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1. 发明授权

US07714072B2 Polymer composition and process to manufacture high molecular weight-high density polyethylene and film therefrom 有权
标题翻译：聚合物组合物和制备高分子量 - 高密度聚乙烯及其膜的方法
公开(公告)号：US07714072B2
公开(公告)日：2010-05-11
申请号：US10553788
申请日：2004-05-05
申请人： William J. Michie, Jr. , Anthony C. Neubauer , Brad A. Cobler , Carl F. Baker
发明人： William J. Michie, Jr. , Anthony C. Neubauer , Brad A. Cobler , Carl F. Baker
IPC分类号： C08F8/06 , C08L23/30 , C08F2/34
CPC分类号： C08F210/16 , B29C47/0014 , B29C47/0021 , B29C47/38 , B29C47/404 , C08F8/00 , C08L23/0815 , C08L2205/02 , C08L2308/00 , Y10S525/938 , C08F10/02 , C08F2/001 , C08L2666/06 , C08F210/14 , C08F2500/12 , C08F2500/07 , C08F2500/04 , C08F2500/09 , C08F2500/26
摘要： The present invention is a multimodal polyethylene composition having (1) a density of at least about 0.940 g/cm3; (2) a melt flow index (I5) of from about 0.2 to about 1.5 g/10 mm; (3) a melt flow index ratio (I21/I5) of from about 20 to about 50; (4) a molecular weight distribution, Mw/Mn, of from about 20 to about 40; and (5) a bubble stability measured on an HS50S stationary extrusion system with an BF 10-25 die, HK 300 air ring, A8 take off, and WS8 surface winder, with a 100 mm die diameter having a 50 mm 21:1 L/D grooved feed extruder used for a film of about 6×10−6 m thickness of at least about 1.22 m/s line speed, at least about 45 kg/hr (0.013 kg/sec) output rate, or at least about 0.5 lb/hr/rpm (0.0000011 kg/s/rps) specific output rate or a combination thereof.
摘要翻译：本发明是一种多峰聚乙烯组合物，其具有（1）至少约0.940g / cm 3的密度; （2）约0.2至约1.5g / 10mm的熔体流动指数（I5）; （3）约20至约50的熔体流动指数比（I21 / I5）; （4）约20至约40的分子量分布Mw / Mn; 和（5）在具有BF 10-25模具，HK 300空气环，A8起飞和WS8表面卷取机的HS50S固定挤出系统上测量的气泡稳定性，其具有50mm 21:1L的100mm模头直径用于约6×10 -6 m厚度的至少约1.22m / s线速度的至少约45kg / hr（0.013kg / sec）输出速率或至少约0.5的膜的D沟槽进料挤出机 lb / hr / rpm（0.0000011kg / s / rps）特定输出速率或其组合。

