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1. 发明申请

US20080015369A1 Batch, semi-continuous or continuous hydrochlorination of glycerin with reduced volatile chlorinated hydrocarbon by-products and chloracetone levels 有权
标题翻译：分批，半连续或连续氢氯化甘油与挥发性氯化烃副产物和氯丙酮水平降低
公开(公告)号：US20080015369A1
公开(公告)日：2008-01-17
申请号：US11710002
申请日：2007-02-22
申请人： William Kruper , Tina Arrowood , Bruce Bell , John Briggs , Robert Campbell , Bruce Hook , Anh Nguyen , Curt Theriault , Ralf Fitschen
发明人： William Kruper , Tina Arrowood , Bruce Bell , John Briggs , Robert Campbell , Bruce Hook , Anh Nguyen , Curt Theriault , Ralf Fitschen
IPC分类号： C07D301/27 , C07C31/34
CPC分类号： C07D301/27 , C07C29/62 , C07C67/08 , C07C67/287 , C07C69/003 , C07C69/63 , C07C31/36 , C07C31/42
摘要： The present invention relates to a process for converting a multihydroxylated-aliphatic hydrocarbon or ester thereof to a chlorohydrin, by contacting the multihydroxylated-aliphatic hydrocarbon or ester thereof starting material with a source of hydrogen chloride at superatmospheric, atmospheric and subatmospheric pressure conditions for a sufficient time and at a sufficient temperature, preferably wherein such contracting step is carried out without substantial removal of water, to produce the desired chlorohydrin product; wherein the desired product or products can be made in high yield without substantial formation of undesired overchlorinated byproducts; said process carried out without a step undertaken to specifically remove volatile chlorinated hydrocarbon by-products or chloroacetone, wherein the combined concentration of volatile chlorinated hydrocarbon by-products and chloroacetone is less than 2000 ppm throughout any stage of the said process.
摘要翻译：本发明涉及一种将多羟基化脂肪族烃或其酯转化为氯代醇的方法，其通过使多羟基化的脂族烃或其起始原料与超大气压，大气压和低于大气压的条件下的氯化氢源接触足够的时间和足够的温度，优选地其中这种收缩步骤在不基本除去水的情况下进行，以产生所需的氯代醇产物; 其中所需产物或产物可以以高产率制备而不显着形成不需要的过氯化副产物; 所述方法没有进行特别去除挥发性氯化烃副产物或氯丙酮的步骤，其中在所述方法的任何阶段，挥发性氯化烃副产物和氯丙酮的组合浓度小于2000ppm。

2. 发明授权

US08304563B2 Batch, semi-continuous or continuous hydrochlorination of glycerin with reduced volatile chlorinated hydrocarbon by-products and chloroacetone levels 有权
标题翻译：分批，半连续或连续氢氯化甘油与挥发性氯化碳氢化合物副产物和氯丙酮水平降低
公开(公告)号：US08304563B2
公开(公告)日：2012-11-06
申请号：US13017645
申请日：2011-01-31
申请人： William J. Kruper , Tina Arrowood , Bruce M. Bell , John Briggs , Robert M. Campbell , Bruce D. Hook , Anh Nguyen , Curt Theriault , Ralf Fitschen
发明人： William J. Kruper , Tina Arrowood , Bruce M. Bell , John Briggs , Robert M. Campbell , Bruce D. Hook , Anh Nguyen , Curt Theriault , Ralf Fitschen
IPC分类号： C07D301/24
CPC分类号： C07D301/27 , C07C29/62 , C07C67/08 , C07C67/287 , C07C69/003 , C07C69/63 , C07C31/36 , C07C31/42
摘要： The present invention relates to a process for converting a multihydroxylated-aliphatic hydrocarbon or ester thereof to a chlorohydrin, by contacting the multihydroxylated-aliphatic hydrocarbon or ester thereof starting material with a source of hydrogen chloride at superatmospheric, atmospheric and subatmospheric pressure conditions for a sufficient time and at a sufficient temperature, preferably wherein such contracting step is carried out without substantial removal of water, to produce the desired chlorohydrin product; wherein the desired product or products can be made in high yield without substantial formation of undesired overchlorinated byproducts; said process carried out without a step undertaken to specifically remove volatile chlorinated hydrocarbon by-products or chloroacetone, wherein the combined concentration of volatile chlorinated hydrocarbon by-products and chloroacetone is less than 2000 ppm throughout any stage of the said process.
摘要翻译：本发明涉及一种将多羟基化脂肪族烃或其酯转化为氯代醇的方法，其通过使多羟基化的脂族烃或其起始原料与超大气压，大气压和低于大气压的条件下的氯化氢源接触足够的时间和足够的温度，优选地其中这种收缩步骤在不基本除去水的情况下进行，以产生所需的氯代醇产物; 其中所需产物或产物可以以高产率制备而不显着形成不需要的过氯化副产物; 所述方法没有进行特别去除挥发性氯化烃副产物或氯丙酮的步骤，其中在所述方法的任何阶段，挥发性氯化烃副产物和氯丙酮的组合浓度小于2000ppm。

