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1. 发明授权

US06995226B2 Open-ring copolymer, hydrogenated open-ring copolymer, process for production of both, and compositions 有权
标题翻译：开环共聚物，氢化开环共聚物，二者的生产方法和组合物
公开(公告)号：US06995226B2
公开(公告)日：2006-02-07
申请号：US10480002
申请日：2002-06-05
申请人： Kazunori Taguchi , Yasuo Tsunogae , Hitomi Takeuchi , Yasuhiro Wakisaka , Kei Sakamoto
发明人： Kazunori Taguchi , Yasuo Tsunogae , Hitomi Takeuchi , Yasuhiro Wakisaka , Kei Sakamoto
IPC分类号： C08G61/08
CPC分类号： C08G61/06
摘要： A ring-opened metathesis copolymer and its hydrogenated product having a desired monomer unit ratio and a high molecular weight and having hydroxyl groups or hydroxycarbonyl groups can be obtained by conducting a ring-opening metathesis copolymerization of a norbornene-type monomer having hydroxyl groups or hydroxycarbonyl groups with an unsubstituted norbornene-type monomer having at least three rings in the presence of a catalyst predominantly comprised of an organic ruthenium compound having coordinated therewith a neutral electron-donating ligand, and, if desired, hydrogenating the resulting copolymer. The thus-obtained ring-opened metathesis copolymer and its hydrogenation product are characterized by having a low water absorption, good adhesion to metal and other materials, good compatibility with a curing agent and other compounds, and high heat resistance, and exhibiting reduced signal retardation and signal noise.
摘要翻译：通过进行具有羟基或羟基羰基的降冰片烯型单体的开环易位共聚，可以获得具有所需单体单元比和高分子量并具有羟基或羟基羰基的开环复分解共聚物及其氢化产物具有至少三个环的未取代的降冰片烯型单体的基团在主要由与其配位有中性给电子配体的有机钌化合物组成的催化剂的存在下进行，并且如果需要，氢化所得共聚物。由此获得的开环复分解共聚物及其氢化产物的特征在于具有低吸水性，对金属和其他材料的良好粘附性，与固化剂和其它化合物的良好相容性，以及高耐热性，并且表现出降低的信号延迟和信号噪声。

2. 发明授权

US06908970B2 Process for producing hydrogenated product of cyclic olefin polymer prepared through ring-opening polymerization 有权
标题翻译：通过开环聚合制备环烯烃聚合物氢化产物的方法
公开(公告)号：US06908970B2
公开(公告)日：2005-06-21
申请号：US10265244
申请日：2002-10-07
申请人： Yasuo Tsunogae , Masato Sakamoto , Masaharu Tokoro , Kazunori Taguchi
发明人： Yasuo Tsunogae , Masato Sakamoto , Masaharu Tokoro , Kazunori Taguchi
IPC分类号： C08G61/08 , C08F8/04
CPC分类号： C08G61/08
摘要： A process for producing a hydrogenated product of a polymer prepared through ring-opening polymerization which comprises a polymerization step of polymerizing a cyclic olefin through ring-opening polymerization in the presence of a polymerization catalyst comprising an organoruthenium compound or an organoosmium compound to prepare a polymer, and a hydrogenation step of adding a hydrogenation catalyst and hydrogen into a polymerization system resulting from the polymerization step to hydrogenate the carbon-carbon double bonds of the polymer prepared through the ring-opening polymerization. When the organoruthenium compound- or organoosmium compound-containing catalyst further comprises a carbene compound, the catalyst exhibits a higher activity for the ring-opening polymerization.
摘要翻译：一种通过开环聚合制备的聚合物的氢化产物的制备方法，该方法包括在包含有机钌化合物或有机锇化合物的聚合催化剂存在下，通过开环聚合使环烯烃聚合的聚合步骤，以制备聚合物以及将氢化催化剂和氢气加入到由聚合步骤得到的聚合体系中氢化通过开环聚合制备的聚合物的碳 - 碳双键的氢化步骤。当含有机钌化合物或有机锇化合物的催化剂还包含卡宾化合物时，催化剂对开环聚合具有较高的活性。

