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1. 发明授权

US06866977B2 Photoconductive elements having a polymeric barrier layer 失效
标题翻译：具有聚合物阻挡层的光导元件
公开(公告)号：US06866977B2
公开(公告)日：2005-03-15
申请号：US10243702
申请日：2002-09-14
申请人： Louis J. Sorriero , Michel F. Molaire , Marie B. O'Regan , Wayne T. Ferrar , David S. Weiss , Jane Robin Cowdery
发明人： Louis J. Sorriero , Michel F. Molaire , Marie B. O'Regan , Wayne T. Ferrar , David S. Weiss , Jane Robin Cowdery
IPC分类号： C08G73/10 , C08G73/14 , C08G73/16 , G03G5/14 , G03G5/10
CPC分类号： C08G73/16 , C08G73/1082 , C08G73/14 , G03G5/142
摘要： Disclosed are photoconductive elements including a conductive support, e.g., an electrically conductive film, drum, or belt, on which a negatively chargeable photoconductive layer is disposed. An electrical barrier layer is disposed between the conductive support and the photoconductive layer. The barrier layer provides a high energy barrier to the injection of positive charges, but transports electrons under an applied electric field. In embodiments, the barrier layer can transport charge by electronic mechanisms, and, is not substantially affected by humidity changes. The barrier layer includes a polyamide-co-imide having covalently bonded as repeat units in the polymer chain, aromatic tetracarbonylbisimide groups of the formula: wherein Ar1 and Ar2 respectively represent tetravalent or trivalent aromatic groups of 6 to about 20 carbon atoms, and X is O, C(CF3)2, S═O or SO2. The amount of aromatic tetracarbonylbisimide content in the polymer is selected such that the barrier layer can be coated onto the support as a relatively thick layer, which provides for enhanced performance as a photoconductor when used in an electrophotographic process.
摘要翻译：公开了包括导电性支持体（例如，导电膜，鼓或带）的光电导元件，其上设置有带负电的光导电层。电阻挡层设置在导电支撑体和光电导层之间。阻挡层为注入正电荷提供了高能量势垒，但在施加的电场下传输电子。在实施例中，阻挡层可以通过电子机构输送电荷，并且基本上不受湿度变化的影响。阻挡层包括在聚合物链中具有作为重复单元共价键合的聚酰胺 - 共 - 酰亚胺，下式的芳族四羰基双酰亚胺基团：其中Ar 1和Ar 2分别表示6至约20的四价或三价芳族基团碳原子，X是O，C（CF 3）2，S = O或SO 2。选择聚合物中芳族四羰基二酰亚胺含量的量使得阻挡层可以涂覆在载体上作为相对较厚的层，当用于电子照相方法时，这提供了作为光电导体的增强的性能。

2. 发明授权

US06593046B2 Photoconductive elements having a polymeric barrier layer 有权
标题翻译：具有聚合物阻挡层的光导元件
公开(公告)号：US06593046B2
公开(公告)日：2003-07-15
申请号：US09954907
申请日：2001-09-18
申请人： Louis J. Sorriero , Michel F. Molaire , Marie B. O'Regan , Wayne T. Ferrar , David S. Weiss , Jane Robin Cowdery
发明人： Louis J. Sorriero , Michel F. Molaire , Marie B. O'Regan , Wayne T. Ferrar , David S. Weiss , Jane Robin Cowdery
IPC分类号： G03G510
CPC分类号： C08G73/1082 , C08G73/14 , C08G73/16 , G03G5/142
摘要： Disclosed are photoconductive elements including a conductive support, e.g., an electrically conductive film, drum, or belt, on which a negatively chargeable photoconductive layer is disposed. An electrical barrier layer is disposed between the conductive support and the photoconductive layer. The barrier layer provides a high energy barrier to the injection of positive charges, but transports electrons under an applied electric field. In embodiments, the barrier layer can transport charge by electronic, or both electronic and ionic mechanisms, and, is not substantially affected by humidity changes. The barrier layer includes a polyester-co-imides, polyesterionomer-co-imides, or polyamide-co-imides having covalently bonded as repeat units in the polymer chain, aromatic tetracarbonylbisimide groups of the formula: wherein Ar1 and Ar2 respectively represent tetravalent or trivalent aromatic groups of 6 to about 20 carbon atoms, and X is O, C(CF3)2, S═O or SO2.
摘要翻译：公开了包括导电性支持体（例如，导电膜，鼓或带）的光电导元件，其上设置有带负电的光导电层。电阻挡层设置在导电支撑体和光电导层之间。阻挡层为注入正电荷提供了高能量势垒，但在施加的电场下传输电子。在实施例中，阻挡层可以通过电子或电子和离子机制两者传输电荷，并且基本上不受湿度变化的影响。阻挡层包括在聚合物链中共价键合作为重复单元的聚酯 - 共 - 酰亚胺，聚酯型聚异氰酸酯 - 共 - 酰亚胺或聚酰胺 - 共 - 酰亚胺，其中Ar 1和Ar 2分别表示四价或三价的芳族四羰基二酰亚胺基团 6至约20个碳原子的芳基，X是O，C（CF 3）2，S = O或SO 2。

