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1. 发明授权

US4772746A Preparation of 4-pentenoates 失效
标题翻译： 4-戊烯酸酯的制备
公开(公告)号：US4772746A
公开(公告)日：1988-09-20
申请号：US870108
申请日：1986-06-03
申请人： Wolfgang Hoelderich , Rolf Fischer , Klaus-Dieter Malsch , Hubert Lendle
发明人： Wolfgang Hoelderich , Rolf Fischer , Klaus-Dieter Malsch , Hubert Lendle
IPC分类号： C07C69/155 , B01J29/00 , C07B61/00 , C07C67/333 , C07C69/52
CPC分类号： C07C67/333
摘要： 4-Pentenoates are prepared by isomerization by a process in which isomeric pentenoates are treated at elevated temperatures in the presence of a zeolite containing metals of group eight of the Periodic Table and the 4-pentenoate is distilled off from the reaction mixture, and the zeolite contains iron, cobalt and/or nickel.
摘要翻译：通过异构化方法制备4-戊烯酸酯，其中异构戊烯酸酯在含有元素周期表第八组金属的沸石存在下在升高的温度下进行处理，而从反应混合物中蒸馏除去4-戊烯酸酯含有铁，钴和/或镍。

2. 发明授权

US4780448A Preparation of a catalyst containing copper and silica 失效
标题翻译：制备含铜和二氧化硅的催化剂
公开(公告)号：US4780448A
公开(公告)日：1988-10-25
申请号：US14072
申请日：1987-01-30
申请人： Franz J. Broecker , Rolf Fischer , Klaus-Dieter Malsch , Wolfgang Reiss , Rolf Schnabel , Hans-Martin Weitz
发明人： Franz J. Broecker , Rolf Fischer , Klaus-Dieter Malsch , Wolfgang Reiss , Rolf Schnabel , Hans-Martin Weitz
IPC分类号： C07C29/136 , B01J23/72 , C07B61/00 , C07C27/00 , C07C29/149 , C07C31/20 , C07C67/00 , B01J21/08 , B01J21/18
CPC分类号： B01J23/72 , C07C29/149
摘要： A catalyst containing copper and silica is prepared by a process in which an aqueous alkali metal silicate solution containing from 1 to 26% by weight of SiO.sub.2 is brought to a pH of from 0.5 to 2.0 with nitric acid, an aqueous copper nitrate solution containing from 5 to 15% by weight of Cu is added, after the addition of the nitric acid, so that a clear solution containing from 0.18 to 3.0 moles of Cu per mole of SiO.sub.2 is formed, the resulting solution is mixed with an aqueous alkali metal carbonate solution at from 40.degree. to 80.degree. C., the pH of the mixture being kept at from 7.5 to 8.5, and the precipitated material is separated off, dried, calcined by heating at from 250.degree. to 400.degree. C. and pressed in a conventional manner to give catalyst moldings. The catalyst thus obtained is used for the hydrogenation of dialkyl dicarboxylates to diols.
摘要翻译：含有铜和二氧化硅的催化剂是通过一种方法制备的，其中含有1至26重量％的SiO 2的碱金属硅酸盐水溶液用硝酸使其pH为0.5至2.0，硝酸铜水溶液含有加入5〜15重量％的Cu后，加入硝酸后，形成每摩尔SiO 2含有0.18〜3.0摩尔Cu的透明溶液，得到的溶液与碱金属碳酸盐水溶液溶液在40〜80℃下，将混合物的pH值保持在7.5〜8.5，析出的物质分离出来，干燥，在250〜400℃下加热煅烧，常规方式提供催化剂模塑。由此获得的催化剂用于将二羧酸二烷基酯氢化成二醇。

