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1. 发明授权

US07495143B2 Hydrocarbon conversion using nanocrystalline zeolite Y 失效
标题翻译：使用纳米晶体沸石Y进行烃转化
公开(公告)号：US07495143B2
公开(公告)日：2009-02-24
申请号：US12072180
申请日：2008-02-25
申请人： Xingtao Gao , Johannes Hendrik Koegler , Lawrence L. Murrell , Philip J. Angevine
发明人： Xingtao Gao , Johannes Hendrik Koegler , Lawrence L. Murrell , Philip J. Angevine
IPC分类号： C07C2/58
CPC分类号： B01J29/088 , B01J29/084 , B01J35/023 , B01J37/08 , B01J2229/40 , B01J2229/42 , B01J2229/64 , C01B39/04 , C01B39/24 , C07C2/58 , C07C2/66 , C07C6/126 , C07C2521/04 , C07C2521/06 , C07C2521/08 , C07C2521/12 , C07C2529/08 , C07C2529/12 , C07C2529/14 , C07C2529/16 , C10G29/205 , C10G2300/1081 , C10G2300/1088 , C10G2300/1096 , C10G2300/305 , C10G2300/4018 , C10G2400/02 , C10G2400/30 , Y02P20/52 , C07C9/14 , C07C15/073 , C07C15/085
摘要： A process for alkylation of a hydrocarbon compound includes providing a catalyst including a zeolite Y having a crystal size of no more than 100 nm, and reacting an alkylatable hydrocarbon with an alkylating agent in the presence of the catalyst under alkylation reaction conditions to provide a gasoline product having a Research Octane Number of over 99.5.
摘要翻译：烃化合物的烷基化方法包括提供包含结晶尺寸不超过100nm的沸石Y的催化剂，并且在烷基化反应条件下在催化剂存在下使烷基化烃与烷基化剂反应以提供汽油研究辛烷值超过99.5的产品。

2. 发明申请

US20080154083A1 Hydrocarbon conversion using nanocrystalline zeolite Y 失效
公开(公告)号：US20080154083A1
公开(公告)日：2008-06-26
申请号：US12072180
申请日：2008-02-25
申请人： Xingtao Gao , Johannes Hendrik Koegler , Lawrence L. Murrell , Philip J. Angevine
发明人： Xingtao Gao , Johannes Hendrik Koegler , Lawrence L. Murrell , Philip J. Angevine
IPC分类号： C07C2/56
CPC分类号： B01J29/088 , B01J29/084 , B01J35/023 , B01J37/08 , B01J2229/40 , B01J2229/42 , B01J2229/64 , C01B39/04 , C01B39/24 , C07C2/58 , C07C2/66 , C07C6/126 , C07C2521/04 , C07C2521/06 , C07C2521/08 , C07C2521/12 , C07C2529/08 , C07C2529/12 , C07C2529/14 , C07C2529/16 , C10G29/205 , C10G2300/1081 , C10G2300/1088 , C10G2300/1096 , C10G2300/305 , C10G2300/4018 , C10G2400/02 , C10G2400/30 , Y02P20/52 , C07C9/14 , C07C15/073 , C07C15/085
摘要： A process for alkylation of a hydrocarbon compound includes providing a catalyst including a zeolite Y having a crystal size of no more than 100 nm, and reacting an alkylatable hydrocarbon with an alkylating agent in the presence of the catalyst under alkylation reaction conditions to provide a gasoline product having a Research Octane Number of over 99.5.

