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    • 1. 发明授权
    • Composition for sealing glass
    • 密封玻璃的组成
    • US07964523B2
    • 2011-06-21
    • US12214543
    • 2008-06-19
    • Yoshitaka MayumiHideyuki Kuribayashi
    • Yoshitaka MayumiHideyuki Kuribayashi
    • C03C3/064C03C3/068C03C3/066C03C8/14C03C8/20C03C8/02
    • C03C3/068C03C8/02C03C8/24H01M8/0282H01M2008/1293
    • A powder composition for forming a highly expansible crystallized glass substantially free of alkali metals is disclosed, which composition can provide, through its firing at a temperature of not more than 900° C., a seal between metal and ceramic. The powder composition is a powder composition for the formation of a sealing crystallized glass which is substantially free of alkali metals and consists of the powder of a glass containing, calculated as oxides, SiO2: 10-30% by mass, B2O3: 20-30% by mass, CaO: 10-40% by mass, MgO: 15-40% by mass, BaO+SrO+ZnO: 0-10% by mass, La2O3: 0-5% by mass, Al2O3: 0-5% by mass, and RO2: 0-3% by mass (wherein R represents Zr, Ti, or Sn), wherein the crystallized glass that is formed by firing the powder composition at 900±50° C. has a coefficient of thermal expansion of 90-120×10−7/° C. at 50-550 ° C.
    • 公开了一种用于形成基本上不含碱金属的高度可膨胀的结晶玻璃的粉末组合物,该组合物可以通过在不高于900℃的温度下烧制金属和陶瓷之间的密封来提供。 粉末组合物是用于形成密封结晶玻璃的粉末组合物,其基本上不含碱金属,并且由以氧化物计的SiO 2:10-30质量%,B 2 O 3:20-30的玻璃粉末组成 质量%CaO:10〜40质量%,MgO:15〜40质量%,BaO + SrO + ZnO:0〜10质量%,La2O3:0-5质量%,Al2O3:0-5% ,RO2:0〜3质量%(其中,R表示Zr,Ti或Sn),其中通过在900±50℃下烧成粉末组合物而形成的结晶化玻璃的热膨胀系数为 90-120×10-7 /℃,在50-550℃
    • 2. 发明申请
    • Composition for sealing glass
    • 密封玻璃的组成
    • US20090318278A1
    • 2009-12-24
    • US12214543
    • 2008-06-19
    • Yoshitaka MayumiHideyuki Kuribayashi
    • Yoshitaka MayumiHideyuki Kuribayashi
    • C03C14/00C03C3/068C03C3/064C03C3/066
    • C03C3/068C03C8/02C03C8/24H01M8/0282H01M2008/1293
    • A powder composition for forming a highly expansible crystallized glass substantially free of alkali metals is disclosed, which composition can provide, through its firing at a temperature of not more than 900° C., a seal between metal and ceramic. The powder composition is a powder composition for the formation of a sealing crystallized glass which is substantially free of alkali metals and consists of the powder of a glass containing, calculated as oxides, SiO2: 10-30% by mass, B2O3: 20-30% by mass, CaO: 10-40% by mass, MgO: 15-40% by mass, BaO+SrO+ZnO: 0-10% by mass, La2O3: 0-5% by mass, Al2O3: 0-5% by mass, and RO2: 0-3% by mass (wherein R represents Zr, Ti, or Sn), wherein the crystallized glass that is formed by firing the powder composition at 900±50° C. has a coefficient of thermal expansion of 90-120×10−7/° C. at 50-550 ° C.
