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1. 发明授权

US08679602B2 Ethylene-based polymers and compositions, methods of making the same and articles prepared therefrom 有权
标题翻译：乙烯基聚合物和组合物，其制备方法和由其制备的制品
公开(公告)号：US08679602B2
公开(公告)日：2014-03-25
申请号：US12701153
申请日：2010-02-05
申请人： William J. Michie, Jr. , Sarah M. Hayne , Sarah E. Patterson , Robert James Jorgensen , Dale A. Wright
发明人： William J. Michie, Jr. , Sarah M. Hayne , Sarah E. Patterson , Robert James Jorgensen , Dale A. Wright
IPC分类号： B29D22/00
CPC分类号： C08F210/16 , C08F4/69 , C08F210/14 , C08F2500/12 , C08F2500/18 , C08F2500/20 , C08F2500/04 , C08F2500/10
摘要： The invention provides an ethylene-based interpolymer comprising the following features: a) density from 0.910 to 0.930 g/cc; b) melt index (I2) from 0.1 to 0.5 g/10 min; and c) a high density fraction in an ATREF short chain branch distribution (SCBD) curve, eluting above 92° C., of greater than 10 percent to less than 28 percent of the total ATREF SCBD curve area. The invention also provides a composition comprising an ethylene-based interpolymer that comprises the following features: a) a density from 0.919 to 0.928 g/cc; b) a melt index (I2) from 0.1 to 0.8 g/10 min; and c) a high density fraction in an ATREF short chain branch distribution (SCBD) curve, eluting above 92° C., of greater than 10 percent to less than 28 percent of the total ATREF SCBD curve area. The invention also provides a hollow tube comprising at least one component formed from a composition comprising an ethylene-based interpolymer that comprises the following features: a) a density from 0.919 to 0.928 g/cc; b) a melt index (I2) from 0.1 to 0.8 g/10 min; and c) a high density fraction in an ATREF short chain branch distribution (SCBD) curve, eluting above 92° C., of greater than 10 percent to less than 28 percent of the total ATREF SCBD curve area; and wherein the tube has a hydrostatic design basis (HDB) of at least 1000-psi at 23° C. per ASTM D-2837 regression method.
摘要翻译：本发明提供一种乙烯基互聚物，其包含以下特征：a）0.910至0.930g / cc的密度; b）熔融指数（I 2）为0.1至0.5g / 10min; 和c）在92℃以上洗脱的ATREF短链分支分布（SCBD）曲线中的高密度分数大于总ATREF SCBD曲线区域的10％至小于28％。本发明还提供包含乙烯基互聚物的组合物，其包含以下特征：a）0.919至0.928g / cc的密度; b）0.1至0.8g / 10min的熔体指数（I 2）; 和c）在92℃以上洗脱的ATREF短链分支分布（SCBD）曲线中的高密度分数大于总ATREF SCBD曲线区域的10％至小于28％。本发明还提供一种中空管，其包含由包含乙烯基互聚物的组合物形成的至少一种组分，所述组合物包含以下特征：a）密度为0.919至0.928g / cc; b）0.1至0.8g / 10min的熔体指数（I 2）; 和c）在92℃以上洗脱的ATREF短链分支分布（SCBD）曲线中的高密度分数大于总ATREF SCBD曲线区域的大于10％至小于28％; 并且其中所述管在23℃下根据ASTM D-2837回归方法具有至少1000-psi的流体静力学设计基准（HDB）。