3. 发明授权

US07037993B2 Norbornene-based ring-opening polymerization polymer, product of hydrogenation of norbornene-based ring-opening polymerization polymer, and processes for producing these 有权
标题翻译：基于降冰片烯的开环聚合聚合物，降冰片烯类开环聚合聚合物的氢化产物及其制备方法
公开(公告)号：US07037993B2
公开(公告)日：2006-05-02
申请号：US10510513
申请日：2003-04-07
申请人： Kazunori Taguchi , Seiji Okada , Yasuo Tsunogae
发明人： Kazunori Taguchi , Seiji Okada , Yasuo Tsunogae
IPC分类号： C08G61/06
CPC分类号： C08G61/08 , C08G61/06
摘要： A norbornene ring-opened polymer which in the molecule has repeating units represented by the formula (1): wherein R1 represents Q, R2 represents Q or C(═O)R5, R3 represents Q or C(═O)R6, and R4 represents Q or X—C(═O)R7 (wherein Q represents hydrogen, a C1-10 hydrocarbon group, etc.; R5, R6 and R7 each represents hydroxyl, C1-10 alkoxyl, etc., provided that R6 and R7 may be bonded to each other to constitute oxygen, NH, etc.; X represents methylene, etc., provided that when R2 is Q, then R3 is C(═O)R6 and R4 is X—C(═O)R7 and that when R4 is Q, then R2 is C(═O)R5, R3 is C(═O)R6, and the configuration of R2 and R3 is trans, and m is 0 or 1), the polymer having a weight-average molecular weight as determined by gel permeation chromatography of 1,000 to 1,000,000. Also provided is a hydrogenation product of the norbornene ring-opened polymer. The norbornene ring-opened polymer and the hydrogenation product are excellent in heat resistance, electrical properties, etc.
摘要翻译：分子中具有由式（1）表示的重复单元的降冰片烯开环聚合物：其中R 1表示Q，R 2表示Q或C（-O ）R 5，R 3表示Q或C（-O）R 6，R 4表示Q 或XC（-O）R 7（其中Q表示氢，C 1-10烃基等; R 5，R R 6和R 7各自表示羟基，C 1-10烷氧基等，条件是R 6和 R 7可以彼此键合以构成氧，NH等; X表示亚甲基等，条件是当R 2为Q时，则R 0 > 3 是C（-O）R 6和R 4是XC（-O）R 7，当R 4是Q，则R 2是C（-O）R 5，R 3是C（ - O）R 6，R 2和R 3的构型为反式，m为0或1），所述聚合物具有重量平均分子量 d通过凝胶渗透色谱法为1,000至1,000,000。还提供了降冰片烯开环聚合物的氢化产物。降冰片烯开环聚合物和氢化产物的耐热性，电性能等优异。

4. 发明申请

US20050148746A1 Norbornene-based ring-opening polymerization polymer, product of hydrogenation of norbornene-based ring-opening polymerization polymer, and processes for producing these 有权
标题翻译：基于降冰片烯的开环聚合聚合物，降冰片烯类开环聚合聚合物的氢化产物及其制备方法
公开(公告)号：US20050148746A1
公开(公告)日：2005-07-07
申请号：US10510513
申请日：2003-04-07
申请人： Kazunori Taguchi , Seiji Okada , Yasuo Tsunogae
发明人： Kazunori Taguchi , Seiji Okada , Yasuo Tsunogae
IPC分类号： C08G61/06 , C08G61/08 , C08F10/00
CPC分类号： C08G61/08 , C08G61/06
摘要： A norbornene ring-opened polymer which in the molecule has repeating units represented by the formula (1): wherein R1 represents Q, R2 represents Q or C(═O)R5, R3 represents Q or C(═O)R6, and R4 represents Q or X—C(═O)R7 (wherein Q represents hydrogen, a C1-10 hydrocarbon group, etc.; R5, R6 and R7 each represents hydroxyl, C1-10 alkoxyl, etc., provided that R6 and R7 may be bonded to each other to constitute oxygen, NH, etc.; X represents methylene, etc., provided that when R2 is Q, then R3 is C(═O)R6 and R4 is X—C(═O)R7 and that when R4 is Q, then R2 is C(═O)R5, R3 is C(═O)R6, and the configuration of R2 and R3 is trans, and m is 0 or 1), the polymer having a weight-average molecular weight as determined by gel permeation chromatography of 1,000 to 1,000,000. Also provided is a hydrogenation product of the norbornene ring-opened polymer. The norbornene ring-opened polymer and the hydrogenation product are excellent in heat resistance, electrical properties, etc.
摘要翻译：分子中具有由式（1）表示的重复单元的降冰片烯开环聚合物：其中R 1表示Q，R 2表示Q或C（-O ）R 5，R 3表示Q或C（-O）R 6，R 4表示Q 或XC（-O）R 7（其中Q表示氢，C 1-10烃基等; R 5，R R 6和R 7各自表示羟基，C 1-10烷氧基等，条件是R 6和 R 7可以彼此键合以构成氧，NH等; X表示亚甲基等，条件是当R 2为Q时，则R 0 > 3 是C（-O）R 6和R 4是XC（-O）R 7，当R 4是Q，则R 2是C（-O）R 5，R 3是C（ - O）R 6，R 2和R 3的构型为反式，m为0或1），所述聚合物具有重量平均分子量 d通过凝胶渗透色谱法为1,000至1,000,000。还提供了降冰片烯开环聚合物的氢化产物。降冰片烯开环聚合物和氢化产物的耐热性，电性能等优异。

