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1. 发明授权

US06908970B2 Process for producing hydrogenated product of cyclic olefin polymer prepared through ring-opening polymerization 有权
标题翻译：通过开环聚合制备环烯烃聚合物氢化产物的方法
公开(公告)号：US06908970B2
公开(公告)日：2005-06-21
申请号：US10265244
申请日：2002-10-07
申请人： Yasuo Tsunogae , Masato Sakamoto , Masaharu Tokoro , Kazunori Taguchi
发明人： Yasuo Tsunogae , Masato Sakamoto , Masaharu Tokoro , Kazunori Taguchi
IPC分类号： C08G61/08 , C08F8/04
CPC分类号： C08G61/08
摘要： A process for producing a hydrogenated product of a polymer prepared through ring-opening polymerization which comprises a polymerization step of polymerizing a cyclic olefin through ring-opening polymerization in the presence of a polymerization catalyst comprising an organoruthenium compound or an organoosmium compound to prepare a polymer, and a hydrogenation step of adding a hydrogenation catalyst and hydrogen into a polymerization system resulting from the polymerization step to hydrogenate the carbon-carbon double bonds of the polymer prepared through the ring-opening polymerization. When the organoruthenium compound- or organoosmium compound-containing catalyst further comprises a carbene compound, the catalyst exhibits a higher activity for the ring-opening polymerization.
摘要翻译：一种通过开环聚合制备的聚合物的氢化产物的制备方法，该方法包括在包含有机钌化合物或有机锇化合物的聚合催化剂存在下，通过开环聚合使环烯烃聚合的聚合步骤，以制备聚合物以及将氢化催化剂和氢气加入到由聚合步骤得到的聚合体系中氢化通过开环聚合制备的聚合物的碳 - 碳双键的氢化步骤。当含有机钌化合物或有机锇化合物的催化剂还包含卡宾化合物时，催化剂对开环聚合具有较高的活性。

2. 发明授权

US06486264B1 Process for producing hydrogenated ring-opening polymerization polymer of cycloolefin 有权
标题翻译：制备环烯烃氢化开环聚合聚合物的方法
公开(公告)号：US06486264B1
公开(公告)日：2002-11-26
申请号：US09980200
申请日：2001-11-30
申请人： Yasuo Tsunogae , Masato Sakamoto , Masaharu Tokoro , Kazunori Taguchi
发明人： Yasuo Tsunogae , Masato Sakamoto , Masaharu Tokoro , Kazunori Taguchi
IPC分类号： C08F804
CPC分类号： C08G61/08
摘要： A process for producing a hydrogenated product of a polymer prepared through ring-opening polymerization which comprises a polymerization step of polymerizing a cyclic olefin through ring-opening polymerization in the presence of a polymerization catalyst comprising an organoruthenium compound or an organoosmium compound to prepare a polymer, and a hydrogenation step of adding a hydrogenation catalyst and hydrogen into a polymerization system resulting from the polymerization step to hydrogenate the carbon-carbon double bonds of the polymer prepared through the ring-opening polymerization. When the organoruthenium compound- or organoosmium compound-containing catalyst further comprises a carbene compound, the catalyst exhibits a higher activity for the ring-opening polymerization.
摘要翻译：一种通过开环聚合制备的聚合物的氢化产物的制备方法，该方法包括在包含有机钌化合物或有机锇化合物的聚合催化剂存在下，通过开环聚合使环烯烃聚合的聚合步骤，以制备聚合物以及将氢化催化剂和氢气加入到由聚合步骤得到的聚合体系中氢化通过开环聚合制备的聚合物的碳 - 碳双键的氢化步骤。当含有机钌化合物或有机锇化合物的催化剂还包含卡宾化合物时，催化剂对开环聚合具有较高的活性。

