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1. 发明授权

US07718838B2 Olefin production process 有权
标题翻译：烯烃生产过程
公开(公告)号：US07718838B2
公开(公告)日：2010-05-18
申请号：US11637407
申请日：2006-12-12
申请人： William M. Woodard , Warren M. Ewert , Harvey D. Hensley , Mark E. Lashier , Glyndal D. Cowan , Jeffrey W. Freeman , Ralph V. Franklin , Ronald D. Knudsen , Richard L. Anderson , Lyle R. Kallenbach , Bruce E. Kreischer
发明人： William M. Woodard , Warren M. Ewert , Harvey D. Hensley , Mark E. Lashier , Glyndal D. Cowan , Jeffrey W. Freeman , Ralph V. Franklin , Ronald D. Knudsen , Richard L. Anderson , Lyle R. Kallenbach , Bruce E. Kreischer
IPC分类号： C07C2/26
CPC分类号： B01J31/122 , B01J31/0231 , B01J31/04 , B01J31/143 , B01J31/181 , B01J2231/20 , B01J2531/62 , C07C2/30 , C07C2527/08 , C07C2527/10 , C07C2527/126 , C07C2527/135 , C07C2531/02 , C07C2531/14 , C07C2531/22 , Y02P20/584 , C07C11/107
摘要： A process is provided to stabilize and/or reactivate an olefin production catalyst system which comprises contacting an olefin production catalyst system, either before or after use, with an aromatic compound.
摘要翻译：提供了一种稳定和/或重新活化烯烃生产催化剂体系的方法，其包括将烯烃生产催化剂体系在使用前或使用后与芳族化合物接触。

2. 发明授权

US07157612B2 Olefin production process 有权
标题翻译：烯烃生产过程
公开(公告)号：US07157612B2
公开(公告)日：2007-01-02
申请号：US10872250
申请日：2004-06-18
申请人： Warren M. Ewert , William M. Woodard , Harvey D. Hensley , Mark E. Lashier , Glyndal D. Cowan , Jeffrey W. Freeman , Ralph V. Franklin , Ronald D. Knudsen , Richard L. Anderson , Lyle R. Kallenbach , Bruce E. Kreischer
发明人： Warren M. Ewert , William M. Woodard , Harvey D. Hensley , Mark E. Lashier , Glyndal D. Cowan , Jeffrey W. Freeman , Ralph V. Franklin , Ronald D. Knudsen , Richard L. Anderson , Lyle R. Kallenbach , Bruce E. Kreischer
IPC分类号： C07C2/26 , C07C2/30
CPC分类号： B01J31/122 , B01J31/0231 , B01J31/04 , B01J31/143 , B01J31/181 , B01J2231/20 , B01J2531/62 , C07C2/30 , C07C2527/08 , C07C2527/10 , C07C2527/126 , C07C2527/135 , C07C2531/02 , C07C2531/14 , C07C2531/22 , Y02P20/584 , C07C11/107
摘要： A process is provided to stabilize and/or reactivate an olefin production catalyst system which comprises contacting an olefin production catalyst system, either before or after use, with an aromatic compound.
摘要翻译：提供了一种稳定和/或重新活化烯烃生产催化剂体系的方法，其包括将烯烃生产催化剂体系在使用前或使用后与芳族化合物接触。

3. 发明授权

US5689028A Process to regulate olefin production by catalyst system inhibition 失效
标题翻译：通过催化剂体系抑制调节烯烃生产的工艺
公开(公告)号：US5689028A
公开(公告)日：1997-11-18
申请号：US573655
申请日：1995-12-18
申请人： Mark E. Lashier , Jeffrey W. Freeman , Ronald D. Knudsen
发明人： Mark E. Lashier , Jeffrey W. Freeman , Ronald D. Knudsen
IPC分类号： C08F2/00 , B01J31/40 , C07C2/08 , C07C2/30 , C07C7/00 , C07C7/148 , C07C7/17 , C07C7/171 , C07C11/00 , C08F4/60 , C08F4/64 , C07C2/24 , B01J31/00
CPC分类号： B01J31/181 , B01J31/04 , B01J31/122 , B01J31/143 , B01J31/223 , B01J31/2234 , B01J31/4015 , C07C2/30 , C07C7/005 , C07C7/1485 , C07C7/17 , C07C7/171 , B01J2231/20 , B01J2531/62 , B01J31/0244 , B01J31/2208 , B01J31/34 , C07C2531/02 , C07C2531/14 , Y02P20/584
摘要： A process is provided to inhibit trimerization catalyst system activity which comprises the sequential steps of contacting a reactor effluent stream with alcohol; removing any desired olefin products; adding an aqueous base to the non-olefin portion; removing a precipitate; separating the aqueous and organic phases; and adding an acid to the aqueous phase.
摘要翻译：提供了一种抑制三聚催化剂体系活性的方法，其包括使反应器流出物流与醇接触的顺序步骤; 去除任何所需的烯烃产物; 向所述非烯烃部分加入碱水溶液; 去除沉淀物; 分离水相和有机相; 并向水相中加入酸。