5. 发明授权

US06486264B1 Process for producing hydrogenated ring-opening polymerization polymer of cycloolefin 有权
标题翻译：制备环烯烃氢化开环聚合聚合物的方法
公开(公告)号：US06486264B1
公开(公告)日：2002-11-26
申请号：US09980200
申请日：2001-11-30
申请人： Yasuo Tsunogae , Masato Sakamoto , Masaharu Tokoro , Kazunori Taguchi
发明人： Yasuo Tsunogae , Masato Sakamoto , Masaharu Tokoro , Kazunori Taguchi
IPC分类号： C08F804
CPC分类号： C08G61/08
摘要： A process for producing a hydrogenated product of a polymer prepared through ring-opening polymerization which comprises a polymerization step of polymerizing a cyclic olefin through ring-opening polymerization in the presence of a polymerization catalyst comprising an organoruthenium compound or an organoosmium compound to prepare a polymer, and a hydrogenation step of adding a hydrogenation catalyst and hydrogen into a polymerization system resulting from the polymerization step to hydrogenate the carbon-carbon double bonds of the polymer prepared through the ring-opening polymerization. When the organoruthenium compound- or organoosmium compound-containing catalyst further comprises a carbene compound, the catalyst exhibits a higher activity for the ring-opening polymerization.
摘要翻译：一种通过开环聚合制备的聚合物的氢化产物的制备方法，该方法包括在包含有机钌化合物或有机锇化合物的聚合催化剂存在下，通过开环聚合使环烯烃聚合的聚合步骤，以制备聚合物以及将氢化催化剂和氢气加入到由聚合步骤得到的聚合体系中氢化通过开环聚合制备的聚合物的碳 - 碳双键的氢化步骤。当含有机钌化合物或有机锇化合物的催化剂还包含卡宾化合物时，催化剂对开环聚合具有较高的活性。

6. 发明申请

US20140005338A1 POLYMERIZABLE COMPOSITION, RESIN SHAPED ARTICLE, AND LAMINATE 审中-公开
标题翻译：可聚合组合物，树脂形状和层压材料
公开(公告)号：US20140005338A1
公开(公告)日：2014-01-02
申请号：US14003504
申请日：2012-03-08
申请人： Akihiko Yoshiwara , Yasuo Tsunogae
发明人： Akihiko Yoshiwara , Yasuo Tsunogae
IPC分类号： C08F232/08
CPC分类号： C08F232/08 , C08G61/08 , C08G2261/3325 , C08G2261/418
摘要： A polymerizable composition which contains a cycloolefin monomer and a ruthenium carbene complex which is expressed by the following general formula (I): (in which general formula (I), R1 and R2 respectively independently represent a hydrogen atom, halogen atom, or cyclic or chain C1 to C20 hydrocarbon group which may contain a halogen atom, oxygen atom, nitrogen atom, sulfur atom, phosphorus atom, or silicon atom; X1 and X2 respectively independently represent an anionic ligand; L1 and L2 respectively independently represent a neutral electron donor ligand; L2 is a group with a higher three-dimensionally bulk than L1, where L1 and L2 are at cis positions with each other; R1 and R2 may bond with each other to form an aliphatic ring or aromatic ring which may contain a hetero atom; and R1, R2, X1, X2, L1, and L2 may bond with each other in any combination to form a multidentate chelating ligand).
摘要翻译：含有由以下通式（I）表示的环烯烃单体和钌卡宾络合物的可聚合组合物（其中通式（I），R 1和R 2分别独立地表示氢原子，卤素原子或环状或可以含有卤素原子，氧原子，氮原子，硫原子，磷原子或硅原子的C1〜C20烃链; X1和X2分别独立地表示阴离子配体; L1和L2分别独立地表示中性给电子体配体 ; L2是具有比L1更高的三维体积的基团，其中L1和L2彼此是顺式位置; R1和R2可以彼此键合以形成可以含有杂原子的脂族环或芳香环; 并且R1，R2，X1，X2，L1和L2可以以任何组合彼此键合形成多齿螯合配体）。

