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1. 发明授权

US07099546B2 Method for making a plastic graded index optical fiber and resulting graded index optical fiber 失效
标题翻译：制造塑料渐变折射率光纤和得到的渐变折射率光纤的方法
公开(公告)号：US07099546B2
公开(公告)日：2006-08-29
申请号：US10493998
申请日：2002-11-18
申请人： Xavier Andrieu , Bernard Boutevin , Alain Pastouret , Alain Rousseau , Jean-Marc Sage
发明人： Xavier Andrieu , Bernard Boutevin , Alain Pastouret , Alain Rousseau , Jean-Marc Sage
IPC分类号： G02B6/028 , C03B37/023
CPC分类号： G02B1/046 , B29C47/0014 , B29C47/025 , B29C47/28
摘要： The present invention concerns a method of manufacturing a graded index plastic optical fiber having an index that varies continuously between the center and the periphery of the fiber, from at least one polymer P and at least one reactive diluent D1 to allow the refractive index of said fiber to be varied. Said polymer P is a terpolymer comprising at least three repeating units P1, P2 and P3 with the following general formulae:
摘要翻译：本发明涉及一种制造渐变折射率塑料光纤的方法，其具有指数，其在纤维的中心和周边之间从至少一种聚合物P和至少一种反应性稀释剂D1连续变化，以允许所述纤维要变化。所述聚合物P是包含至少三个具有以下通式的重复单元P1，P2和P3的三元共聚物：

2. 发明申请

US20050069268A1 Method for making a plastic graded index optical fiber and resulting graded index optical fiber 失效
标题翻译：制造塑料渐变折射率光纤和得到的渐变折射率光纤的方法
公开(公告)号：US20050069268A1
公开(公告)日：2005-03-31
申请号：US10493998
申请日：2002-11-18
申请人： Xavier Andrieu , Bernard Boutevin , Alain Pastouret , Alain Rousseau , Jean-Marc Sage
发明人： Xavier Andrieu , Bernard Boutevin , Alain Pastouret , Alain Rousseau , Jean-Marc Sage
IPC分类号： G02B6/00 , G02B1/04 , G02B6/18
CPC分类号： G02B1/046 , B29C47/0014 , B29C47/025 , B29C47/28
摘要： The present invention concerns a method of manufacturing a graded index plastic optical fiber having an index that varies continuously between the center and the periphery of the fiber, from at least one polymer P and at least one reactive diluent D1 to allow the refractive index of said fiber to be varied. Said polymer P is a terpolymer comprising at least three repeating units P1, P2 and P3 with the following general formulae:
摘要翻译：本发明涉及一种制造渐变折射率塑料光纤的方法，其具有指数，其在纤维的中心和周边之间从至少一种聚合物P和至少一种反应性稀释剂D1连续变化，以允许所述纤维要变化。所述聚合物P是包含至少三个具有以下通式的重复单元P1，P2和P3的三元共聚物：

3. 发明申请

US20050062180A1 Method for making a plastic optical fiber, and resulting plastic optical fiber 审中-公开
标题翻译：制造塑料光纤的方法，以及所得的塑料光纤
公开(公告)号：US20050062180A1
公开(公告)日：2005-03-24
申请号：US10496100
申请日：2002-11-18
申请人： Xavier Andrieu , Bernard Boutevin , Alain Pastouret , Alain Rousseau , Jean-Marc Sage
发明人： Xavier Andrieu , Bernard Boutevin , Alain Pastouret , Alain Rousseau , Jean-Marc Sage
IPC分类号： G02B6/00 , C08F214/18 , C08F218/00 , G02B1/04 , B29D11/00
CPC分类号： G02B1/046
摘要： The present invention concerns a method of manufacturing a plastic optical fiber from at least one polymer P, said method being characterized in that said polymer P is a copolymer comprising at least two repeating units P1 and P2 with the following general formulae, i and j corresponding to a repeat number of units: said copolymer P being transparent, amorphous in nature and having a motif P2 content in the range from substantially 30 mole % to 70 mole % when X═F or Cl in P1.
摘要翻译：本发明涉及从至少一种聚合物P制造塑料光纤的方法，所述方法的特征在于所述聚合物P是包含至少两个具有以下通式的重复单元P1和P2的共聚物：i和j对应重复数量的单元：所述共聚物P本质上是透明的，无定形的，并且当X = F或Cl在P1中时，基团P2含量基本上为30摩尔％至70摩尔％。

