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1. 发明授权

US08734999B2 Carbon nanotube forming substrate, carbon nanotube complex, energy device, method for manufacturing energy device, and apparatus including energy device 有权
标题翻译：碳纳米管形成基板，碳纳米管复合体，能量装置，能量装置的制造方法以及包括能量装置的装置
公开(公告)号：US08734999B2
公开(公告)日：2014-05-27
申请号：US13145310
申请日：2011-02-14
申请人： Takuma Asari , Hironori Kumagai , Shigeo Hayashi , Yasuhiro Hashimoto , Naoki Yoshikawa , Takashi Okada
发明人： Takuma Asari , Hironori Kumagai , Shigeo Hayashi , Yasuhiro Hashimoto , Naoki Yoshikawa , Takashi Okada
IPC分类号： H01M4/583 , H01M10/04 , H01M4/139 , B05D3/00 , H01G9/00 , B82Y40/00
CPC分类号： H01M4/133 , H01G11/36 , H01M4/1393 , H01M4/587 , H01M4/661 , H01M4/663 , H01M10/0525 , Y02E60/13 , Y10T29/417 , Y10T29/49108 , Y10T29/49115 , Y10T428/23993
摘要： Provided are a substrate on which carbon nanotubes each having one end connected to the substrate can be formed at a high synthetic rate and from which the carbon nanotubes are less likely to be peeled off. The substrate is a substrate for forming the carbon nanotubes and includes a buffer layer 13 formed on at least one of surfaces of a substrate main body 14 and containing aluminum atoms and fluorine atoms. The carbon nanotube complex includes the substrate and a plurality of carbon nanotubes 11 each having one end connected to a surface of the buffer layer 13.
摘要翻译：可以以高合成速度形成各自具有与基板连接的一端的碳纳米管的基板，并且碳纳米管不容易被剥离。基板是用于形成碳纳米管的基板，并且包括形成在基板主体14的至少一个表面上并且含有铝原子和氟原子的缓冲层13。碳纳米管复合体包括基板和多个碳纳米管11，每个碳纳米管11的一端连接到缓冲层13的表面。

2. 发明授权

US08277967B2 Energy device, method for manufacturing the same, and apparatus including the same 有权
标题翻译：能量装置及其制造方法以及包括该能量装置的装置
公开(公告)号：US08277967B2
公开(公告)日：2012-10-02
申请号：US12441504
申请日：2008-01-22
申请人： Takuma Asari , Toshiya Yokogawa , Shigeo Hayashi , Yasuhiro Hashimoto , Hironori Kumagai
发明人： Takuma Asari , Toshiya Yokogawa , Shigeo Hayashi , Yasuhiro Hashimoto , Hironori Kumagai
IPC分类号： H01M6/10
CPC分类号： H01M4/583 , H01G9/0029 , H01G11/26 , H01G11/36 , H01M4/0428 , H01M4/133 , H01M4/1393 , H01M4/587 , H01M4/62 , H01M4/661 , H01M4/667 , H01M10/0525 , H01M10/0587 , Y02E60/13 , Y10T29/49115
摘要： The present invention provides an energy device including a carbon nanotube electrode which prevents a carbon nanotube from peeling from an electric conductor. The energy device includes rolled electrode bodies, wherein at least one of the electrode bodies is formed such that a carbon nanotube layer is formed on the electric conductor, and concave regions are formed in a stripe shape on the carbon nanotube layer so as to extend in a direction parallel to a roll axis.
摘要翻译：本发明提供一种能量装置，其包括防止碳纳米管从导电体剥离的碳纳米管电极。能量器件包括卷绕的电极体，其中至少一个电极体形成为在导电体上形成碳纳米管层，并且在碳纳米管层上形成条形状的凹陷区域，以便在平行于辊轴的方向。