4. 发明授权

US5563312A Olefin production 失效
标题翻译：烯烃生产
公开(公告)号：US5563312A
公开(公告)日：1996-10-08
申请号：US444479
申请日：1995-05-19
申请人： Ronald D. Knudsen , Jeffrey W. Freeman , Mark E. Lashier
发明人： Ronald D. Knudsen , Jeffrey W. Freeman , Mark E. Lashier
IPC分类号： C08F2/00 , B01J31/02 , B01J31/04 , B01J31/12 , B01J31/18 , B01J31/22 , B01J31/30 , C07C2/08 , C07C2/30 , C07C2/32 , C07C11/107 , C08F4/22 , C08F4/60 , C08F4/69 , C07C2/24
CPC分类号： B01J31/04 , B01J31/0244 , B01J31/122 , B01J31/128 , B01J31/143 , B01J31/223 , B01J31/4007 , B01J2231/20 , B01J2531/62
摘要： A process is provided to stabilize and/or reactivate an olefin production catalyst system which comprises contacting an olefin production catalyst system, either before or after use, with an aromatic compound.
摘要翻译：提供了一种稳定和/或重新活化烯烃生产催化剂体系的方法，其包括将烯烃生产催化剂体系在使用前或使用后与芳族化合物接触。

5. 发明授权

US5543375A Olefin production 失效
公开(公告)号：US5543375A
公开(公告)日：1996-08-06
申请号：US198331
申请日：1994-02-18
申请人： Mark E. Lashier , Jeffrey W. Freeman , Ronald D. Knudsen
发明人： Mark E. Lashier , Jeffrey W. Freeman , Ronald D. Knudsen
IPC分类号： C08F2/00 , B01J31/02 , B01J31/04 , B01J31/12 , B01J31/18 , B01J31/22 , B01J31/30 , C07C2/08 , C07C2/30 , C07C2/32 , C07C11/107 , C08F4/22 , C08F4/60 , C08F4/69 , B01J31/34
CPC分类号： B01J31/04 , B01J31/0244 , B01J31/122 , B01J31/128 , B01J31/143 , B01J31/223 , B01J31/4007 , B01J2231/20 , B01J2531/62
摘要： A process is provided to stabilize and/or reactivate an olefin production catalyst system which comprises contacting an olefin production catalyst system, either before or after use, with an aromatic compound.

6. 发明授权

US5210361A Allyl alkali metal alkene addition process 失效
标题翻译：烯丙基碱金属烯烃加成工艺
公开(公告)号：US5210361A
公开(公告)日：1993-05-11
申请号：US769278
申请日：1991-10-01
申请人： Mark E. Lashier , Mark E. Lashier , Henry L. Hsieh
发明人： Mark E. Lashier , Mark E. Lashier , Henry L. Hsieh
IPC分类号： B01J31/22 , C07C2/30
CPC分类号： B01J31/122 , B01J31/0212 , B01J31/2291 , B01J31/26 , C07C2/30 , B01J21/04 , B01J21/08 , B01J21/12 , B01J2231/323 , B01J2531/13 , C07C2531/12
摘要： A process is provided comprising contacting a hydrocarbyl lithium with an alkali metal hydrocarbyloxide in the presence of propylene. Optionally, a catalytic support is used during said contacting. Optionally, at least one other alpha-olefin is present during said contacting.In another embodiment a process is provided comprising: (a) contacting a hydrocarbyl lithium with an alkali metal hydrocarbyloxide in the presence of propylene; and thereafter (b) recovering an allyl alkali metal compound; and thereafter (c) contacting said allyl alkali metal compound with at least one alpha-olefin. Optionally, a catalytic support is also used during steps a, b, and c.
摘要翻译：提供了一种方法，包括在丙烯存在下使烃基锂与碱金属烃氧化物接触。任选地，在所述接触期间使用催化载体。任选地，在所述接触期间存在至少一种其它α-烯烃。在另一个实施方案中，提供了一种方法，包括：（a）在丙烯存在下使烃基锂与碱金属烃氧化物接触; （b）回收烯丙基碱金属化合物; 然后（c）使所述烯丙基碱金属化合物与至少一种α-烯烃接触。任选地，在步骤a，b和c期间也使用催化载体。