3. 发明授权

US07906690B2 Batch, semi-continuous or continuous hydrochlorination of glycerin with reduced volatile chlorinated hydrocarbon by-products and chloracetone levels 有权
标题翻译：分批，半连续或连续氢氯化甘油与挥发性氯化烃副产物和氯丙酮水平降低
公开(公告)号：US07906690B2
公开(公告)日：2011-03-15
申请号：US11710002
申请日：2007-02-22
申请人： William J. Kruper, Jr. , Tina Arrowood , Bruce Michael Bell , John Briggs , Robert M. Campbell , Bruce D. Hook , Anh Nguyen , Curt Theriault , Ralf Fitschen
发明人： William J. Kruper, Jr. , Tina Arrowood , Bruce Michael Bell , John Briggs , Robert M. Campbell , Bruce D. Hook , Anh Nguyen , Curt Theriault , Ralf Fitschen
IPC分类号： C07C31/34
CPC分类号： C07D301/27 , C07C29/62 , C07C67/08 , C07C67/287 , C07C69/003 , C07C69/63 , C07C31/36 , C07C31/42
摘要： The present invention relates to a process for converting a multihydroxylated-aliphatic hydrocarbon or ester thereof to a chlorohydrin, by contacting the multihydroxylated-aliphatic hydrocarbon or ester thereof starting material with a source of hydrogen chloride at superatmospheric, atmospheric and subatmospheric pressure conditions for a sufficient time and at a sufficient temperature, preferably wherein such contracting step is carried out without substantial removal of water, to produce the desired chlorohydrin product; wherein the desired product or products can be made in high yield without substantial formation of undesired overchlorinated byproducts; said process carried out without a step undertaken to specifically remove volatile chlorinated hydrocarbon by-products or chloroacetone, wherein the combined concentration of volatile chlorinated hydrocarbon by-products and chloroacetone is less than 2000 ppm throughout any stage of the said process.
摘要翻译：本发明涉及一种将多羟基化脂肪族烃或其酯转化为氯代醇的方法，其通过使多羟基化的脂族烃或其起始原料与超大气压，大气压和低于大气压的条件下的氯化氢源接触足够的时间和足够的温度，优选地其中这种收缩步骤在不基本除去水的情况下进行，以产生所需的氯代醇产物; 其中所需产物或产物可以以高产率制备而不显着形成不需要的过氯化副产物; 所述方法没有进行特别去除挥发性氯化烃副产物或氯丙酮的步骤，其中在所述方法的任何阶段，挥发性氯化烃副产物和氯丙酮的组合浓度小于2000ppm。