3. 发明申请

US20100086837A1 ENERGY DEVICE, METHOD FOR MANUFACTURING THE SAME, AND APPARATUS INCLUDING THE SAME 有权
标题翻译：能量装置，其制造方法以及包括其的装置
公开(公告)号：US20100086837A1
公开(公告)日：2010-04-08
申请号：US12441504
申请日：2008-01-22
申请人： Takuma Asari , Toshiya Yokogawa , Shigeo Hayashi , Yasuhiro Hashimoto , Hironori Kumagai
发明人： Takuma Asari , Toshiya Yokogawa , Shigeo Hayashi , Yasuhiro Hashimoto , Hironori Kumagai
IPC分类号： H01M6/10
CPC分类号： H01M4/583 , H01G9/0029 , H01G11/26 , H01G11/36 , H01M4/0428 , H01M4/133 , H01M4/1393 , H01M4/587 , H01M4/62 , H01M4/661 , H01M4/667 , H01M10/0525 , H01M10/0587 , Y02E60/13 , Y10T29/49115
摘要： The present invention provides an energy device including a carbon nanotube electrode which prevents a carbon nanotube from peeling from an electric conductor. The energy device includes rolled electrode bodies, wherein at least one of the electrode bodies is formed such that a carbon nanotube layer is formed on the electric conductor, and concave regions are formed in a stripe shape on the carbon nanotube layer so as to extend in a direction parallel to a roll axis.
摘要翻译：本发明提供一种能量装置，其包括防止碳纳米管从导电体剥离的碳纳米管电极。能量器件包括卷绕的电极体，其中至少一个电极体形成为在导电体上形成碳纳米管层，并且在碳纳米管层上形成条形状的凹陷区域，以便在平行于辊轴的方向。

4. 发明申请

US20090317597A1 NANOSTRUCTURE AND METHOD FOR MANUFACTURING THE SAME 有权
标题翻译：纳米结构及其制造方法
公开(公告)号：US20090317597A1
公开(公告)日：2009-12-24
申请号：US12520959
申请日：2008-01-16
申请人： Hironori Kumagai , Yasuhiro Hashimoto , Shigeo Hayashi , Takuma Asari , Toshiya Yokogawa
发明人： Hironori Kumagai , Yasuhiro Hashimoto , Shigeo Hayashi , Takuma Asari , Toshiya Yokogawa
IPC分类号： B32B3/00 , B05D3/02
CPC分类号： C25D11/02 , B01J23/745 , B01J23/8906 , B01J35/006 , B01J37/0226 , B01J37/0244 , B82Y30/00 , C25D11/04 , C25D11/045 , Y10T29/417 , Y10T29/49108 , Y10T29/49115 , Y10T428/1352 , Y10T428/2462
摘要： The present invention provides a nanostructure on an upper surface of which a small-diameter carbon nanotube (CNT) is formed and which improves an adhesive strength between a substrate and the CNT while controlling an orientation of the CNT, and a method for manufacturing the nanostructure. The nanostructure includes a substrate 101, a porous layer 102 formed on the substrate 101 to have a fine pore, a fine pore diameter control layer 103 formed on the porous layer 102, and a carbon nanotube 701 formed to extend from the fine pore defined by the fine pore diameter control layer 103, and one end of the carbon nanotube is fixed by the fine pore diameter control layer 103. It is preferable that the substrate 101 and the fine pore diameter control layer 103 be electrically conductive. It is preferable that the porous layer 102 be an anode oxide film. It is preferable that a melting point of the fine pore diameter control layer 103 be 600° C. or higher.
摘要翻译：本发明提供了在上表面上形成小直径碳纳米管（CNT）的纳米结构，并且在控制CNT的取向的同时改善了基板和CNT之间的粘合强度，以及纳米结构的制造方法。纳米结构包括基板101，形成在基板101上的具有细孔的多孔层102，形成在多孔层102上的细孔径控制层103和形成为从由多孔层102限定的细孔延伸的细孔微细孔径控制层103和碳纳米管的一端由细孔直径控制层103固定。优选的是，基板101和细孔直径控制层103是导电的。多孔层102优选为阳极氧化膜。优选细孔径控制层103的熔点为600℃以上。