3. 发明授权

US07084222B2 Ruthenium complexes, process for preparation thereof, and processes for producing open-ring polymer of cycloolefins and hydrogenation products thereof by using the complex as catalyst 失效
标题翻译：钌络合物，其制备方法以及通过使用络合物作为催化剂制备环烯烃的开环聚合物及其氢化产物的方法
公开(公告)号：US07084222B2
公开(公告)日：2006-08-01
申请号：US10489921
申请日：2002-09-19
申请人： Masato Sakamoto , Seiji Okada , Yasuo Tsunogae , Shintaro Ikeda , Wolfgang A. Herrmann , Karl Oefele
发明人： Masato Sakamoto , Seiji Okada , Yasuo Tsunogae , Shintaro Ikeda , Wolfgang A. Herrmann , Karl Oefele
IPC分类号： C08F4/80 , C07F15/00
CPC分类号： C07D239/04 , C07D233/02 , C07F15/0046 , C08G61/08
摘要： The present invention relates to ruthenium complex compound wherein a heteroatom-containing carbene compound having a six-membered ring structure is bonded to ruthenium and a process for the preparation thereof; a process for producing ring-opened cyclic olefin polymer by subjecting a cyclic olefin to ring-opening metathesis polymerization in the presence of such a ruthenium complex compound; and a process for producing hydrogenated product of ring-opened cyclic olefin polymers by hydrogenating the carbon-carbon double bonds of the above ring-opened polymers. The invention gives hydrogenated product of ring-opened cyclic olefin polymers having physical properties different from those of hydrogenated product of ring-opened polymers of the prior art. Particularly, the use of dicyclopentadiene can give a hydrogenated product of ring-opened cyclic olefin polymer excellent in heat resistance, and this product can be advantageously used as parts or formed products for medical appliances or electrical components.
摘要翻译：本发明涉及具有六元环结构的含杂原子的卡宾化合物与钌结合的钌络合物及其制备方法，在这种钌络合物的存在下，通过使环状烯烃进行开环易位聚合来制造开环式环烯烃聚合物的方法; 以及通过氢化上述开环聚合物的碳 - 碳双键来制备开环环烯烃聚合物的氢化产物的方法。本发明提供了具有与现有技术的开环聚合物的氢化产物不同的物理性质的开环环烯烃聚合物的氢化产物。特别地，二环戊二烯的使用可以得到耐热性优异的开环式环状烯烃聚合物的氢化物，该产品可有利地用作医疗器具或电子部件的部件或成形品。

4. 发明授权

US07037993B2 Norbornene-based ring-opening polymerization polymer, product of hydrogenation of norbornene-based ring-opening polymerization polymer, and processes for producing these 有权
标题翻译：基于降冰片烯的开环聚合聚合物，降冰片烯类开环聚合聚合物的氢化产物及其制备方法
公开(公告)号：US07037993B2
公开(公告)日：2006-05-02
申请号：US10510513
申请日：2003-04-07
申请人： Kazunori Taguchi , Seiji Okada , Yasuo Tsunogae
发明人： Kazunori Taguchi , Seiji Okada , Yasuo Tsunogae
IPC分类号： C08G61/06
CPC分类号： C08G61/08 , C08G61/06
摘要： A norbornene ring-opened polymer which in the molecule has repeating units represented by the formula (1): wherein R1 represents Q, R2 represents Q or C(═O)R5, R3 represents Q or C(═O)R6, and R4 represents Q or X—C(═O)R7 (wherein Q represents hydrogen, a C1-10 hydrocarbon group, etc.; R5, R6 and R7 each represents hydroxyl, C1-10 alkoxyl, etc., provided that R6 and R7 may be bonded to each other to constitute oxygen, NH, etc.; X represents methylene, etc., provided that when R2 is Q, then R3 is C(═O)R6 and R4 is X—C(═O)R7 and that when R4 is Q, then R2 is C(═O)R5, R3 is C(═O)R6, and the configuration of R2 and R3 is trans, and m is 0 or 1), the polymer having a weight-average molecular weight as determined by gel permeation chromatography of 1,000 to 1,000,000. Also provided is a hydrogenation product of the norbornene ring-opened polymer. The norbornene ring-opened polymer and the hydrogenation product are excellent in heat resistance, electrical properties, etc.
摘要翻译：分子中具有由式（1）表示的重复单元的降冰片烯开环聚合物：其中R 1表示Q，R 2表示Q或C（-O ）R 5，R 3表示Q或C（-O）R 6，R 4表示Q 或XC（-O）R 7（其中Q表示氢，C 1-10烃基等; R 5，R R 6和R 7各自表示羟基，C 1-10烷氧基等，条件是R 6和 R 7可以彼此键合以构成氧，NH等; X表示亚甲基等，条件是当R 2为Q时，则R 0 > 3 是C（-O）R 6和R 4是XC（-O）R 7，当R 4是Q，则R 2是C（-O）R 5，R 3是C（ - O）R 6，R 2和R 3的构型为反式，m为0或1），所述聚合物具有重量平均分子量 d通过凝胶渗透色谱法为1,000至1,000,000。还提供了降冰片烯开环聚合物的氢化产物。降冰片烯开环聚合物和氢化产物的耐热性，电性能等优异。