2. 发明授权

US08344068B2 Polyethylene compositions, methods of making the same, and articles prepared therefrom 有权
标题翻译：聚乙烯组合物，其制备方法和由其制备的制品
公开(公告)号：US08344068B2
公开(公告)日：2013-01-01
申请号：US12446652
申请日：2007-10-19
申请人： William J. Michie, Jr. , Dane Chang , Lonnie G. Hazlitt , Stephanie M. Whited , Michael A. Kinnan , Anthony C. Neubauer , Thoi H. Ho
发明人： William J. Michie, Jr. , Dane Chang , Lonnie G. Hazlitt , Stephanie M. Whited , Michael A. Kinnan , Anthony C. Neubauer , Thoi H. Ho
IPC分类号： C08F8/00 , C08L23/04
CPC分类号： C08L23/26 , C08L23/0815 , C08L2205/02 , C08L2666/06
摘要： The invention is related to compositions suitable for the fabrication of pipes, and other articles, with excellent performance properties. The invention provides a composition, comprising a blend, wherein said blend comprises a high molecular weight ethylene-based interpolymer and a low molecular weight ethylene-based interpolymer, and the high molecular weight ethylene-based interpolymer is a heterogeneously branched linear or a homogeneously branched linear ethylene-based interpolymer, and has a density from 0.922 g/cc to 0.929 g/cc, and a high load melt index (I21) from 0.2 g/10 min to 1.0 g/10 min, and the low molecular weight ethylene-based interpolymer is heterogeneously branched linear or a homogeneously branched linear ethylene-based interpolymer, and has a density from 0.940 g/cc to 0.955 g/cc, and a melt index (I2) from 6 g/10 min to 50 g/10 min. The blend has a single peak in an ATREF profile eluting above 30° C., and has a coefficient of viscosity average molecular weight (CM?) less than −0.0032 in the log(calculated Mv) versus elution temperature, said CMv calculated in the range of elution temperatures from 70° C. to 90° C. The Mv is the viscosity average molecular weight.
摘要翻译：本发明涉及适于制造具有优异性能的管道和其它制品的组合物。本发明提供一种包含共混物的组合物，其中所述共混物包含高分子量乙烯基互聚物和低分子量乙烯基互聚物，并且高分子量乙烯基互聚物是非均匀支化的线性或均匀分支的线性乙烯类互聚物，密度为0.922g / cc〜0.929g / cc，高负荷熔融指数（I21）为0.2g / 10min〜1.0g / 10min，低分子量乙烯 - 基于异构支化的线型或均匀支化的线性乙烯基互聚物，其密度为0.940g / cc至0.955g / cc，熔体指数（I 2）为6g / 10min至50g / 10min 。共混物在30℃以上洗脱的ATREF谱中具有单峰，并且在对数（计算的Mv）相对于洗脱温度具有小于-0.0032的粘均分子量（CM 3）系数，所述CMv计算为洗脱温度范围为70℃至90℃.Mv为粘均分子量。

3. 发明授权

US09492963B2 Process for making tailored polyetheylene resins for sheets 有权
标题翻译：制造量身定制的聚乙烯树脂的方法
公开(公告)号：US09492963B2
公开(公告)日：2016-11-15
申请号：US12282223
申请日：2007-03-09
申请人： William J. Michie, Jr. , Todd A. Hogan , Felipe Martinez Barreneche , Anthony C. Neubauer , Stephane Costeux
发明人： William J. Michie, Jr. , Todd A. Hogan , Felipe Martinez Barreneche , Anthony C. Neubauer , Stephane Costeux
IPC分类号： B29C47/08 , B29C47/00 , B29C47/10 , C08J5/18 , B29C47/92 , B29K23/00
CPC分类号： B29C47/0869 , B29C47/0004 , B29C47/1072 , B29C47/92 , B29C2947/922 , B29C2947/92266 , B29C2947/92485 , B29C2947/92761 , B29C2947/92933 , B29K2023/065 , C08J5/18 , C08J2323/08
摘要： This invention relates to coupling of polyethylene resins, more specifically coupling of polyethylene resins for use in extruded profiles, especially extruded profiles for sheet extrusion and cut sheet thermoforming applications and geomembranes. The process involves conveying a HDPE resin through an extruder, wherein the extruder comprises a feed zone, a first melt zone downstream of the feed zone, a second melt zone downstream of the first melt zone, and a third melt zone downstream of the second melt zone. The resin is melted in the first zone, contacted with oxygen in the second melt zone, and contacted antioxidant in the third melt zone.
摘要翻译：本发明涉及聚乙烯树脂的偶联，更具体地说，用于挤出型材的聚乙烯树脂的偶联，特别是用于片材挤出和切割片材热成型应用的挤出型材以及土工膜。该方法包括将HDPE树脂输送通过挤出机，其中挤出机包括进料区，进料区下游的第一熔融区，第一熔融区下游的第二熔融区，第二熔体下游的第三熔融区区。树脂在第一区域熔化，与第二熔融区域中的氧气接触，并在第三熔融区域中与抗氧化剂接触。