5. 发明授权

US09362563B2 Energy storage device, method for manufacturing the same, and apparatus including the same 有权
标题翻译：储能装置及其制造方法以及包括该储能装置的装置
公开(公告)号：US09362563B2
公开(公告)日：2016-06-07
申请号：US12602934
申请日：2009-03-12
申请人： Takuma Asari , Hironori Kumagai , Shigeo Hayashi , Yasuhiro Hashimoto , Takahiro Kawashima
发明人： Takuma Asari , Hironori Kumagai , Shigeo Hayashi , Yasuhiro Hashimoto , Takahiro Kawashima
IPC分类号： H01M8/00 , H01M4/587 , H01G9/008 , H01G9/04 , H01G11/12 , H01G11/26 , H01G11/28 , H01G11/36 , H01G11/86 , H01M4/62 , H01M4/66 , H01M10/052
CPC分类号： H01M4/587 , H01G9/016 , H01G9/058 , H01G11/12 , H01G11/26 , H01G11/28 , H01G11/36 , H01G11/86 , H01M4/625 , H01M4/663 , H01M10/052 , Y02E60/13 , Y02T10/7011 , Y02T10/7022
摘要： The present invention provides a highly reliable energy storage device capable of preventing a reaction current from flowing in a carbon nanotube electrode by ionizing a catalyst metal or a substrate metal to cause the metal to flow out to an electrolytic solution. An energy storage device of the present invention includes: at least a pair of electrode bodies that are a cathode and an anode; and an electrolytic solution. At least one of the electrode bodies is configured such that a layer of carbon nanotubes is formed on an electric conductor. A coupling region where one ends of the carbon nanotubes are coupled to and electrically connected to the electric conductor and a non-coupling region where ends of the carbon nanotubes are not coupled to the electric conductor are formed on a surface of the electric conductor. The carbon nanotubes having one ends connected to the coupling region are toppled to cover a surface of the non-coupling region.
摘要翻译：本发明提供一种高可靠性的能量储存装置，其能够通过使催化剂金属或基板金属离子化而使反应电流流过碳纳米管电极，使金属流出至电解液。本发明的能量存储装置包括：至少一对电极体，其是阴极和阳极; 和电解液。至少一个电极体被配置为使得在导电体上形成碳纳米管层。在电导体的表面上形成有耦合区域，其中碳纳米管的一端耦合到电导体并且电连接到电导体，并且非耦合区域，其中碳纳米管的端部未联接到导电体。具有连接到耦合区域的一端的碳纳米管被推倒以覆盖非耦合区域的表面。

6. 发明授权

US09269504B2 Electrode, method for producing electrode, and energy device, electronic device, and transportation device including electrode 有权
标题翻译：电极，电极的制造方法以及能量装置，电子装置以及包括电极的输送装置
公开(公告)号：US09269504B2
公开(公告)日：2016-02-23
申请号：US14118154
申请日：2012-05-24
申请人： Yasuhiro Hashimoto , Takuma Asari , Shigeo Hayashi , Hironori Kumagai
发明人： Yasuhiro Hashimoto , Takuma Asari , Shigeo Hayashi , Hironori Kumagai
IPC分类号： H01M4/13 , H01G11/36 , H01G11/22 , H01G11/28 , H01G11/66 , H01M4/66 , H01M4/62 , H01M10/0525 , B82Y30/00
CPC分类号： H01G11/36 , B82Y30/00 , H01G11/22 , H01G11/28 , H01G11/66 , H01M4/625 , H01M4/663 , H01M4/667 , H01M10/0525 , Y02E60/13 , Y02T10/7011 , Y02T10/7022 , Y10S977/746 , Y10S977/948 , Y10T156/10
摘要： Disclosed herein is an electrode for energy devices such as electric double layer capacitors, which includes conductive fibers made of carbon, such as carbon nanotubes, as an electrode active material and has a high capacitance. The electrode for energy devices includes a current collector and a plurality of conductive fibers (e.g., carbon nanotubes) provided to stand on a surface of the current collector so that their one ends are electrically connected to the surface of the current collector, wherein the conductive fibers are made of carbon and have carboxyl group-containing functional groups or oxo group-containing functional groups and hydroxyl group-containing functional groups attached thereto. The conductive fibers preferably carry a quinone group-containing compound.
摘要翻译：本文公开了一种用于诸如双电层电容器的能量装置的电极，其包括由诸如碳纳米管的碳制成的导电纤维作为电极活性材料并具有高电容。用于能量装置的电极包括集电器和多个导电纤维（例如，碳纳米管），其设置在支架的表面上，使得它们的一端电连接到集电器的表面，其中导电纤维由碳制成并具有含羧基的官能团或含氧基的官能团和含有羟基的官能团。导电纤维优选含有含醌基的化合物。