5. 发明授权

US06995226B2 Open-ring copolymer, hydrogenated open-ring copolymer, process for production of both, and compositions 有权
标题翻译：开环共聚物，氢化开环共聚物，二者的生产方法和组合物
公开(公告)号：US06995226B2
公开(公告)日：2006-02-07
申请号：US10480002
申请日：2002-06-05
申请人： Kazunori Taguchi , Yasuo Tsunogae , Hitomi Takeuchi , Yasuhiro Wakisaka , Kei Sakamoto
发明人： Kazunori Taguchi , Yasuo Tsunogae , Hitomi Takeuchi , Yasuhiro Wakisaka , Kei Sakamoto
IPC分类号： C08G61/08
CPC分类号： C08G61/06
摘要： A ring-opened metathesis copolymer and its hydrogenated product having a desired monomer unit ratio and a high molecular weight and having hydroxyl groups or hydroxycarbonyl groups can be obtained by conducting a ring-opening metathesis copolymerization of a norbornene-type monomer having hydroxyl groups or hydroxycarbonyl groups with an unsubstituted norbornene-type monomer having at least three rings in the presence of a catalyst predominantly comprised of an organic ruthenium compound having coordinated therewith a neutral electron-donating ligand, and, if desired, hydrogenating the resulting copolymer. The thus-obtained ring-opened metathesis copolymer and its hydrogenation product are characterized by having a low water absorption, good adhesion to metal and other materials, good compatibility with a curing agent and other compounds, and high heat resistance, and exhibiting reduced signal retardation and signal noise.
摘要翻译：通过进行具有羟基或羟基羰基的降冰片烯型单体的开环易位共聚，可以获得具有所需单体单元比和高分子量并具有羟基或羟基羰基的开环复分解共聚物及其氢化产物具有至少三个环的未取代的降冰片烯型单体的基团在主要由与其配位有中性给电子配体的有机钌化合物组成的催化剂的存在下进行，并且如果需要，氢化所得共聚物。由此获得的开环复分解共聚物及其氢化产物的特征在于具有低吸水性，对金属和其他材料的良好粘附性，与固化剂和其它化合物的良好相容性，以及高耐热性，并且表现出降低的信号延迟和信号噪声。

6. 发明申请

US20050148746A1 Norbornene-based ring-opening polymerization polymer, product of hydrogenation of norbornene-based ring-opening polymerization polymer, and processes for producing these 有权
标题翻译：基于降冰片烯的开环聚合聚合物，降冰片烯类开环聚合聚合物的氢化产物及其制备方法
公开(公告)号：US20050148746A1
公开(公告)日：2005-07-07
申请号：US10510513
申请日：2003-04-07
申请人： Kazunori Taguchi , Seiji Okada , Yasuo Tsunogae
发明人： Kazunori Taguchi , Seiji Okada , Yasuo Tsunogae
IPC分类号： C08G61/06 , C08G61/08 , C08F10/00
CPC分类号： C08G61/08 , C08G61/06
摘要： A norbornene ring-opened polymer which in the molecule has repeating units represented by the formula (1): wherein R1 represents Q, R2 represents Q or C(═O)R5, R3 represents Q or C(═O)R6, and R4 represents Q or X—C(═O)R7 (wherein Q represents hydrogen, a C1-10 hydrocarbon group, etc.; R5, R6 and R7 each represents hydroxyl, C1-10 alkoxyl, etc., provided that R6 and R7 may be bonded to each other to constitute oxygen, NH, etc.; X represents methylene, etc., provided that when R2 is Q, then R3 is C(═O)R6 and R4 is X—C(═O)R7 and that when R4 is Q, then R2 is C(═O)R5, R3 is C(═O)R6, and the configuration of R2 and R3 is trans, and m is 0 or 1), the polymer having a weight-average molecular weight as determined by gel permeation chromatography of 1,000 to 1,000,000. Also provided is a hydrogenation product of the norbornene ring-opened polymer. The norbornene ring-opened polymer and the hydrogenation product are excellent in heat resistance, electrical properties, etc.
摘要翻译：分子中具有由式（1）表示的重复单元的降冰片烯开环聚合物：其中R 1表示Q，R 2表示Q或C（-O ）R 5，R 3表示Q或C（-O）R 6，R 4表示Q 或XC（-O）R 7（其中Q表示氢，C 1-10烃基等; R 5，R R 6和R 7各自表示羟基，C 1-10烷氧基等，条件是R 6和 R 7可以彼此键合以构成氧，NH等; X表示亚甲基等，条件是当R 2为Q时，则R 0 > 3 是C（-O）R 6和R 4是XC（-O）R 7，当R 4是Q，则R 2是C（-O）R 5，R 3是C（ - O）R 6，R 2和R 3的构型为反式，m为0或1），所述聚合物具有重量平均分子量 d通过凝胶渗透色谱法为1,000至1,000,000。还提供了降冰片烯开环聚合物的氢化产物。降冰片烯开环聚合物和氢化产物的耐热性，电性能等优异。

