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1. 发明授权

US5241112A Preparation of trialkylacetic acids, particularly of pivalic acid, using solid acid catalysis 失效
标题翻译：使用固体酸催化制备特异酸，特别是酸性酸
公开(公告)号：US5241112A
公开(公告)日：1993-08-31
申请号：US682810
申请日：1991-04-09
申请人： William A. Sanderson , Michael A. Richard
发明人： William A. Sanderson , Michael A. Richard
IPC分类号： B01J31/02 , C07B61/00 , C07C51/14 , C07C53/126 , C07F9/38
CPC分类号： C07F9/3808 , C07C51/14
摘要： This invention is a process for the production of trialkyl acetic acids, particularly of pivalic acid, from branched olefins, particularly isobutene, and carbon monoxide using a solid acid catalyst and optionally with minor amounts of a Lewis acid such as boron trifluoride.
摘要翻译：本发明是使用固体酸催化剂和任选地与少量路易斯酸如三氟化硼从支链烯烃，特别是异丁烯和一氧化碳生产三烷基乙酸，特别是新戊酸的方法。

2. 发明授权

US5227521A Preparation of trialkylacetic acids, particularly of pivalic acid, using Lewis acid catalysts 失效
标题翻译：使用柠檬酸催化剂制备特异酸，特别是酸性酸
公开(公告)号：US5227521A
公开(公告)日：1993-07-13
申请号：US683439
申请日：1991-04-09
申请人： Michael A. Richard , William A. Sanderson
发明人： Michael A. Richard , William A. Sanderson
IPC分类号： C07C51/14
CPC分类号： C07C51/14
摘要： This invention is a process for the production of trialkyl acetic acids, particularly of pivalic acid, from branched olefins, particularly isobutene, and carbon monoxide using catalytic amounts of a Lewis acid such as boron trifluoride.
摘要翻译：本发明是使用催化量的路易斯酸如三氟化硼从支链烯烃，特别是异丁烯和一氧化碳生产三烷基乙酸，特别是新戊酸的方法。

3. 发明授权

US4098784A Red-1-hydroxy-3,6-disulfo-8-acetamido-2-(3 phosphonophenylazo)naphthalene dyes 失效
标题翻译：红-1-羟基-3,6-二磺基-8-乙酰氨基-2-（3膦酰苯偶氮）萘染料
公开(公告)号：US4098784A
公开(公告)日：1978-07-04
申请号：US710153
申请日：1976-07-30
申请人： Ronald Swidler , William A. Sanderson
发明人： Ronald Swidler , William A. Sanderson
IPC分类号： C07F9/12 , C07F9/38 , C09B1/32 , C09B1/34 , C09B1/42 , C09B29/00 , C09B67/26 , C09B69/00 , D06P1/22 , D06P1/384 , D06P1/642 , D06P3/68 , D21H21/28 , C09B29/30 , D06P1/06 , D06P3/60
CPC分类号： C07F9/3882 , C07F9/12 , C09B1/32 , C09B1/34 , C09B1/42 , C09B29/00 , C09B29/30 , C09B67/0073 , C09B69/007 , D06P1/06 , D06P1/127 , D06P1/38 , D06P1/6421 , D06P3/68 , D06P3/8257 , D21H21/28
摘要： A dye of the formula: ##STR1## and the alkali metal and ammonium salts thereof are disclosed as novel compositions of matter useful in reactive dyeing of cellulose fibers to give bright red dyeings which exhibit good lightfastness and color strength.
摘要翻译：公开了下式的染料及其碱金属盐和铵盐作为可用于纤维素纤维的活性染色的新型组合物，以产生具有良好的耐光性和着色强度的亮红色染色。

4. 发明授权

US4028403A Process for preparing m-aminobenzenephosphonic acid 失效
标题翻译：制备间氨基苯膦酸的方法
公开(公告)号：US4028403A
公开(公告)日：1977-06-07
申请号：US693230
申请日：1976-06-07
申请人： William A. Sanderson
发明人： William A. Sanderson
IPC分类号： C07F9/38
CPC分类号： C07F9/3834
摘要： M-Aminobenzenephosphonic acid is prepared from the relatively inexpensive starting material benzenephosphonous acid by nitrating the acid starting material under controlled conditions followed by oxidation and reduction procedures to produce the desired product in high yields.
摘要翻译：通过在控制条件下硝酸化酸性起始原料，然后进行氧化和还原方法，从相对便宜的原料苯膦酸制备M-氨基苯膦酸，以高产率生产所需产物。

5. 发明授权

US5246901A Polysulfonic acids 失效
标题翻译：多糖类
公开(公告)号：US5246901A
公开(公告)日：1993-09-21
申请号：US197464
申请日：1988-05-23
申请人： William A. Sanderson
发明人： William A. Sanderson
IPC分类号： B01J31/02 , C07F9/30 , C07F9/38
CPC分类号： C07F9/3834 , C07F9/304
摘要： This invention provides novel compositions comprising aryl phosphonic or phosphinic acids substituted with more than one sulfo radical. These novel compounds may be reacted with tetravalent metal ions to provide polymers having an inorganic backbone, which polymers are useful as acid catalysts.
摘要翻译：本发明提供包含被多于一个磺基取代的芳基膦酸或次膦酸的新型组合物。这些新化合物可以与四价金属离子反应以提供具有无机骨架的聚合物，该聚合物可用作酸催化剂。

