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1. 发明授权

US4723032A Modified polyamines and a process for their production 失效
标题翻译：改性多胺及其制备方法
公开(公告)号：US4723032A
公开(公告)日：1988-02-02
申请号：US437641
申请日：1982-10-29
申请人： Werner Rasshofer , Dieter Dieterich
发明人： Werner Rasshofer , Dieter Dieterich
IPC分类号： C08G18/00 , C07C67/00 , C07C239/00 , C07C269/02 , C07C275/14 , C07C325/00 , C07C333/00 , C08G18/10 , C08G18/50 , C08G18/82 , C08G18/83 , C08G73/00 , C08G73/02 , C07C125/06
CPC分类号： C08G18/83 , C08G18/10 , C08G18/5048
摘要： Modified polyamines containing carbamates, urethane and/or urea and/or thiourethane groups and having a primary amine content of from 0.1 to 20.2 wt % are produced by (a) mixing an organic isocyanate with a base in the presence of at least one hydrogen-active compound and water and (b) converting the carbamate, urethane and/or urea and/or thiourethane groups to amino groups. The isocyanate starting material has an isocyanate content of from 0.5 to 40 wt. %. The hydrogen-active compound contains a hydroxy and/or amino and/or thiol group. Water is used in a quantity such that one mol of water is present for each isocyanate equivalent. Conversion to form the amino groups is accomplished by treatment with a proton donor and/or thermal decomposition and/or solvent extraction. The polyamines thus-produced are particularly useful in the production of polyurethanes.
摘要翻译：含有氨基甲酸酯，氨基甲酸酯和/或脲和/或硫代氨基甲酸酯基团并且伯胺含量为0.1至20.2重量％的改性多胺通过以下步骤来制备：（a）在至少一种氢气存在下，将有机异氰酸酯与碱混合，活性化合物和水，和（b）将氨基甲酸酯，氨基甲酸酯和/或脲和/或硫代氨基甲酸酯基团转化为氨基。异氰酸酯原料的异氰酸酯含量为0.5〜40重量％。％。氢活性化合物含有羟基和/或氨基和/或硫醇基团。水的使用量使得每个异氰酸酯当量存在一摩尔的水。通过用质子供体和/或热分解和/或溶剂萃取处理来实现形成氨基的转化。如此生产的聚胺在聚氨酯的生产中特别有用。

2. 发明授权

US4532266A Polymer-containing polyether polyamines and a process for the production of these polyamines 失效
标题翻译：含聚合物的聚醚多胺和这些多胺的制备方法
公开(公告)号：US4532266A
公开(公告)日：1985-07-30
申请号：US360037
申请日：1982-03-19
申请人： Werner Rasshofer , Gerhard Balle , Dieter Dieterich , Holger Meyborg
发明人： Werner Rasshofer , Gerhard Balle , Dieter Dieterich , Holger Meyborg
IPC分类号： C08G18/10 , C08G18/12 , C08G18/50 , C08G18/63 , C07C127/15 , C07C127/24
CPC分类号： C08G18/632 , C08G18/10 , C08G18/12 , C08G18/5048
摘要： Polyether-based urethane-group-containing polyamines containing polymers and/or copolymers of unsaturated monomers and, optionally, urea and/or biuret and/or allophanate groups are produced by (a) reacting an NCO-prepolymer in aqueous alkaline solution at 0.degree. to 40.degree. C. to form a carbamate; (b) converting this carbamate to an amine by adding an ion exchanger to the reaction mixture; and (c) separating the polyamine from the reaction mixture. The NCO-prepolymers used as starting materials are prepolymers of (i) polyalkylene ether polyols having a molecular weight of from 1,000 to 10,000 containing from 1 to 60 wt. % of graft (co)polymers of unsaturated monomers; and (ii) excess molar quantities of organic polyisocyanate; and optionally, (iii) a low molecular weight chain-extending agent. The product polyamines have a molecular weight of from 1,000 to 10,000 and contain from 0.65 to 59.3 wt. % graft (co)polymer and from 0.11 to 2.9 wt. % terminal NH.sub.2 groups attached to the ethers by urethane groups in the polyisocyanate. The product polyamines are particularly useful in the production of polyurethanes.
摘要翻译：通过（a）使NCO预聚物在0℃的碱性水溶液中反应，制备含有聚氨酯基的聚胺和/或不饱和单体和任选的脲和/或缩二脲和/或脲基甲酸酯基团的聚合物和/ 至40℃以形成氨基甲酸酯; （b）通过向反应混合物中加入离子交换剂将该氨基甲酸酯转化为胺; 和（c）从反应混合物中分离多胺。用作原料的NCO-预聚物是（i）分子量为1,000至10,000的聚亚烷基醚多元醇的预聚物，其含有1至60wt。％的不饱和单体的接枝（共）聚合物; 和（ii）有机多异氰酸酯的过量摩尔数; 和（iii）低分子量链增长剂。产物多胺的分子量为1,000至10,000，含有0.65至59.3重量％％的接枝（共）聚合物和0.11-2.9重量％通过多异氰酸酯中的氨基甲酸酯连接到醚上的末端NH 2基团。产物多胺在聚氨酯的生产中特别有用。