2. 发明授权

US08629214B2 Ethylene-based polymer compositions for use as a blend component in shrinkage film applications 有权
标题翻译：在收缩膜应用中用作共混组分的乙烯基聚合物组合物
公开(公告)号：US08629214B2
公开(公告)日：2014-01-14
申请号：US13453541
申请日：2012-04-23
申请人： Teresa P. Karjala , Rongjuan Cong , Colleen M. Tice , Sarah M. Hayne , Mehmet Demirors , Lori L. Kardos
发明人： Teresa P. Karjala , Rongjuan Cong , Colleen M. Tice , Sarah M. Hayne , Mehmet Demirors , Lori L. Kardos
IPC分类号： C08F8/00 , C08L23/04
CPC分类号： C08F10/00 , C08F210/16 , C08J5/18 , C08J2323/08 , C08L23/06 , C08L23/0815 , C08L2205/02 , C08L2205/025 , C08L2314/06 , C08L2666/06 , C08F4/64193 , C08F210/14 , C08F2500/03 , C08F2500/04 , C08F2500/05 , C08F2500/11 , C08F2500/12 , C08F2500/17 , C08F2500/20 , C08F2500/26
摘要： An ethylene-based polymer composition has been discovered and is characterized by a Comonomer Distribution Constant greater than about 45. The new ethylene-based polymer compositions and blends thereof with one or more polymers, such as LDPE, are useful for making many articles, especially including films.
摘要翻译：已经发现乙烯基聚合物组合物，其特征在于大于约45的共聚单体分布常数。新的基于乙烯的聚合物组合物及其与一种或多种聚合物如LDPE的共混物可用于制备许多制品，特别是包括电影。

3. 发明授权

US08372931B2 Ethylene-based polymer compositions 有权
标题翻译：乙烯基聚合物组合物
公开(公告)号：US08372931B2
公开(公告)日：2013-02-12
申请号：US12827222
申请日：2010-06-30
申请人： Theresa J. Hermel-Davidock , Mehmet Demirors , Sarah M. Hayne , Rongjuan Cong
发明人： Theresa J. Hermel-Davidock , Mehmet Demirors , Sarah M. Hayne , Rongjuan Cong
IPC分类号： C08F10/02 , C08F110/02
CPC分类号： C08F10/02 , C08F10/00 , C08F210/16 , C08J5/18 , C08J2323/08 , C08L23/0815 , C08L2205/02 , C08L2314/06 , C08L2666/06 , C08F4/64193 , C08F210/14 , C08F2500/03 , C08F2500/04 , C08F2500/05 , C08F2500/12 , C08F2500/20
摘要： The present invention provides an ethylene-based polymer composition characterized by a Comonomer Distribution Constant in the range of from greater than 45 to less than 400, wherein the composition has less than 120 total unsaturation unit/1,000,000C, and method of producing the same.
摘要翻译：本发明提供了一种乙烯类聚合物组合物，其特征在于共聚单体分布常数在大于45至小于400的范围内，其中组合物的总不饱和单位小于120个/ 1,000,000℃，及其制备方法。

4. 发明申请

US20120237741A1 COMPOSITION FOR STRETCH HOOD, METHOD OF PRODUCING THE SAME, AND ARTICLES MADE THEREFROM 有权
标题翻译：拉伸组合物，其制造方法及其制造方法
公开(公告)号：US20120237741A1
公开(公告)日：2012-09-20
申请号：US13424978
申请日：2012-03-20
申请人： Prashant Mandare , Gregory Bunker , Rajen M. Patel , Yi Jin , Selim Bensason , Mehmet Demirors , Theresa J. Hermel-Davidock , Sarah M. Hayne , Jose E. Ruiz
发明人： Prashant Mandare , Gregory Bunker , Rajen M. Patel , Yi Jin , Selim Bensason , Mehmet Demirors , Theresa J. Hermel-Davidock , Sarah M. Hayne , Jose E. Ruiz
IPC分类号： B32B27/32
CPC分类号： B32B27/32 , B32B1/08 , C08F10/00 , C08L23/0815 , C08L2205/02 , Y10T428/1352 , Y10T428/24942 , Y10T428/26 , Y10T428/266 , Y10T428/269 , Y10T428/31855 , C08L2666/06 , C08F4/64193 , C08L23/04 , C08F4/64137
摘要： The instant invention provides a composition suitable for stretch hood, method of producing the same, and articles made therefrom. The article according to the present invention comprises a multi-layer film according to the present invention has a thickness of at least 3 mils comprising at least one inner layer and two exterior layers, wherein the inner layer comprises at least 50 weight percent polyethylene copolymer having a melt index less than 2 grams/10 minutes, a density less than or equal to 0.910 g/cm3, a total heat of fusion less than 120 Joules/gram and a heat of fusion above 115° C. of less than 5 Joules/gram, the total heat of fusion of the inner layer less than the heat of fusion of either of the two exterior layers, and wherein the multi-layer film has an elastic recovery of at least 40% when stretched to 100% elongation.
摘要翻译：本发明提供了适用于拉伸罩的组合物，其制造方法以及由其制成的制品。根据本发明的制品包括根据本发明的多层膜具有至少3密耳的厚度，其包含至少一个内层和两个外层，其中所述内层包含至少50重量％的聚乙烯共聚物，其具有小于2克/ 10分钟的熔体指数，小于或等于0.910克/厘米3的密度，小于120焦耳/克的熔融热总和小于5焦耳/克的熔点在115℃以上，克，内层的总熔化热小于两个外层之一的熔化热，并且其中当拉伸至100％伸长时，多层膜具有至少40％的弹性回复率。

