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    • 1. 发明授权
    • Process for purification of phytosterol from fatty acids and their esters
    • 从脂肪酸及其酯纯化植物甾醇的方法
    • US06762312B1
    • 2004-07-13
    • US10129329
    • 2002-05-03
    • Yasuyuki HattoriJun KonoMasamitsu Horio
    • Yasuyuki HattoriJun KonoMasamitsu Horio
    • C07J900
    • C11B7/00C07J9/00C11B7/0008C11C1/10C11C3/003
    • The present invention provides a process for producing a highly pure phytosterol, at high yield in particular, by an easy treatment from a crude fatty acid ester derived from a vegetable fat and/or oil. That is, the present invention provides a process for producing phytosterol, which comprises (A) bringing a crude fatty acid product derived from a vegetable fat and/or oil including phytosterol into contact with a mixed solvent of an organic solvent and water to crystallize the phytosterol and separating the crystals from the mixed solvent; or (B) mixing a crude fatty acid ester derived from a vegetable fat and/or oil including the phytosterol and a fatty acid ester with a lower alcohol, allowing the mixture to stand at a temperature of 1 to 40° C. to precipitate crystals including the fatty acid ester and separating the crystals to take the lower alcohol solution including the phytosterol.
    • 本发明提供一种以高产率生产高纯度植物甾醇的方法,特别是通过从植物脂肪和/或油衍生得到的粗脂肪酸酯的容易处理。 也就是说,本发明提供了一种生产植物甾醇的方法,其包括(A)将来自植物油脂和/或包含植物甾醇的油的粗脂肪酸产物与有机溶剂和水的混合溶剂接触,使 植物甾醇并将晶体与混合溶剂分离; 或(B)将来源于植物脂肪和/或包含植物甾醇和脂肪酸酯的油的粗脂肪酸酯与低级醇混合,使混合物在1至40℃的温度下静置以沉淀晶体 包括脂肪酸酯并分离晶体以摄取含有植物甾醇的低级醇溶液。
    • 3. 发明申请
    • Sulfuric acid amine salt, sulfonic acid amine salt, production thereof and softener composition
    • 硫酸胺盐,磺酸胺盐,其生产和软化剂组成
    • US20060116314A1
    • 2006-06-01
    • US11332161
    • 2006-01-17
    • Jun KonoTomokatsu KusumiAkira SakaguchiYasuki OhtawaIkuo SuganoKazutaka ShiratsuchiShuji Tagata
    • Jun KonoTomokatsu KusumiAkira SakaguchiYasuki OhtawaIkuo SuganoKazutaka ShiratsuchiShuji Tagata
    • C11D3/00
    • C11D1/65C07C231/12C07C303/24C07C303/32C07C305/04C11D1/146C11D1/62C11D3/001C07C233/36C07C309/04C07C309/20C07C309/31
    • Provided is a process for preparing a sulfuric acid amine salt (I) represented by the formula (I), which is a neutralization compound between a sulfated compound having a long chain alkyl or alkenyl group and an amine having a long chain alkyl or alkenyl group, useful as softener. wherein R31 is a linear or branched C18-36 alkyl or alkenyl group, or a group represented by the formula R36—(OA)n- (wherein R36 is a linear or branched C12-36 alkyl or alkenyl group, OA is an oxyalkylene group having 2 to 4 carbon atoms and n is a number of from 0.1 to 10 on average), R32 is a is a linear or branched C10-36 alkyl or alkenyl group, X is —CONH—, —NHCO—, —COO— or —OCO—, R33 is a linear or branched C1-6 alkylene group, R34 is a linear or branched C1-6 alkyl or hydroxyalkyl group, or a group represented by R5—[B—R6]b—, R35 is a linear or branched C1-6 alkyl or hydroxyalkyl group, wherein R5 is a linear or branched C10-36 alkyl or alkenyl group, R6 is a linear or branched C1-6 alkylene group, B is a group selected from the group consisting of —COO—, —OCO—, —CONH— and —NHCO—, b is a number of 0 or 1 and m is a number of 0 or 1. A sulfonic acid amine salt may be obtained.
