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    • 1. 发明申请
    • Sulfuric acid amine salt, sulfonic acid amine salt, production thereof and softener composition
    • 硫酸胺盐,磺酸胺盐,其生产和软化剂组成
    • US20060116314A1
    • 2006-06-01
    • US11332161
    • 2006-01-17
    • Jun KonoTomokatsu KusumiAkira SakaguchiYasuki OhtawaIkuo SuganoKazutaka ShiratsuchiShuji Tagata
    • Jun KonoTomokatsu KusumiAkira SakaguchiYasuki OhtawaIkuo SuganoKazutaka ShiratsuchiShuji Tagata
    • C11D3/00
    • C11D1/65C07C231/12C07C303/24C07C303/32C07C305/04C11D1/146C11D1/62C11D3/001C07C233/36C07C309/04C07C309/20C07C309/31
    • Provided is a process for preparing a sulfuric acid amine salt (I) represented by the formula (I), which is a neutralization compound between a sulfated compound having a long chain alkyl or alkenyl group and an amine having a long chain alkyl or alkenyl group, useful as softener. wherein R31 is a linear or branched C18-36 alkyl or alkenyl group, or a group represented by the formula R36—(OA)n- (wherein R36 is a linear or branched C12-36 alkyl or alkenyl group, OA is an oxyalkylene group having 2 to 4 carbon atoms and n is a number of from 0.1 to 10 on average), R32 is a is a linear or branched C10-36 alkyl or alkenyl group, X is —CONH—, —NHCO—, —COO— or —OCO—, R33 is a linear or branched C1-6 alkylene group, R34 is a linear or branched C1-6 alkyl or hydroxyalkyl group, or a group represented by R5—[B—R6]b—, R35 is a linear or branched C1-6 alkyl or hydroxyalkyl group, wherein R5 is a linear or branched C10-36 alkyl or alkenyl group, R6 is a linear or branched C1-6 alkylene group, B is a group selected from the group consisting of —COO—, —OCO—, —CONH— and —NHCO—, b is a number of 0 or 1 and m is a number of 0 or 1. A sulfonic acid amine salt may be obtained.
    • 提供一种制备式(I)表示的硫酸胺盐(I)的方法,其是具有长链烷基或烯基的硫酸化合物和具有长链烷基或链烯基的胺之间的中和化合物 ,用作软化剂。 其中R 31是直链或支链C 18-18 -S烷基或烯基,或由式R 36表示的基团 - (OA )其中R 36为直链或支链C 12〜36的烷基或链烯基,OA为氧化烯基,其具有2〜 4个碳原子,n是平均为0.1至10的数),R 32是a是直链或支链的C 10-16 -S-烷基或烯基,X 是-CONH-,-NHCO-,-COO-或-OCO-,R 33是直链或支链C 1-6亚烷基,R 34 直链或支链C 1-6烷基或羟烷基,或由R 5表示的基团 - [BR 6] - , - 35是直链或支链C 1-6烷基或羟烷基,其中R 5 O >是直链或支链C 10-30烷基或链烯基,R 6是直链或支链C 1-6 - 亚烷基, B是选自-COO的基团 - , - OCO - , - CONH-和-NHCO-,b为0或1的数,m为0或1的数。可以获得磺酸胺盐。
    • 2. 发明申请
    • SULFURIC ACID AMINE SALT, SULFONIC ACID AMINE SALT, PRODUCTION THEREOF AND SOFTENER COMPOSITION
    • 硫酸铵盐,磺酸钠盐,其生产和固体组合物
    • US20070111923A1
    • 2007-05-17
    • US11621790
    • 2007-01-10
    • Jun KonoTomokatsu KusumiAkira SakaguchiYasuki OhtawaIkuo SuganoKazutaka ShiratsuchiShuji Tagata
    • Jun KonoTomokatsu KusumiAkira SakaguchiYasuki OhtawaIkuo SuganoKazutaka ShiratsuchiShuji Tagata
    • C11D1/755
    • C11D1/65C07C231/12C07C303/24C07C303/32C07C305/04C11D1/146C11D1/62C11D3/001C07C233/36C07C309/04C07C309/20C07C309/31
    • Provided is a process for preparing a sulfuric acid amine salt (I) represented by the formula (I), which is a neutralization compound between a sulfated compound having a long chain alkyl or alkenyl group and an amine having a long chain alkyl or alkenyl group, useful as softener. wherein R31 is a linear or branched C18-36 alkyl or alkenyl group, or a group represented by the formula R36−(OA)n- (wherein R36 is a linear or branched C12-36 alkyl or alkenyl group, OA is an oxyalkylene group having 2 to 4 carbon atoms and n is a number of from 0.1 to 10 on average), R32 is a is a linear or branched C10-36alkyl or alkenyl group, X is —CONH—, —NHCO—, —COO— or —OCO—, R33 is a linear or branched C1-6 alkylene group, R34 is a linear or branched C1-6 alkyl or hydroxyalkyl group, or a group represented by R5—[B—R6]b—, R35 is a linear or branched C1-6 alkyl or hydroxyalkyl group, wherein R5 is a linear or branched C10-36 alkyl or alkenyl group, R6 is a linear or branched C1-6 alkylene group, B is a group selected from the group consisting of —COO—, —OCO—, —CCNH— and —NHCO—, b is a number of 0 or 1 and m is a number of 0 or 1. A sulfonic acid amine salt may be obtained.