7. 发明申请

US20050014916A1 Ruthenium complexes, process for preparation thereof, and processes for producing open-ring polymer of cycloolefins and hydrogenation products thereof by using the complex as catalyst 失效
标题翻译：钌络合物，其制备方法以及通过使用络合物作为催化剂制备环烯烃的开环聚合物及其氢化产物的方法
公开(公告)号：US20050014916A1
公开(公告)日：2005-01-20
申请号：US10489921
申请日：2002-09-19
申请人： Masato Sakamoto , Seiji Okada , Yasuo Tsunogae , Shintaro Ikeda , Wolfgang Herrmann , Karl Oefele
发明人： Masato Sakamoto , Seiji Okada , Yasuo Tsunogae , Shintaro Ikeda , Wolfgang Herrmann , Karl Oefele
IPC分类号： C07D233/02 , C07D239/04 , C07F15/00 , C08F4/06 , C08G61/08
CPC分类号： C07D239/04 , C07D233/02 , C07F15/0046 , C08G61/08
摘要： The present invention relates to ruthenium complex compound wherein a heteroatom-containing carbene compound having a six-membered ring structure is bonded to ruthenium and a process for the preparation thereof; a process for producing ring-opened cyclic olefin polymer by subjecting a cyclic olefin to ring-opening metathesis polymerization in the presence of such a ruthenium complex compound; and a process for producing hydrogenated product of ring-opened cyclic olefin polymers by hydrogenating the carbon-carbon double bonds of the above ring-opened polymers. The invention gives hydrogenated product of ring-opened cyclic olefin polymers having physical properties different from those of hydrogenated product of ring-opened polymers of the prior art. Particularly, the use of dicyclopentadiene can give a hydrogenated product of ring-opened cyclic olefin polymer excellent in heat resistance, and this product can be advantageously used as parts or formed products for medical appliances or electrical components.
摘要翻译：本发明涉及具有六元环结构的含杂原子的卡宾化合物与钌结合的钌络合物及其制备方法，在这种钌络合物的存在下，通过使环状烯烃进行开环易位聚合来制造开环式环烯烃聚合物的方法; 以及通过氢化上述开环聚合物的碳 - 碳双键来制备开环环烯烃聚合物的氢化产物的方法。本发明提供了具有与现有技术的开环聚合物的氢化产物不同的物理性质的开环环烯烃聚合物的氢化产物。特别地，二环戊二烯的使用可以得到耐热性优异的开环式环状烯烃聚合物的氢化物，该产品可有利地用作医疗器具或电子部件的部件或成形品。

8. 发明授权

US06815516B2 Copolymer formed by ring-opening polymerization, product of hydrogenation of copolymer formed by ring-opening polymerization, and process for producing these 有权
标题翻译：通过开环聚合形成的共聚物，通过开环聚合形成的共聚物的氢化产物及其制备方法
公开(公告)号：US06815516B2
公开(公告)日：2004-11-09
申请号：US10148956
申请日：2002-06-07
申请人： Masato Sakamoto , Yasuo Tsunogae
发明人： Masato Sakamoto , Yasuo Tsunogae
IPC分类号： C08F23208
CPC分类号： C08G61/06
摘要： A ring-opened metathesis copolymer formed by the ring-opening metathesis copolymerization of a cycloolefin monomer having a carboxylic anhydride group selected from bicycloheptene derivatives, tetracyclododecene derivatives and hexacycloheptadecene derivatives with a cycloolefin monomer selected from bicycloheptene derivatives, tetracycloheptene derivatives and hexacycloheptene derivatives; and a hydrogenation product of the copolymer. This copolymer is produced by using a polymerization catalyst comprises an organoruthenium compound having a heterocyclic carbene compound as a ligand. The ring-opened metathesis copolymer and the hydrogenation product thereof have a low dielectric constant, a low water absorption, a high adhesion to metals and a high heat resistance.
摘要翻译：通过选自双环庚烯衍生物，四环十二碳烯衍生物和六环十七碳烯衍生物的具有羧酸酐基团的环烯烃单体与选自双环庚烯衍生物，四环庚烯衍生物和六环己烯衍生物的环烯烃单体的开环易位共聚形成的开环复分解共聚物; 和共聚物的氢化产物。该共聚物通过使用包含具有杂环卡宾化合物作为配体的有机钌化合物的聚合催化剂制备。开环复分解共聚物及其氢化产物具有低介电常数，低吸水率，对金属的高粘附性和高耐热性。