4. 发明授权

US06428893B1 Graded index plastics optical fiber and a method of continuously fabricating a graded index plastics optical fiber 失效
标题翻译：渐变折射率塑料光纤和连续制造渐变折射率塑料光纤的方法
公开(公告)号：US06428893B1
公开(公告)日：2002-08-06
申请号：US09409341
申请日：1999-09-30
申请人： Jean-Yves Barraud , Dominique Morichere , Alain Pastouret , Bernard Boutevin , Alain Rousseau
发明人： Jean-Yves Barraud , Dominique Morichere , Alain Pastouret , Bernard Boutevin , Alain Rousseau
IPC分类号： B32B900
CPC分类号： G02B6/02038 , D01F8/10 , Y10T428/2933 , Y10T428/2964
摘要： A method of continuous application of a graded index plastics optical fiber in which the refractive index is highest in the center and decreases progressively towards the periphery, said fiber having a plurality of layers of resin deposited concentrically, the method comprising making a plurality of mixtures, each mixture comprising at least one polymer P and a reactive diluting agent including at least two monomers, then depositing said mixtures in the form of coaxial layers, allowing interdiffusing to take place between the layers, and finally crosslinking the polymer P and/or the reactive diluting agent.
摘要翻译：一种连续应用渐变折射率塑料光纤的方法，其中中心的折射率最高并且朝向周边逐渐减小，所述纤维具有多个同心沉积的树脂层，该方法包括制备多种混合物，每个混合物包含至少一种聚合物P和包含至少两种单体的活性稀释剂，然后以同轴层的形式沉积所述混合物，允许相互扩散在层之间发生，最后交联聚合物P和/或反应性稀释剂。

5. 发明授权

US5496899A Crosslinkable polymer material which may be used in non-linear optics and process for obtaining it 失效
标题翻译：可用于非线性光学的可交联聚合物材料和用于获得它的方法
公开(公告)号：US5496899A
公开(公告)日：1996-03-05
申请号：US298318
申请日：1994-09-01
申请人： Franck Foll , Dominique Bosc , Julienne Liang , Alain Rousseau , Bernard Boutevin
发明人： Franck Foll , Dominique Bosc , Julienne Liang , Alain Rousseau , Bernard Boutevin
IPC分类号： C08J7/16 , C07C245/08 , C08F8/00 , C08F12/00 , C08F16/00 , C08F18/00 , C08F20/00 , C08F20/36 , C08F246/00 , C08F291/00 , C08F299/00 , C08G18/62 , C08G18/67 , C08G18/70 , C08G59/32 , C08G81/02 , G02F1/35 , G02F1/355 , G02F1/361 , C08F8/30
CPC分类号： C08F20/36 , C07C245/08 , G02F1/3617
摘要： The invention relates to a crosslinkable material that is active in non-linear optics, containing a polymer which carries chromophores each included in a polymer unit of formula: ##STR1## in which: T is part of the polymer chain,A is an --NO.sub.2, --CN or --C(CN).dbd.C(CN).sub.2 group,R.sub.1 is a hydrogen atom or a methyl or ethyl group,R.sub.2 is a CH.sub.2, C.sub.2 H.sub.4, C.sub.3 H.sub.6 or C.sub.4 H.sub.8 group, and:either X=Y is an azo group, F being a hydrogen atom and G being a group --C(O)--O--W or a group --C(O)--O--(CH.sub.2).sub.n --O--W, n being an integer between 2 and 6 and W being a hydrogen atom or a dimerizable group,or X=Y is an azomethine group, one of the groups F and G being a group --O--W or --R.sub.3 --O--W, R.sub.3 being a group --O--C(O)--R.sub.4 -- or --O--R.sub.4 --, where R.sub.4 is a C.sub.1 to C.sub.6 alkyl, the other of the groups F and G being a hydrogen atom and W being a hydrogen atom or a dimerizable group.
摘要翻译：本发明涉及一种在非线性光学元件中有活性的可交联材料，其含有每个包含在下式的聚合物单元中的发色团的聚合物：其中：T是聚合物链的一部分，A是 -NO 2，-CN或-C（CN）= C（CN）2基团，R 1为氢原子或甲基或乙基，R 2为CH 2，C 2 H 4，C 3 H 6或C 4 H 8基团，X = Y 是偶氮基，F是氢原子，G是基团-C（O）-OW或基团-C（O）-O-（CH 2）nOW，n是2和6之间的整数，W是氢原子或二聚化基团，或X = Y是偶氮甲碱基，基团F和G中的一个基团为-OW或-R3-OW，R3为基团-OC（O）-R4-或-O- R4-，其中R4是C1-C6烷基，基团F和G中的另一个是氢原子，W是氢原子或二聚化基团。