3. 发明授权

US07361797B2 Hydrocarbon conversion using nanocrystalline zeolite Y 有权
标题翻译：使用纳米晶体沸石Y进行烃转化
公开(公告)号：US07361797B2
公开(公告)日：2008-04-22
申请号：US10774774
申请日：2004-02-09
申请人： Xingtao Gao , Johannes Hendrik Koegler , Lawrence L. Murrell , Philip J. Angevine
发明人： Xingtao Gao , Johannes Hendrik Koegler , Lawrence L. Murrell , Philip J. Angevine
IPC分类号： C07C2/68
CPC分类号： B01J29/088 , B01J29/084 , B01J35/023 , B01J37/08 , B01J2229/40 , B01J2229/42 , B01J2229/64 , C01B39/04 , C01B39/24 , C07C2/58 , C07C2/66 , C07C6/126 , C07C2521/04 , C07C2521/06 , C07C2521/08 , C07C2521/12 , C07C2529/08 , C07C2529/12 , C07C2529/14 , C07C2529/16 , C10G29/205 , C10G2300/1081 , C10G2300/1088 , C10G2300/1096 , C10G2300/305 , C10G2300/4018 , C10G2400/02 , C10G2400/30 , Y02P20/52 , C07C9/14 , C07C15/073 , C07C15/085
摘要： A process for alkylation of a hydrocarbon compound includes providing a catalyst including a zeolite Y having a crystal size of no more than 100 nm, and reacting an alkylatable hydrocarbon with an alkylating agent in the presence of the catalyst under alkylation reaction conditions to provide a gasoline product having a Research Octane Number of over 99.5.
摘要翻译：烃化合物的烷基化方法包括提供包含结晶尺寸不超过100nm的沸石Y的催化剂，并且在烷基化反应条件下在催化剂存在下使烷基化烃与烷基化剂反应以提供汽油研究辛烷值超过99.5的产品。

4. 发明授权

US06793911B2 Nanocrystalline inorganic based zeolite and method for making same 失效
标题翻译：纳米晶体无机基沸石及其制备方法
公开(公告)号：US06793911B2
公开(公告)日：2004-09-21
申请号：US10067719
申请日：2002-02-05
申请人： Johannes Hendrik Koegler , Chuen Y. Yeh , Philip J. Angevine
发明人： Johannes Hendrik Koegler , Chuen Y. Yeh , Philip J. Angevine
IPC分类号： C01B2924
CPC分类号： C01B39/04 , C01B39/24 , Y10S423/21
摘要： A method for making a zeolite includes impregnating a porous inorganic oxide with a liquid solution containing an inorganic micropore-forming directing agent. The amount of liquid solution is no more than about 100% of the pore volume of the porous inorganic oxide, and the concentration of the directing agent in the liquid solution ranges from 21% to about 60% by weight. The impregnated amorphous inorganic oxide is heated at a synthesis temperature of from about 50° C. to about 150° C. for a duration of time sufficient to form a zeolite-containing product. The method herein is advantageous for the transformation of a mesoporous or macroporous amorphous inorganic material to a composite structure containing the original mesoporous or macropores, but wherein at least some of the porous inorganic oxide material is converted to nanocrystalline zeolite, such as zeolite Y.
摘要翻译：制造沸石的方法包括用含有无机微孔形成导向剂的液体溶液浸渍多孔无机氧化物。液体溶液的量不超过多孔无机氧化物的孔体积的约100％，液体溶液中的引导剂的浓度为21重量％至约60重量％。将浸渍的无定形无机氧化物在约50℃至约150℃的合成温度下加热足够长的时间以形成含沸石的产物。这里的方法有利于将介孔或大孔无定形无机材料转化成含有原始介孔或大孔的复合结构，但是其中至少一些多孔无机氧化物材料被转化为纳米晶体沸石，例如沸石Y.

