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1. 发明授权

US4709097A Conversion of 1,3-dioxanes to 4-oxa-aldehydes 失效
标题翻译： 1,3-二恶烷转化为4-氧杂 - 醛
公开(公告)号：US4709097A
公开(公告)日：1987-11-24
申请号：US851782
申请日：1986-04-14
申请人： Wolfgang Hoelderich , Franz Merger , Rolf Fischer
发明人： Wolfgang Hoelderich , Franz Merger , Rolf Fischer
IPC分类号： B01J29/00 , B01J29/06 , B01J29/86 , B01J29/88 , C07B41/06 , C07B61/00 , C07C45/00 , C07C45/60 , C07C47/198 , C07C47/277 , C07C47/37 , C07C47/47 , C07C67/00 , C07C69/145 , C07C69/708 , C07D213/30 , C07D307/12 , C07D307/42 , C07D319/00 , C07D319/06 , C07D333/00 , C07D333/16 , C07D405/04 , C07D407/04 , C07D409/04 , C07D521/00
CPC分类号： C07D213/30 , C07C45/60 , C07C47/198 , C07C47/277 , C07C47/37 , C07C47/47 , C07C67/293 , C07C67/333 , C07C69/145 , C07C69/716 , C07D307/12 , C07D307/42 , C07D333/16
摘要： 4-oxa-aldehydes are prepared by catalytic isomerization of a 1,3-dioxane using an acidic zeolite catalyst.
摘要翻译：使用酸性沸石催化剂通过1,3-二恶烷的催化异构化制备4-氧杂 - 醛。

2. 发明授权

US4694107A Preparation of ketones by isomerization of aldehydes 失效
标题翻译：通过醛的异构化制备酮
公开(公告)号：US4694107A
公开(公告)日：1987-09-15
申请号：US865007
申请日：1986-07-02
申请人： Wolfgang Hoelderich , Franz Merger , Wolf D. Mross , Rolf Fischer
发明人： Wolfgang Hoelderich , Franz Merger , Wolf D. Mross , Rolf Fischer
IPC分类号： C07C45/67 , B01J29/00 , B01J29/06 , B01J29/86 , B01J29/88 , C07B31/00 , C07B41/06 , C07B61/00 , C07C45/00 , C07C45/54 , C07C49/04 , C07C49/105 , C07C67/00
CPC分类号： C07C45/54 , B01J29/86 , B01J29/88
摘要： Ketones are prepared by isomerization of aldehydes at elevated temperatures over zeolites.
摘要翻译：酮通过在升高的温度下通过沸石异构化醛来制备。

3. 发明授权

US4599458A Preparation of 2-methylalk-2-enals 失效
标题翻译： 2-甲基-2-烯的制备
公开(公告)号：US4599458A
公开(公告)日：1986-07-08
申请号：US742200
申请日：1985-06-07
申请人： Rolf Fischer , Wolfgang Hoelderich , Franz Merger , Wolf D. Mross , Hans-Martin Weitz
发明人： Rolf Fischer , Wolfgang Hoelderich , Franz Merger , Wolf D. Mross , Hans-Martin Weitz
IPC分类号： C07C45/67 , C07C47/21 , C07C47/22 , C07C47/232 , C07C45/61
CPC分类号： C07C45/67 , C07C47/21 , C07C47/22 , C07C47/232
摘要： 2-Methylalk-2-enals of the formula ##STR1## where R.sup.1 and R.sup.2 are each hydrogen, alkyl or an aromatic radical, are prepared by isomerization of an acrolein derivative of the formula ##STR2## with a zeolite catalyst, an aluminum silicate and/or an aluminum phosphate.
摘要翻译：其中R 1和R 2各自为氢，烷基或芳族基团的通式为其的化合物的2-甲基-2-烯酮-2-烯是通过使用沸石催化剂，铝的方法异构化式II的丙烯醛衍生物来制备的硅酸盐和/或磷酸铝。