3. 发明授权

US4386218A Polyamines and processes for the production of such polyamines and of polyurethane plastics therefrom 失效
标题翻译：用于生产这种多胺和聚氨酯塑料的多胺和方法
公开(公告)号：US4386218A
公开(公告)日：1983-05-31
申请号：US308326
申请日：1981-10-05
申请人： Werner Rasshofer , Dieter Dieterich , Holger Meyborg
发明人： Werner Rasshofer , Dieter Dieterich , Holger Meyborg
IPC分类号： C07C275/62 , B01J23/02 , B01J31/08 , C07B61/00 , C07C271/20 , C07C271/26 , C07C273/18 , C07C275/00 , C07C275/14 , C08G18/00 , C08G18/10 , C08G18/32 , C08G18/50 , C08G18/65 , C08G18/83 , C07C127/15 , C07C127/24
CPC分类号： C08G18/83 , C07C273/1809 , C08G18/10 , C08G18/5048
摘要： A compound having a terminal isocyanate group is hydrolyzed to produce a polyamine having a urethane and/or a urea and/or a biuret group. More particularly, a carbamate is made by mixing an isocyanate prepolymer having urethane and/or urea and/or biuret groups present with aqueous base solutions at a temperature of from 0.degree. to 0.degree. C. and in quantities such that the equivalent ratio of hydroxyl to isocyanate groups is between from 0.3:1 to .gtoreq.1.01 to 1. The carbamate is then treated with an acid ion exchanger to form an amine. The amine is then removed from any other material which may be present. A preferred polyamine thus-produced corresponds to the general formula: ##STR1## in which each R radical may represent a divalent straight or branched-chain aliphatic radical; a divalent cycloaliphatic radical; a 4,4'- and/or a 2,4'-dicyclohexylmethane radical; or a 2,4- and/or 2,6-methyl cyclohexane radical. Such an amine may be reacted with a polyisocyanate and optionally with other known additives to form a polyurethane plastic or foam.
摘要翻译：将具有末端异氰酸酯基的化合物水解以制备具有氨基甲酸酯和/或脲和/或缩二脲基的多胺。更具体地，氨基甲酸酯是通过在0℃至0℃的温度下混合存在有氨基甲酸酯和/或脲和/或缩二脲基的异氰酸酯预聚物和/或缩二脲基与碱水溶液形成的，其量使得羟基的当量比到异氰酸酯基团之间的比例为0.3:1至> / = 1.01:1。然后用酸式离子交换剂处理氨基甲酸酯以形成胺。然后将胺从可能存在的任何其它材料中除去。如此制备的优选的多胺对应于通式：其中每个R基团可以表示二价直链或支链脂族基团; 二价脂环族基团; 4,4'-和/或2,4'-二环己基甲基基团; 或2,4-和/或2,6-甲基环己烷基。这样的胺可以与多异氰酸酯和任选地与其它已知的添加剂反应以形成聚氨酯塑料或泡沫。