5. 发明授权

US07510644B2 Zeolites and molecular sieves and the use thereof 失效
标题翻译：沸石和分子筛及其用途
公开(公告)号：US07510644B2
公开(公告)日：2009-03-31
申请号：US11023724
申请日：2004-12-28
申请人： Rudolf Overbeek , Nelleke van der Puil , Chuen Y. Yeh , Lawrence L. Murrell , Yun-Feng Chang , Philip Jay Angevine , Johannes Hendrik Koegler
发明人： Rudolf Overbeek , Nelleke van der Puil , Chuen Y. Yeh , Lawrence L. Murrell , Yun-Feng Chang , Philip Jay Angevine , Johannes Hendrik Koegler
IPC分类号： C10G11/00 , C10G11/04 , C01B39/26 , C01B39/42
CPC分类号： C10G47/16 , B01D53/02 , B01J6/001 , B01J8/18 , B01J20/183 , B01J29/18 , B01J29/7007 , B01J29/7034 , B01J35/0006 , B01J35/002 , B01J37/0009 , B01J37/08 , B01J37/14 , B01J2219/0254 , B01J2229/40 , B01J2229/64 , C01B39/04 , C01B39/265 , C01B39/42 , C01B39/48 , C07C2/66 , C07C2529/18 , C07C2529/40 , C07C2529/70 , C10G11/05 , C10G29/205 , C10G45/64 , C07C15/073
摘要： A method for making a zeolite includes providing a reaction mixture containing mixed inorganic oxides and an organic templating agent, heating the reaction mixture, removing the templating agent at a temperature of no greater than 550° C. and under conditions such that the resulting zeolite is has an AAI of at least 1.2. The zeolite is preferably zeolite beta, TEA-mordenite or TEA-ZSM-12.
摘要翻译：制备沸石的方法包括提供含有混合无机氧化物和有机模板剂的反应混合物，加热反应混合物，在不高于550℃的温度下除去模板剂，并在使得所得沸石为具有至少1.2的AAI。沸石优选为沸石β，TEA-丝光沸石或TEA-ZSM-12。

6. 发明授权

US06809055B2 Zeolites and molecular sieves and the use thereof 失效
标题翻译：沸石和分子筛及其用途
公开(公告)号：US06809055B2
公开(公告)日：2004-10-26
申请号：US09981926
申请日：2001-10-17
申请人： Rudolf Overbeek , Nelleke van der Puil , Chuen Y. Yeh , Lawrence L. Murrell , Yun-Feng Chang , Philip Jay Angevine , Johannes Hendrik Koegler
发明人： Rudolf Overbeek , Nelleke van der Puil , Chuen Y. Yeh , Lawrence L. Murrell , Yun-Feng Chang , Philip Jay Angevine , Johannes Hendrik Koegler
IPC分类号： B01J2906
CPC分类号： C10G47/16 , B01J29/06 , B01J29/7007 , B01J35/002 , B01J37/0009 , B01J37/08 , B01J2229/40 , B01J2229/64 , C01B37/00 , C01B39/02 , C01B39/04 , C01B39/48 , C07C2/66 , C07C2529/40 , C10G29/205 , C10G45/64 , C07C15/073
摘要： An improved zeolite having a high number of strong acid sites wherein said zeolite has an AAI of at least 1.0. In a preferred embodiment, such zeolite is produced by controlling conditions after production of the crystalline structure such that loss of tetrahedral aluminum is minimized to thereby provide a zeolite with the above defined AAI.
摘要翻译：具有大量强酸性位点的改进的沸石，其中所述沸石的AAI为至少1.0。在优选的实施方案中，通过控制晶体结构生产后的条件来制备这种沸石，使得四面体铝的损失最小化，从而提供具有上述限定的AAI的沸石。