7. 发明授权

US5196622A Alkene addition process 失效
标题翻译：烯酸加成工艺
公开(公告)号：US5196622A
公开(公告)日：1993-03-23
申请号：US796142
申请日：1991-11-22
申请人： Ted M. Pettijohn , Mark E. Lashier
发明人： Ted M. Pettijohn , Mark E. Lashier
IPC分类号： C07C2/72
CPC分类号： C07C2/72 , C07C2531/02 , C07C2531/12
摘要： A process is provided comprising contacting a hydrocarbyl alkali metal compound with a nitrogen-containing compound in the presence of an aromatic compound and at least one alpha-olefin. Optionally, a catalytic support is present during this contacting. In another embodiment of this invention a process is provided comprising: (a) contacting a hydrocarbyl alkali metal compound with a nitrogen-containing compound in the presence of an aromatic compound; and thereafter (b) recovering an aromatic/alkali metal/nitrogen complex; and thereafter (c) contacting said aromatic/alkali metal/nitrogen complex with an alpha-olefin. Optionally, a catalytic support is present during steps a, b, and c.
摘要翻译：提供了一种方法，包括在芳族化合物和至少一种α-烯烃的存在下使烃基碱金属化合物与含氮化合物接触。任选地，在该接触期间存在催化载体。在本发明的另一个实施方案中，提供了一种方法，包括：（a）在芳族化合物存在下使烃基碱金属化合物与含氮化合物接触; （b）回收芳香/碱金属/氮络合物; 然后（c）使所述芳族/碱金属/氮络合物与α-烯烃接触。任选地，在步骤a，b和c期间存在催化载体。