4. 发明授权

US4565645A Single-stage process for the production of polyamines and polyamines produced by such process 失效
标题翻译：通过这种方法生产的多胺和多胺的单阶段方法
公开(公告)号：US4565645A
公开(公告)日：1986-01-21
申请号：US506263
申请日：1983-06-21
申请人： Werner Rasshofer , Dieter Dieterich
发明人： Werner Rasshofer , Dieter Dieterich
IPC分类号： C08G18/00 , B01J27/232 , B01J31/04 , C07B61/00 , C07C67/00 , C07C209/00 , C07C209/62 , C07C211/51 , C07C211/53 , C07C271/06 , C07C275/62 , C08G18/10 , C08G18/30 , C08G18/38 , C08G18/50 , C08G18/83 , C08G73/00 , C08G73/02 , C09K3/00 , C08G18/08 , C08G18/20
CPC分类号： C08G18/5048 , C08G18/10 , C08G18/3819
摘要： Polyamines containing from 0.19 to 20.3 wt % primary amino groups are produced by hydrolyzing in a single stage an isocyanate with an excess of water, a relatively weak basic compound and a water-miscible polar solvent at a temperature from 50.degree. to 165.degree. C. The hydrolysis is conducted in a manner such that the reactants are substantially homogeneous during the reaction. The isocyanate should have an NCO-content of from 0.5 to 40 wt %. The weakly basic compound may be a carbonate or hydrogen carbonate of an alkali metal or an alkali or alkaline earth salt of a monocarboxylic or polycarboxylic acid or mixtures of such materials. The polyamines produced by this process are particularly useful in the production of polyurethanes.
摘要翻译：含有0.19〜20.3重量％伯氨基的多胺是通过在50℃〜165℃的温度下，用过量的水，相对弱碱性化合物和水混溶性极性溶剂在单一阶段水解异氰酸酯来生产的。以这样的方式进行水解，使得反应物在反应期间基本上是均匀的。异氰酸酯的NCO含量应为0.5〜40重量％。弱碱性化合物可以是碱金属或单羧酸或多元羧酸的碱金属或碱土金属盐或这些物质的混合物的碳酸盐或碳酸氢盐。通过该方法生产的多胺在聚氨酯的生产中特别有用。

5. 发明授权

US4418160A Polyamines and processes for the production of such polyamines and of polyurethane plastics therefrom 失效
标题翻译：用于生产这种多胺和聚氨酯塑料的多胺和方法
公开(公告)号：US4418160A
公开(公告)日：1983-11-29
申请号：US412614
申请日：1982-08-30
申请人： Werner Rasshofer , Dieter Dieterich , Holger Meyborg
发明人： Werner Rasshofer , Dieter Dieterich , Holger Meyborg
IPC分类号： C07C275/62 , B01J23/02 , B01J31/08 , C07B61/00 , C07C271/20 , C07C271/26 , C07C273/18 , C07C275/00 , C07C275/14 , C08G18/00 , C08G18/10 , C08G18/32 , C08G18/50 , C08G18/65 , C08G18/83 , C08G18/14
CPC分类号： C08G18/83 , C07C273/1809 , C08G18/10 , C08G18/5048
摘要： A compound having a terminal isocyanate group is hydrolyzed to produce a polyamine having a urethane and/or a urea and/or a biuret group. More particularly, a carbamate is made by mixing an isocyanate prepolymer having urethane and/or urea and/or biuret groups present with aqueous base solutions at a temperature of from 0.degree. to 0.degree. C. and in quantities such that the equivalent ratio of hydroxyl to isocyanate groups is between from 0,3:1 to .gtoreq.1,01 to 1. The carbamate is then treated with an acid ion exchanger to form an amine. The amine is then removed from any other material which may be present. A preferred polyamine thus-produced corresponds to the general formula: ##STR1## in which each R radical may represent a divalent straight or branched- chain aliphatic radical; a divalent cycloaliphatic radical; a 4,4'- and/or a 2,4'-dicyclohexylmethane radical; or a 2,4- and/or 2,6-methyl cyclohexane radical. Such an amine may be reacted with a polyisocyanate and optionally with other known additives to form a polyurethane plastic or foam.
摘要翻译：将具有末端异氰酸酯基的化合物水解以制备具有氨基甲酸酯和/或脲和/或缩二脲基的多胺。更具体地，氨基甲酸酯是通过在0℃至0℃的温度下混合存在有氨基甲酸酯和/或脲和/或缩二脲基的异氰酸酯预聚物和/或缩二脲基与碱水溶液形成的，其量使得羟基的当量比到异氰酸酯基团之间的比例为0.3:1至> / = 1,01:1。然后用酸性离子交换剂处理氨基甲酸酯以形成胺。然后将胺从可能存在的任何其它材料中除去。如此制备的优选的多胺对应于通式：其中每个R基团可以表示二价直链或支链脂族基团; 二价脂环族基团; 4,4'-和/或2,4'-二环己基甲基基团; 或2,4-和/或2,6-甲基环己烷基。这样的胺可以与多异氰酸酯和任选地与其它已知的添加剂反应以形成聚氨酯塑料或泡沫。