4. 发明授权

US08404905B2 Batch, semi-continuous or continuous hydrochlorination of glycerin with reduced volatile chlorinated hydrocarbon by-products and chloroacetone levels 失效
标题翻译：分批，半连续或连续氢氯化甘油与挥发性氯化碳氢化合物副产物和氯丙酮水平降低
公开(公告)号：US08404905B2
公开(公告)日：2013-03-26
申请号：US13017681
申请日：2011-01-31
申请人： William J. Kruper , Tina Arrowood , Bruce M. Bell , John Briggs , Robert M. Campbell , Bruce D. Hook , Anh Nguyen , Curt Theriault , Ralf Fitschen
发明人： William J. Kruper , Tina Arrowood , Bruce M. Bell , John Briggs , Robert M. Campbell , Bruce D. Hook , Anh Nguyen , Curt Theriault , Ralf Fitschen
IPC分类号： C07C29/00 , C07C31/34 , C07D301/27
CPC分类号： C07D301/27 , C07C29/62 , C07C67/08 , C07C67/287 , C07C69/003 , C07C69/63 , C07C31/36 , C07C31/42
摘要： The present invention relates to a process for converting a multihydroxylated-aliphatic hydrocarbon or ester thereof to a chlorohydrin, by contacting the multihydroxylated-aliphatic hydrocarbon or ester thereof starting material with a source of hydrogen chloride at superatmospheric, atmospheric and subatmospheric pressure conditions for a sufficient time and at a sufficient temperature, preferably wherein such contracting step is carried out without substantial removal of water, to produce the desired chlorohydrin product; wherein the desired product or products can be made in high yield without substantial formation of undesired overchlorinated byproducts; said process carried out without a step undertaken to specifically remove volatile chlorinated hydrocarbon by-products or chloroacetone, wherein the combined concentration of volatile chlorinated hydrocarbon by-products and chloroacetone is less than 2000 ppm throughout any stage of the said process.
摘要翻译：本发明涉及一种将多羟基化脂肪族烃或其酯转化为氯代醇的方法，其通过使多羟基化的脂族烃或其起始原料与超大气压，大气压和低于大气压的条件下的氯化氢源接触足够的时间和足够的温度，优选地其中这种收缩步骤在不基本除去水的情况下进行，以产生所需的氯代醇产物; 其中所需产物或产物可以以高产率制备而不显着形成不需要的过氯化副产物; 所述方法没有进行特别去除挥发性氯化烃副产物或氯丙酮的步骤，其中在所述方法的任何阶段，挥发性氯化烃副产物和氯丙酮的组合浓度小于2000ppm。

5. 发明申请

US20110124892A1 BATCH, SEMI-CONTINUOUS OR CONTINUOUS HYDROCHLORINATIONOF GLYCERIN WITH REDUCED VOLATILE CHLORINATED HYDROCARBON BY-PRODUCTS AND CHLOROACETONE LEVELS 失效
公开(公告)号：US20110124892A1
公开(公告)日：2011-05-26
申请号：US13017681
申请日：2011-01-31
申请人： William J. Kruper, JR. , Tina Arrowood , Bruce Michael Bell , John Briggs , Robert M. Campbell , Bruce D. Hook , Anh Nguyen , Curt Theriault , Ralf Fitschen
发明人： William J. Kruper, JR. , Tina Arrowood , Bruce Michael Bell , John Briggs , Robert M. Campbell , Bruce D. Hook , Anh Nguyen , Curt Theriault , Ralf Fitschen
IPC分类号： C07D301/26 , C07C29/60 , C07C67/00
CPC分类号： C07D301/27 , C07C29/62 , C07C67/08 , C07C67/287 , C07C69/003 , C07C69/63 , C07C31/36 , C07C31/42
摘要： The present invention relates to a process for converting a multihydroxylated-aliphatic hydrocarbon or ester thereof to a chlorohydrin, by contacting the multihydroxylated-aliphatic hydrocarbon or ester thereof starting material with a source of hydrogen chloride at superatmospheric, atmospheric and subatmospheric pressure conditions for a sufficient time and at a sufficient temperature, preferably wherein such contracting step is carried out without substantial removal of water, to produce the desired chlorohydrin product; wherein the desired product or products can be made in high yield without substantial formation of undesired overchlorinated byproducts; said process carried out without a step undertaken to specifically remove volatile chlorinated hydrocarbon by-products or chloroacetone, wherein the combined concentration of volatile chlorinated hydrocarbon by-products and chloroacetone is less than 2000 ppm throughout any stage of the said process.