3. 发明授权

US06451956B2 Polymer and photoconductive element having a polymeric barrier layer 失效
标题翻译：具有聚合物阻挡层的聚合物和光电导元件
公开(公告)号：US06451956B2
公开(公告)日：2002-09-17
申请号：US09877763
申请日：2001-06-08
申请人： Louis J. Sorriero , Marie B. O'Regan , Michel F. Molaire
发明人： Louis J. Sorriero , Marie B. O'Regan , Michel F. Molaire
IPC分类号： C08G7310
CPC分类号： C08G73/16 , C08G73/1082 , C08G73/14 , G03G5/142
摘要： In a photoconductive element comprising a conductive support, e.g., an electrically conductive film, drum or belt on which a negatively chargeable photoconductive layer is formed, an electrical barrier layer is formed between the support and the photoconductive layer. The barrier layer provides a high energy barrier to the injection of positive charges but transports electrons under an applied electric field. The barrier layer of the invention transports charge by electronic rather than ionic mechanisms and, therefore, is not substantially affected by humidity changes. The barrier layer comprises a polyester-co-imide, polyesterionomer-co-imide or polyamide-co-imide having covalently bonded as repeating units in the polymer chain, aromatic tetracarboxylbisimide groups of the formula: wherein Ar1 and Ar2 represent, respectively, tetravalent and trivalent aromatic groups of 6 to 20 carbon atoms.
摘要翻译：在包含导电性支持体（例如形成有可带电电荷的光电导层的导电膜，鼓或带）的光电导元件中，在支撑体和光电导层之间形成电阻隔层。阻挡层为注入正电荷提供了高能量势垒，但在施加的电场下传输电子。本发明的阻挡层通过电子而不是离子机制传输电荷，因此基本上不受湿度变化的影响。阻挡层包括在聚合物链中共价键合作为重复单元的聚酯 - 共 - 酰亚胺，聚酯共聚物 - 共 - 酰亚胺或聚酰胺 - 共 - 酰亚胺，下式的芳族四羧基双酰亚胺基团：其中Ar1和Ar2分别表示四价和 6-20个碳原子的三价芳族基团。

