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    • 6. 发明授权
    • Isoindoline dyes, their preparation and use
    • 异二氢吲哚染料,其制备和用途
    • US4373102A
    • 1983-02-08
    • US128156
    • 1980-03-07
    • Peter NeumannWolfgang ElserGustav BockWolf-Dieter Kermer
    • Peter NeumannWolfgang ElserGustav BockWolf-Dieter Kermer
    • C09B23/00C07D209/44C07F9/572C08K5/00C08K5/34C09B57/00C09B57/04D06P3/52C07D401/10C07D403/10C07D413/10
    • C07D209/44C07F9/5728C08K5/0041C09B57/04
    • Novel dyes of the formula ##STR1## where A is cyano, carbo-C.sub.1 -C.sub.4 -alkoxy, carbamyl, N-C.sub.1 -C.sub.4 -alkylcarbamyl, N-phenylcarbamyl, acetyl, benzoyl, 4-nitrophenyl or 4-cyanophenyl,X is hydrogen, chlorine, C.sub.1 -C.sub.4 -alkyl or C.sub.1 -C.sub.4 -alkoxy, and if n is 2 the substituents may be identical or different,n is 1 or 2,R.sup.1 is hydrogen, methyl, ethyl or 2-hydroxyethyl andR.sup.2 is phenyl or cyclohexyl, orR.sup.1 is hydrogen andR.sup.2 is C.sub.1 -C.sub.4 -alkyl, orR.sup.1 and R.sup.2 are C.sub.1 -C.sub.6 -alkyl, allyl or phenyl-C.sub.1 -C.sub.4 -alkyl orthe group ##STR2## is a saturated heterocyclic five-membered or six-membered ring which may additionally contain an oxygen or a further nitrogen as ring members,Y is hydrogen, hydroxyl, methyl or ethyl; ##STR3## where R.sup.3 is linear or branched C.sub.1 -C.sub.12 -alkyl, or is phenyl; ##STR4## where R.sup.4 is hydrogen or C.sub.1 -C.sub.4 -alkyl and R.sup.5 is hydrogen, linear or branched C.sub.1 -C.sub.12 -alkyl or trifluoromethyl; chloromethyl; C.sub.1 -C.sub.4 -alkoxymethyl, phenoxymethyl, benzyl, phenylethyl, C.sub.3 -C.sub.7 -cycloalkyl, phenyl, H.sub.5 C.sub.6 --CH.dbd.CH-- or --CH.sub.2 --PO(OR.sup.6).sub.2, where R.sup.6 is C.sub.1 -C.sub.4 -alkyl; or ##STR5## where R.sup.7 is C.sub.1 -C.sub.12 -alkyl, phenyl or C.sub.1 -C.sub.12 -alkylphenyl; or Y is N-C.sub.1 -C.sub.4 -alkylamino if R.sup.1 and R.sup.2 are C.sub.1 -C.sub.4 -alkyl, or Y is N,N-di-C.sub.1 -C.sub.4 -alkylamino, N-pyrrolidinyl, N-piperidinyl or N-morpholinyl if ##STR6## has the same meaning, and Z is hydrogen or, if R.sup.1 and R.sup.2 are C.sub.1 -C.sub.4 -alkyl or allyl and Y is ##STR7## Z is hydrogen, methoxy or ethoxy, and alkyl, phenyl, phenoxy and phenylthio may contain additional substituents.The dyes give blue to violet hues on synthetics, in particular on linear polyester fibers. Where Z is methoxy or ethoxy, greenish blue dyeings are obtained. The dyeings are very deep, clear and brilliant.Some of the dyes may also be used for the mass coloring of thermoplastics.
    • 其中A为氰基,C 1 -C 4 - 烷氧基,氨基甲酰基,N-C 1 -C 4 - 烷基氨基甲酰基,N-苯基氨基甲酰基,乙酰基,苯甲酰基,4-硝基苯基或4-氰基苯基的新颖染料X为氢 ,氯,C 1 -C 4 - 烷基或C 1 -C 4 - 烷氧基,如果n为2,则取代基可以相同或不同,n为1或2,R 1为氢,甲基,乙基或2-羟基乙基,R 2为苯基或 环己基或R 1为氢,R 2为C 1 -C 4 - 烷基,或R 1和R 2为C 1 -C 6 - 烷基,烯丙基或苯基-C 1 -C 4 - 烷基,或基团为饱和杂环五元或六元 可以另外含有氧或另外的氮作为环成员,Y是氢,羟基,甲基或乙基; 其中R 3是直链或支链C 1 -C 12 - 烷基,或是苯基; 其中R 4是氢或C 1 -C 4烷基,R 5是氢,直链或支链C 1 -C 12 - 烷基或三氟甲基; 氯甲基 C 1 -C 4 - 烷氧基甲基,苯氧基甲基,苄基,苯乙基,C 3 -C 7 - 环烷基,苯基,H 5 C 6 -CH = CH-或-CH 2 PO(OR 6)2,其中R 6是C 1 -C 4烷基; 或者其中R 7是C 1 -C 12 - 烷基,苯基或C 1 -C 12 - 烷基苯基; 或者如果R 1和R 2是C 1 -C 4 - 烷基,则Y是N-C 1 -C 4 - 烷基氨基,或者Y是N,N-二-C 1 -C 4烷基氨基,N-吡咯烷基,N-哌啶基或N-吗啉基,如果具有相同的含义,并且Z是氢,或者如果R 1和R 2是C 1 -C 4 - 烷基或烯丙基,Y是Z是氢,甲氧基或乙氧基,并且烷基,苯基,苯氧基和苯硫基可以含有另外的取代基 。 染料在合成纤维上产生蓝色至紫色色调,特别是在线性聚酯纤维上。 当Z为甲氧基或乙氧基时,得到绿蓝色染色。 染色非常深刻,清晰,辉煌。 一些染料也可用于热塑性塑料的大量着色。