5. 发明申请

US20110003940A1 ETHYLENE-BASED POLYMER COMPOSITIONS FOR USE AS A BLEND COMPONENT IN SHRINKAGE FILM APPLICATIONS 审中-公开
标题翻译：用作收缩膜应用中的混合组分的基于乙烯的聚合物组合物
公开(公告)号：US20110003940A1
公开(公告)日：2011-01-06
申请号：US12814902
申请日：2010-06-14
申请人： Teresa P. Karjala , Rongjuan Cong , Colleen M. Tice , Sarah M. Hayne , Mehmet Demirors , Lori L. Kardos
发明人： Teresa P. Karjala , Rongjuan Cong , Colleen M. Tice , Sarah M. Hayne , Mehmet Demirors , Lori L. Kardos
IPC分类号： C08F210/14 , C08L23/06 , C08L23/08
CPC分类号： C08F10/02 , C08F10/00 , C08F210/16 , C08J5/18 , C08J2323/08 , C08L23/0815 , C08L2205/02 , C08L2314/06 , C08L2666/06 , C08F4/64193 , C08F210/14 , C08F2500/03 , C08F2500/04 , C08F2500/05 , C08F2500/12 , C08F2500/20
摘要： An ethylene-based polymer composition has been discovered and is characterized by a Comonomer Distribution Constant greater than about 45. The new ethylene-based polymer compositions are useful for making many articles, especially including films. Formulations made into films comprising the new polymers are also disclosed, especially blends with synthetic polymer like LDPE where the % LDPE is less than 50% in which the MD shrink tension is greater than 15 cN, puncture is greater than 75 ft-lb/in3, and haze is less than 20%. The polymers are made using a metal complex of a polyvalent aryloxyether.
摘要翻译：已经发现乙烯基聚合物组合物，其特征在于大于约45的共聚单体分布常数。新的基于乙烯的聚合物组合物可用于制备许多制品，特别是包括膜。还公开了制备成包含新聚合物的膜的制剂，特别是与合成聚合物如LDPE的共混物，其中LDPE小于50％，MD收缩张力大于15cN，穿刺度大于75ft-lb / in3 ，雾度小于20％。聚合物使用多价芳氧基醚的金属络合物制成。

