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1. 发明授权

US4652600A Sulfomaleation of polyolefins (C-1966) 失效
标题翻译：聚烯烃的磺化成型（C-1966）
公开(公告)号：US4652600A
公开(公告)日：1987-03-24
申请号：US809030
申请日：1985-12-16
申请人： Warren A. Thaler , Stanley J. Brois , Francis N. Ferrara
发明人： Warren A. Thaler , Stanley J. Brois , Francis N. Ferrara
IPC分类号： C08F8/34 , C08F8/46
CPC分类号： C08F8/34
摘要： A method for controlling the viscosity of organic liquids, said organic liquid having a solubility parameter of from about 6 to about 10.5, which comprises incorporating into said organic liquid a minor amount of a polymer which is a sulfomaleic anhydride adduct or sulfoester maleic anhydride adduct with an unsaturated hydrocarbon polymer, said adduct being hydrolyzed and neutralized.
摘要翻译：一种用于控制有机液体的粘度的方法，所述有机液体的溶解度参数为约6至约10.5，其包括向所述有机液体中加入少量的聚合物，所述聚合物是磺基马来酸酐加合物或磺酸酯马来酸酐加合物，不饱和烃聚合物，所述加合物被水解和中和。

2. 发明授权

US4587304A Sulfomaleation of polyolefins 失效
标题翻译：聚烯烃的磺化成型
公开(公告)号：US4587304A
公开(公告)日：1986-05-06
申请号：US778269
申请日：1985-09-20
申请人： Warren A. Thaler , Stanley J. Brois , Francis N. Ferrara
发明人： Warren A. Thaler , Stanley J. Brois , Francis N. Ferrara
IPC分类号： C10M159/12 , C08F8/34 , C08F8/44 , C08F8/46 , C10M133/04 , C10M151/04 , C10N10/02 , C10N10/04 , C10N10/06 , C10N10/08 , C10N10/16 , C10N30/02
CPC分类号： C08F8/46
摘要： The present invention relates to novel polymers which are sulfomaleic anhydride adducts of an unsaturated hydrocarbon, wherein the novel polymers are produced by contacting sulfomaleic anhydride or derivatives with an unsaturated hydrocarbon to form the novel polymer, which has a M.sub.n of about 900 to about 10.sup.7.
摘要翻译：本发明涉及新型聚合物，它是不饱和烃的磺基马来酸酐加合物，其中新型聚合物是通过使磺基马来酸酐或衍生物与不饱和烃接触而形成新型聚合物，其具有约900至约107 。

3. 发明授权

US4737303A Sulfomaleation of organic molecules and polymers 失效
标题翻译：有机分子和聚合物的磺化
公开(公告)号：US4737303A
公开(公告)日：1988-04-12
申请号：US911761
申请日：1986-09-26
申请人： Warren A. Thaler , Stanley J. Brois , Francis N. Ferrara
发明人： Warren A. Thaler , Stanley J. Brois , Francis N. Ferrara
IPC分类号： C08F8/34 , C08F8/46
CPC分类号： C08F8/34 , C08F8/32 , C08F2810/20
摘要： A covalently bonded reaction product of:(a) a sulfomaleic anhydride adduct with an unsaturated hydrocarbon polymer; and(b) a polar molecule containing at least one primary or secondary amino group.
摘要翻译：共价键合的反应产物：（a）磺基马来酸酐加合物与不饱和烃聚合物; 和（b）含有至少一个伯或仲氨基的极性分子。