4. 发明授权

US06294301B1 Polymer and photoconductive element having a polymeric barrier layer 失效
标题翻译：具有聚合物阻挡层的聚合物和光电导元件
公开(公告)号：US06294301B1
公开(公告)日：2001-09-25
申请号：US09574775
申请日：2000-05-19
申请人： Louis J. Sorriero , Marie B. O'Regan , Michel F. Molaire
发明人： Louis J. Sorriero , Marie B. O'Regan , Michel F. Molaire
IPC分类号： G03G510
CPC分类号： C08G73/16 , C08G73/1082 , C08G73/14 , G03G5/142
摘要： In a photoconductive element comprising a conductive support, e.g., an electrically conductive film, drum or belt on which a negatively chargeable photoconductive layer is formed, an electrical barrier layer is formed between the support and the photoconductive layer. The barrier layer provides a high energy barrier to the injection of positive charges but transports electrons under an applied electric field. The barrier layer of the invention transports charge by electronic rather than ionic mechanisms and, therefore, is not substantially affected by humidity changes. The barrier layer comprises a polyester-co-imide, polyesterionomer-co-imide or polyamide-co-imide having covalently bonded as repeating units in the polymer chain, aromatic tetracarboxylbisimide groups of the formula: wherein Ar1 and Ar2 represent, respectively, tetravalent and trivalent aromatic groups of 6 to 20 carbon atoms.
摘要翻译：在包含导电性支持体（例如形成有可带电电荷的光电导层的导电膜，鼓或带）的光电导元件中，在支撑体和光电导层之间形成电阻隔层。阻挡层为注入正电荷提供了高能量势垒，但在施加的电场下传输电子。本发明的阻挡层通过电子而不是离子机制传输电荷，因此基本上不受湿度变化的影响。阻挡层包括在聚合物链中共价键合作为重复单元的聚酯 - 共 - 酰亚胺，聚酯共聚物 - 共 - 酰亚胺或聚酰胺 - 共 - 酰亚胺，下式的芳族四羧基双酰亚胺基团：其中Ar1和Ar2分别表示四价和 6-20个碳原子的三价芳族基团。

5. 发明授权

US6066425A Electrophotographic charge generating element containing primer layer 有权
标题翻译：含有底漆层的电子照相电荷产生元件
公开(公告)号：US6066425A
公开(公告)日：2000-05-23
申请号：US222639
申请日：1998-12-30
申请人： Wayne T. Ferrar , Louis J. Sorriero , J. Robin Cowdery , David S. Weiss
发明人： Wayne T. Ferrar , Louis J. Sorriero , J. Robin Cowdery , David S. Weiss
IPC分类号： G03G5/047 , G03G5/05 , G03G5/07 , G03G5/147 , G03G5/087
CPC分类号： G03G5/0578 , G03G5/047 , G03G5/14773 , Y10T428/24802
摘要： Electrophotographic charge generating elements comprise a solid electrolyte layer having improved image discrimination and layer adhesion. The solid electrolyte layer includes a complex of a silsesquioxane and a charge carrier, and is adhered to an underlying photoconductor layer using a primer layer that includes specific addition polymers. This primer layer has a resistivity of at least 10.sup.10 ohms/square and contains substantially no free ACTIVE moieties as defined herein. Such groups, when present in the primer layer, appear to reduce image discrimination.
摘要翻译：电子照相电荷产生元件包括具有改进的图像鉴别和层粘合的固体电解质层。固体电解质层包括倍半硅氧烷和电荷载体的络合物，并且使用包含特定加成聚合物的底涂层粘附到下面的光电导体层。该底层具有至少1010欧姆/平方的电阻率，并且基本上不含本文定义的游离的活性部分。当这些基团存在于底漆层中时，似乎减少了图像鉴别。

6. 发明授权

US5780192A Electrophotographic elements exhibiting reduced numbers of black spots in discharge area development systems 失效
标题翻译：在放电区域开发系统中显示出黑点数目的电子照相元件
公开(公告)号：US5780192A
公开(公告)日：1998-07-14
申请号：US800247
申请日：1997-02-13
申请人： Marie B. O'Regan , Anne F. Lairmore , Jeffrey R. Murray , Louis J. Sorriero , Albert V. Buettner , David S. Weiss
发明人： Marie B. O'Regan , Anne F. Lairmore , Jeffrey R. Murray , Louis J. Sorriero , Albert V. Buettner , David S. Weiss
IPC分类号： G03G5/047 , G03G5/05
CPC分类号： G03G5/056 , G03G5/047
摘要： A multiactive photoconductive element exhibiting reduced black spots in discharged area development systems. The element includes (A) a conductive layer, (B) an aggregate charge generation layer in direct physcial contact with the conductive layer and (C) a charge transport layer. The charge generation layer contains (i) a binder an adhesive polymer. The charge transport layer contains a binder according to formula II: ##STR1## wherein the Ar, R.sup.1, R.sup.2, R.sup.7, R.sup.8, R.sup.3, R.sup.4, R.sup.5, R.sup.6, R.sup.9, R.sup.10, R.sup.11, and R.sup.12 and x are defined in the specification.
摘要翻译：在排出区域显影系统中表现出减少的黑点的多活性光电导元件。元件包括（A）导电层，（B）与导电层直接物理接触的聚集电荷产生层和（C）电荷传输层。电荷产生层包含（i）粘合剂，粘合剂聚合物。电荷传输层包含根据式II的粘合剂：其中Ar，R1，R2，R7，R8，R3，R4，R5，R6，R9，R10，R11和R12和x定义在规范。