    • 公开了一种用于形成基本上不含碱金属的高度可膨胀的结晶玻璃的粉末组合物,该组合物可以通过在不高于900℃的温度下烧制金属和陶瓷之间的密封来提供。 粉末组合物是用于形成密封结晶玻璃的粉末组合物,其基本上不含碱金属,并且由以氧化物计的SiO 2:10-30质量%,B 2 O 3:20-30的玻璃粉末组成 质量%CaO:10〜40质量%,MgO:15〜40质量%,BaO + SrO + ZnO:0〜10质量%,La2O3:0-5质量%,Al2O3:0-5% ,RO2:0〜3质量%(其中,R表示Zr,Ti或Sn),其中通过在900±50℃下烧成粉末组合物而形成的结晶化玻璃的热膨胀系数为 90-120x10-7 /℃,50-550℃
    • 4. 发明授权
    • Composition for producing low temperature co-fired substrate
    • 用于生产低温共烧基材的组合物
    • US5468694A
    • 1995-11-21
    • US156059
    • 1993-11-22
    • Tomoyuki TaguchiHideyuki KuribayashiJun TanakaTomomi KonagaYoshihiro Morigami
    • Tomoyuki TaguchiHideyuki KuribayashiJun TanakaTomomi KonagaYoshihiro Morigami
    • C03C8/14C03C10/00C03C10/06H05K1/03C03C3/064
    • C03C8/14C03C10/0054H05K1/0306
    • A novel crystallizable glass composition for producing a novel low temperature co-fired glass-ceramic substrate having patterns of a low electrical-resistance conductor such as Ag, Ag-Pd, Au, and/or Cu is obtained. Being subjected to a firing process, the novel crystallizable glass can precipitate mullite as main crystalline phase, and at least one subordinate crystalline phase among forsterite, spinel, sapphirine, and similar crystalline phases. And also, the novel crystallizable glass powder composition with a inorganic filler as external additive having a minimum of 1.4 m.sup.2 /g. of mean specific surface area can precipitate both mullite phase and cordierite phase. The mixing weight ratio of the filler to the crystallizable glass powder is from 0.1/99.9 to 20/80. The crystallizable glass composition comprises following oxide components expressed in terms of percent by weight on the oxide basis; 45-58% of Al.sub.2 O.sub.3, 20-35% of SiO.sub.2, 5-15% of B.sub.2 O.sub.3, 5-20% of MgO, and 0-4% of alkali metal oxide. The substrates produced from the above compositions have high flexural strength, low dielectric constant, low loss factor, and controllable thermal expansion coefficient of ranging from about 30 to about 70.times.10.sup.- 7 /.degree.C. As for the substrate containing both mullite phase and cordierite phase, as the substrate has a low thermal expansion coefficient, it can be combined with AlN to produce a composite structure package.
    • 获得了具有诸如Ag,Ag-Pd,Au和/或Cu等低电阻导体图形的新型低温共烧玻璃陶瓷基板的可结晶玻璃组合物。 经过焙烧处理后,新型可结晶玻璃可以将莫来石沉淀为主晶相,并在镁橄榄石,尖晶石,蓝宝石和类似结晶相中至少存在一个以下结晶相。 另外,作为外部添加剂的无机填料的新型可结晶玻璃粉末组合物的最小值为1.4m 2 / g。 的平均比表面积可以沉淀莫来石相和堇青石相。 填料与可结晶玻璃粉末的混合重量比为0.1 / 99.9〜20/80。 可结晶玻璃组合物包含以氧化物为基准的以重量百分比表示的以下氧化物组分; 45-58%的Al2O3,20-35%的SiO2,5-15%的B2O3,5-20%的MgO和0-4%的碱金属氧化物。 由上述组合物制备的基材具有约30至约70×10 -7 /℃范围内的高弯曲强度,低介电常数,低损耗因数和可控热膨胀系数。对于含有莫来石相和堇青石相的基材 由于基板具有低的热膨胀系数,因此可以与AlN组合以产生复合结构封装。
    • 5. 发明授权
    • Polyamide fibers
    • 聚酰胺纤维
    • US5371153A
    • 1994-12-06
    • US225927
    • 1994-04-11
    • Hideyuki KuribayashiTatsuya Koizumi
    • Hideyuki KuribayashiTatsuya Koizumi
    • C08J5/06D06M13/385D06M15/55D06M15/693B05D1/36B32B25/00C08F283/04
    • C08J5/06D06M13/385D06M15/55D06M15/693C08J2321/00Y10T428/2945Y10T428/2947
    • The present process for producing aromatic polyamide fibers for reinforcement of rubbers lies in that, in the first step, the fibers are dipped in an epoxy treating solution containing aromatic glycidylamines having 2 or more epoxy groups in one molecule and aromatic amines at a specific ratio and dried and cured, and thereafter, in the second step, the fibers are dipped in a treating solution for the second step containing resorcin formaldehyde resins and rubber latices and dried and cured. More preferably, specific chlorophenol compounds are added to the treating solution for the second step.The aromatic polyamide fibers obtained by the process of the present invention provide rubber products excellent in water resistance when they are used for reinforcement of rubbers, and the products have high adhesive strength in initial adhesion and besides, small decrease in adhesive strength even if they are dipped in water for a long time.