7. 发明授权

US08822000B2 Nanostructure and method for manufacturing the same 有权
标题翻译：纳米结构及其制造方法
公开(公告)号：US08822000B2
公开(公告)日：2014-09-02
申请号：US12520959
申请日：2008-01-16
申请人： Hironori Kumagai , Yasuhiro Hashimoto , Shigeo Hayashi , Takuma Asari , Toshiya Yokogawa
发明人： Hironori Kumagai , Yasuhiro Hashimoto , Shigeo Hayashi , Takuma Asari , Toshiya Yokogawa
IPC分类号： H01M4/583 , H01M10/04 , B05D3/00 , B01J35/00 , B01J23/745 , B01J37/02 , B82Y30/00 , C25D11/02 , C25D11/04 , B01J23/89
CPC分类号： C25D11/02 , B01J23/745 , B01J23/8906 , B01J35/006 , B01J37/0226 , B01J37/0244 , B82Y30/00 , C25D11/04 , C25D11/045 , Y10T29/417 , Y10T29/49108 , Y10T29/49115 , Y10T428/1352 , Y10T428/2462
摘要： The present invention provides a nanostructure on an upper surface of which a small-diameter carbon nanotube (CNT) is formed and which improves an adhesive strength between a substrate and the CNT while controlling an orientation of the CNT, and a method for manufacturing the nanostructure. The nanostructure includes a substrate 101, a porous layer 102 formed on the substrate 101 to have a fine pore, a fine pore diameter control layer 103 formed on the porous layer 102, and a carbon nanotube 701 formed to extend from the fine pore defined by the fine pore diameter control layer 103, and one end of the carbon nanotube is fixed by the fine pore diameter control layer 103. It is preferable that the substrate 101 and the fine pore diameter control layer 103 be electrically conductive. It is preferable that the porous layer 102 be an anode oxide film. It is preferable that a melting point of the fine pore diameter control layer 103 be 600° C. or higher.
摘要翻译：本发明提供了在上表面上形成小直径碳纳米管（CNT）的纳米结构，并且在控制CNT的取向的同时改善了基板和CNT之间的粘合强度，以及纳米结构的制造方法。纳米结构包括基板101，形成在基板101上的具有细孔的多孔层102，形成在多孔层102上的细孔径控制层103和形成为从由多孔层102限定的细孔延伸的细孔微细孔径控制层103和碳纳米管的一端由细孔直径控制层103固定。优选的是，基板101和细孔直径控制层103是导电的。多孔层102优选为阳极氧化膜。优选细孔径控制层103的熔点为600℃以上。

8. 发明申请

US20100178564A1 ENERGY STORAGE DEVICE, METHOD FOR MANUFACTURING THE SAME, AND APPARATUS INCLUDING THE SAME 有权
标题翻译：能量储存装置及其制造方法以及包括其的装置
公开(公告)号：US20100178564A1
公开(公告)日：2010-07-15
申请号：US12602934
申请日：2009-03-12
申请人： Takuma Asari , Hironori Kumagai , Shigeo Hayashi , Yasuhiro Hashimoto , Takahiro Kawashima
发明人： Takuma Asari , Hironori Kumagai , Shigeo Hayashi , Yasuhiro Hashimoto , Takahiro Kawashima
IPC分类号： H01M4/583 , B05D5/12 , H01G9/155
CPC分类号： H01M4/587 , H01G9/016 , H01G9/058 , H01G11/12 , H01G11/26 , H01G11/28 , H01G11/36 , H01G11/86 , H01M4/625 , H01M4/663 , H01M10/052 , Y02E60/13 , Y02T10/7011 , Y02T10/7022
摘要： The present invention provides a highly reliable energy storage device capable of preventing a reaction current from flowing in a carbon nanotube electrode by ionizing a catalyst metal or a substrate metal to cause the metal to flow out to an electrolytic solution. An energy storage device of the present invention includes: at least a pair of electrode bodies that are a cathode and an anode; and an electrolytic solution. At least one of the electrode bodies is configured such that a layer of carbon nanotubes is formed on an electric conductor. A coupling region where one ends of the carbon nanotubes are coupled to and electrically connected to the electric conductor and a non-coupling region where ends of the carbon nanotubes are not coupled to the electric conductor are formed on a surface of the electric conductor. The carbon nanotubes having one ends connected to the coupling region are toppled to cover a surface of the non-coupling region.
摘要翻译：本发明提供一种高可靠性的能量储存装置，其能够通过使催化剂金属或基板金属离子化而使反应电流流过碳纳米管电极，使金属流出至电解液。本发明的能量存储装置包括：至少一对电极体，其是阴极和阳极; 和电解液。至少一个电极体被配置为使得在导电体上形成碳纳米管层。在电导体的表面上形成有耦合区域，其中碳纳米管的一端耦合到电导体并且电连接到电导体，并且非耦合区域，其中碳纳米管的端部未联接到导电体。具有连接到耦合区域的一端的碳纳米管被推倒以覆盖非耦合区域的表面。