7. 发明申请

US20090221750A1 Thermoplastic Resin, Method for Producing Same and Molding Material 审中-公开
标题翻译：热塑性树脂，其制造方法和成型材料
公开(公告)号：US20090221750A1
公开(公告)日：2009-09-03
申请号：US11886727
申请日：2006-03-20
申请人： Yasuo Tsunogae , Shigetaka Hayano , Atsushi Ishiguro
发明人： Yasuo Tsunogae , Shigetaka Hayano , Atsushi Ishiguro
IPC分类号： C08L51/06 , C08L53/00
CPC分类号： C08G81/021 , C08G61/06 , C08G61/08
摘要： A thermoplastic resin comprising a block copolymer or a graft copolymer possessing (A) a crystalline hydrogenated norbornene ring-opening polymer unit and (B) a non-crystalline polymer unit having a glass transition temperature of 40 to 300° C.; A method for producing thermoplastic resin comprising hydrogenating a block copolymer or a graft copolymer possessing a norbornene ring-opening polymer unit (C) and a polymer unit (D) which is converted into the above-mentioned non-crystalline polymer unit (B) after hydrogenation, in the presence of a hydrogenation catalyst; and a molding material comprising the thermoplastic resin are provided. The thermoplastic resin of the present invention excels in transparency, heat resistance, and mechanical strength.
摘要翻译：包含具有（A）结晶氢化降冰片烯开环聚合物单元的嵌段共聚物或接枝共聚物的热塑性树脂和（B）玻璃化转变温度为40〜300℃的非结晶性聚合物单元。一种制备热塑性树脂的方法，包括将具有降冰片烯开环聚合物单元（C）的嵌段共聚物或接枝共聚物和聚合物单元（D）氢化，所述聚合物单元（D）经过转化成上述非晶态聚合物单元（B）在氢化催化剂的存在下进行氢化; 并且提供包含热塑性树脂的成型材料。本发明的热塑性树脂的透明性，耐热性和机械强度优异。

8. 发明申请

US20090124769A1 Process for producing cycloolefin addition polymer, catalyst for addition polymerization of cycloolefin, and transition metal compound 有权
标题翻译：环烯加成聚合物的制造方法，环烯烃的加成聚合用催化剂和过渡金属化合物
公开(公告)号：US20090124769A1
公开(公告)日：2009-05-14
申请号：US12073704
申请日：2008-03-07
申请人： Kei Nishii , Sigetaka Hayano , Yasuo Tsunogae
发明人： Kei Nishii , Sigetaka Hayano , Yasuo Tsunogae
IPC分类号： C08F4/42 , C07F17/00 , C08F4/52
CPC分类号： C07F7/28 , C08F4/65912 , C08F4/6592 , C08F210/02 , Y10S526/943 , C08F232/00
摘要： A process for producing a cycloolefin addition polymer comprising addition-polymerizing a cycloolefin in the presence of a catalyst comprising a combination of a specific transition metal compound of Group 4 of the Periodic Table, with an organoaluminum oxy compound, and/or a compound capable of reacting with the Group 4 transition metal compound to form an ion pair. The specific group 4 transition metal compound preferably has a structure such that the group 4 transition metal is bonded to a cyclopentadienyl ring in an η1 mode. The above-mentioned catalyst exhibits high activity for both of addition homopolymerization of a cycloolefin and addition copolymerization of a cycloolefin with an α-olefin.
摘要翻译：一种制备环烯加成聚合物的方法，包括在包含周期表第4族的特定过渡金属化合物与有机铝氧化合物的组合的催化剂存在下，将环烯加成聚合，和/或能够与第4族过渡金属化合物反应形成离子对。特别的第4族过渡金属化合物优选具有使第4族过渡金属以eta1模式键合到环戊二烯基环上的结构。上述催化剂对于环烯烃的加成均聚和环烯烃与α-烯烃的加成共聚均显示出高活性。