6. 发明授权

US4150021A Esters of cellulose with phosphonic acid dyes having a sulfonamide bridge 失效
标题翻译：具有磺酰胺桥膦酸染料的纤维素酯
公开(公告)号：US4150021A
公开(公告)日：1979-04-17
申请号：US876052
申请日：1978-02-08
申请人： Ronald Swidler , William A. Sanderson
发明人： Ronald Swidler , William A. Sanderson
IPC分类号： C09B69/00 , D06P1/38 , C09B62/82 , D06P1/04 , D06P3/34
CPC分类号： C09B69/007 , D06P1/38
摘要： Dyes of the formula ##STR1## are disclosed which are useful in dyeings where the phosphonic acid group serves both as a water-solubilizing group and as a group capable of reacting to bond covalently with the fiber to be dyed. Application of the dyes to cellulose results in reactive dyeing by immobilization of the dye as a cellulose phosphonate ester. The dye substituent is a chromophore, e.g. an anthraquinone or azo chromophore, while R may be hydrogen or lower alkyl.
摘要翻译：公开了用于染色的式“IMAGE”的染料，其中膦酸基团既用作水溶性基团又作为能够与待染色的纤维共价键合的基团。染料对纤维素的应用通过固定染料作为纤维素膦酸酯而导致活性染色。染料取代基是发色团，例如蒽醌或偶氮发色团，而R可以是氢或低级烷基。

7. 发明授权

US4129588A Selective manufacture of anhydrous modifications of methyl phosphonic acid and use thereof in making pure methyl phosphonic acid and salts thereof 失效
标题翻译：甲基膦酸的无水改性的选择性制备及其制备纯甲基膦酸及其盐的用途
公开(公告)号：US4129588A
公开(公告)日：1978-12-12
申请号：US394982
申请日：1973-09-07
申请人： William A. Sanderson
发明人： William A. Sanderson
IPC分类号： C07F9/38
CPC分类号： C07F9/3895 , C07F9/3808
摘要： Pyro-methyl phosphonic acid (methyl phosphonic acid monoanhydride) is obtained in a high degree of purity and a yield approaching 100% of theory by the pyrolysis of dimethyl hydrogen phosphite in liquid phase. The pyrolysis product is then converted to methyl phosphonic acid by boiling with water. If desired, the resulting aqueous acid solution may be directly converted to a salt, e.g., to monoammonium methyl phosphonate by the addition of one mole of ammonia per mole of methyl phosphonic acid, or water may be evaporated from the aqueous acid solution and crystalline methyl phosphonic acid may thus be recovered.
摘要翻译：通过液相中二甲基亚磷酸氢盐的热解，以高纯度和理论值接近100％得到焦甲基膦酸（甲基膦酸单酐）。然后通过用水煮沸将热解产物转化成甲基膦酸。如果需要，所得到的酸性水溶液可以通过每摩尔甲基膦酸加入1摩尔氨直接转化成盐，例如加入甲基膦酸单铵盐，或者可以从酸性水溶液和结晶甲基因此可以回收膦酸。

