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    • 3. 发明授权
    • Coating agents of polyurethane dispersions and the use thereof for top
coats and finishes
    • 聚氨酯分散体的涂层剂及其用于顶部涂层和表面处理剂的用途
    • US4652466A
    • 1987-03-24
    • US841492
    • 1986-03-19
    • Wilhelm ThomaKlaus NollKlaus NachtkampJosef PedainWalter Schroer
    • Wilhelm ThomaKlaus NollKlaus NachtkampJosef PedainWalter Schroer
    • C08G18/08C08G18/12C08G18/42C08G18/44C08G18/66C08G18/72C08G18/75C08J7/04B05D5/00
    • C08G18/0804C08G18/12C08G18/42C08G18/4238C08G18/44C08G18/6644C08G18/722C08G18/75C08J7/047C08J2327/06Y10T428/3158
    • This invention relates to coating compositions based on aqueous polyurethane dispersions, as well as the use of the coating compositions for the production of top coats or finishes on flexible substrates, particularly on PVC. The present coating agents contain an aqueous polyurethane dispersion having certain physico-chemical properties and the following composition of the solid substance:(A) from about 30 to 60%, by weight, of a hexane diol-1,6-polyester diol having a molecular weight of from about 500 to 6000;(B) up to about 8%, by weight, of a relatively low molecular weight triol having a molecular weight of from about 91 to 399;(C) from about 3 to 30%, by weight, of one or more mono- or poly-functional compounds bearing cationic and/or anionic groups and/or containing non-ionic polyoxyethylene segments;(D) from about 20 to 50%, by weight, of a diisocyanate corresponding to the following general formula: ##STR1## wherein R.sub.1, R.sub.2 and R.sub.3, which may be the same or different, each represents hydrogen or a straight- or branched-chain aliphatic hydrocarbon radical containing from 1 to 4 carbon atoms;(E) from about 2.5 to 20%, by weight, of other aliphatic and/or cycloaliphatic diisocyanates; and(F) from about 0.5 to 4%, by weight, of hydrazine; and optionally conventional additives, auxiliaries and catalysts.
    • 本发明涉及基于水性聚氨酯分散体的涂料组合物,以及用于在柔性基材上,特别是PVC上生产顶涂层或表面处理剂的涂料组合物的用途。 本发明的涂层剂含有具有一定物理化学性质和以下固体物质组成的水性聚氨酯分散体:(A)约30至60重量%的己二醇-1,6-聚酯二醇,其具有 分子量为约500至6000; (B)至多约8重量%的分子量为约91至399的较低分子量三醇; (C)约3至30重量%的一种或多种带有阳离子和/或阴离子基团和/或含有非离子聚氧乙烯链段的单官能或多官能化合物; (D)约20至50重量%的对应于以下通式的二异氰酸酯:其中R 1,R 2和R 3可以相同或不同,各自表示氢或直链或支链 含有1至4个碳原子的链脂族烃基; (E)约2.5至20重量%的其它脂族和/或脂环族二异氰酸酯; 和(F)约0.5至4重量%的肼; 和任选的常规添加剂,助剂和催化剂。