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    • 10. 发明授权
    • Removal of linear internal olefins from steam active dehydrogenation
recycle stream
    • 从蒸汽活性脱氢再循环流中除去线性内烯烃
    • US5113023A
    • 1992-05-12
    • US552868
    • 1990-07-16
    • Richard L. Anderson
    • Richard L. Anderson
    • C07C41/06
    • C07C41/06
    • A process in which isobutane (isoparaffins), containing normal butane (normal paraffins), is dehydrogenated, and the principal product, isobutene, (isoolefin) contains some butene-1 and butene-2 (1-olefins and linear internal olefins). This mixture is subjected to a catalyzed etherification reaction with an alcohol to yield tertiaryalkyl ether. Some unreacted butene-1 and butene-2 (linear olefins) appear in the effluent from the ether reacton zone. These detrimentally affect the advantage of recycling that part of the effluent constituted by isobutane (isoparaffin) to the dehydrogenation reactor, because, as they build up in the closed system, undesirable coke lay down on the dehydrogenating catalyst occurs. The undesirable butene-1 is hydroisomerized to butene-2 which is removed from the recycle stream by fractionation.
    • 其中含有正丁烷(正链烷烃)的异丁烷(异链烷烃)被脱氢,主要产物异丁烯(异烯烃)含有一些丁烯-1和丁烯-2(1-烯烃和线性内烯烃))的方法。 将该混合物与醇进行催化醚化反应,得到叔烷基醚。 在醚反应区的流出物中出现一些未反应的丁烯-1和丁烯-2(直链烯烃)。 这些有害地影响将由异丁烷(异链烷烃)构成的部分流出物回收到脱氢反应器的优点,因为当它们在封闭系统中积聚时,发生在脱氢催化剂上放置不希望的焦炭。 将不期望的丁烯-1加氢异构化成丁烯-2,其通过分馏从再循环流中除去。