4. 发明授权

US08920891B2 Rheology modified relatively high melt strength polyethylene compositions and methods of making pipes, films, sheets, and blow-molded articles 有权
标题翻译：流变改性相对较高的熔体强度聚乙烯组合物和制造管，膜，片和吹塑制品的方法
公开(公告)号：US08920891B2
公开(公告)日：2014-12-30
申请号：US11721388
申请日：2005-12-09
申请人： William J. Michie, Jr. , Dane Chang , Anthony C. Neubauer , Mridula Kapur , Todd A. Hogan , Felipe B. Martinez , Stephane Costeux
发明人： William J. Michie, Jr. , Dane Chang , Anthony C. Neubauer , Mridula Kapur , Todd A. Hogan , Felipe B. Martinez , Stephane Costeux
IPC分类号： C08J9/20 , C08K5/43 , C08L23/08
CPC分类号： C08K5/43 , C08L23/0807 , C08L2205/02 , Y10T428/1352 , Y10T428/139 , C08L23/08 , C08L2666/06
摘要： A polymer composition comprises a low-molecular-weight (LMW) ethylene polymer component and a high-molecular-weight (HMW) ethylene polymer component coupled with a polysulfonyl azide. Preferably, the LMW polyethylene component and the HMW polyethylene component co-crystallize in the composition such that it exhibits a single or substantially single peak in a lamella thickness distribution (LTD) curve. The ethylene polymer for the LMW and the HMW polyethylene components can be either homopolymer or ethylene copolymer. Preferably, both components are an ethylene copolymer of the same, or different, composition (that is, with the same or different comonomers). A method of making a pipe that includes selecting a polymer composition having a substantially single peak in the LTD curve is described. Compositions comprising a chromium-catalyzed ethylene polymer, coupled with a polysulfonyl azide are also described herein.
摘要翻译：聚合物组合物包含与聚磺酰叠氮基偶联的低分子量（LMW）乙烯聚合物组分和高分子量（HMW）乙烯聚合物组分。优选地，LMW聚乙烯组分和HMW聚乙烯组分在组合物中共结晶，使得其在薄片厚度分布（LTD）曲线中表现出单一或基本上单峰。用于LMW和HMW聚乙烯组分的乙烯聚合物可以是均聚物或乙烯共聚物。优选地，两种组分都是相同或不同组成（即相同或不同的共聚单体）的乙烯共聚物。描述了制造管道的方法，其包括选择在LTD曲线中具有基本单峰的聚合物组合物。本文还描述了包含铬催化的乙烯聚合物与聚磺酰叠氮化物偶联的组合物。

5. 发明授权

US10787553B2 Polyethylene composition and articles made therefrom 有权
公开(公告)号：US10787553B2
公开(公告)日：2020-09-29
申请号：US14363092
申请日：2012-11-28
申请人： Dow Global Technologies LLC , William J. Michie, Jr. , Dale A. Wright , Robert J. Jorgensen , Carl F. Baker , Burkhard E. Wagner , Joe B. Garrett, Jr. , Matthew H. Mills
发明人： William J. Michie, Jr. , Dale A. Wright , Robert J. Jorgensen , Carl F. Baker , Burkhard E. Wagner , Joe B. Garrett, Jr. , Matthew H. Mills
IPC分类号： C08F210/16 , C08J9/16 , C08F110/02 , C08F10/02
摘要： A polyethylene composition comprising a granular polyethylene resin characterized by a resin solid density of from 0.91 to 0.97 g/cm3, a ratio of intraparticle void volume to interparticle void volume of from 0.33 to 0.67, and a total resin porosity, Φtotal, of equal to or greater than 0.45 is provided. Further provided are articles made from the polyethylene composition.