3. 发明授权

US4940805A Preparation of 1,4-butanediol or tetrahydrofuran or both 失效
标题翻译： 1,4-丁二醇或四氢呋喃或二者的制备
公开(公告)号：US4940805A
公开(公告)日：1990-07-10
申请号：US230015
申请日：1988-08-08
申请人： Rolf Fischer , Hans-Juergen Gosch , Wolfgang Harder , Klaus-Dieter Malsch , Manfred Eggersdorfer , Lothar Franz , Horst Zimmermann , Karl Brenner , Klaus Halbritter , Wolfgang Sauer , Hans-Juergen Scheiper
发明人： Rolf Fischer , Hans-Juergen Gosch , Wolfgang Harder , Klaus-Dieter Malsch , Manfred Eggersdorfer , Lothar Franz , Horst Zimmermann , Karl Brenner , Klaus Halbritter , Wolfgang Sauer , Hans-Juergen Scheiper
IPC分类号： B01J27/18 , B01J27/19 , C07B61/00 , C07C27/00 , C07C29/136 , C07C29/147 , C07C29/149 , C07C29/17 , C07C29/56 , C07C31/20 , C07C67/00 , C07D307/08
CPC分类号： C07D307/08 , C07C29/177
摘要： Process for the preparation of 1,4-butanediol or tetrahydrofuran or both by the catalytic hydrogenation of maleic anhydride, succinic anhydride, maleic acid, succinic acid, fumaric acid, or the alkyl esters of these acids at temperatures of from 100.degree. C. to 350.degree. C. and pressures of from 50 bar to 350 bar over a catalyst containing cobalt as the active metal and one or both of the elements copper and phosphorus, if necessary in the presence of an aliphatic alcohol.
摘要翻译：通过马来酸酐，琥珀酸酐，马来酸，琥珀酸，富马酸或这些酸的烷基酯的催化氢化制备1,4-丁二醇或四氢呋喃或二者的方法，温度为100℃至 350℃，并且在含有钴作为活性金属的催化剂和一种或两种元素铜和磷的催化剂中，如果需要，在脂族醇的存在下，压力为50巴至350巴。

4. 发明授权

US4933487A Preparation of 4-pentenates 失效
标题翻译： 4-戊烯酸酯的制备
公开(公告)号：US4933487A
公开(公告)日：1990-06-12
申请号：US327408
申请日：1989-03-22
申请人： Wolfgang Hoelderich , Heinrich Aichinger , Fritz Naeumann , Rolf Fischer
发明人： Wolfgang Hoelderich , Heinrich Aichinger , Fritz Naeumann , Rolf Fischer
IPC分类号： B01J29/08 , B01J29/00 , B01J29/035 , B01J29/12 , B01J29/40 , B01J29/65 , B01J29/86 , C07B61/00 , C07C67/333 , C07C69/52 , C07C69/533
CPC分类号： C07C67/333 , Y02P20/582
摘要： In an improved process for preparing 4-pentenates by isomerization, where isomeric pentenates are treated at elevated temperatures with zeolites and 4-pentenates are distilled out of the reaction mixture, the improvement comprises using pentenates in mixture with alkanols.
摘要翻译：在通过异构化制备4-戊烯酸酯的改进方法中，其中异构戊烯酸酯在升高的温度下用沸石和4-戊烯酸酯从反应混合物中蒸馏出来，其改进包括使用与烷醇混合的戊烯酸酯。