    • 提供一种制备式(I)表示的硫酸胺盐(I)的方法,其是具有长链烷基或烯基的硫酸化合物和具有长链烷基或链烯基的胺之间的中和化合物 ,用作软化剂。 其中R 31是直链或支链C 18-18 -S烷基或烯基,或由式R 36表示的基团 - (OA )其中R 36为直链或支链C 12〜36的烷基或链烯基,OA为氧化烯基,其具有2〜 4个碳原子,n是平均为0.1至10的数),R 32是a是直链或支链的C 10-16 -S-烷基或烯基,X 是-CONH-,-NHCO-,-COO-或-OCO-,R 33是直链或支链C 1-6亚烷基,R 34 直链或支链C 1-6烷基或羟烷基,或由R 5表示的基团 - [BR 6] - , - 35是直链或支链C 1-6烷基或羟烷基,其中R 5 O >是直链或支链C 10-30烷基或链烯基,R 6是直链或支链C 1-6 - 亚烷基, B是选自-COO- ,-OCO-,-CCNH-和-NHCO-,b是0或1的数,m是0或1的数。可以获得磺酸胺盐。
    • 3. 发明授权
    • Sulfuric acid amine salt, sulfonic acid amine salt, production thereof and softener composition
    • 硫酸胺盐,磺酸胺盐,其生产和软化剂组成
    • US07179783B2
    • 2007-02-20
    • US11332161
    • 2006-01-17
    • Jun KonoTomokatsu KusumiAkira SakaguchiYasuki OhtawaIkuo SuganoKazutaka ShiratsuchiShuji Tagata
    • Jun KonoTomokatsu KusumiAkira SakaguchiYasuki OhtawaIkuo SuganoKazutaka ShiratsuchiShuji Tagata
    • C11D1/65
    • C11D1/65C07C231/12C07C303/24C07C303/32C07C305/04C11D1/146C11D1/62C11D3/001C07C233/36C07C309/04C07C309/20C07C309/31
    • Provided is a process for preparing a sulfuric acid amine salt (I) represented by the formula (I), which is a neutralization compound between a sulfated compound having a long chain alkyl or alkenyl group and an amine having a long chain alkyl or alkenyl group, useful as softener. wherein R31 is a linear or branched C18-36 alkyl or alkenyl group, or a group represented by the formula R36—(OA)n- (wherein R36 is a linear or branched C12-36 alkyl or alkenyl group, OA is an oxyalkylene group having 2 to 4 carbon atoms and n is a number of from 0.1 to 10 on average), R32 is a is a linear or branched C10-36 alkyl or alkenyl group, X is —CONH—, —NHCO—, —COO— or —OCO—, R33 is a linear or branched C1-6 alkylene group, R34 is a linear or branched C1-6 alkyl or hydroxyalkyl group, or a group represented by R5—[B—R6]b—, R35 is a linear or branched C1-6 alkyl or hydroxyalkyl group, wherein R5 is a linear or branched C10-36 alkyl or alkenyl group, R6 is a linear or branched C1-6 alkylene group, B is a group selected from the group consisting of —COO—, —OCO—, —CONH— and —NHCO—, b is a number of 0 or 1 and m is a number of 0 or 1. A sulfonic acid amine salt may be obtained.