9. 发明授权

US06653424B1 Norbornene open-ring polymers, products of hydrogenation thereof and processes for the production of both 有权
标题翻译：降冰片烯开环聚合物，其氢化产物和两者的生产方法
公开(公告)号：US06653424B1
公开(公告)日：2003-11-25
申请号：US10049648
申请日：2002-02-25
申请人： Masato Sakamoto , Daisuke Uchida , Yasuo Tsunogae , Hiroshi Kurakata
发明人： Masato Sakamoto , Daisuke Uchida , Yasuo Tsunogae , Hiroshi Kurakata
IPC分类号： C08F3208
CPC分类号： C08G61/08
摘要： Using a polymerization catalyst comprising as a main ingredient a metal compound containing a transition metal of group 6 of the periodic table and having at least one imide group and at least two substituent (A) selected from the group consisting of an alkoxy group, an aryloxy group, an alkylamide group and an arylamide group, a polycyclic norbornene monomer is polymerized to give a ring-opened norbornene polymer having a weight average molecular weight of 500 to 1,000,000 as expressed in terms of polystyrene and a melting point of 140° C. or higher. This polymer is hydrogenated to give a hydrogenated product having a melting point of 140° C. or higher.
摘要翻译：使用包含作为主要成分的含有元素周期表第6族过渡金属并具有至少一个酰亚胺基团的金属化合物和至少两个选自烷氧基，芳氧基基团，烷基酰胺基和芳基酰胺基，多环降冰片烯单体聚合得到如聚苯乙烯和熔点为140℃表示的重均分子量为500至1,000,000的开环降冰片烯聚合物，或更高。将该聚合物氢化，得到熔点为140℃以上的氢化物。

10. 发明申请

US20140005338A1 POLYMERIZABLE COMPOSITION, RESIN SHAPED ARTICLE, AND LAMINATE 审中-公开
标题翻译：可聚合组合物，树脂形状和层压材料
公开(公告)号：US20140005338A1
公开(公告)日：2014-01-02
申请号：US14003504
申请日：2012-03-08
申请人： Akihiko Yoshiwara , Yasuo Tsunogae
发明人： Akihiko Yoshiwara , Yasuo Tsunogae
IPC分类号： C08F232/08
CPC分类号： C08F232/08 , C08G61/08 , C08G2261/3325 , C08G2261/418
摘要： A polymerizable composition which contains a cycloolefin monomer and a ruthenium carbene complex which is expressed by the following general formula (I): (in which general formula (I), R1 and R2 respectively independently represent a hydrogen atom, halogen atom, or cyclic or chain C1 to C20 hydrocarbon group which may contain a halogen atom, oxygen atom, nitrogen atom, sulfur atom, phosphorus atom, or silicon atom; X1 and X2 respectively independently represent an anionic ligand; L1 and L2 respectively independently represent a neutral electron donor ligand; L2 is a group with a higher three-dimensionally bulk than L1, where L1 and L2 are at cis positions with each other; R1 and R2 may bond with each other to form an aliphatic ring or aromatic ring which may contain a hetero atom; and R1, R2, X1, X2, L1, and L2 may bond with each other in any combination to form a multidentate chelating ligand).
摘要翻译：含有由以下通式（I）表示的环烯烃单体和钌卡宾络合物的可聚合组合物（其中通式（I），R 1和R 2分别独立地表示氢原子，卤素原子或环状或可以含有卤素原子，氧原子，氮原子，硫原子，磷原子或硅原子的C1〜C20烃链; X1和X2分别独立地表示阴离子配体; L1和L2分别独立地表示中性给电子体配体 ; L2是具有比L1更高的三维体积的基团，其中L1和L2彼此是顺式位置; R1和R2可以彼此键合以形成可以含有杂原子的脂族环或芳香环; 并且R1，R2，X1，X2，L1和L2可以以任何组合彼此键合形成多齿螯合配体）。

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