    • 提供一种制备式(I)表示的硫酸胺盐(I)的方法,其是具有长链烷基或烯基的硫酸化合物和具有长链烷基或链烯基的胺之间的中和化合物 ,用作软化剂。 其中R 31是直链或支链C 18-18 -S烷基或烯基,或由式R 36表示的基团 - (OA )其中R 36为直链或支链C 12〜36的烷基或链烯基,OA为氧化烯基,其具有2〜 4个碳原子,n是平均为0.1至10的数),R 32是a是直链或支链的C 10-16 -S-烷基或烯基,X 是-CONH-,-NHCO-,-COO-或-OCO-,R 33是直链或支链C 1-6亚烷基,R 34 直链或支链C 1-6烷基或羟烷基,或由R 5表示的基团 - [BR 6] - , - 35是直链或支链C 1-6烷基或羟烷基,其中R 5 O >是直链或支链C 10-30烷基或链烯基,R 6是直链或支链C 1-6 - 亚烷基, B是选自-COO的基团 - , - OCO - , - CONH-和-NHCO-,b为0或1的数,m为0或1的数。可以获得磺酸胺盐。
    • 5. 发明申请
    • SULFURIC ACID AMINE SALT, SULFONIC ACID AMINE SALT, PRODUCTION THEREOF AND SOFTENER COMPOSITION
    • 硫酸铵盐,磺酸钠盐,其生产和固体组合物
    • US20070111923A1
    • 2007-05-17
    • US11621790
    • 2007-01-10
    • Jun KonoTomokatsu KusumiAkira SakaguchiYasuki OhtawaIkuo SuganoKazutaka ShiratsuchiShuji Tagata
    • Jun KonoTomokatsu KusumiAkira SakaguchiYasuki OhtawaIkuo SuganoKazutaka ShiratsuchiShuji Tagata
    • C11D1/755
    • C11D1/65C07C231/12C07C303/24C07C303/32C07C305/04C11D1/146C11D1/62C11D3/001C07C233/36C07C309/04C07C309/20C07C309/31
    • Provided is a process for preparing a sulfuric acid amine salt (I) represented by the formula (I), which is a neutralization compound between a sulfated compound having a long chain alkyl or alkenyl group and an amine having a long chain alkyl or alkenyl group, useful as softener. wherein R31 is a linear or branched C18-36 alkyl or alkenyl group, or a group represented by the formula R36−(OA)n- (wherein R36 is a linear or branched C12-36 alkyl or alkenyl group, OA is an oxyalkylene group having 2 to 4 carbon atoms and n is a number of from 0.1 to 10 on average), R32 is a is a linear or branched C10-36alkyl or alkenyl group, X is —CONH—, —NHCO—, —COO— or —OCO—, R33 is a linear or branched C1-6 alkylene group, R34 is a linear or branched C1-6 alkyl or hydroxyalkyl group, or a group represented by R5—[B—R6]b—, R35 is a linear or branched C1-6 alkyl or hydroxyalkyl group, wherein R5 is a linear or branched C10-36 alkyl or alkenyl group, R6 is a linear or branched C1-6 alkylene group, B is a group selected from the group consisting of —COO—, —OCO—, —CCNH— and —NHCO—, b is a number of 0 or 1 and m is a number of 0 or 1. A sulfonic acid amine salt may be obtained.