    • 提供一种制备式(I)表示的硫酸胺盐(I)的方法,其是具有长链烷基或烯基的硫酸化合物和具有长链烷基或链烯基的胺之间的中和化合物 ,用作软化剂。 其中R 31是直链或支链C 18-18 -S烷基或烯基,或由式R 36表示的基团 - (OA )其中R 36为直链或支链C 12〜36的烷基或链烯基,OA为氧化烯基,其具有2〜 4个碳原子,n是平均为0.1至10的数),R 32是a是直链或支链的C 10-16 -S-烷基或烯基,X 是-CONH-,-NHCO-,-COO-或-OCO-,R 33是直链或支链C 1-6亚烷基,R 34 直链或支链C 1-6烷基或羟烷基,或由R 5表示的基团 - [BR 6] - , - 35是直链或支链C 1-6烷基或羟烷基,其中R 5 O >是直链或支链C 10-30烷基或链烯基,R 6是直链或支链C 1-6 - 亚烷基, B是选自-COO的基团 - , - OCO - , - CONH-和-NHCO-,b为0或1的数,m为0或1的数。可以获得磺酸胺盐。
    • 4. 发明授权
    • Softener composition
    • 软化剂组成
    • US06855682B2
    • 2005-02-15
    • US10092983
    • 2002-03-08
    • Yasuki OhtawaTakeshi TomifujiAkira SakaguchiTohru Katoh
    • Yasuki OhtawaTakeshi TomifujiAkira SakaguchiTohru Katoh
    • C11D1/40C11D1/42C11D1/44C11D1/62C11D1/645C11D1/72C11D1/74C11D1/835
    • C07C213/06C07C213/08C11D1/40C11D1/42C11D1/44C11D1/62C11D1/645C11D1/72C11D1/74C11D1/835C07C219/06
    • A softener composition, which contains tri-long-chain alkyl quaternary ammonium salt that has been considered to be difficult to use as a softener base agent, and which can provide a softener composition that provides a sufficient softening performance, is provided with (A) a cationic surfactant comprising at least one selected from the group consisting of quaternary ammonium salts represented by the formulae (I), (II) or (III), wherein the ratio of quaternary ammonium salt represented by the formula (I) to the total amount of these salts exceeds 50 weight %, with the ratio thereof represented by (III) being set to not more than 10%, and (B) at least one nonionic surfactant. In this case, (A) may include tertiary amine. (wherein, R1, R2 and R3 represent long-chain alkyl groups, etc. having total carbon atoms of 8 to 40, which may be intersected by an ether group, an ester group or an amide group; R4 represents an alkyl group, etc. having carbon atoms of 1 to 6, and X− represents an anionic group.)
    • (A)提供了一种软化剂组合物,其含有被认为难以用作软化剂基剂的三长链烷基季铵盐,并且可以提供提供足够的软化性能的柔软剂组合物, 包含选自由式(I),(II)或(III)表示的季铵盐中的至少一种的阳离子表面活性剂,其中由式(I)表示的季铵盐与总计 的这些盐超过50重量%,其由(III)表示的比例设定为不超过10%,和(B)至少一种非离子表面活性剂。 在这种情况下,(A)可以包括叔胺(其中,R 1,R 2和R 3表示总碳原子数为8〜40的长链烷基等,其可以是 由醚基,酯基或酰胺基相交; R 4表示碳原子数1〜6的烷基等,X 1表示阴离子基)。
    • 5. 发明授权
    • Softener composition
    • 软化剂组成
    • US07115779B2
    • 2006-10-03
    • US10967176
    • 2004-10-19
    • Yasuki OhtawaTakeshi TomifujiAkira SakaguchiTohru Katoh
    • Yasuki OhtawaTakeshi TomifujiAkira SakaguchiTohru Katoh
    • C07C211/00C07C213/00C07C215/00C07C217/00C07C221/00
    • C07C213/06C07C213/08C11D1/40C11D1/42C11D1/44C11D1/62C11D1/645C11D1/72C11D1/74C11D1/835C07C219/06
    • A softener composition, which contains tri-long-chain alkyl quaternary ammonium salt that has been considered to be difficult to use as a softener base agent, and which can provide a softener composition that provides a sufficient softening performance, is provided with (A) a cationic surfactant comprising at least one selected from the group consisting of quaternary ammonium salts represented by the formulae (I), (II) or (III), wherein the ratio of quaternary ammonium salt represented by the formula (I) to the total amount of these salts exceeds 50 weight %, with the ratio thereof represented by (III) being set to not more than 10%, and (B) at least one nonionic surfactant. In this case, (A) may include tertiary amine. (wherein, R1, R2 and R3 represent long-chain alkyl groups, etc. having total carbon atoms of 8 to 40, which may be intersected by an ether group, an ester group or an amide group; R4 represents an alkyl group, etc. having carbon atoms of 1 to 6, and X− represents an anionic group.)