9. 发明授权

US08531818B2 Electric double layer capacitor and method for manufacturing the same 有权
标题翻译：双电层电容器及其制造方法
公开(公告)号：US08531818B2
公开(公告)日：2013-09-10
申请号：US13060383
申请日：2009-11-06
申请人： Yasuhiro Hashimoto , Takuma Asari , Hironori Kumagai , Shigeo Hayashi
发明人： Yasuhiro Hashimoto , Takuma Asari , Hironori Kumagai , Shigeo Hayashi
IPC分类号： H01G9/155
CPC分类号： H01G11/84 , H01G11/12 , H01G11/28 , H01G11/36 , Y02E60/13 , Y10T29/417
摘要： An electric double layer capacitor 200 is configured such that a positive electrode 206, a separator 205, and a negative electrode 207 stacked in this order are contained in a container, and a portion between the positive electrode 206 and the negative electrode 207 is filled with an electrolytic solution. A polar plate of one or each of the positive electrode 206 and the negative electrode 207 includes a current collector 201, 203 and a plurality of electrically-conductive fine fibers 202, 204 formed and standing on a surface of the current collector such that one end of each of the fine fibers is electrically connected to the surface of the current collector. A surface of the polar plate is covered with the separator 205, the surface corresponding to the surface of the current collector. The polar plate and the separator 205 are pressure bonded to be integrated with each other. In the electric double layer capacitor using the electrically-conductive fine fiber, such as a carbon nanotube, as an active material, energy density can be increased by densely compressing the active material.
摘要翻译：电双层电容器200被构造成使得按照这个顺序堆叠的正电极206，隔膜205和负电极207被容纳在容器中，并且正电极206和负电极207之间的部分填充有电解液。正电极206和负电极207中的一个或每个的极板包括集电体201,203和形成并站立在集电体的表面上的多个导电细纤维202,204，使得一端的每个细纤维电连接到集电器的表面。极板的表面被分离器205覆盖，该表面对应于集电体的表面。极板和分离器205被压接以彼此一体化。在使用诸如碳纳米管的导电细纤维作为活性材料的双电层电容器中，通过密集地压缩活性材料可以增加能量密度。

10. 发明申请

US20120028123A1 CARBON NANOTUBE FORMING SUBSTRATE, CARBON NANOTUBE COMPLEX, ENERGY DEVICE, METHOD FOR MANUFACTURING ENERGY DEVICE, AND APPARATUS INCLUDING ENERGY DEVICE 有权
标题翻译：碳纳米管形成基板，碳纳米管复合体，能量装置，制造能量装置的方法以及包括能量装置的装置
公开(公告)号：US20120028123A1
公开(公告)日：2012-02-02
申请号：US13145310
申请日：2011-02-14
申请人： Takuma Asari , Hironori Kumagai , Shigeo Hayashi , Yasuhiro Hashimoto , Naoki Yoshikawa , Takashi Okada
发明人： Takuma Asari , Hironori Kumagai , Shigeo Hayashi , Yasuhiro Hashimoto , Naoki Yoshikawa , Takashi Okada
IPC分类号： H01M4/583 , C09K109/00 , H01M10/04 , H01M4/139 , B05D3/00 , B05D3/14 , B05D5/00 , H01G9/00 , B32B3/02 , H01G9/042 , B82Y99/00 , B82Y40/00
CPC分类号： H01M4/133 , H01G11/36 , H01M4/1393 , H01M4/587 , H01M4/661 , H01M4/663 , H01M10/0525 , Y02E60/13 , Y10T29/417 , Y10T29/49108 , Y10T29/49115 , Y10T428/23993
摘要： Provided are a substrate on which carbon nanotubes each having one end connected to the substrate can be formed at a high synthetic rate and from which the carbon nanotubes are less likely to be peeled off. The substrate is a substrate for forming the carbon nanotubes and includes a buffer layer 13 formed on at least one of surfaces of a substrate main body 14 and containing aluminum atoms and fluorine atoms. The carbon nanotube complex includes the substrate and a plurality of carbon nanotubes 11 each having one end connected to a surface of the buffer layer 13.
摘要翻译：可以以高合成速度形成各自具有与基板连接的一端的碳纳米管的基板，并且碳纳米管不容易被剥离。基板是用于形成碳纳米管的基板，并且包括形成在基板主体14的至少一个表面上并且含有铝原子和氟原子的缓冲层13。碳纳米管复合体包括基板和多个碳纳米管11，每个碳纳米管11的一端连接到缓冲层13的表面。

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