6. 发明授权

US09663642B2 Polyethylene compositions, method of producing the same, fibers made therefrom, and method of making the same 有权
公开(公告)号：US09663642B2
公开(公告)日：2017-05-30
申请号：US12739511
申请日：2009-07-09
申请人： Randy E. Pepper , Mridula Kapur , Gert J. Claasen , Edward N. Knickerbocker , Nathan J. Wiker , William J. Michie, Jr. , Mark B. Davis
发明人： Randy E. Pepper , Mridula Kapur , Gert J. Claasen , Edward N. Knickerbocker , Nathan J. Wiker , William J. Michie, Jr. , Mark B. Davis
IPC分类号： C08L23/04 , D01F6/04 , D01F6/30 , D04H3/007 , D01D5/12 , D01D10/02 , D04H3/16 , D04H1/56 , D01D5/10 , C08L23/08
CPC分类号： D01F6/30 , C08F210/02 , C08L23/04 , C08L23/0815 , C08L2205/02 , C08L2205/16 , C08L2314/06 , D01D5/08 , D01D5/10 , D01D5/12 , D01D10/02 , D01F6/04 , D04H1/56 , D04H3/007 , D04H3/16 , Y10T428/249921 , Y10T442/30 , Y10T442/3976 , Y10T442/60 , C08L2666/06
摘要： The instant invention discloses fibers. The fibers according to the instant invention comprise a polyethylene composition comprising: (a) less than or equal to 100 percent by weight of the units derived from ethylene; and (b) less than 20 percent by weight of units derived from one or more α-olefin comonomers; wherein the polyethylene composition has a density in the range of 0.920 to 0.970 g/cm3, a molecular weight distribution (Mw/Mn) in the range of 1.70 to 3.5, a melt index (I2) in the range of 0.2 to 1000 g/10 minutes, a molecular weight distribution (Mz/Mw) in the range of less than 2.5, vinyl unsaturation of less than 0.1 vinyls per one thousand carbon atoms present in the backbone of the composition.

7. 发明授权

US09056970B2 High-density polyethylene compositions, method of producing the same, closure devices made therefrom, and method of making such closure devices 有权
标题翻译：高密度聚乙烯组合物，其制造方法，由其制成的封闭装置以及制造这种闭合装置的方法
公开(公告)号：US09056970B2
公开(公告)日：2015-06-16
申请号：US13144465
申请日：2010-01-27
申请人： Mark B. Davis , Dale M. Elley-Bristow , William J. Michie, Jr. , Stephanie M. Whited , Theresa J. Hermel-Davidock
发明人： Mark B. Davis , Dale M. Elley-Bristow , William J. Michie, Jr. , Stephanie M. Whited , Theresa J. Hermel-Davidock
IPC分类号： C08L23/08 , C08F297/08 , C08L23/04 , C08F2/00 , C08L23/06
CPC分类号： C08L23/04 , C08F2/001 , C08F297/08 , C08F297/083 , C08L23/06 , C08L23/08 , C08L23/0815 , C08L2205/02 , C08L2205/025 , C08L2205/06 , C08L2666/06
摘要： The instant invention is a high-density polyethylene composition, method of producing the same, closure devices made therefrom, and method of making such closure devices. The high-density polyethylene composition according to the present invention comprises (a) a first component comprising a high molecular weight ethylene alpha-olefin copolymer having a density in the range of 0.927 to 0.938 g/cm3, and a melt flow rate (I21) in the range of 4 to 10 g/10 minutes, and (b) a second component comprising a low molecular weight ethylene polymer having a density in the range of 0.960 to 0.975 g/cm3, and a melt index (I2) in the range of 100 to 1200 g/10 minutes; and wherein the high-density polyethylene composition has a melt index (I2) in the range of from 2 to 10 g/10 minutes, a density in the range of from 0.950 to 0.960 g/cm3, and a flow direction shrinkage to cross flow direction shrinkage ratio in the range of from 2 to 3.2, and an environmental stress crack resistance (ESCR) (F50) according to ASTM D-1693, condition B at 50° C., and using 10 percent Branched Octylphenoxy Poly(Ethyleneoxy) Ethanol, in the range of equal to or greater than 50 hours.
摘要翻译：本发明是高密度聚乙烯组合物，其制造方法，由其制成的封闭装置，以及制造这种闭合装置的方法。根据本发明的高密度聚乙烯组合物包含（a）包含密度在0.927至0.938g / cm 3范围内的高分子量乙烯α-烯烃共聚物和熔体流动速率（I21）的第一组分，在4至10g / 10分钟的范围内，和（b）包含密度在0.960至0.975g / cm 3范围内的低分子量乙烯聚合物的第二组分和在该范围内的熔体指数（I 2）为100〜1200g / 10分钟; 并且其中所述高密度聚乙烯组合物具有在2至10g / 10分钟范围内的熔体指数（I 2），在0.950至0.960g / cm 3范围内的密度和横向流动方向收缩方向收缩率在2至3.2范围内，以及根据ASTM D-1693，条件B在50℃下的环境应力开裂抗力（ESCR）（F50），并使用10％支链辛基苯氧基聚（乙烯氧基）乙醇在等于或大于50小时的范围内。