6. 发明申请

US20050084230A1 Polymers based on CTFE/VCA/HFP or TFE/VCA/HFP 审中-公开
标题翻译：基于CTFE / VCA / HFP或TFE / VCA / HFP的聚合物
公开(公告)号：US20050084230A1
公开(公告)日：2005-04-21
申请号：US10847963
申请日：2004-05-18
申请人： Thierry Pascal , Bernard Boutevin , Georges Kostov , Alain Rousseau , Jerome Alric , Jerome Fournier
发明人： Thierry Pascal , Bernard Boutevin , Georges Kostov , Alain Rousseau , Jerome Alric , Jerome Fournier
IPC分类号： G02B6/00 , C08F210/02 , C08F214/00 , C08F234/02
CPC分类号： C08F234/02 , C08F214/00
摘要： A subject-matter of the invention is a copolymer comprising at least 3 units, P1, P2 and P3, with the following general formulae: with X1, X2 and X3, which are identical or different, taken from the group of atoms consisting of H, F, Cl and Br; with R1 taken from the group of atoms consisting of H, F, Cl and Br; with R2 a carbonaceous group comprising from 1 to 10 partially or completely fluorinated carbon atoms; with Y1 and Y2, which are identical or different, taken either from the group of atoms consisting of H, F, Cl and Br or from the family of the carbonaceous groups comprising from 1 to 10 carbon atoms; with Y3 a carbonyl group or a divalent carbonaceous group; the content of P2 unit in the copolymer being between 30 and 70 mol % for respectively a content of P1 and P3 units in the copolymer of between 70 and 30 mol % and the weight-average molar mass (Mw) of the said copolymer being between 103 and 106 g/mol. Preferably, the copolymer is of CTFE/VCA/HFP or TFE/VCA/HFP type.
摘要翻译：本发明的主题是包含至少3个单元的共聚物，P1，P2和P3，具有以下通式：X 1，X 2和X 2 相同或不同的取代自H，F，Cl和Br组成的原子团; 其中R 1取自H，F，Cl和Br组成的原子团; R 2是含有1至10个部分或完全氟化的碳原子的碳质基团; Y 1和Y 2相同或不同，取自H，F，Cl和Br组成的原子团或来自碳质物质的族包含1至10个碳原子的基团; 具有Y 3或X 2的羰基或二价碳质基团; 共聚物中P2单元的含量分别为30-70mol％，共聚物中P1和P3单元的含量为70-30mol％，所述共聚物的重均摩尔质量（Mw）介于 10 3和106μg/ mol。优选共聚物为CTFE / VCA / HFP或TFE / VCA / HFP型。

7. 发明授权

US5635576A Crosslinkable material which may be used in opto-electronics, process for producing this material, and monomer allowing this material to be obtained 失效
标题翻译：可用于光电子学的可交联材料，用于生产该材料的方法，以及获得该材料的单体
公开(公告)号：US5635576A
公开(公告)日：1997-06-03
申请号：US528109
申请日：1995-09-13
申请人： Franck Foll , Dominique Bosc , Alain Rousseau , Bernard Boutevin
发明人： Franck Foll , Dominique Bosc , Alain Rousseau , Bernard Boutevin
IPC分类号： C07C251/24 , C08F20/36 , C09B55/00 , C09B69/10 , G02F1/361 , C08F126/02 , C08F124/00
CPC分类号： G02F1/3613 , C07C251/24 , C08F20/36 , C09B55/002 , C09B69/107 , G02F1/3611
摘要： The invention relates to a crosslinkable material containing a polymer onto which chromophores are laterally grafted, characterized in that each chromophore is within a polymer unit which corresponds to the following formula (I): ##STR1## in which: X represents a part of the polymer chain,A is a group --NO.sub.2, --CN, --C(CN).dbd.C(CN).sub.2 or --SO.sub.2 R.sub.4, R.sub.4 being a C.sub.1 to C.sub.6 alkyl,D is a nitrogen, sulphur or oxygen atom,R.sub.1 is a hydrogen atom or a C.sub.1 to C.sub.6 alkyl if D is a nitrogen atom, or nothing if D is a sulphur or oxygen atom,R.sub.2 is a C.sub.1 to C.sub.6 aliphatic alkyl group,and E is a group chosen from --OH, --O--CO--(CH.sub.2).sub.n --COOH, --O--W, --O--CO--R.sub.3 O--W and --O--R.sub.3 --O--W, n being an integer between 2 and 6, W being a photodimerizable group and R.sub.3 being a C.sub.1 to C.sub.6 alkyl,and the said material additionally containing complementary anchoring functional groups capable of attaching themselves to E during the crosslinking.
摘要翻译：本发明涉及含有聚合物的可交联材料，其上发色团被横向接枝，其特征在于每个发色团都在与下式（I）相对应的聚合物单元内：其中：X表示部分的聚合物链，A是-NO 2，-CN，-C（CN）= C（CN）2或-SO 2 R 4基团，R 4是C 1 -C 6烷基，D是氮，硫或氧原子，R 1是如果D为氮原子，则为氢原子或C1至C6烷基，如果D为硫或氧原子，则为R2，C1为C6脂肪族烷基，E为选自-OH，-O- CO-（CH 2）n -COOH，-OW，-O-CO-R 3 O-W和-O-R 3 -OW，n为2至6的整数，W为可光二聚化基团，R 3为C 1至C 6烷基，并且所述材料另外含有能够在交联期间自身附着于E的互补锚定官能团。