6. 发明申请

US20110124890A1 BATCH, SEMI-CONTINUOUS OR CONTINUOUS HYDROCHLORINATIONOF GLYCERIN WITH REDUCED VOLATILE CHLORINATED HYDROCARBON BY-PRODUCTS AND CHLOROACETONE LEVELS 有权
标题翻译：具有降低挥发性氯化氢的碳氢化合物副产物和氯仿酮水平的甘氨酸的连续或连续或连续氢化
公开(公告)号：US20110124890A1
公开(公告)日：2011-05-26
申请号：US13017645
申请日：2011-01-31
申请人： William J. Kruper , Tina Arrowood , Bruce M. Bell , John Briggs , Robert M. Campbell , Bruce D. Hook , Anh Nguyen , Curt Theriault , Ralf Fitschen
发明人： William J. Kruper , Tina Arrowood , Bruce M. Bell , John Briggs , Robert M. Campbell , Bruce D. Hook , Anh Nguyen , Curt Theriault , Ralf Fitschen
IPC分类号： C07D301/30 , C07C31/42
CPC分类号： C07D301/27 , C07C29/62 , C07C67/08 , C07C67/287 , C07C69/003 , C07C69/63 , C07C31/36 , C07C31/42
摘要： The present invention relates to a process for converting a multihydroxylated-aliphatic hydrocarbon or ester thereof to a chlorohydrin, by contacting the multihydroxylated-aliphatic hydrocarbon or ester thereof starting material with a source of hydrogen chloride at superatmospheric, atmospheric and subatmospheric pressure conditions for a sufficient time and at a sufficient temperature, preferably wherein such contracting step is carried out without substantial removal of water, to produce the desired chlorohydrin product; wherein the desired product or products can be made in high yield without substantial formation of undesired overchlorinated byproducts; said process carried out without a step undertaken to specifically remove volatile chlorinated hydrocarbon by-products or chloroacetone, wherein the combined concentration of volatile chlorinated hydrocarbon by-products and chloroacetone is less than 2000 ppm throughout any stage of the said process.
摘要翻译：本发明涉及一种将多羟基化脂肪族烃或其酯转化为氯代醇的方法，其通过使多羟基化的脂族烃或其起始原料与超大气压，大气压和低于大气压的条件下的氯化氢源接触足够的时间和足够的温度，优选地其中这种收缩步骤在不基本除去水的情况下进行，以产生所需的氯代醇产物; 其中所需产物或产物可以以高产率制备而不显着形成不需要的过氯化副产物; 所述方法没有进行特别去除挥发性氯化烃副产物或氯丙酮的步骤，其中在所述方法的任何阶段，挥发性氯化烃副产物和氯丙酮的组合浓度小于2000ppm。

7. 发明申请

US20080045728A1 Conversion of a Multihydroxylated-Aliphatic Hydrocarbon or Ester Thereof to a Chlorohydrin 有权
标题翻译：将多羟基化脂肪族烃或酯转化为氯代醇
公开(公告)号：US20080045728A1
公开(公告)日：2008-02-21
申请号：US11628269
申请日：2005-07-18
申请人： William Kruper , David Schreck , Kenneth Kearns , Richard Varjian , Mark Jones , Robert Campbell , Bruce Hook , John Briggs , Jeffrey Hippler
发明人： William Kruper , David Schreck , Kenneth Kearns , Richard Varjian , Mark Jones , Robert Campbell , Bruce Hook , John Briggs , Jeffrey Hippler
IPC分类号： C07D301/02 , C07C31/36 , C07C69/63
CPC分类号： C07D301/24 , C07C29/62 , C07C29/82 , C07C31/36 , C07C31/42
摘要： The present invention relates to a process for converting a multihydroxylated-aliphatic hydrocarbon or ester thereof to a chlorohydrin, by contacting the multihydroxylated-aliphatic hydrocarbon or ester thereof starting material with a source of a superatmospheric partial pressure of hydrogen chloride for a sufficient time and at a sufficient temperature, and wherein such contracting step is carried out without substantial removal of water, to produce the desired chlorohydrin product; wherein the desired product or products can be made in high yield without substantial formation of undesired overchlorinated byproducts. In addition, certain catalysts of the present invention may be used in the present process at superatmospheric, atmospheric and subatmospheric pressure conditions with improved results.
摘要翻译：本发明涉及将多羟基化脂肪族烃或其酯转化为氯代醇的方法，该方法是将多羟基化脂族烃或其起始原料与氯化氢的超大气压分压源接触足够的时间和足够的温度，并且其中这种收缩步骤在不显着除去水的情况下进行，以产生所需的氯代醇产物; 其中所需的产物或产物可以高产率制备而不显着形成不需要的过氯化副产物。此外，本发明的某些催化剂可以在超大气压，大气压和低于大气压的条件下用于本方法，并具有改进的结果。