7. 发明授权

US07700248B2 Organic charge transporting polymers including charge transport moieties and silane groups, and silsesquioxane compositions prepared therefrom 失效
标题翻译：包括电荷传输部分和硅烷基团的有机电荷传输聚合物和由其制备的倍半硅氧烷组合物
公开(公告)号：US07700248B2
公开(公告)日：2010-04-20
申请号：US10615089
申请日：2003-07-08
申请人： Xin Jin , Wayne T. Ferrar , David S. Weiss , Louis J. Sorriero
发明人： Xin Jin , Wayne T. Ferrar , David S. Weiss , Louis J. Sorriero
IPC分类号： G03G5/047
CPC分类号： G03G5/0596 , C08F230/08 , G03G5/0589 , G03G5/071
摘要： Disclosed are polymers which include tertiary aryl amine moieties that can function as hole transport agents and which also have reactive silane groups thereon capable of being condensed to a silsesquioxane composition, as well as the silsesquioxane compositions prepared therefrom. The silsesquioxanes can be coated onto substrates to form abrasion-resistant layers having hole transport properties useful in devices that require charge transport properties, such as light-emitting diodes and organic electrophotographic elements such as photoreceptors or photoconductors. Also disclosed are electrophotographic elements which comprise an electrically conducting layer, a charge generating layer overlying the electrically conducting layer, and a charge transport layer overlying the electrically conducting layer. The charge transport layer, which can be an overcoat overlying the charge generating layer, comprises the condensed reaction product of the disclosed polymers.
摘要翻译：公开了包括可以用作空穴传输剂的叔芳基胺部分的聚合物，并且其上还具有能够被缩合成倍半硅氧烷组合物的反应性硅烷基团，以及由其制备的倍半硅氧烷组合物。可以将倍半硅氧烷涂覆到基材上以形成具有空穴传输特性的耐磨层，该层具有可用于需要电荷传输性能的器件，例如发光二极管和有机电子照相元件如感光体或感光体。还公开了电子照相元件，其包括导电层，覆盖导电层的电荷产生层和覆盖在导电层上的电荷传输层。可以是覆盖电荷产生层的外涂层的电荷输送层包括所公开的聚合物的缩合反应产物。

8. 发明授权

US06949139B2 Process for forming cocrystals containing chlorine-free titanyl phthalocyanines and low concentration of titanyl fluorophthalocyanine using organic milling aid 失效
标题翻译：使用有机研磨助剂形成含有无氯氧钛酞菁和低浓度氧钛酞菁的共晶体的方法
公开(公告)号：US06949139B2
公开(公告)日：2005-09-27
申请号：US10655289
申请日：2003-09-04
申请人： Michel F. Molaire , Louis J. Sorriero
发明人： Michel F. Molaire , Louis J. Sorriero
IPC分类号： C09B67/04 , G03G5/06 , C09B67/50
CPC分类号： C09B67/0002 , G03G5/0696
摘要： In a process for forming an amorphous pigment mixture consisting essentially of TiOPc and TiOFPc and containing more than about 75 weight percent of TiOPc, a mixture of crude crystalline TiOPc and TiOFPc pigments in a weight ratio of at least 75:25 TiOPc:TiOFPc is combined with at least about 5 wt. %, based on the total weight of TiOPc and TiOFPc, of an organic milling aid. The mixture is treated under conditions effective to form a substantially amorphous pigment mixture of TiOPc and TiOFPc. The organic milling aid can be separated from the substantially amorphous pigment mixture, which can be converted to a nanoparticulate cocrystalline TiOPc/TiOFPc composition.
摘要翻译：在形成基本上由TiOPc和TiOFPc并且含有大于约75重量％的TiOPc的非晶颜料混合物的方法中，以至少75:25的TiOPc：TiOFPc的重量比的粗结晶TiOPc和TiOFPc颜料的混合物组合至少约5wt。％，基于TiOPc和TiOFPc的总重量的有机研磨助剂。在有效形成TiOPc和TiOFPc的基本上无定形的颜料混合物的条件下处理该混合物。有机研磨助剂可以与基本上无定形的颜料混合物分离，其可以转化成纳米颗粒共结晶TiOPc / TiOFPc组合物。

