:0〜3质量%(其中,R表示Zr,Ti或Sn),其中通过在900±50℃下烧成粉末组合物而形成的结晶化玻璃的热膨胀系数为 90-120x10-7 /℃,50-550℃
    • 6. 发明授权
    • Glass composition and sealing material
    • 玻璃组成和密封材料
    • US08741792B2
    • 2014-06-03
    • US13580519
    • 2011-02-24
    • Takafumi AkamatsuYoshitaka Mayumi
    • Takafumi AkamatsuYoshitaka Mayumi
    • C03C8/02C03C8/14
    • C03C8/24C03C8/02C03C8/14H01M8/0282H01M2008/1293Y10T428/2982
    • Provided is a glass composition that has a low reactivity with the constituent materials forming a solid oxide fuel cell while having a thermal expansion coefficient suitable for sealing a solid oxide fuel cell, and a glass composition and sealing material that are suitable for sealing a solid oxide fuel cell. The present invention, which relates to a sealing glass composition, is a sealing glass composition used for sealing a solid oxide fuel cell, characterized by having a composition ratio of, expressed in terms of oxide, 40 to 55% by mass of SiO2, 0 to 5.0% by mass of Al2O3, 0 to 8.0% by mass of B2O3, 20 to 30% by mass of MgO, and 10 to 24% by mass of CaO, wherein a total of the MgO and the CaO is 40 to 54% by mass.
    • 本发明提供一种具有与形成固体氧化物型燃料电池的构成材料的反应性低的玻璃组合物,同时具有适用于密封固体氧化物型燃料电池的热膨胀系数,以及适于密封固体氧化物的玻璃组合物和密封材料 燃料电池。 涉及密封玻璃组合物的本发明是用于密封固体氧化物燃料电池的密封玻璃组合物,其特征在于,以氧化物计,组成比为40〜55质量%的SiO 2,0 至5.0质量%的Al 2 O 3,0〜8.0质量%的B 2 O 3,20〜30质量%的MgO和10〜24质量%的CaO,其中,MgO和CaO的合计为40〜54质量% 的质量。
    • 7. 发明申请
    • Glass Composition and Sealing Material
    • 玻璃成分和密封材料
    • US20120316052A1
    • 2012-12-13
    • US13580519
    • 2011-02-24
    • Takafumi AkamatsuYoshitaka Mayumi
    • Takafumi AkamatsuYoshitaka Mayumi
    • C03C8/00C03C8/24B32B5/16
    • C03C8/24C03C8/02C03C8/14H01M8/0282H01M2008/1293Y10T428/2982
    • Provided is a glass composition that has a low reactivity with the constituent materials forming a solid oxide fuel cell while having a thermal expansion coefficient suitable for sealing a solid oxide fuel cell, and a glass composition and sealing material that are suitable for sealing a solid oxide fuel cell. The present invention, which relates to a sealing glass composition, is a sealing glass composition used for sealing a solid oxide fuel cell, characterized by having a composition ratio of, expressed in terms of oxide, 40 to 55% by mass of SiO2, 0 to 5.0% by mass of Al2O3, 0 to 8.0% by mass of B2O3, 20 to 30% by mass of MgO, and 10 to 24% by mass of CaO, wherein a total of the MgO and the CaO is 40 to 54% by mass.
    • 本发明提供一种具有与形成固体氧化物型燃料电池的构成材料的反应性低的玻璃组合物,同时具有适用于密封固体氧化物型燃料电池的热膨胀系数,以及适于密封固体氧化物的玻璃组合物和密封材料 燃料电池。 涉及密封玻璃组合物的本发明是用于密封固体氧化物燃料电池的密封玻璃组合物,其特征在于,以氧化物计,组成比为40〜55质量%的SiO 2,0 至5.0质量%的Al 2 O 3,0〜8.0质量%的B 2 O 3,20〜30质量%的MgO和10〜24质量%的CaO,其中,MgO和CaO的合计为40〜54质量% 的质量。
    • 8. 发明授权
    • Glass composition for sealing
    • 玻璃组合物用于密封
    • US08288298B2
    • 2012-10-16
    • US12674558
    • 2008-08-21
    • Yoshitaka MayumiHideyuki Kuribayasi
    • Yoshitaka MayumiHideyuki Kuribayasi
    • C03C8/24C03C3/066
    • H01M8/0282C03C8/02C03C8/24C04B37/005C04B37/025C04B2235/9607C04B2237/10C04B2237/32C04B2237/40H01M8/1231Y10T428/2982
    • Disclosed is a glass composition which is adapted to use in providing a hermetic seal between a metal and a ceramic, a metal and a metal, and a ceramic and a ceramic, to form crystallized glass having high strength and high thermal expansion which allow it to be used at high temperatures of 950° C. and over. The glass composition is substantially free of alkali metals, and contains, as calculated as oxide, 15-30 mass % of SiO2, 0-5 mass % of Al2O3, 20-35 mass % of B2O3, 10-25 mass % of CaO, 25-40 mass % of MgO, 3-8 mass % (3.0% excluded) of ZrO2, and 0-3 mass % of CeO2, wherein the crystallized glass which is formed by firing a glass powder made of the glass composition at a temperature of 850-1050° C. has a thermal expansion coefficient of 90-110×10−7/° C. at 50-550° C. and flexural strength of not less than 80 MPa.
    • 公开了适用于在金属和陶瓷,金属和金属以及陶瓷和陶瓷之间提供气密密封的玻璃组合物,以形成具有高强度和高热膨胀的结晶玻璃, 在950°C及以上的高温下使用。 玻璃组合物基本上不含碱金属,并且以氧化物计含有15-30质量%的SiO 2,0-5质量%的Al 2 O 3,20-35质量%的B 2 O 3,10-25质量%的CaO, 25-40质量%的MgO,3〜8质量%(3.0%除外)的ZrO 2和0〜3质量%的CeO 2,其中通过在玻璃组合物中煅烧由玻璃组合物制成的玻璃粉末, 的850-1050℃,在50-550℃下的热膨胀系数为90-110×10-7 /℃,弯曲强度不低于80MPa。