8. 发明申请

US20080015370A1 Process for the conversion of a crude glycerol, crude mixtures of naturally derived multicomponent aliphatic hydrocarbons or esters thereof to a chlorohydrin 有权
标题翻译：将粗甘油，天然衍生的多组分脂族烃或其酯的粗混合物转化为氯代醇的方法
公开(公告)号：US20080015370A1
公开(公告)日：2008-01-17
申请号：US11710010
申请日：2007-02-22
申请人： Bruce Hook , John Briggs , Robert Campbell , William Kruper , David Schreck , Richard Varjian , Jeffrey Hippler
发明人： Bruce Hook , John Briggs , Robert Campbell , William Kruper , David Schreck , Richard Varjian , Jeffrey Hippler
IPC分类号： C07D301/27 , C07C31/34
CPC分类号： C07D301/27 , C07C29/62 , C07C67/287 , C07C69/003 , C07C69/63 , C07C31/36 , C07C31/42
摘要： A process for converting a crude glycerol, crude mixtures of naturally derived multihydroxylated-aliphatic hydrocarbons or esters thereof to a chlorohydrin, by contacting the crude glycerol, crude mixtures of naturally derived multihydroxylated-aliphatic hydrocarbons or esters thereof starting material with a source of a superatmospheric partial pressure of hydrogen chloride for a sufficient time and at a sufficient temperature, and wherein such contracting step is carried out without substantial removal of water, to produce the desired chlorohydrin product; wherein the desired product or products can be made in high yield without substantial formation of undesired overchlorinated byproducts; wherein said crude glycerol, said ester of crude glycerol, or mixture thereof is derived from a renewable raw material. Chlorohydrins made by the process of the present invention are useful in preparing epoxides such as epichlorohydrins.
摘要翻译：通过将粗甘油，天然衍生的多羟基化脂肪族烃或其酯的起始原料的粗混合物与超大气压源的原料甘油，天然衍生的多羟基化脂肪族烃或其酯的粗混合物与氯代醇反应，氯化氢的分压足够的时间和足够的温度，并且其中这种收缩步骤在不基本除去水的情况下进行，以产生所需的氯代醇产物; 其中所需产物或产物可以以高产率制备而不显着形成不需要的过氯化副产物; 其中所述粗甘油，所述粗甘油酯或其混合物衍生自可再生原料。通过本发明方法制备的氯代醇可用于制备环氧化物如表氯醇。