4. 发明授权

US4939280A Conversion of 1,3-dioxanes to 4-oxaaldehydes 失效
标题翻译： 1,3-二恶烷转化为4-氧杂醛
公开(公告)号：US4939280A
公开(公告)日：1990-07-03
申请号：US188416
申请日：1988-04-29
申请人： Wolfgang Hoelderich , Franz Merger , Helmut Lermer
发明人： Wolfgang Hoelderich , Franz Merger , Helmut Lermer
IPC分类号： C07C45/60 , C07C47/198 , C07C47/277 , C07D335/02
CPC分类号： C07C47/198 , C07C45/60 , C07C47/277 , C07D335/02
摘要： 4-Oxaaldehydes of the formula ##STR1## are prepared by catalytic isomerization of 1,3-dioxanes by a process in which a 1,3-dioxane of the formula ##STR2## where R.sup.1, R.sup.2, R.sup.4 and R.sup.5 are identical or different and are each hydrogen, a straight-chain or branched alkyl, alkenyl or alkynyl radical of not more than 18 carbon atoms, a cycloalkyl or cycloalkenyl radical of 5 to 8 carbon atoms, an aryl, alkylaryl, aralkyl or alkenylaryl radical of 5 to 16 carbon atoms or a heterocyclic radical, and furthermore R.sup.1 and R.sup.2 and/or R.sup.4 and R.sup.5 together with the carbon atom to which they are bonded may form a cycloalkane, a cycloalkene or a heterocyclic structure, and the stated radicals may furthermore carry substituents which are inert under the reaction conditions, and R.sup.3 is hydrogen or straight-chain or branched alkyl, is isomerized using a phosphate as a catalyst.
摘要翻译：通过其中R1，R2，R4和R5相同或不同的式“IMAGE”的1,3-二恶烷的方法，通过1,3-二恶烷的催化异构化制备式“IMAGE”的4-氧代醛，各自为氢，不超过18个碳原子的直链或支链烷基，烯基或炔基，5至8个碳原子的环烷基或环烯基，5至16个碳的芳基，烷基芳基，芳烷基或烯基芳基原子或杂环基团，此外，R 1和R 2和/或R 4和R 5与它们所键合的碳原子一起可以形成环烷烃，环烯烃或杂环结构，并且所述基团还可以携带惰性的取代基在反应条件下，R 3为氢或直链或支链烷基，使用磷酸酯作为催化剂异构化。

5. 发明授权

US5003089A Preparation of cyclic 6-membered to 8-membered vinylene-1,2-dioxy compounds 失效
标题翻译：环状6元至8元亚乙烯基-1,2-二氧化合物的制备
公开(公告)号：US5003089A
公开(公告)日：1991-03-26
申请号：US379412
申请日：1989-07-13
申请人： Franz Merger , Juergen Frank , Wolfgang Hoelderich , Toni Dockner , Manfred Sauerwald
发明人： Franz Merger , Juergen Frank , Wolfgang Hoelderich , Toni Dockner , Manfred Sauerwald
IPC分类号： B01J29/04 , C07B61/00 , C07C43/13 , C07C47/198 , C07D319/06 , C07D319/08 , C07D319/12 , C07D321/08 , C07D321/10 , C07D321/12 , C07D335/02 , C07D495/10 , C07D521/00
CPC分类号： C07D495/10 , C07C43/13 , C07D319/06 , C07D319/12 , C07D321/08 , C07D321/12 , Y02P20/582
摘要： Cyclic 6-membered to 8-membered 1,2-vinylenedioxy compounds of the general formula I ##STR1## where A is ##STR2## R.sup.1 to R.sup.7 independently of one another are each hydrogen, C.sub.1 -C.sub.8 -alkyl, C.sub.2 -C.sub.16 -alkoxyalkyl, C.sub.2 -C.sub.8 -alkenyl, C.sub.2 -C.sub.8 -alkynyl, C.sub.5 -C.sub.8 -cycloalkyl, aryl, C.sub.7 -C.sub.10 -alkylphenyl, C.sub.7 -C.sub.10 -phenalkyl, C.sub.8 -C.sub.10 -phenalkenyl or a heterocyclic structure, or R.sup.2 and R.sup.3, R.sup.2 and R.sup.4, R.sup.3 and R.sup.4, R.sup.2 and R.sup.6, R.sup.3 and R.sup.6, R.sup.4 and R.sup.5 or R.sup.6 and R.sup.7 together form a cycloaliphatic or heterocyclic ring, and R.sup.1 to R.sup.7 may furthermore carry substituents which are inert under the reaction conditions, and n is 0 or 1, are prepared by a process in which a cyclic 2-oxymethyl-1,3-dioxa compound or one of its derivatives of the general formula II ##STR3## where R.sup.1 to R.sup.7, A and n have the abovementioned meanings, and R.sup.8 is hydrogen or C.sub.1 -C.sub.12 -alkyl, is converted in the presence of an acidic catalyst at from 150.degree. to 450.degree. C. and under from 0.001 to 50 bar, some of the compounds obtained being novel.
摘要翻译：其中A为彼此独立的通式I（I）的环状6元至8元1,2-亚乙烯基二氧基化合物各自为氢，C 1 -C 8 - 烷基，C 2 -C 18 - C16 - 烷氧基烷基，C2-C8-烯基，C2-C8-炔基，C5-C8-环烷基，芳基，C7-C10-烷基苯基，C7-C10-苯基烷基，C8-C10-苯基烯基或杂环结构，或R2和R3 ，R 2和R 4，R 3和R 4，R 2和R 6，R 3和R 6，R 4和R 5或R 6和R 7共同形成脂环族或杂环，并且R 1至R 7还可以具有在反应条件下为惰性的取代基，n为 0或1的化合物通过其中R 1至R 7，A和n具有上述通式II的环状2-氧甲基-1,3-二氧杂化合物或其衍生物之一的方法制备意义，R8是氢或C1-C12烷基，在酸性催化剂存在下，在150-450℃下，在0.001至50巴下进行转化，得到的一些化合物是新的。