6. 再颁专利

USRE32677E Polyamines, a process for the production of polyamines and their use in the production of polyurethanes 失效
标题翻译：聚胺，一种生产聚胺的方法及其在聚氨酯生产中的应用
公开(公告)号：USRE32677E
公开(公告)日：1988-05-24
申请号：US848607
申请日：1986-04-07
申请人： Werner Rasshofer , Gerhard Grogler , Klaus Konig , Dieter Dieterich
发明人： Werner Rasshofer , Gerhard Grogler , Klaus Konig , Dieter Dieterich
IPC分类号： C08G18/00 , C07C67/00 , C07C209/00 , C07C209/62 , C07C211/13 , C08G18/10 , C08G18/32 , C08G18/50 , C08G18/64 , C08G18/83
CPC分类号： C08G18/83 , C08G18/10 , C08G18/5048 , C08G18/6415
摘要： The invention relates to a simplified, economic process for the production of polyamines by the alkaline hydrolysis of compounds containing terminal aromatic and/or aliphatic isocyanate groups (including modified isocyanates or NCO-prepolymers and semi-prepolymers with NCO-contents of from 0.5 to 40% by weight), with strong aqueous bases, direct isolation of the polyamines from the carbamate stage being possible by thermal carbamate decomposition and/or solvent extraction.The invention also relates to the use of the aromatic and/or aliphatic polyamines containing primary NH.sub.2 -groups obtainable by the process according to the invention for the production of polyurethanes, such as optionally cellular polyurethane plastics and polyurethane foams.

7. 发明授权

US4540720A Polyamines, a process for the production of polyamines and their use in the production of polyurethanes 失效
标题翻译：聚胺，一种生产聚胺的方法及其在聚氨酯生产中的应用
公开(公告)号：US4540720A
公开(公告)日：1985-09-10
申请号：US401472
申请日：1982-07-26
申请人： Werner Rasshofer , Gerhard Grogler , Klaus Konig , Dieter Dieterich
发明人： Werner Rasshofer , Gerhard Grogler , Klaus Konig , Dieter Dieterich
IPC分类号： C08G18/00 , C07C67/00 , C07C209/00 , C07C209/62 , C07C211/13 , C08G18/10 , C08G18/32 , C08G18/50 , C08G18/64 , C08G18/83 , C07C127/15 , C07C127/24
CPC分类号： C08G18/83 , C08G18/10 , C08G18/5048 , C08G18/6415
摘要： The invention relates to a simplified, economic process for the production of polyamines by the alkaline hydrolysis of compounds containing terminal aromatic and/or aliphatic isocyanate groups (including modified isocyanates or NCO-prepolymers and semi-prepolymers with NCO-contents of from 0.5 to 40% by weight), with strong aqueous bases, direct isolation of the polyamines from the carbamate stage being possible by thermal carbamate decomposition and/or solvent extraction.The invention also relates to the use of the aromatic and/or aliphatic polyamines containing primary NH.sub.2 -groups obtainable by the process according to the invention for the production of polyurethanes, such as optionally cellular polyurethane plastics and polyurethane foams.
摘要翻译：本发明涉及通过碱性水解含有末端芳族和/或脂族异氰酸酯基团的化合物（包括NCO-含量为0.5至40的改性异氰酸酯或NCO-预聚物和半预聚物来生产多胺的简化经济方法通过强碱水溶液，通过热氨基甲酸酯分解和/或溶剂萃取可以直接从氨基甲酸酯阶段分离多胺。本发明还涉及通过根据本发明的方法可获得的含有伯NH 2基团的芳族和/或脂族多胺用于生产聚氨酯，例如任选的细胞聚氨酯塑料和聚氨酯泡沫的用途。

8. 发明授权

US4870206A Aromatic polyisocyanates, their preparation and use as components for adhesives 失效
标题翻译：芳族聚异氰酸酯，它们的制备和用作粘合剂的组分
公开(公告)号：US4870206A
公开(公告)日：1989-09-26
申请号：US210908
申请日：1988-06-24
申请人： Josef Sanders , Rudolf Hombach , Helmut Reiff , Dieter Dieterich , Manfred Dollhausen
发明人： Josef Sanders , Rudolf Hombach , Helmut Reiff , Dieter Dieterich , Manfred Dollhausen
IPC分类号： C07C67/00 , C07C69/00 , C07C241/00 , C07C265/12 , C07C265/14 , C08G18/10 , C08G18/69 , C08G18/77 , C09J175/00
CPC分类号： C07C265/12 , C08G18/10 , C08G18/69 , C08G18/771 , C09J175/00
摘要： New compounds containing isocyanatophenoxy groups, corresponding to ##STR1## wherein R.sup.1 denotes a residue of a n-valent polyhydroxyl compound having a molecular weight of about 92-6000, R.sup.2 denotes hydrogen or methyl group and n denotes an integer of from 3 to 8 were found to be suitable as hardeners in the preparation of adhesives.
摘要翻译：含有异氰酸酯基苯氧基的新化合物，对应于，其中R1表示分子量为约92-6000的n价多羟基化合物的残基，R2表示氢或甲基，n表示3至8的整数为发现在粘合剂的制备中适合用作硬化剂。