7. 发明授权

US08105968B2 Bimetallic alkylation catalysts 有权
标题翻译：双金属烷基化催化剂
公开(公告)号：US08105968B2
公开(公告)日：2012-01-31
申请号：US11906945
申请日：2007-10-04
申请人： Anne Mae Gaffney , Philip Jay Angevine , Cheun Yuan Yeh , Johannes Hendrik Koegler , Jingguang Chen , Emanuel Hermanus van Broekhoven
发明人： Anne Mae Gaffney , Philip Jay Angevine , Cheun Yuan Yeh , Johannes Hendrik Koegler , Jingguang Chen , Emanuel Hermanus van Broekhoven
IPC分类号： B01J29/06
CPC分类号： B01J29/072 , B01J23/40 , B01J23/42 , B01J23/44 , B01J23/8913 , B01J23/892 , B01J29/146 , B01J35/002 , B01J35/0053 , B01J2229/186 , C10G29/205 , C10G2300/1088 , C10G2400/02
摘要： Solid acid catalysts for use in alkylation processes are described. The solid acid catalysts include a multimetallic (e.g. bimetallic, trimetallic or tetrametallic) component that performs a hydrogenating function for the reactivation (or regeneration) of the catalyst in the presence of hydrogen. The multimetallic catalyst includes a noble metal such as platinum or palladium. The invention also relates to alkylation processes using the multimetallic solid acid catalysts having a multimetallic component for hydrogenation.
摘要翻译：描述了用于烷基化方法的固体酸催化剂。固体酸催化剂包括在氢存在下进行催化剂再活化（或再生）的氢化功能的多金属（例如双金属，三金属或四金属）组分。多金属催化剂包括贵金属如铂或钯。本发明还涉及使用具有用于氢化的多金属组分的多金属固体酸催化剂的烷基化方法。

8. 发明授权

US06762143B2 Catalyst containing microporous zeolite in mesoporous support 失效
标题翻译：含有介孔载体中的微孔沸石的催化剂
公开(公告)号：US06762143B2
公开(公告)日：2004-07-13
申请号：US09995227
申请日：2001-11-27
申请人： Zhiping Shan , Jacobus Cornelius Jansen , Chuen Y. Yeh , Johannes Hendrik Koegler , Thomas Maschmeyer
发明人： Zhiping Shan , Jacobus Cornelius Jansen , Chuen Y. Yeh , Johannes Hendrik Koegler , Thomas Maschmeyer
IPC分类号： B01J2906
CPC分类号： B82Y30/00 , B01J21/06 , B01J21/12 , B01J23/26 , B01J23/38 , B01J23/44 , B01J23/50 , B01J23/52 , B01J29/005 , B01J29/0308 , B01J29/04 , B01J29/041 , B01J29/084 , B01J29/40 , B01J29/70 , B01J29/7007 , B01J29/80 , B01J29/87 , B01J29/88 , B01J29/89 , B01J35/002 , B01J35/1023 , B01J35/1038 , B01J35/1047 , B01J35/1057 , B01J35/1061 , B01J35/108 , B01J35/109 , B01J37/0018 , B01J37/033 , B01J37/10 , B01J2229/32 , B01J2229/36 , B01J2229/42 , B01J2229/62 , C01B13/366 , C01B33/126 , C01B37/005 , C01B37/02 , C01P2006/12 , C01P2006/14 , C01P2006/16 , C07C2/66 , C07C45/46 , C07D301/06 , C07D301/10 , C10G2/332 , C10G11/04 , C10G11/05 , C10G27/04 , C10G29/205 , C10G45/00 , C10G45/04 , C10G45/12 , C10G45/60 , C10G45/62 , C10G45/64 , C10G47/14 , C10G49/08 , C10G50/00 , C07C15/073 , C07C49/84
摘要： A catalytic material includes a microporous zeolite supported on a mesoporous inorganic oxide support. The microporous zeolite can include zeolite beta, zeolite Y or ZSM-5. The mesoporous inorganic oxide can be, e.g., silica or alumina, and can optionally include other metals. Methods for making and using the catalytic material are described herein.
摘要翻译：催化材料包括负载在介孔无机氧化物载体上的微孔沸石。微孔沸石可以包括沸石β，沸石Y或ZSM-5。介孔无机氧化物可以是例如二氧化硅或氧化铝，并且可以任选地包括其它金属。本文描述了制备和使用催化材料的方法。