8. 发明授权

US5414187A Acid catalyst and use thereof in alkylation of olefins with tertiary alkanes 失效
标题翻译：酸催化剂及其在与叔烷烃烷基化烯烃中的应用
公开(公告)号：US5414187A
公开(公告)日：1995-05-09
申请号：US968998
申请日：1992-10-30
申请人： David L. King , Michael D. Cooper , William A. Sanderson
发明人： David L. King , Michael D. Cooper , William A. Sanderson
IPC分类号： B01J21/08 , B01J27/08 , B01J27/16 , B01J31/02 , B01J37/02 , C07C2/62 , C07C2/66 , C07C5/27 , C07C37/08 , C07C45/45 , C07C45/46 , C07C45/49 , C07C45/53 , C07C45/74 , C07C51/353 , C07C67/04 , C07C67/08 , C07C205/06 , C07C409/24 , C07C409/26 , C07D301/14 , C10G29/20
CPC分类号： B01J31/0259 , B01J27/08 , B01J31/0211 , B01J31/0225 , B01J31/0227 , B01J31/0231 , B01J31/0258 , B01J31/0271 , B01J37/0201 , C07C2/62 , C07C2/66 , C07C201/08 , C07C37/08 , C07C409/24 , C07C45/455 , C07C45/46 , C07C45/49 , C07C45/53 , C07C45/74 , C07C5/2794 , C07C51/353 , C07C67/04 , C07C67/08 , C07D301/14 , C10G29/205 , B01J21/08 , B01J2231/323 , B01J2531/48 , B01J27/16 , C07C2527/08 , C07C2527/10 , C07C2527/1213 , C07C2527/125 , C07C2527/126 , C07C2527/128 , C07C2527/133 , C07C2527/135 , C07C2527/14 , C07C2531/025 , Y02P20/52
摘要： The present invention provides a process for the conversion of a reactant into a reaction product in the presence of a novel acid catalyst complex comprising an organosulfonic acid having the formula[(R.sup.2 O).sub.2 P(O)].sub.y R(SO.sub.r R.sup.1).sub.xwherein R is an organo radical having at least one covalent carbon-fluorine bond, R.sup.1 is hydrogen, R.sup.1 is a hydrocarbyl radical having up to 20 carbon atoms or hydrogen, r is 2 or 3, x is an integer from 1 to 3, y is an integer of from 1 to 3 with the proviso that the phosphorus and the sulfur are covalently bonded to a carbon atom and which organosulfonic acid has been contacted with a Lewis Acid to produce a catalyst complex containing said Lewis Acid. In the elected claims, a process for providing a high octane alkylate stream by converting a mixture comprising isoparaffins and olefins into said alkylate in the presence of said acid catalyst complex, is described.
摘要翻译：本发明提供了一种在包含具有式[（R 2 O）2 P（O）] y R（SOr R 1）x的有机磺酸的新型酸催化剂络合物的存在下将反应物转化为反应产物的方法，其中R是具有至少一个共价碳 - 氟键的有机基团，R 1是氢，R 1是具有至多20个碳原子的烃基或氢，r是2或3，x是1至3的整数，y是 1至3，条件是磷和硫共价结合到碳原子上，并且有机磺酸已经与路易斯酸接触以产生含有路易斯酸的催化剂络合物。在所选择的权利要求中，描述了在所述酸催化剂络合物的存在下，通过将包含异链烷烃和烯烃的混合物转化成所述烷基化物来提供高辛烷基烷基化物流的方法。

9. 发明授权

US4942218A Process for the preparation of polymers having an inorganic backbone 失效
标题翻译：制备具有无机主链的聚合物的方法
公开(公告)号：US4942218A
公开(公告)日：1990-07-17
申请号：US197459
申请日：1988-05-23
申请人： William A. Sanderson , David L. King
发明人： William A. Sanderson , David L. King
IPC分类号： C08G79/14
CPC分类号： C08G79/14
摘要： The present invention provides a method of making a polymer by reacting, in the absence of water, an organic compound having the general formula R-H wherein R represents an organo radical having at least one unsaturated carbon-carbon bond and H is covalently bonded to one of said carbons, with PX.sub.3, wherein X is a halide radical, and zirconium ions to yield a reaction product and oxidizing and hydrolyzing such reaction product to yield a polymer represented by the general formula Zr(O.sub.3 PR).sub.n wherein n varies from about 1 to about 2.5. R may comprise sulfonic acid groups or may comprise sulfonatable site for sulfonation during the oxidation step. In either case, the resulting product is useful as an acid catalyst.
摘要翻译：本发明提供一种制备聚合物的方法，该方法通过在没有水的情况下使具有通式RH的有机化合物反应，其中R表示具有至少一个不饱和碳 - 碳键的有机基团，并且H共价键合至所述碳与PX3反应，其中X为卤化物基团，锆离子产生反应产物，氧化和水解该反应产物，得到由通式Zr（O3PR）n表示的聚合物，其中n为约1至约 2.5。 R可以包含磺酸基团，或者可以包括在氧化步骤期间磺化的可磺化位点。在任一情况下，所得产物可用作酸催化剂。

10. 发明授权

US4150020A Reactive xylylene diphosphonic acid dyes 失效
标题翻译：活性二甲苯二膦酸染料
公开(公告)号：US4150020A
公开(公告)日：1979-04-17
申请号：US860115
申请日：1977-12-13
申请人： Ronald Swidler , William A. Sanderson
发明人： Ronald Swidler , William A. Sanderson
IPC分类号： C07F9/38 , C07F9/6503 , C07F9/6521 , C09B69/00 , D06P1/38 , C09B62/80 , C09B62/82 , D06P1/384 , D06P3/10
CPC分类号： D06P1/38 , C07F9/38 , C07F9/65037 , C07F9/65217 , C09B69/007
摘要： P-Xylylenediphosphonic acid groups connected through the aromatic ring to a variety of chromophores provide a class of novel dyes of the general formula ##STR1## wherein "Dye" represents the chromophore. These dyes may be covalently bonded to fibers and other substrates containing hydroxyl, amino, or thiol groups to form phosphonic acid esters or amides by reaction in the presence of a carbodiimide such as cyanamide or dicyandiamide.
摘要翻译：通过芳环与多种发色团连接的对亚苄基二膦酸基团提供一类通式“IMAGE”的新型染料，其中“染料”表示发色团。这些染料可以通过在碳二亚胺如氨腈或双氰胺的存在下反应而与含有羟基，氨基或硫醇基团的纤维和其它底物共价键合以形成膦酸酯或酰胺。

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