8. 发明授权

US08247497B2 Polymer molding compositions 有权
标题翻译：聚合物模塑组合物
公开(公告)号：US08247497B2
公开(公告)日：2012-08-21
申请号：US11578983
申请日：2005-05-05
申请人： Debra R. Wilson , William J. Michie, Jr. , Spyro P. Petsalis
发明人： Debra R. Wilson , William J. Michie, Jr. , Spyro P. Petsalis
IPC分类号： C08L23/00 , C08L23/04 , C08K5/00
CPC分类号： C08L23/06 , C08L23/0815 , C08L2205/02 , C08L2205/025 , C08L2666/06
摘要： The invention relates to formulated compositions which can be easily formed into bottle caps, without the need for a liner, while still maintaining pressure requirements, such as for carbonated beverages. The compositions may include an ethylene polymer having a density in the range of from about 0.947 to 0.962 g/cm3, a melt index of from about 1 to about 10 g/10 min., and another ethylene polymer having a density in the range of from about 0.912 to 0.932 g/cm3, a melt index of from about 0.25 to about 6 g/10 min., wherein the two ethylene polymers have a density difference of equal to or greater than 0.03 g/cm3. In other cases, the composition may include a single component resin with a density in the 0.935-0.955 g/cm3 range with a melt index in the range of 0.3-1.2 g/10 minutes, and wherein the resin comprises a polyethylene polymer.
摘要翻译：本发明涉及配制的组合物，其可以容易地形成瓶盖，而不需要衬垫，同时仍然保持压力要求，例如用于碳酸饮料。组合物可以包括密度在约0.947至0.962g / cm 3范围内的乙烯聚合物，熔体指数为约1至约10g / 10分钟，而另一种乙烯聚合物的密度范围为约0.912至0.932g / cm 3，熔体指数为约0.25至约6g / 10min，其中两种乙烯聚合物具有等于或大于0.03g / cm 3的密度差。在其它情况下，组合物可以包括密度在0.935-0.955g / cm 3范围内的单组分树脂，熔体指数在0.3-1.2g / 10分钟的范围内，并且其中树脂包含聚乙烯聚合物。

9. 发明授权

US07989549B2 Polymer compositions and method of making pipes 有权
标题翻译：聚合物组合物和制造管道的方法
公开(公告)号：US07989549B2
公开(公告)日：2011-08-02
申请号：US11202756
申请日：2005-08-12
申请人： Zhiqiang Jimmy Zhou , William J. Michie, Jr.
发明人： Zhiqiang Jimmy Zhou , William J. Michie, Jr.
IPC分类号： C08L23/00 , C08L23/04
CPC分类号： C08F210/16 , C08F4/65912 , C08F10/00 , C08L23/06 , C08L23/0815 , C08L2205/02 , C08L2308/00 , C08L2314/02 , C08F4/65927 , C08F2/001 , C08L2666/06 , C08F210/14 , C08F2500/02 , C08F2500/07 , C08F2500/12 , C08F2500/18 , C08F2500/26 , C08F2500/05 , C08F210/08 , C08F2500/01
摘要： A polymer composition comprises a low-molecular-weight (LMW) ethylene polymer component and a high-molecular-weight (HMW) ethylene polymer component. Preferably, the LMW polyethylene component and the HMW polyethylene component co-crystallize in the composition such that it exhibits a single or substantially single peak in a lamella thickness distribution (“LTD”) curve. The ethylene polymer for the LMW and the HMW polyethylene components can be either homopolyethylene or ethylene copolymer. Preferably, both components are an ethylene copolymer of the same or different composition (i.e., with the same or different comonomers). A method of making a pipe that includes selecting a polymer composition having a substantially single peak in the LTD curve is described.
摘要翻译：聚合物组合物包含低分子量（LMW）乙烯聚合物组分和高分子量（HMW）乙烯聚合物组分。优选地，LMW聚乙烯组分和HMW聚乙烯组分在组合物中共结晶，使得其在薄片厚度分布（“LTD”）曲线中表现出单一或基本上单峰。用于LMW和HMW聚乙烯组分的乙烯聚合物可以是均聚乙烯或乙烯共聚物。优选地，两种组分都是相同或不同组成的乙烯共聚物（即与相同或不同的共聚单体）。描述了制造管道的方法，其包括选择在LTD曲线中具有基本单峰的聚合物组合物。