8. 发明授权

US06258989B1 Hydrocarbon upgrading process 有权
标题翻译：碳氢化合物升级过程
公开(公告)号：US06258989B1
公开(公告)日：2001-07-10
申请号：US09410516
申请日：1999-09-30
申请人： Steven A. Owen , Marvin M. Johnson , Tin-Tack Peter Cheung , Mark E. Lashier
发明人： Steven A. Owen , Marvin M. Johnson , Tin-Tack Peter Cheung , Mark E. Lashier
IPC分类号： C07C202
CPC分类号： C10G69/00 , C07C2/02 , C07C2603/68 , C10G65/06 , C10G69/126 , C07C13/61
摘要： A hydrocarbon feedstock containing C5 olefins, C5 diolefins, CPD, DCPD, and aromatics is processed by the steps of heating a hydrocarbon feedstock containing CPD, DCPD, C5 diolefins, benzene, toluene, and xylene in a heating zone, to dimerize CPD to DCPD, thereby forming a first effluent; separating the first effluent into a C6+ stream and a C5 diolefin stream; separating the C6+ stream into a C6-C9 stream and a C10+ stream; separating the C10+ stream into a fuel oil stream and a DCPD stream; and hydrotreating the C6-C9 stream to thereby form a BTX stream. In an alternate embodiment, the hydrocarbon feedstock is processed by the steps of heating the hydrocarbon feedstock in a heating zone, to dimerize CPD to DCPD, thereby forming a first effluent; separating the first effluent into a C5-C9 stream and a C10+ stream; separating the C10+ stream into a fuel oil stream and a DCPD stream; contacting the C5-C9 stream with a selective hydrogenation catalyst, in a first reaction zone and in the presence of hydrogen, to hydrogenate at least a portion of the diolefins, alkynes, and styrene contained in the C5-C9 stream, thereby forming a second effluent; separating the second effluent into a C6-C9 stream and a C5 olefin stream; and contacting the C6-C9 stream with a hydrodesulfurization catalyst, in a second reaction zone and in the presence of hydrogen, to desulfurize at least a portion of the sulfur-containing compounds contained in the C6-C9 stream thereby forming a BTX stream.
摘要翻译：通过在加热区中加热含有CPD，DCPD，C5二烯烃，苯，甲苯和二甲苯的烃原料以将CPD二聚化为DCPD的步骤来处理含有C5烯烃，C5二烯烃，CPD，DCPD和芳族化合物的烃原料，从而形成第一流出物; 将第一流出物分离成C6 +流和C5二烯烃流; 将C6 +流分离成C6-C9流和C10 +流; 将C10 +流分离成燃料油流和DCPD流; 并加氢处理C6-C9流，从而形成BTX流。在替代实施方案中，烃原料通过以下步骤加工：在加热区中加热烃原料，将CPD二聚到DCPD，由此形成第一流出物; 将第一流出物分离成C5-C9流和C10 +流; 将C10 +流分离成燃料油流和DCPD流; 在第一反应区和氢的存在下，将C5-C9流与选择性氢化催化剂接触，氢化C5-C9流中所含的二烯烃，炔烃和苯乙烯的至少一部分，从而形成第二流出物将第二流出物分离成C6-C9流和C5烯烃流; 并在第二反应区和氢气存在下使C6-C9流与加氢脱硫催化剂接触，以将C6-C9流中至少一部分含硫化合物脱硫，从而形成BTX流。

9. 发明授权

US06737557B2 Hydrocarbon upgrading process 有权
标题翻译：碳氢化合物升级过程
公开(公告)号：US06737557B2
公开(公告)日：2004-05-18
申请号：US09801558
申请日：2001-03-08
申请人： Tin-Tack Peter Cheung , Steven A. Owen , Marvin M. Johnson , Mark E. Lashier
发明人： Tin-Tack Peter Cheung , Steven A. Owen , Marvin M. Johnson , Mark E. Lashier
IPC分类号： C07C709
CPC分类号： C10G69/00 , C07C2/02 , C07C2603/68 , C10G65/06 , C10G69/126 , C07C13/61
摘要： A process for recovering DCPD from a hydrocarbon feedstock comprising introducing the hydrocarbon feedstock to a first column, recovering an overhead stream from the first column comprising C9− hydrocarbons, recovering a bottom stream from the first column comprising C10+ hydrocarbons, feeding the bottom stream from the first column to a second column, recovering an overhead stream from the second column comprising DCPD, and recovering a bottom stream from the second column comprising fuel oil, wherein the two columns are sized and operated at defined conditions such as pressures, temperatures, reflux rates, and reboil rates.
摘要翻译：一种从烃原料回收DCPD的方法，包括将烃原料引入第一塔，从包含C 9烃的第一塔回收塔顶物流，从包含C10 +烃的第一塔回收底部物流，将来自从第一塔到第二塔，从包括DCPD的第二塔回收塔顶流，以及从包括燃料油的第二塔回收底部流，其中两个塔的尺寸和操作在限定的条件下，例如压力，温度，回流速率，并重新燃起利率。

10. 发明授权

US5859303A Olefin production 失效
标题翻译：烯烃生产
公开(公告)号：US5859303A
公开(公告)日：1999-01-12
申请号：US574031
申请日：1995-12-18
申请人： Mark E. Lashier
发明人： Mark E. Lashier
IPC分类号： B01J31/22 , C07C2/08 , C07C2/30 , C07C11/02 , C10G50/00
CPC分类号： C07C2/30 , C07C2527/132 , C07C2531/04 , C07C2531/12 , C07C2531/14 , C07C2531/22
摘要： A process is provided to trimerize or oligomerize olefins in the presence of an olefin oligomerization catalyst and a solvent which is a product of the olefin oligomerization process.
摘要翻译：提供了在烯烃低聚催化剂和作为烯烃低聚方法的产物的溶剂的存在下使烯烃三聚或低聚的方法。

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