9. 发明授权

US4496491A Aromatic diisocyanates containing N,N-disubstituted sulfonamide groups and processes for their production 失效
标题翻译：含有N，N-二取代磺酰胺基团的芳族二异氰酸酯及其制备方法
公开(公告)号：US4496491A
公开(公告)日：1985-01-29
申请号：US401036
申请日：1982-07-22
申请人： Richard Kopp , Gerhard Grogler , Helmut Reiff , Dieter Dieterich
发明人： Richard Kopp , Gerhard Grogler , Helmut Reiff , Dieter Dieterich
IPC分类号： C08G18/00 , C07C67/00 , C07C241/00 , C07C265/14 , C07D295/26 , C08G18/77 , C07C119/048
CPC分类号： C07D295/26 , C08G18/775
摘要： Diisocyanates corresponding to the formula ##STR1## in which R.sup.1, R.sup.2, R.sup.3, R.sup.4, R.sup.5 and R.sup.6 (an isocyanate-containing radical) are as defined herein are made by several processes. These diisocyanates may be made by phosgenating the diamine in which the diisocyanate is based. They may also be produced by treating the bis-urethane of the tertiary alcohol corresponding to the diisocyanate with phosgene. Such diisocyanates may also be made by treating a specific type of bis-urea with hydrogen chloride. The diisocyanates corresponding to the above-given formula are particularly useful in the production of polyurethanes having good flame-proof and mechanical properties.
摘要翻译：其中R 1，R 2，R 3，R 4，R 5和R 6（含异氰酸酯的基团）如本文所定义的式“IMAGE”的二异氰酸酯通过几种方法制备。这些二异氰酸酯可以通过使二异氰酸酯所基于的二胺光气化而制成。它们也可以通过用光气处理对应于二异氰酸酯的叔醇的双 - 氨基甲酸酯来制备。这种二异氰酸酯也可以通过用氯化氢处理特定类型的双脲来制备。对应于上述给定配方的二异氰酸酯特别可用于生产具有良好的阻燃和机械性能的聚氨酯。

10. 发明授权

US4440901A Process for the production of plastic based on polyisocyanates 失效
标题翻译：基于多异氰酸酯生产塑料的方法
公开(公告)号：US4440901A
公开(公告)日：1984-04-03
申请号：US509910
申请日：1983-07-01
申请人： Helmut Reiff , Dieter Dieterich
发明人： Helmut Reiff , Dieter Dieterich
IPC分类号： C08G18/00 , C08G18/10 , C08G18/34 , C08G18/42 , C08G18/48 , C08G18/65 , C08G18/73 , C08G18/75
CPC分类号： C08G18/75 , C08G18/10 , C08G18/34 , C08G18/4263 , C08G18/4887
摘要： The present invention is directed to a process for the production of plastics based on an isocyanate-polyaddition product by(1) forming an isocyanate group-containing prepolymer from(a) a compound which has a molecular weight of from 146 to about 10,000, is substantially free from hydroxyl groups, contains at least two terminal carboxyl groups and optionally contains ether and/or ester groups,(b) excess quantities of an organic nonaromatic polyisocyanate which has at least one cyclohexane ring and exclusively contains aliphatically- and/or cycloaliphatically-bound isocyanate groups and(c) up to 10 equivalent percent, based on the isocyanate-reactive groups in component (a), of a compound which is monofunctional for the purposes of the isocyanate-addition reaction and,(2) reacting the product of step (1) with(d) a chain-lengthening agent such as water, a polyamine containing at least two primary and/or secondary amino groups or hydrazine or a derivative thereof containing at least two primary and/or secondary amino groups.
摘要翻译：本发明涉及通过（1）从（a）分子量为146至约10,000的化合物形成含异氰酸酯基的预聚物来生产基于异氰酸酯加聚产物的塑料的方法，是基本上不含羟基，含有至少两个末端羧基并且任选地含有醚和/或酯基，（b）过量的有机非芳族聚异氰酸酯，其具有至少一个环己烷环并且仅含有脂族和/或脂环结合异氰酸酯基团和（c）基于组分（a）中异氰酸酯反应性基团的异氰酸酯加成反应中单官能化合物的至多10当量％，和（2）使步骤（1）与（d）链增长剂如水，含有至少两个伯和/或仲氨基的多胺或肼或其衍生物至少包含两个伯和/或仲氨基。

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