5. 发明授权

US4709097A Conversion of 1,3-dioxanes to 4-oxa-aldehydes 失效
标题翻译： 1,3-二恶烷转化为4-氧杂 - 醛
公开(公告)号：US4709097A
公开(公告)日：1987-11-24
申请号：US851782
申请日：1986-04-14
申请人： Wolfgang Hoelderich , Franz Merger , Rolf Fischer
发明人： Wolfgang Hoelderich , Franz Merger , Rolf Fischer
IPC分类号： B01J29/00 , B01J29/06 , B01J29/86 , B01J29/88 , C07B41/06 , C07B61/00 , C07C45/00 , C07C45/60 , C07C47/198 , C07C47/277 , C07C47/37 , C07C47/47 , C07C67/00 , C07C69/145 , C07C69/708 , C07D213/30 , C07D307/12 , C07D307/42 , C07D319/00 , C07D319/06 , C07D333/00 , C07D333/16 , C07D405/04 , C07D407/04 , C07D409/04 , C07D521/00
CPC分类号： C07D213/30 , C07C45/60 , C07C47/198 , C07C47/277 , C07C47/37 , C07C47/47 , C07C67/293 , C07C67/333 , C07C69/145 , C07C69/716 , C07D307/12 , C07D307/42 , C07D333/16
摘要： 4-oxa-aldehydes are prepared by catalytic isomerization of a 1,3-dioxane using an acidic zeolite catalyst.
摘要翻译：使用酸性沸石催化剂通过1,3-二恶烷的催化异构化制备4-氧杂 - 醛。

6. 发明授权

US5189182A Preparation of 5-methylbutyrolactone 失效
标题翻译： 5-甲基丁酰胺的制备
公开(公告)号：US5189182A
公开(公告)日：1993-02-23
申请号：US236199
申请日：1988-08-25
申请人： Rudolf Kummer , Heinz-Walter Schneider , Werner Bertleff , Rolf Fischer , Uwe Vagt , Fritz Naeumann , Wolfgang Hoelderich , Matthias Schwarzmann
发明人： Rudolf Kummer , Heinz-Walter Schneider , Werner Bertleff , Rolf Fischer , Uwe Vagt , Fritz Naeumann , Wolfgang Hoelderich , Matthias Schwarzmann
IPC分类号： C07D315/00
CPC分类号： C07D315/00
摘要： 5-Methylbutyrolactone is prepared by a process in which a pentenoic ester of the formula IX--CO.sub.2 R (I),where X is CH.sub.2 .dbd.CH--CH.sub.2 --CH.sub.2 --, CH.sub.3 --CH.dbd.CH--CH.sub.2 -- or CH.sub.3 --CH.sub.2 --CH.dbd.CH-- and R is alkyl, cycloalkyl, aralkyl or aryl, or a mixture of these esters is reacted with water at from 50.degree. to 350.degree. C. in the presence or absence of a diluenta) over a zeolite and/or phosphate catalyst orb) in the presence of from 0.01 to 0.25 mole of a sulfonic acid, a Lewis acid and/or a non-oxidizing mineral acid per mole of pentenoic ester or over from 0.1 to 40% by weight, based on the pentenoic ester, of a strongly acidic ion exchanger as a catalyst in a first stage, or the pentenoic ester of the formula I, where X and R have the stated meanings, is hydrolyzed in a first stage with the aid of a strongly acidic ion exchanger as a catalyst to give the pentenoic acid of the formula I, where R is hydrogen, and the resulting pentenoic acid is subjected to cyclization in a second stage in the presence of from 0.005 to 0.1 mole of a sulfonic acid, a Lewis acid or a non-oxidizing mineral acid per mole of pentenoic acid or over from 0.1 to 20% by weight, based on the pentenoic acid, of a strongly acidic ion exchanger at from 50.degree. to 350.degree. C.
摘要翻译：通过以下方法制备5-甲基丁内酯，其中式I X-CO 2 R（I）的戊烯酸酯，其中X为CH 2 = CH-CH 2 -CH 2 - ，CH 3 -CH = CH-CH 2 - 或CH 3 -CH 2 -CH = CH-和R是烷基，环烷基，芳烷基或芳基，或这些酯的混合物与水在50-350℃下在存在或不存在稀释剂a）的情况下与沸石和/或磷酸盐催化剂或b）在0.01至0.25摩尔磺酸，路易斯酸和/或非氧化性无机酸/摩尔烯酸酯存在下或基于戊烯酸酯为0.1至40重量％的作为第一阶段的催化剂的强酸性离子交换剂或其中X和R具有所述含义的式I的戊烯酸在第一阶段中借助于强酸性离子交换剂作为催化剂得到式I的戊烯酸，其中R是氢，所得戊烯酸在第二阶段中在0.005t的存在下进行环化 o 0.1摩尔磺酸，路易斯酸或非氧化性无机酸/摩尔烯酸，或超过0.1-20重量％，基于戊烯酸，强酸性离子交换剂为50〜 350℃