9. 发明授权

US06713154B1 Insulating material containing cycloolefin polymer 失效
标题翻译：含环烯烃聚合物的绝缘材料
公开(公告)号：US06713154B1
公开(公告)日：2004-03-30
申请号：US09445310
申请日：1999-12-06
申请人： Yasuo Tsunogae , Yasuhiro Wakizaka , Junji Kodemura , Tohru Hosaka
发明人： Yasuo Tsunogae , Yasuhiro Wakizaka , Junji Kodemura , Tohru Hosaka
IPC分类号： B32B310
CPC分类号： B32B15/085 , B32B27/32 , B32B27/325 , B32B2307/204 , B32B2307/206 , B32B2307/306 , B32B2307/7265 , B32B2457/08 , H01B3/44 , H05K1/032 , Y10T428/24273 , Y10T428/24322 , Y10T428/3175
摘要： An insulating material comprising a cycloolefin polymer, specifically, an interlayer insulating material for a high-density assembly board having interlayer-connecting via holes at most 200 &mgr;m in diameter, comprising a cycloolefin polymer containing at least 50 mol % of a repeating unit derived from a cycloolefin monomer; a dry film formed from a curable resin composition comprising a polymer having a number average molecular weight within a range of 1,000 to 1,000,000 as measured by gel permeation chromatography, and a hardener; and a resin-attached metal foil obtained by forming a film of a cycloolefin polymer on one side of a metal foil. Laminates, multi-layer laminates and build-up multi-layer laminates making use of these materials, and production processes thereof.
摘要翻译：一种包含环烯烃聚合物的绝缘材料，特别是用于高密度组装板的层间绝缘材料，其具有直径最大为200μm的夹层连接通孔，其包含含有至少50mol％重复单元的环烯烃聚合物环烯烃单体; 由通过凝胶渗透色谱法测定的数均分子量在1,000〜1,000,000范围内的聚合物的固化性树脂组合物形成的干膜和硬化剂; 以及通过在金属箔的一面上形成环烯烃聚合物膜而获得的树脂附着金属箔。使用这些材料的层压板，多层层压板和堆积多层层压板及其制造方法。

10. 发明授权

US09045617B2 Ring-opening polymer of cyclopentene and method of production of same 有权
标题翻译：环戊烯的开环聚合物及其生产方法
公开(公告)号：US09045617B2
公开(公告)日：2015-06-02
申请号：US13521262
申请日：2011-01-14
申请人： Yasuo Tsunogae , Yoshihisa Takeyama
发明人： Yasuo Tsunogae , Yoshihisa Takeyama
IPC分类号： C08F232/04 , C08K3/04 , C08K3/36 , C08F4/78 , C08L7/00
CPC分类号： C08K3/04 , C08G2261/3321 , C08G2261/418 , C08K3/36 , C08L65/00
摘要： There is provided a ring-opening polymer of cyclopentene wherein a cis ratio of the cyclopentene-derived structural units is 30% or more, a weight average molecular weight (Mw) is 100,000 to 1,000,000, and a functional group containing a structure represented by the general formula (1) or (2) is included at an end of the polymer chain. —Y—H (1) (in the above general formula (1), Y represents an oxygen atom or a sulfur atom.) —NH-Q (2) (in the above general formula (2), Q represents a hydrogen atom or a hydrocarbon group or a silyl group which may have a substituent group.)
摘要翻译：提供环戊烯的开环聚合物，其中环戊烯衍生的结构单元的顺式比例为30％以上，重均分子量（Mw）为100,000〜1,000,000，以及含有由通式（1）或（2）包括在聚合物链的末端。 -Y-H（1）（在上述通式（1）中，Y表示氧原子或硫原子。）-NH-Q（2）（在上述通式（2）中，Q表示氢原子或可以具有取代基的烃基或甲硅烷基。）

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