9. 发明授权

US08765082B2 Combined carbon dioxide and oxygen process for ethylbenzene dehydrogenation to styrene 失效
标题翻译：乙苯脱氢合成二氧化碳和氧气过程到苯乙烯
公开(公告)号：US08765082B2
公开(公告)日：2014-07-01
申请号：US13567207
申请日：2012-08-06
申请人： Stephen C. Arnold , Johannes Hendrik Koegler , Anne Mae Gaffney , Chuen Yuan Yeh , Ruozhi Song
发明人： Stephen C. Arnold , Johannes Hendrik Koegler , Anne Mae Gaffney , Chuen Yuan Yeh , Ruozhi Song
IPC分类号： B01J8/02 , C07C5/48
CPC分类号： C01B3/50 , C01B3/382 , C01B3/48 , C01B13/0251 , C01B2203/0244 , C01B2203/0283 , C01B2203/04 , C01B2203/0405 , C01B2203/0415 , C01B2203/042 , C01B2203/0475 , C01B2203/048 , C01B2203/0495 , C01B2203/1252 , C01B2210/0046 , C01B2210/0053 , C07C5/48 , Y02P20/52 , C07C15/46 , C07C11/08 , C07C11/06 , C07C11/04 , C07C11/09 , C07C11/167
摘要： Processes for using a combination of carbon dioxide and oxygen in the dehydrogenation of hydrocarbons are provided. A hydrocarbon feedstock, carbon dioxide and oxygen are fed to an oxidative dehydrogenation reactor system containing one or more catalysts that promote dehydrogenation of the hydrocarbon feedstock to produce a dehydrogenated hydrocarbon product. The processes of the present invention may be used, for example, to produce styrene monomer by dehydrogenation of ethylbenzene using carbon dioxide and oxygen as oxidants.
摘要翻译：提供了在烃的脱氢中使用二氧化碳和氧气的组合的方法。将烃原料，二氧化碳和氧气进料到含有促进烃原料脱氢以产生脱氢烃产物的一种或多种催化剂的氧化脱氢反应器系统中。本发明的方法可以用于例如使用二氧化碳和氧气作为氧化剂使乙苯脱氢生产苯乙烯单体。

10. 发明申请

US20120294776A1 Combined Carbon Dioxide and Oxygen Process for Ethylbenzene Dehydrogenation to Styrene 失效
标题翻译：用于乙苯脱氢至苯乙烯的二氧化碳和氧气的合成方法
公开(公告)号：US20120294776A1
公开(公告)日：2012-11-22
申请号：US13567207
申请日：2012-08-06
申请人： Stephen C. Arnold , Johannes Hendrik Koegler , Anne Mae Gaffney , Chuen Yuan Yeh , Ruozhi Song
发明人： Stephen C. Arnold , Johannes Hendrik Koegler , Anne Mae Gaffney , Chuen Yuan Yeh , Ruozhi Song
IPC分类号： B01J19/00
CPC分类号： C01B3/50 , C01B3/382 , C01B3/48 , C01B13/0251 , C01B2203/0244 , C01B2203/0283 , C01B2203/04 , C01B2203/0405 , C01B2203/0415 , C01B2203/042 , C01B2203/0475 , C01B2203/048 , C01B2203/0495 , C01B2203/1252 , C01B2210/0046 , C01B2210/0053 , C07C5/48 , Y02P20/52 , C07C15/46 , C07C11/08 , C07C11/06 , C07C11/04 , C07C11/09 , C07C11/167
摘要： Processes for using a combination of carbon dioxide and oxygen in the dehydrogenation of hydrocarbons are provided. A hydrocarbon feedstock, carbon dioxide and oxygen are fed to an oxidative dehydrogenation reactor system containing one or more catalysts that promote dehydrogenation of the hydrocarbon feedstock to produce a dehydrogenated hydrocarbon product. The processes of the present invention may be used, for example, to produce styrene monomer by dehydrogenation of ethylbenzene using carbon dioxide and oxygen as oxidants.
摘要翻译：提供了在烃的脱氢中使用二氧化碳和氧气的组合的方法。将烃原料，二氧化碳和氧气进料到含有促进烃原料脱氢以产生脱氢烃产物的一种或多种催化剂的氧化脱氢反应器系统中。本发明的方法可以用于例如使用二氧化碳和氧气作为氧化剂使乙苯脱氢生产苯乙烯单体。

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