7. 发明授权

US4806679A Isomerization of diacyloxybutenes 失效
标题翻译：二酰氧基丁烯异构化
公开(公告)号：US4806679A
公开(公告)日：1989-02-21
申请号：US633279
申请日：1984-07-23
申请人： Wolfgang Hoelderich , Rolf Fischer , Otto Hertel , Wolf D. Mross , Hans-Martin Weitz
发明人： Wolfgang Hoelderich , Rolf Fischer , Otto Hertel , Wolf D. Mross , Hans-Martin Weitz
IPC分类号： C07C67/34 , B01J29/00 , B01J29/04 , C07B61/00 , C07C67/00 , C07C69/025 , C07C69/16 , C07C67/293 , C07C69/28
CPC分类号： C07C67/00
摘要： 1,4-Diacyloxybut-2-enes and 3,4-diacyloxybut-1-enes are converted into one another in the gas phase or liquid phase at from 100.degree. to 350.degree. C. under atmospheric or superatmospheric pressure in the presence of a zeolite as a catalyst.
摘要翻译： 1,4-二酰氧基丁-2-烯和3,4-二酰氧基丁-1-烯在气相或液相中在大气压或超大气压下在100-350℃下，在沸石作为催化剂。

8. 发明授权

US5144061A Preparation of alkenecarboxylic esters 失效
标题翻译：烷基羧酸酯的制备
公开(公告)号：US5144061A
公开(公告)日：1992-09-01
申请号：US116865
申请日：1987-11-05
申请人： Wolfgang Hoelderich , Fritz Naeumann , Rolf Fischer
发明人： Wolfgang Hoelderich , Fritz Naeumann , Rolf Fischer
IPC分类号： B01J27/16 , B01J27/00 , B01J29/00 , B01J29/04 , B01J29/06 , B01J29/08 , B01J29/82 , B01J29/83 , C07B61/00 , C07C67/03 , C07C67/327 , C07C69/533
CPC分类号： C07C67/03
摘要： The present invention relates to a method for producing optically active alcohol derivatives, which are useful as fungicides, herbicides or plant growth regulators, represented by the formula, ##STR1## by carrying out the asymmetric reduction of a ketone compound represented by the formula, ##STR2## with a boron hydride-reducing agent modified with an optically active amino alcohol represented by the formula, ##STR3## and also relates to the boron hydride type compound obtained by reacting the above optically active amino alcohol with a boron hydride compound and its production method.
摘要翻译：本发明涉及一种光学活性醇衍生物的制备方法，其可用作杀真菌剂，除草剂或植物生长调节剂，由下式表示：通过进行由式表示的酮化合物的不对称还原， IMAGE>与用式表示的光学活性氨基醇改性的硼氢化物还原剂，也涉及通过使上述光学活性氨基醇与硼氢化合物反应获得的硼氢化物型化合物及其生产方法。