9. 发明授权

US08236975B2 Process for the conversion of a crude glycerol, crude mixtures of naturally derived multicomponent aliphatic hydrocarbons or esters thereof to a chlorohydrin 有权
标题翻译：将粗甘油，天然衍生的多组分脂族烃或其酯的粗混合物转化为氯代醇的方法
公开(公告)号：US08236975B2
公开(公告)日：2012-08-07
申请号：US13023783
申请日：2011-02-09
申请人： Bruce D. Hook , John Briggs , Robert M. Campbell , William J. Kruper , David J. Schreck , Richard D. Varjian , Jeffrey G. Hippler
发明人： Bruce D. Hook , John Briggs , Robert M. Campbell , William J. Kruper , David J. Schreck , Richard D. Varjian , Jeffrey G. Hippler
IPC分类号： C07D301/24
CPC分类号： C07D301/27 , C07C29/62 , C07C67/287 , C07C69/003 , C07C69/63 , C07C31/36 , C07C31/42
摘要： A process for converting a crude glycerol, crude mixtures of naturally derived multihydroxylated-aliphatic hydrocarbons or esters thereof to a chlorohydrin, by contacting the crude glycerol, crude mixtures of naturally derived multihydroxylated-aliphatic hydrocarbons or esters thereof starting material with a source of a superatmospheric partial pressure of hydrogen chloride for a sufficient time and at a sufficient temperature, and wherein such contracting step is carried out without substantial removal of water, to produce the desired chlorohydrin product; wherein the desired product or products can be made in high yield without substantial formation of undesired overchlorinated byproducts; wherein said crude glycerol, said ester of crude glycerol, or mixture thereof is derived from a renewable raw material. Chlorohydrins made by the process of the present invention are useful in preparing epoxides such as epichlorohydrins.
摘要翻译：通过将粗甘油，天然衍生的多羟基化脂肪族烃或其酯的起始原料的粗混合物与超大气压源的原料甘油，天然衍生的多羟基化脂肪族烃或其酯的粗混合物与氯代醇反应，氯化氢的分压足够的时间和足够的温度，并且其中这种收缩步骤在不基本除去水的情况下进行，以产生所需的氯代醇产物; 其中所需产物或产物可以以高产率制备而不显着形成不需要的过氯化副产物; 其中所述粗甘油，所述粗甘油酯或其混合物衍生自可再生原料。通过本发明方法制备的氯代醇可用于制备环氧化物如表氯醇。

10. 发明申请

US20070100169A1 Minimization of ligand degradation products, of reversion of same to useful phosphine ligands 有权
标题翻译：最小化配体降解产物，将其转化为有用的膦配体
公开(公告)号：US20070100169A1
公开(公告)日：2007-05-03
申请号：US10562602
申请日：2004-06-28
申请人： John Briggs , Wei-Jun Peng , Brian Roesch , Anthony Abatjoglou , Donald Morrison
发明人： John Briggs , Wei-Jun Peng , Brian Roesch , Anthony Abatjoglou , Donald Morrison
IPC分类号： C07F9/02 , C07C45/49
CPC分类号： C07F9/5022 , C07C29/16 , C07C45/50 , C07C45/62 , C07C67/38 , C07C33/03 , C07C69/738 , C07C47/21 , C07C47/02
摘要： A process for the minimization of phosphonium ion ligand degradation products formed during reaction of a polyunsaturated olefin or an unconjugated functionalized olefin in the presence of a transition metal-triorganophosphine ligand complex catalyst to form as a product, by-product, or intermediate product a conjugated functionalized olefin having a carbon-carbon double bond conjugated to an αelectronwithdrawing group, such as, an α,β-unsaturated aldehyde, ketone, ester, acid, or nitrile. The minimization process involves conducting the reaction under selected conditions of conversion, temperature, pressure, or a combination thereof; and/or by selecting a triorganophosphine ligand with a specified steric and/or electronic property. Further, a process for reversion of phosphonium ion ligand degradation product(s) back to useful triorganophosphine ligand(s), the reversion involving treating a reaction product fluid containing the degradation product(s) with an inert gas, hydrogen, synthesis gas, or a mixture thereof under conditions sufficient to regenerate the triorganophosphine ligand(s).
摘要翻译：一种在过渡金属 - 三有机膦配体催化剂存在下，在多不饱和烯烃或非共轭官能化烯烃反应期间形成的鏻离子配体降解产物最小化的方法，以形成产物，副产物或中间产物，共轭具有与α-电子牵伸基团例如α，β-不饱和醛，酮，酯，酸或腈共轭的碳 - 碳双键的官能化烯烃。最小化方法包括在选择的转化条件，温度，压力或其组合下进行反应; 和/或通过选择具有特定空间和/或电子性质的三有机膦配体。此外，将鏻离子配位体降解产物还原回有用的三有机膦配体的方法，涉及用惰性气体，氢气，合成气体或其混合物处理含有降解产物的反应产物流体的逆转其混合物在足以再生三有机膦配体的条件下进行。

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