8. 发明授权

US09040650B2 Resins of the phenoplast type obtained from phenolic compounds and from macromolecular hardeners bearing aldehyde functions 有权
标题翻译：从酚类化合物和具有醛官能团的大分子硬化剂获得的酚醛树脂类型的树脂
公开(公告)号：US09040650B2
公开(公告)日：2015-05-26
申请号：US13510624
申请日：2010-11-19
申请人： Sylvain Caillol , Bernard Boutevin , Ghislain David , Carine Burguiere
发明人： Sylvain Caillol , Bernard Boutevin , Ghislain David , Carine Burguiere
IPC分类号： C08G14/00 , C08G8/04
CPC分类号： C08G8/04
摘要： A method for preparing a formaldehyde-free phenolic plastic resin, includes a step of preparing a hardener via careful oxidation of a polyol and a step of reacting the hardener with phenolic compounds.
摘要翻译：一种制备无甲醛酚醛树脂的方法包括通过多元醇的细致氧化制备硬化剂的步骤和使固化剂与酚类化合物反应的步骤。

9. 发明申请

US20130280620A1 HALOGEN COPOLYMERS COMPRISING AT LEAST ONE REPETITIVE VINYL ETHER UNIT HAVING ONE CARBONATE PENDANT GROUP 有权
标题翻译：包含至少一个具有一个碳酸根基团的重复的乙烯基单体的共聚物
公开(公告)号：US20130280620A1
公开(公告)日：2013-10-24
申请号：US13878578
申请日：2011-10-06
申请人： Hervé Galiano , Bruno Ameduri , Bernard Boutevin , Ali Alaaeddine
发明人： Hervé Galiano , Bruno Ameduri , Bernard Boutevin , Ali Alaaeddine
IPC分类号： H01M10/0565 , C08F224/00
CPC分类号： C08F224/00 , C08F214/18 , C08F214/186 , C08F216/1416 , H01M10/052 , H01M10/0565 , H01M2220/20 , H01M2300/0082 , Y02E60/122
摘要： This invention concerns copolymers that may be used for incorporation into electrolytic membranes for lithium generators, comprising at least one vinyl ether repetitive motif comprising a pendant cyclic carbonate group.
摘要翻译：本发明涉及可用于结合到锂发生器的电解膜中的共聚物，其包括至少一种包含环状碳酸酯侧基的乙烯基醚重复基序。

10. 发明申请

US20130123456A1 Method for Functionalizing Natural Fatty Substances 有权
标题翻译：功能化天然脂肪物质的方法
公开(公告)号：US20130123456A1
公开(公告)日：2013-05-16
申请号：US13807146
申请日：2011-06-30
申请人： Sylvain Caillol , Bernard Boutevin , Myriam Desroches
发明人： Sylvain Caillol , Bernard Boutevin , Myriam Desroches
IPC分类号： C07C319/18
CPC分类号： C07C319/18 , C11C3/00
摘要： The invention relates to a method for functionalizing natural fatty substances: According to said method, plant oils including at least two unsaturations and the derivatives thereof, fatty acids including at least one unsaturated compound and the derivatives thereof, and mixtures of same, are reacted with a thiol derivative of formula (I), at a temperature of between 0° C. and the temperature of total degradation of the natural fatty substance and in the presence of a thermal initiator compound or a redox initiator, or by UV radiation, or by UV radiation and in the presence of a photoinitiator. The invention also relates to the resulting functionalized fatty substances and to the use thereof for the preparation of polymers. The invention further relates to a method for preparing polymers from at least one functionalized fatty substance obtained by said functionalization method.
摘要翻译：本发明涉及一种功能化天然脂肪物质的方法：根据所述方法，包括至少两种不饱和的植物油及其衍生物，包含至少一种不饱和化合物的脂肪酸及其衍生物及其衍生物及其混合物与式（I）的硫醇衍生物在0℃和天然脂肪物质的总降解温度之间，在热引发剂化合物或氧化还原引发剂的存在下，或通过UV辐射，或通过 UV辐射和光引发剂存在下。本发明还涉及得到的官能化脂肪物质及其用于制备聚合物的用途。本发明还涉及由通过所述官能化方法获得的至少一种官能化脂肪物质制备聚合物的方法。

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