9. 发明授权

US07011919B2 Self-dispersing titanyl phthalocyanine pigment compositions and electrophotographic charge generation layers containing same 失效
标题翻译：自分散钛酞菁颜料组合物和含有它们的电子照相电荷产生层
公开(公告)号：US07011919B2
公开(公告)日：2006-03-14
申请号：US10655528
申请日：2003-09-04
申请人： Michel F. Molaire , Louis J. Sorriero
发明人： Michel F. Molaire , Louis J. Sorriero
IPC分类号： G03G15/06
CPC分类号： G03G5/0696 , C09B67/0002
摘要： In a process for forming a self-dispersing crystalline phthalocyanine pigment composition of monodisperse nanoparticles, a mixture containing titanyl fluorophthalocyanines, unsubstituted titanyl phthalocyanine, and an organic monomeric dispersant but substantially free of organic solvents or inorganic salts is dry milled, thereby forming a substantially amorphous phthalocyanine pigment composition. The substantially amorphous composition is contacted with an organic solvent having a hydrogen bonding parameter gammac lower than about 8, thereby forming a self-dispersing cocrystalline phthalocyanine pigment composition of monodisperse nanoparticles containing titanyl fluorophthalocyanines and titanyl phthalocyanine, which can be used to form the charge generation layer of an electrophotographic element.
摘要翻译：在形成单分散纳米颗粒的自分散结晶酞菁颜料组合物的方法中，将含有钛氧基酞菁，未取代的氧钛酞菁和有机单体分散剂但基本上不含有机溶剂或无机盐的混合物干磨，从而形成基本无定形的酞菁颜料组合物。将基本上无定形的组合物与氢键参数低于约8的有机溶剂接触，从而形成包含钛氧基酞菁和氧钛酞菁的单分散纳米颗粒的自分散共结晶酞菁颜料组合物，其中，可以用于形成电子照相元件的电荷产生层。

10. 发明授权

US06666596B2 Re-application of dye to a dye donor element of thermal printers 失效
标题翻译：将染料重新应用于热敏打印机的染料供体元件
公开(公告)号：US06666596B2
公开(公告)日：2003-12-23
申请号：US09861157
申请日：2001-05-18
申请人： Elizabeth G. Burns , Susan L. Dawson , Elizabeth A. Gallo , Daniel J. Harrison , Louis J. Sorriero , Ludmila S. Weiss
发明人： Elizabeth G. Burns , Susan L. Dawson , Elizabeth A. Gallo , Daniel J. Harrison , Louis J. Sorriero , Ludmila S. Weiss
IPC分类号： B41J3116
CPC分类号： B41M5/38221 , B41J17/38 , B41J31/16
摘要： Apparatus is disclosed for re-applying dye to a dye donor element of a dye transfer thermal printer. A reservoir contains a supply of dye that is thermally transferred from the reservoir to the dye donor element by diffusion of dye into the dye donor element. The reservoir has a diffusion controlled permeation membrane through which dye is delivered to the dye donor element, while inhibiting diffusion of a binder, whereby the dye diffuses between the reservoir and the dye donor element but the binder does not.
摘要翻译：公开了用于将染料重新施加到染料转移热敏打印机的染料供体元件的装置。储存器包含通过将染料扩散到染料供体元件中而从储存器热传递到染料供体元件的染料供应。储存器具有扩散控制渗透膜，通过该扩散控制的渗透膜，染料被输送到染料供体元件，同时抑制粘合剂的扩散，由此染料在储存器和染料供体元件之间扩散，但粘合剂不会扩散。

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