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    • 9. 发明授权
    • Photoconductive elements having a polymeric barrier layer
    • 具有聚合物阻挡层的光导元件
    • US06593046B2
    • 2003-07-15
    • US09954907
    • 2001-09-18
    • Louis J. SorrieroMichel F. MolaireMarie B. O'ReganWayne T. FerrarDavid S. WeissJane Robin Cowdery
    • Louis J. SorrieroMichel F. MolaireMarie B. O'ReganWayne T. FerrarDavid S. WeissJane Robin Cowdery
    • G03G510
    • C08G73/1082C08G73/14C08G73/16G03G5/142
    • Disclosed are photoconductive elements including a conductive support, e.g., an electrically conductive film, drum, or belt, on which a negatively chargeable photoconductive layer is disposed. An electrical barrier layer is disposed between the conductive support and the photoconductive layer. The barrier layer provides a high energy barrier to the injection of positive charges, but transports electrons under an applied electric field. In embodiments, the barrier layer can transport charge by electronic, or both electronic and ionic mechanisms, and, is not substantially affected by humidity changes. The barrier layer includes a polyester-co-imides, polyesterionomer-co-imides, or polyamide-co-imides having covalently bonded as repeat units in the polymer chain, aromatic tetracarbonylbisimide groups of the formula: wherein Ar1 and Ar2 respectively represent tetravalent or trivalent aromatic groups of 6 to about 20 carbon atoms, and X is O, C(CF3)2, S═O or SO2.
    • 公开了包括导电性支持体(例如,导电膜,鼓或带)的光电导元件,其上设置有带负电的光导电层。 电阻挡层设置在导电支撑体和光电导层之间。 阻挡层为注入正电荷提供了高能量势垒,但在施加的电场下传输电子。 在实施例中,阻挡层可以通过电子或电子和离子机制两者传输电荷,并且基本上不受湿度变化的影响。 阻挡层包括在聚合物链中共价键合作为重复单元的聚酯 - 共 - 酰亚胺,聚酯型聚异氰酸酯 - 共 - 酰亚胺或聚酰胺 - 共 - 酰亚胺,其中Ar 1和Ar 2分别表示四价或三价的芳族四羰基二酰亚胺基团 6至约20个碳原子的芳基,X是O,C(CF 3)2,S = O或SO 2。