6. 发明授权

US08829115B2 Ethylene-based polymer composition 有权
标题翻译：乙烯基聚合物组合物
公开(公告)号：US08829115B2
公开(公告)日：2014-09-09
申请号：US13581726
申请日：2011-03-02
申请人： Theresa J. Hermel-Davidock , Mehmet Demirors , Sarah M. Hayne , Rongjuan Cong , Lori L. Kardos , Teresa P. Karjala
发明人： Theresa J. Hermel-Davidock , Mehmet Demirors , Sarah M. Hayne , Rongjuan Cong , Lori L. Kardos , Teresa P. Karjala
IPC分类号： C08L23/04 , C08F2/00 , C08F4/642 , C08F4/659 , C08F10/02 , C08L23/08 , C08F10/00 , C08F210/16 , B32B27/32 , C08L23/02
CPC分类号： C08L23/04 , C08F10/00 , C08F210/16 , C08L23/02 , C08L23/08 , C08L23/0815 , C08L2205/02 , C08F2/001 , C08L2666/06 , C08F210/14 , C08F2500/05 , C08F2500/09 , C08F2500/20 , C08F4/64193
摘要： An ethylene-based polymer composition has been discovered and is characterized by a Comonomer Distribution Constant greater than about 45. The new ethylene-based polymer compositions are useful for making many articles, especially including films. The polymers are made using a metal complex of a polyvalent aryloxyether.
摘要翻译：已经发现乙烯基聚合物组合物，其特征在于大于约45的共聚单体分布常数。新的基于乙烯的聚合物组合物可用于制备许多制品，特别是包括膜。聚合物使用多价芳氧基醚的金属络合物制成。

7. 发明授权

US08389086B2 Composition for stretch hood, method of producing the same, and articles made therefrom 有权
标题翻译：用于拉伸罩的组合物，其制造方法和由其制成的制品
公开(公告)号：US08389086B2
公开(公告)日：2013-03-05
申请号：US13424978
申请日：2012-03-20
申请人： Prashant Mandare , Gregory Bunker , Rajen M. Patel , Yi Jin , Selim Bensason , Mehmet Demirors , Theresa J. Hermel-Davidock , Sarah M. Hayne , Jose E. Ruiz
发明人： Prashant Mandare , Gregory Bunker , Rajen M. Patel , Yi Jin , Selim Bensason , Mehmet Demirors , Theresa J. Hermel-Davidock , Sarah M. Hayne , Jose E. Ruiz
IPC分类号： B29D22/00 , B29D23/00 , B32B1/08
CPC分类号： B32B27/32 , B32B1/08 , C08F10/00 , C08L23/0815 , C08L2205/02 , Y10T428/1352 , Y10T428/24942 , Y10T428/26 , Y10T428/266 , Y10T428/269 , Y10T428/31855 , C08L2666/06 , C08F4/64193 , C08L23/04 , C08F4/64137
摘要： The instant invention provides a composition suitable for stretch hood, method of producing the same, and articles made therefrom. The article according to the present invention comprises a multi-layer film according to the present invention has a thickness of at least 3 mils comprising at least one inner layer and two exterior layers, wherein the inner layer comprises at least 50 weight percent polyethylene copolymer having a melt index less than 2 grams/10 minutes, a density less than or equal to 0.910 g/cm3, a total heat of fusion less than 120 Joules/gram and a heat of fusion above 115° C. of less than 5 Joules/gram, the total heat of fusion of the inner layer less than the heat of fusion of either of the two exterior layers, and wherein the multi-layer film has an elastic recovery of at least 40% when stretched to 100% elongation.
摘要翻译：本发明提供了适用于拉伸罩的组合物，其制造方法以及由其制成的制品。根据本发明的制品包括根据本发明的多层膜具有至少3密耳的厚度，其包含至少一个内层和两个外层，其中所述内层包含至少50重量％的聚乙烯共聚物，其具有小于2克/ 10分钟的熔体指数，小于或等于0.910克/厘米3的密度，小于120焦耳/克的熔融热总和小于5焦耳/克的熔点在115℃以上，克，内层的总熔化热小于两个外层之一的熔化热，并且其中当拉伸至100％伸长时，多层膜具有至少40％的弹性回复率。