    • 用于增强橡胶的芳香族聚酰胺纤维的制造方法的原理在于,在第一步骤中,将纤维浸渍在一分子中含有具有2个以上环氧基的芳香族缩水甘油胺的环氧处理溶液中,并且以特定比例, 干燥固化后,在第二工序中,将纤维浸渍在含有间苯二酚甲醛树脂和橡胶胶乳的第二工序的处理液中,干燥固化。 更优选地,将特定的氯酚化合物加入到用于第二步的处理溶液中。 通过本发明的方法获得的芳族聚酰胺纤维在用于增强橡胶时提供优异的耐水性的橡胶产品,并且该产品在初始粘合中具有高的粘合强度,此外,即使它们是粘合强度也降低了粘合强度 浸在水中很长一段时间。
    • 6. 发明授权
    • Thermoplastic resin composition
    • 热塑性树脂组合物
    • US5237002A
    • 1993-08-17
    • US836382
    • 1992-02-18
    • Taichi NishioHideyuki KuribayashiTakashi Sanada
    • Taichi NishioHideyuki KuribayashiTakashi Sanada
    • C08L51/04C08L63/00C08L71/12C08L77/00
    • C08L77/00C08L51/04C08L71/123C08L63/00Y10S525/905
    • A novel thermoplastic resin composition excellent in heat resistance, impact resistance, hardness is provided which comprises 100 parts by weight of a composition comprising (A) 5-95% by weight of a polyphenylene ether prepared by oxidation polymerization of at least one phenol compound represented by the formula: ##STR1## wherein R.sub.1, R.sub.2, R.sub.3, R.sub.4 and R.sub.5 which may be identical or different and represent a hydrogen atom, a halogen atom, a substituted or unsubstituted hydrocarbon residue, with a proviso that at least one of them is a hydrogen atom and (B) 95-5% by weight of a polyamide and 5-100 parts by weight of (C) a copolymer of an ethylene-.alpha.-olefin copolymer rubber with an alkenyl aromatic compound and an unsaturated carboxylic acid or its anhydride. This composition may further contain 0.01-30 parts by weight of an epoxy compound (D) for 100 parts by weight of the composition of (A) and (B).
    • 提供了耐热性,耐冲击性,硬度优异的新型热塑性树脂组合物,其包含100重量份的组合物,其包含(A)5-95重量%的由至少一种表示的酚化合物的氧化聚合制备的聚苯醚 其中R1,R2,R3,R4和R5可以相同或不同,代表氢原子,卤素原子,取代或未取代的烃基,条件是它们中至少有一个是 氢原子和(B)95-5重量%的聚酰胺和5-100重量份的(C)乙烯-α-烯烃共聚物橡胶与链烯基芳族化合物和不饱和羧酸或其不饱和羧酸的共聚物 酐。 对于100重量份的组合物(A)和(B),该组合物还可以含有0.01-30重量份的环氧化合物(D)。
    • 9. 发明授权
    • Thermoplastic resin composition
    • 热塑性树脂组合物
    • US5112907A
    • 1992-05-12
    • US431822
    • 1989-11-06
    • Taichi NishioHideyuki KuribayashiTakashi Sanada
    • Taichi NishioHideyuki KuribayashiTakashi Sanada
    • C08L71/02C08L51/04C08L51/06C08L63/00C08L71/12C08L77/00
    • C08L77/00C08L51/04C08L71/123C08L63/00Y10S525/905
    • A novel thermoplastic resin composition excellent in heat resistance, impact resistance, hardness is provided which comprises 100 parts by weight of a composition comprising (A) 5-95% by weight of a polyphenylene ether prepared by oxidation polymerization of at least one phenol compound represented by the formula: ##STR1## wherein R.sub.1, R.sub.2, R.sub.3, R.sub.4 and R.sub.5 which may be identical or different and represent a hydrogen atom, a halogen atom, a substituted or unsubstituted hydrocarbon residue, with a proviso that at least one of them is a hydrogen atom and (B) 95-5% by weight of a polyamide and 5-100 parts by weight of (C) a copolymer of an ethylene-.alpha.-olefin copolymer rubber with an alkenyl aromatic compound and an unsaturated carboxylic acid or its anhydride. This composition may further contain 0.01-30 parts by weight of an epoxy compound (D) for 100 parts by weight of the composition of (A) and (B).
    • 提供了耐热性,耐冲击性,硬度优异的新型热塑性树脂组合物,其包含100重量份的组合物,其包含(A)5-95重量%的由至少一种表示的酚化合物的氧化聚合制备的聚苯醚 其中R1,R2,R3,R4和R5可以相同或不同,代表氢原子,卤素原子,取代或未取代的烃基,条件是它们中至少有一个是 氢原子和(B)95-5重量%的聚酰胺和5-100重量份的(C)乙烯-α-烯烃共聚物橡胶与链烯基芳族化合物和不饱和羧酸或其不饱和羧酸的共聚物 酐。 对于100重量份的组合物(A)和(B),该组合物还可以含有0.01-30重量份的环氧化合物(D)。