    • (A)提供了一种软化剂组合物,其含有被认为难以用作软化剂基剂的三长链烷基季铵盐,并且可以提供提供足够的软化性能的柔软剂组合物, 包含选自由式(I),(II)或(III)表示的季铵盐中的至少一种的阳离子表面活性剂,其中由式(I)表示的季铵盐与总计 的这些盐超过50重量%,其由(III)表示的比例设定为不超过10%,和(B)至少一种非离子表面活性剂。 在这种情况下,(A)可以包括叔胺。 (其中,R 1,R 2,R 3和R 3代表总碳原子数为8〜40的长链烷基等, 其可以被醚基,酯基或酰胺基相交; R 4表示具有1至6个碳原子的烷基等,而X-O >表示阴离子基团。)
    • 6. 发明申请
    • Softener composition
    • 软化剂组成
    • US20050107634A1
    • 2005-05-19
    • US10967176
    • 2004-10-19
    • Yasuki OhtawaTakeshi TomifujiAkira SakaguchiTohru Katoh
    • Yasuki OhtawaTakeshi TomifujiAkira SakaguchiTohru Katoh
    • C11D1/40C11D1/42C11D1/44C11D1/62C11D1/645C11D1/72C11D1/74C11D1/835C07C211/62
    • C07C213/06C07C213/08C11D1/40C11D1/42C11D1/44C11D1/62C11D1/645C11D1/72C11D1/74C11D1/835C07C219/06
    • A softener composition, which contains tri-long-chain alkyl quaternary ammonium salt that has been considered to be difficult to use as a softener base agent, and which can provide a softener composition that provides a sufficient softening performance, is provided with (A) a cationic surfactant comprising at least one selected from the group consisting of quaternary ammonium salts represented by the formulae (I), (II) or (III), wherein the ratio of quaternary ammonium salt represented by the formula (I) to the total amount of these salts exceeds 50 weight %, with the ratio thereof represented by (III) being set to not more than 10%, and (B) at least one nonionic surfactant. In this case, (A) may include tertiary amine. (wherein, R1, R2 and R3 represent long-chain alkyl groups, etc. having total carbon atoms of 8 to 40, which may be intersected by an ether group, an ester group or an amide group; R4 represents an alkyl group, etc. having carbon atoms of 1 to 6, and X− represents an anionic group.)
    • (A)提供了一种软化剂组合物,其含有被认为难以用作软化剂基剂的三长链烷基季铵盐,并且可以提供提供足够的软化性能的柔软剂组合物, 包含选自由式(I),(II)或(III)表示的季铵盐中的至少一种的阳离子表面活性剂,其中由式(I)表示的季铵盐与总计 的这些盐超过50重量%,其由(III)表示的比例设定为不超过10%,和(B)至少一种非离子表面活性剂。 在这种情况下,(A)可以包括叔胺。 (其中,R 1,R 2,R 3和R 3代表总碳原子数为8〜40的长链烷基等, 其可以被醚基,酯基或酰胺基相交; R 4表示具有1至6个碳原子的烷基等,X 0〜 >表示阴离子基团。)
    • 10. 发明授权
    • Toner for electrophotography
    • 电子照相用碳粉
    • US08227160B2
    • 2012-07-24
    • US12445549
    • 2007-10-16
    • Yasuhiro HidakaKouhei KatayamaYasuki Ohtawa
    • Yasuhiro HidakaKouhei KatayamaYasuki Ohtawa
    • G03G9/00
    • G03G9/08755G03G9/091G03G9/09783
    • A toner for electrophotography comprising a charge control agent comprising a specified iron-azo complex or a specified metal compound of a benzilic acid derivative, a colorant, and a resin binder comprising a polyester, the polyester being a polyester obtained by polycondensing an alcohol component containing a propylene oxide adduct of bisphenol A and a carboxylic acid component, wherein the propylene oxide adduct of bisphenol A has an average mole of propylene oxide added of from 2.4 to 4.0, and wherein an adduct with 2 mol of propylene oxide is contained in an amount of 60% by mol or less, and an adduct with 4 mol of propylene oxide is contained in an amount of 10% by mol or more, of the propylene oxide adduct of bisphenol A, and wherein the propylene oxide adduct of bisphenol A has a content ratio of primary hydroxyl groups of 10% by mol or less of the entire hydroxyl groups. The toner for electrophotography of the present invention is suitably used in developing latent images and the like formed in electrophotography, electrostatic recording method, electrostatic printing method or the like.
    • 一种用于电子照相的调色剂,其包含电荷控制剂,其包含特定的铁偶氮络合物或特定的苯乙烯酸衍生物金属化合物,着色剂和包含聚酯的树脂粘合剂,所述聚酯是通过将含有 双酚A和羧酸组分的环氧丙烷加成物,其中双酚A的环氧丙烷加合物的平均环氧丙烷加成摩尔数为2.4-4.0,其中与环氧丙烷的摩尔数相同,加入量为2摩尔。 为60摩尔%以下,与双酚A的环氧丙烷加合物相比,含有4摩尔环氧丙烷的加合物的含量为10摩尔%以上,双酚A的环氧丙烷加合物为 伯羟基的含量比例为全部羟基的10摩尔%以下。 本发明的电子照相用调色剂适用于在电子照相,静电记录方法,静电印刷方法等中形成的显影潜像等中。