6. 发明授权

US5012005A Conversion of 1,3-dioxanes to 4-oxaaldehydes 失效
标题翻译： 1,3-二恶烷转化为4-氧杂醛
公开(公告)号：US5012005A
公开(公告)日：1991-04-30
申请号：US385925
申请日：1989-07-27
申请人： Wolfgang Hoelderich , Franz Merger
发明人： Wolfgang Hoelderich , Franz Merger
IPC分类号： C07C45/60 , C07C47/198 , C07C47/277 , C07D335/02
CPC分类号： C07C47/277 , C07C45/60 , C07C47/198 , C07D335/02
摘要： 4-oxaaldehydes of the formula ##STR1## are prepared by catalytic isomerization of 1,3-dioxanes by a process in which a 1,3-dioxane of the formula ##STR2## where R.sup.1, R.sup.2, R.sup.4 and R.sup.5 are identical or different and are each hydrogen, a straight-chain or branched alkyl, alkenyl or alkynyl radical of not more than 18 carbon atoms, a cycloalkyl or cycloalkenyl radical of 5 to 8 carbon atoms, an aryl, alkylaryl, aralkyl, aralkenyl or alkenylaryl radical of 5 to 16 carbon atoms or a heterocyclic radical and furthermore R.sup.1 and R.sup.2 and/or R.sup.4 and R.sup.5 together with the carbon atoms to which they are bonded may form a cycloalkane, a cycloalkene or a heterocyclic structure, and the stated radicals may furthermore carry substituents which are inert under the reaction conditions, and R.sup.3 is hydrogen or straight-chain or branched alkyl, is isomerized using a metal oxide catalyst, which has been treated with an acid, and/or a silica phase having a zeolite structure.
摘要翻译：通过其中R1，R2，R4和R5是相同或不同的式“IMAGE”的1,3-二恶烷的方法，通过1,3-二恶烷的催化异构化制备式“IMAGE”的4-氧代醛，各自为氢，不超过18个碳原子的直链或支链烷基，烯基或炔基，5至8个碳原子的环烷基或环烯基，芳基，烷基芳基，芳烷基，芳烯基或链烯基芳基，其5至 16个碳原子或杂环基团，此外，R 1和R 2和/或R 4和R 5与它们所键合的碳原子一起可以形成环烷烃，环烯烃或杂环结构，并且所述基团还可以具有取代基，使用已用酸处理的金属氧化物催化剂和/或具有沸石结构的二氧化硅相异构化在反应条件下惰性的R 3为氢或直链或支链烷基。

7. 发明授权

US4999453A Preparation of olefinically unsaturated carboxylic esters having a terminal ester group 失效
标题翻译：具有末端酯基的烯属不饱和羧酸酯的制备
公开(公告)号：US4999453A
公开(公告)日：1991-03-12
申请号：US337867
申请日：1989-04-14
申请人： Franz Merger , Hans Horler , Wolfgang Hoelderich , Tom Witzel
发明人： Franz Merger , Hans Horler , Wolfgang Hoelderich , Tom Witzel
IPC分类号： B01J29/04 , B01J29/40 , B01J29/83 , B01J29/85 , B01J29/86 , B01J29/88 , C07B61/00 , C07C67/32 , C07C69/533
CPC分类号： C07C67/32 , C07C69/533 , Y02P20/582
摘要： Olefinically unsaturated carboxylic esters having a terminal ester group and of the general formulae Ia and IbR.sup.1 --CH.sub.2 --CH.dbd.CH--(CH.sub.2).sub.r--1 --COOR.sup.2 (Ia)R.sup.1 --CH.dbd.CH--(CH.sub.2).sub.r --COOR.sup.2 (Ib)and, if desired, further double bond isomers, where R.sup.1 is hydrogen or an organic radical, R.sup.2 is C.sub.1 -C.sub.8 -alkyl and r is from 1 to 20, are prepared by a process in which an .alpha.-substituted .alpha.,.omega.-(n-alkylenedicarboxylic ester) of the general formula II ##STR1## where R.sup.1 and R.sup.2 and r have the abovementioned meanings and R.sup.3 is C.sub.1 -C.sub.8 -alkyl, is converted over an acidic heterogeneous catalyst at from 150.degree. to 800.degree. C. and under from 0.01 to 50 bar.
摘要翻译：具有末端酯基和通式Ia和Ib的烯属不饱和羧酸酯R1-CH2-CH = CH-（CH2）r-1-COOR2（Ia）R1-CH = CH-（CH2）r-COOR2（Ib ），并且如果需要，其中R 1是氢或有机基团的另外的双键异构体，R 2是C 1 -C 8 - 烷基，r是1至20，是通过以下方法制备的，其中α-取代的α，ω- 其中R 1和R 2和r具有上述含义，并且R 3是C 1 -C 8烷基的通式II（II）的（正 - 亚烷基二羧酸酯）在150至800℃的酸性非均相催化剂上转化在0.01至50巴之间。