    • 提供一种制备式(I)表示的硫酸胺盐(I)的方法,其是具有长链烷基或烯基的硫酸化合物和具有长链烷基或链烯基的胺之间的中和化合物 ,用作软化剂。 其中R 31是直链或支链C 18-18 -S烷基或烯基,或由式R 36表示的基团 - (OA )其中R 36为直链或支链C 12〜36的烷基或链烯基,OA为氧化烯基,其具有2〜 4个碳原子,n是平均为0.1至10的数),R 32是a是直链或支链的C 10-16 -S-烷基或烯基,X 是-CONH-,-NHCO-,-COO-或-OCO-,R 33是直链或支链C 1-6亚烷基,R 34 直链或支链C 1-6烷基或羟烷基,或由R 5表示的基团 - [BR 6] - , - 35是直链或支链C 1-6烷基或羟烷基,其中R 5 O >是直链或支链C 10-30烷基或链烯基,R 6是直链或支链C 1-6 - 亚烷基, B是选自-COO- ,-OCO-,-CCNH-和-NHCO-,b是0或1的数,m是0或1的数。可以获得磺酸胺盐。
    • 6. 发明授权
    • Sulfuric acid amine salt, sulfonic acid amine salt, production thereof and softener composition
    • 硫酸胺盐,磺酸胺盐,其生产和软化剂组成
    • US07179783B2
    • 2007-02-20
    • US11332161
    • 2006-01-17
    • Jun KonoTomokatsu KusumiAkira SakaguchiYasuki OhtawaIkuo SuganoKazutaka ShiratsuchiShuji Tagata
    • Jun KonoTomokatsu KusumiAkira SakaguchiYasuki OhtawaIkuo SuganoKazutaka ShiratsuchiShuji Tagata
    • C11D1/65
    • C11D1/65C07C231/12C07C303/24C07C303/32C07C305/04C11D1/146C11D1/62C11D3/001C07C233/36C07C309/04C07C309/20C07C309/31
    • Provided is a process for preparing a sulfuric acid amine salt (I) represented by the formula (I), which is a neutralization compound between a sulfated compound having a long chain alkyl or alkenyl group and an amine having a long chain alkyl or alkenyl group, useful as softener. wherein R31 is a linear or branched C18-36 alkyl or alkenyl group, or a group represented by the formula R36—(OA)n- (wherein R36 is a linear or branched C12-36 alkyl or alkenyl group, OA is an oxyalkylene group having 2 to 4 carbon atoms and n is a number of from 0.1 to 10 on average), R32 is a is a linear or branched C10-36 alkyl or alkenyl group, X is —CONH—, —NHCO—, —COO— or —OCO—, R33 is a linear or branched C1-6 alkylene group, R34 is a linear or branched C1-6 alkyl or hydroxyalkyl group, or a group represented by R5—[B—R6]b—, R35 is a linear or branched C1-6 alkyl or hydroxyalkyl group, wherein R5 is a linear or branched C10-36 alkyl or alkenyl group, R6 is a linear or branched C1-6 alkylene group, B is a group selected from the group consisting of —COO—, —OCO—, —CONH— and —NHCO—, b is a number of 0 or 1 and m is a number of 0 or 1. A sulfonic acid amine salt may be obtained.
    • 提供一种制备式(I)表示的硫酸胺盐(I)的方法,其是具有长链烷基或烯基的硫酸化合物和具有长链烷基或链烯基的胺之间的中和化合物 ,用作软化剂。 其中R 31是直链或支链C 18-18 -S烷基或烯基,或由式R 36表示的基团 - (OA )其中R 36为直链或支链C 12〜36的烷基或链烯基,OA为氧化烯基,其具有2〜 4个碳原子,n是平均为0.1至10的数),R 32是a是直链或支链的C 10-16 -S-烷基或烯基,X 是-CONH-,-NHCO-,-COO-或-OCO-,R 33是直链或支链C 1-6亚烷基,R 34 直链或支链C 1-6烷基或羟烷基,或由R 5表示的基团 - [BR 6] - , - 35是直链或支链C 1-6烷基或羟烷基,其中R 5 O >是直链或支链C 10-30烷基或链烯基,R 6是直链或支链C 1-6 - 亚烷基, B是选自-COO的基团 - , - OCO - , - CONH-和-NHCO-,b为0或1的数,m为0或1的数。可以获得磺酸胺盐。