8. 发明申请

US20130046061A1 ETHYLENE-BASED POLYMER COMPOSITION 有权
标题翻译：基于乙烯的聚合物组合物
公开(公告)号：US20130046061A1
公开(公告)日：2013-02-21
申请号：US13581726
申请日：2011-03-02
申请人： Theresa J. Hermel-Davidock , Mehmet Demirors , Sarah M. Hayne , Rongjuan Cong , Lori L. Kardos , Teresa P. Karjala
发明人： Theresa J. Hermel-Davidock , Mehmet Demirors , Sarah M. Hayne , Rongjuan Cong , Lori L. Kardos , Teresa P. Karjala
IPC分类号： C08F210/02 , C08F2/01 , C08L23/08
CPC分类号： C08L23/04 , C08F10/00 , C08F210/16 , C08L23/02 , C08L23/08 , C08L23/0815 , C08L2205/02 , C08F2/001 , C08L2666/06 , C08F210/14 , C08F2500/05 , C08F2500/09 , C08F2500/20 , C08F4/64193
摘要： An ethylene-based polymer composition has been discovered and is characterized by a Comonomer Distribution Constant greater than about 45. The new ethylene-based polymer compositions are useful for making many articles, especially including films. The polymers are made using a metal complex of a polyvalent aryloxyether.
摘要翻译：已经发现乙烯基聚合物组合物，其特征在于大于约45的共聚单体分布常数。新的基于乙烯的聚合物组合物可用于制备许多制品，特别是包括膜。聚合物使用多价芳氧基醚的金属络合物制成。

9. 发明申请

US20110318514A1 ETHYLENE-BASED POLYMERS AND COMPOSITIONS, METHOD OF MAKING THE SAME AND ARTICLES PREPARED THEREFROM 审中-公开
标题翻译：基于乙烯的聚合物和组合物，其制备方法和制备的制品
公开(公告)号：US20110318514A1
公开(公告)日：2011-12-29
申请号：US13143553
申请日：2010-02-05
申请人： Sarah E. Patterson , William J. Michie, JR. , Robert J. Jorgensen , Dale Wright , Sarah M. Hayne
发明人： Sarah E. Patterson , William J. Michie, JR. , Robert J. Jorgensen , Dale Wright , Sarah M. Hayne
IPC分类号： B32B1/08 , C08F210/16 , C08F4/78
CPC分类号： C08F210/16 , C08F4/69 , C08F210/14 , C08F2500/12 , C08F2500/18 , C08F2500/20 , C08F2500/04 , C08F2500/10
摘要： The invention provides an ethylene-based interpolymer comprising the following features: a) density from 0.910 to 0.930 g/cc; b) melt index (I2) from 0.1 to 0.5 g/10 min; and c) a high density fraction in an ATREF short chain branch distribution (SCBD) curve, eluting above 92° C., of greater than 10 percent to less than 28 percent of the total ATREF SCBD curve area. The invention also provides a composition comprising an ethylene-based interpolymer that comprises the following features: a) a density from 0.919 to 0.928 g/cc; b) a melt index (I2) from 0.1 to 0.8 g/10 min; and c) a high density fraction in an ATREF short chain branch distribution (SCBD) curve, eluting above 92° C., of greater than 10 percent to less than 28 percent of the total ATREF SCBD curve area. The invention also provides a hollow tube comprising at least one component formed from a composition comprising an ethylene-based interpolymer that comprises the following features: a) a density from 0.919 to 0.928 g/cc; b) a melt index (I2) from 0.1 to 0.8 g/10 min; and c) a high density fraction in an ATREF short chain branch distribution (SCBD) curve, eluting above 92° C., of greater than 10 percent to less than 28 percent of the total ATREF SCBD curve area; and wherein the tube has a hydrostatic design basis (HDB) of at least 1000-psi at 23° C. per ASTM D-2837 regression method.
摘要翻译：本发明提供一种乙烯基互聚物，其包含以下特征：a）0.910至0.930g / cc的密度; b）熔融指数（I 2）为0.1至0.5g / 10min; 和c）在92℃以上洗脱的ATREF短链分支分布（SCBD）曲线中的高密度分数大于总ATREF SCBD曲线区域的10％至小于28％。本发明还提供包含乙烯基互聚物的组合物，其包含以下特征：a）0.919至0.928g / cc的密度; b）0.1至0.8g / 10min的熔体指数（I 2）; 和c）在92℃以上洗脱的ATREF短链分支分布（SCBD）曲线中的高密度分数大于总ATREF SCBD曲线区域的10％至小于28％。本发明还提供一种中空管，其包含由包含乙烯基互聚物的组合物形成的至少一种组分，所述组合物包含以下特征：a）密度为0.919至0.928g / cc; b）0.1至0.8g / 10min的熔体指数（I 2）; 和c）在92℃以上洗脱的ATREF短链分支分布（SCBD）曲线中的高密度分数大于总ATREF SCBD曲线区域的大于10％至小于28％; 并且其中所述管在23℃下根据ASTM D-2837回归方法具有至少1000-psi的流体静力学设计基准（HDB）。