10. 发明授权

US08679602B2 Ethylene-based polymers and compositions, methods of making the same and articles prepared therefrom 有权
标题翻译：乙烯基聚合物和组合物，其制备方法和由其制备的制品
公开(公告)号：US08679602B2
公开(公告)日：2014-03-25
申请号：US12701153
申请日：2010-02-05
申请人： William J. Michie, Jr. , Sarah M. Hayne , Sarah E. Patterson , Robert James Jorgensen , Dale A. Wright
发明人： William J. Michie, Jr. , Sarah M. Hayne , Sarah E. Patterson , Robert James Jorgensen , Dale A. Wright
IPC分类号： B29D22/00
CPC分类号： C08F210/16 , C08F4/69 , C08F210/14 , C08F2500/12 , C08F2500/18 , C08F2500/20 , C08F2500/04 , C08F2500/10
摘要： The invention provides an ethylene-based interpolymer comprising the following features: a) density from 0.910 to 0.930 g/cc; b) melt index (I2) from 0.1 to 0.5 g/10 min; and c) a high density fraction in an ATREF short chain branch distribution (SCBD) curve, eluting above 92° C., of greater than 10 percent to less than 28 percent of the total ATREF SCBD curve area. The invention also provides a composition comprising an ethylene-based interpolymer that comprises the following features: a) a density from 0.919 to 0.928 g/cc; b) a melt index (I2) from 0.1 to 0.8 g/10 min; and c) a high density fraction in an ATREF short chain branch distribution (SCBD) curve, eluting above 92° C., of greater than 10 percent to less than 28 percent of the total ATREF SCBD curve area. The invention also provides a hollow tube comprising at least one component formed from a composition comprising an ethylene-based interpolymer that comprises the following features: a) a density from 0.919 to 0.928 g/cc; b) a melt index (I2) from 0.1 to 0.8 g/10 min; and c) a high density fraction in an ATREF short chain branch distribution (SCBD) curve, eluting above 92° C., of greater than 10 percent to less than 28 percent of the total ATREF SCBD curve area; and wherein the tube has a hydrostatic design basis (HDB) of at least 1000-psi at 23° C. per ASTM D-2837 regression method.
摘要翻译：本发明提供一种乙烯基互聚物，其包含以下特征：a）0.910至0.930g / cc的密度; b）熔融指数（I 2）为0.1至0.5g / 10min; 和c）在92℃以上洗脱的ATREF短链分支分布（SCBD）曲线中的高密度分数大于总ATREF SCBD曲线区域的10％至小于28％。本发明还提供包含乙烯基互聚物的组合物，其包含以下特征：a）0.919至0.928g / cc的密度; b）0.1至0.8g / 10min的熔体指数（I 2）; 和c）在92℃以上洗脱的ATREF短链分支分布（SCBD）曲线中的高密度分数大于总ATREF SCBD曲线区域的10％至小于28％。本发明还提供一种中空管，其包含由包含乙烯基互聚物的组合物形成的至少一种组分，所述组合物包含以下特征：a）密度为0.919至0.928g / cc; b）0.1至0.8g / 10min的熔体指数（I 2）; 和c）在92℃以上洗脱的ATREF短链分支分布（SCBD）曲线中的高密度分数大于总ATREF SCBD曲线区域的大于10％至小于28％; 并且其中所述管在23℃下根据ASTM D-2837回归方法具有至少1000-psi的流体静力学设计基准（HDB）。

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