8. 发明授权

US4879405A Preparation of pentenoic esters 失效
标题翻译：戊烯酸酯的制备
公开(公告)号：US4879405A
公开(公告)日：1989-11-07
申请号：US205335
申请日：1988-06-10
申请人： Fritz Naeumann , Wolfgang Hoelderich , Franz Merger
发明人： Fritz Naeumann , Wolfgang Hoelderich , Franz Merger
IPC分类号： B01J29/84 , B01J27/18 , B01J27/182 , B01J29/06 , B01J29/42 , B01J29/82 , B01J29/85 , B01J29/86 , B01J29/88 , B01J29/89 , C07B61/00 , C07C67/293 , C07C67/333 , C07C69/533
CPC分类号： C07C69/533
摘要： Pentenoic esters are prepared by heating formylvaleric esters at from 50.degree. to 400.degree. C. in the presence of zeolites or one or more phosphates selected from the group consisting of aluminum phosphate, silicon aluminum phosphate, boron aluminum phosphate, silicon iron aluminum phosphate, cerium phosphate, zirconium phosphate, boron phosphate, iron phosphate and strontium phosphate.
摘要翻译：戊烯酸酯通过在沸石或一种或多种磷酸盐存在下，在50-400℃下加热甲酰基戊酸酯来制备，所述磷酸盐选自磷酸铝，磷酸铝铝，磷酸铝铝，磷酸铁铝，铈磷酸盐，磷酸锆，磷酸二氢钾，磷酸铁和磷酸锶。

9. 发明授权

US4560822A Preparation of dienes by dehydration of aldehydes 失效
标题翻译：通过醛脱水制备二烯
公开(公告)号：US4560822A
公开(公告)日：1985-12-24
申请号：US730687
申请日：1985-05-03
申请人： Wolfgang Hoelderich , Franz Merger , Wolf D. Mross , Gerd Fouquet
发明人： Wolfgang Hoelderich , Franz Merger , Wolf D. Mross , Gerd Fouquet
IPC分类号： C07C11/12 , B01J29/00 , C07B61/00 , C07C1/00 , C07C1/24 , C07C11/18 , C07C13/21 , C07C13/23 , C07C45/50 , C07C67/00
CPC分类号： C07C1/24 , C07C2101/16 , C07C2529/06 , C07C2529/86 , C07C2529/88
摘要： Dienes are prepared by dehydration of aldehydes at elevated temperatures by a method in which the dehydration is carried out using a zeolite as a catalyst.
摘要翻译：二烯通过使用沸石作为催化剂进行脱水的方法在升高的温度下脱醛而制备。

10. 发明授权

US4933487A Preparation of 4-pentenates 失效
标题翻译： 4-戊烯酸酯的制备
公开(公告)号：US4933487A
公开(公告)日：1990-06-12
申请号：US327408
申请日：1989-03-22
申请人： Wolfgang Hoelderich , Heinrich Aichinger , Fritz Naeumann , Rolf Fischer
发明人： Wolfgang Hoelderich , Heinrich Aichinger , Fritz Naeumann , Rolf Fischer
IPC分类号： B01J29/08 , B01J29/00 , B01J29/035 , B01J29/12 , B01J29/40 , B01J29/65 , B01J29/86 , C07B61/00 , C07C67/333 , C07C69/52 , C07C69/533
CPC分类号： C07C67/333 , Y02P20/582
摘要： In an improved process for preparing 4-pentenates by isomerization, where isomeric pentenates are treated at elevated temperatures with zeolites and 4-pentenates are distilled out of the reaction mixture, the improvement comprises using pentenates in mixture with alkanols.
摘要翻译：在通过异构化制备4-戊烯酸酯的改进方法中，其中异构戊烯酸酯在升高的温度下用沸石和4-戊烯酸酯从反应混合物中蒸馏出来，其改进包括使用与烷醇混合的戊烯酸酯。

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