10. 发明申请

US20100203277A1 ETHYLENE-BASED POLYMERS, METHODS OF MAKING THE SAME AND ARTICLES PREPARED THEREFROM 有权
标题翻译：乙烯基聚合物，其制备方法和制备的制品
公开(公告)号：US20100203277A1
公开(公告)日：2010-08-12
申请号：US12701153
申请日：2010-02-05
申请人： William J. Michie, JR. , Sarah M. Hayne , Sarah E. Patterson , Robert J. Jorgensen , Dale A. Wright
发明人： William J. Michie, JR. , Sarah M. Hayne , Sarah E. Patterson , Robert J. Jorgensen , Dale A. Wright
IPC分类号： B32B1/08 , C08F110/02
CPC分类号： C08F210/16 , C08F4/69 , C08F210/14 , C08F2500/12 , C08F2500/18 , C08F2500/20 , C08F2500/04 , C08F2500/10
摘要： The invention provides an ethylene-based interpolymer comprising the following features: a) density from 0.910 to 0.930 g/cc; b) melt index (I2) from 0.1 to 0.5 g/10 min; and c) a high density fraction in an ATREF short chain branch distribution (SCBD) curve, eluting above 92° C., of greater than 10 percent to less than 28 percent of the total ATREF SCBD curve area. The invention also provides a composition comprising an ethylene-based interpolymer that comprises the following features: a) a density from 0.919 to 0.928 g/cc; b) a melt index (I2) from 0.1 to 0.8 g/10 min; and c) a high density fraction in an ATREF short chain branch distribution (SCBD) curve, eluting above 92° C., of greater than 10 percent to less than 28 percent of the total ATREF SCBD curve area. The invention also provides a hollow tube comprising at least one component formed from a composition comprising an ethylene-based interpolymer that comprises the following features: a) a density from 0.919 to 0.928 g/cc; b) a melt index (I2) from 0.1 to 0.8 g/10 min; and c) a high density fraction in an ATREF short chain branch distribution (SCBD) curve, eluting above 92° C., of greater than 10 percent to less than 28 percent of the total ATREF SCBD curve area; and wherein the tube has a hydrostatic design basis (HDB) of at least 1000-psi at 23° C. per ASTM D-2837 regression method.
摘要翻译：本发明提供一种乙烯基互聚物，其包含以下特征：a）0.910-0.930g / cc的密度; b）熔融指数（I 2）为0.1至0.5g / 10min; 和c）在92℃以上洗脱的ATREF短链分支分布（SCBD）曲线中的高密度分数大于总ATREF SCBD曲线区域的10％至小于28％。本发明还提供包含乙烯基互聚物的组合物，其包含以下特征：a）0.919至0.928g / cc的密度; b）0.1至0.8g / 10min的熔体指数（I 2）; 和c）在92℃以上洗脱的ATREF短链分支分布（SCBD）曲线中的高密度分数大于总ATREF SCBD曲线区域的10％至小于28％。本发明还提供一种中空管，其包含由包含乙烯基互聚物的组合物形成的至少一种组分，所述组合物包含以下特征：a）密度为0.919至0.928g / cc; b）0.1至0.8g / 10min的熔体指数（I 2）; 和c）在92℃以上洗脱的ATREF短链分支分布（SCBD）曲线中的高密度分数大于总ATREF SCBD曲线区域的大于10％至小于28％; 并且其中所述管在23℃下根据ASTM D-2837回归方法具有至少1000-psi的流体静力学设计基准（HDB）。

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