9. 发明授权

US4845269A Preparation of 3-pentenoates from 2-pentenoates 失效
标题翻译：由2-戊烯酸酯制备3-戊烯酸酯
公开(公告)号：US4845269A
公开(公告)日：1989-07-04
申请号：US125560
申请日：1987-11-25
申请人： Rolf Fischer , Wolfgang Hoelderich , Manfred Sauerwald
发明人： Rolf Fischer , Wolfgang Hoelderich , Manfred Sauerwald
IPC分类号： B01J27/16 , B01J23/02 , B01J27/00 , B01J27/18 , B01J29/00 , B01J29/08 , B01J29/70 , C07B61/00 , C07C67/333 , C07C69/52 , C07C69/533
CPC分类号： C07C67/327 , B01J29/084 , B01J29/40 , B01J29/86 , C07C319/18 , C07C67/31 , C07D295/15 , B01J2229/186 , B01J2229/20 , B01J2229/42
摘要： 3-pentenoates are prepared from 2-pentenoates by a process in which(a) a 2-pentenoate of the formula ##STR1## where R.sup.1 is alkyl of 1 to 12 carbon atoms, cycloalkyl of 5 to 8 carbon atoms, aralkyl of 7 to 10 carbon atoms or aryl of 6 to 10 carbon atoms, is reacted with a compound of the formula IIR.sup.2 -X-H IIwhere R.sup.2 has the meanings given for R.sup.1 and X is an oxygen or sulfur atom, or with a compound of the formula III ##STR2## where R.sup.3 is hydrogen or R.sup.3 and R.sup.4 are each alkyl of 1 to 12 carbon atoms, cycloakkyl of 5 to 8 carbon atoms, aralkyl of 7 to 10 carbon atoms or aryl of 6 to 10 carbon atoms, and R.sup.3 and R.sup.4 together with the nitrogen atom on which they are substituents may form a 5-membered to 7-membered ring which may additionally contain a nitrogen or oxygen atom as a hetero atom, at from 20.degree. to 300.degree. C., in the presence or absence of a basic catalyst, to give a compound of the formula IV ##STR3## where Y is --XR.sup.2 or ##STR4## in which X, R.sup.1, R.sup.2, R.sup.3 and R.sup.4 have the above meanings, and(b) the compound of the formula IV is cleaved in the liquid or gas phase in the presence of an acidic catalyst at from 150.degree. to 450.degree. C. to give a mixture of 3- and 2-pentenoates, and the 3-pentenoate is isolated.
摘要翻译：通过以下方法由2-戊烯酸酯制备3-戊烯酸酯，其中（a）式Ⅰ的2-戊烯酸酯，其中R 1为1至12个碳原子的烷基，5至8个碳原子的环烷基，7个芳烷基至10个碳原子或6至10个碳原子的芳基与式II R2-XH II化合物反应，其中R2具有对R 1给定的含义，X是氧或硫原子，或与式 III，其中R 3是氢或R 3和R 4各自为1至12个碳原子的烷基，5至8个碳原子的环烷基，7至10个碳原子的芳烷基或6至10个碳原子的芳基， R4与它们是取代基的氮原子一起可以形成5元至7元环，其可以在20℃至300℃下另外含有作为杂原子的氮原子或氧原子，不存在碱性催化剂，得到其中Y是-XR2或其中X，R1，R2，R3和R4具有上述m的式IV的化合物IV （b）在150℃至450℃的酸性催化剂存在下，式IV化合物在液相或气相中裂解，得到3-和2-戊烯酸酯的混合物，并且 3-戊烯酸酯是分离的。

10. 发明授权

US4694107A Preparation of ketones by isomerization of aldehydes 失效
标题翻译：通过醛的异构化制备酮
公开(公告)号：US4694107A
公开(公告)日：1987-09-15
申请号：US865007
申请日：1986-07-02
申请人： Wolfgang Hoelderich , Franz Merger , Wolf D. Mross , Rolf Fischer
发明人： Wolfgang Hoelderich , Franz Merger , Wolf D. Mross , Rolf Fischer
IPC分类号： C07C45/67 , B01J29/00 , B01J29/06 , B01J29/86 , B01J29/88 , C07B31/00 , C07B41/06 , C07B61/00 , C07C45/00 , C07C45/54 , C07C49/04 , C07C49/105 , C07C67/00
CPC分类号： C07C45/54 , B01J29/86 , B01J29/88
摘要： Ketones are prepared by isomerization of aldehydes at elevated temperatures over zeolites.
摘要翻译：酮通过在升高的温度下通过沸石异构化醛来制备。

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