4. 发明授权

US5023005A Solution of oil and sulfone adduct 失效
标题翻译：油和砜加合物的溶液
公开(公告)号：US5023005A
公开(公告)日：1991-06-11
申请号：US486688
申请日：1990-03-01
申请人： Warren A. Thaler , Stanley J. Brois , Henry K. Hall
发明人： Warren A. Thaler , Stanley J. Brois , Henry K. Hall
IPC分类号： C08F8/34 , C08F8/46
CPC分类号： C08F8/34 , C08F8/32 , C08F2810/20
摘要： A sulfone adduct which comprises the reaction product of: ##STR1## and an unsaturated hydrocarbon polymer wherein X is an alkyl group selected from the group consisting of C.sub.n H.sub.2n +1, wherein n=1 to 18; X is an aryl group selected from the group consisting of C.sub.m H.sub.m-1 wherein m=6 and C.sub.m H.sub.m-2 Z wherein m=6 and Z is selected from the group consisting of OR', R", COOR'", NO.sub.2, Cl, Br, F and I where R', R" and R'" having about 1 to about 18 carbon atoms; wherein said unsaturated hydrocarbon polymer is selected from the group consisting of ethylene propylene terpolymers, ethylene diene copolymers, propylene diene copolymers, polyisoprene, butyl rubber, polybutadiene and styrenebutadiene, and styrene-isoprene random and block copolymers, polypropylenes and polyisobutylenes.
摘要翻译：一种砜加合物，其包含以下反应产物：＆lt; IMAGE＆gt;和不饱和烃聚合物，其中X为选自C n H 2n + 1，其中n = 1-18的烷基; X是选自CmHm-1，其中m = 6和CmHm-2Z的芳基，其中m = 6，Z选自OR'，R“，COOR”，NO 2，Cl Br，F和I，其中R'，R“和R”'具有约1至约18个碳原子; 其中所述不饱和烃聚合物选自乙烯丙烯三元共聚物，乙烯二烯共聚物，丙烯二烯共聚物，聚异戊二烯，丁基橡胶，聚丁二烯和苯乙烯丁二烯，以及苯乙烯 - 异戊二烯无规和嵌段共聚物，聚丙烯和聚异丁烯。

5. 发明授权

US4920179A Sulfonomaleation of organic molecules and polymers 失效
标题翻译：有机分子和聚合物的硫代化
公开(公告)号：US4920179A
公开(公告)日：1990-04-24
申请号：US174380
申请日：1988-03-28
申请人： Warren A. Thaler , Stanley J. Brois , Henry K. Hall
发明人： Warren A. Thaler , Stanley J. Brois , Henry K. Hall
IPC分类号： C08F8/34 , C08F8/46
CPC分类号： C08F8/34 , C08F8/32 , C08F2810/20
摘要： A sulfone adduct which comprises the reaction product of: ##STR1## and an unsaturated hydrocarbon polymer wherein X is an alkyl group selected from the group consisting of C.sub.n H.sub.2n +1, wherein n=1 to 18; X is an aryl group selected from the group consisting of C.sub.m H.sub.m-1 wherein m=6 and C.sub.m H.sub.m-2 Z wherein m=6 and Z is selected from the group consisting of OR', R", COOR'", NO.sub.2, Cl, Br, F and I where R', R" and R'" having about 1 to about 18 carbon atoms; wherein said unsaturated hydrocarbon polymer is selected from the group consisting of ethylene propylene terpolymers, ethylene diene copolymers, propylene diene copolymers, polyisoprene, butyl rubber, polybutadiene and styrenebutadiene, and styrene-isoprene random and block copolymers, polypropylenes and polyisobutylenes.
摘要翻译：一种砜加合物，其包含以下反应产物：＆lt; IMAGE＆gt;和不饱和烃聚合物，其中X为选自C n H 2n + 1，其中n = 1-18的烷基; X是选自CmHm-1，其中m = 6和CmHm-2Z的芳基，其中m = 6，Z选自OR'，R“，COOR”，NO 2，Cl ，Br，F和I，其中R'，R“和R”'具有约1至约18个碳原子; 其中所述不饱和烃聚合物选自乙烯丙烯三元共聚物，乙烯二烯共聚物，丙烯二烯共聚物，聚异戊二烯，丁基橡胶，聚丁二烯和苯乙烯丁二烯，以及苯乙烯 - 异戊二烯无规和嵌段共聚物，聚丙烯和聚异丁烯。

6. 发明授权

US5872084A Dispersants derived from heavy polyamine and second amine 失效
标题翻译：衍生自重多胺和二胺的分散剂
公开(公告)号：US5872084A
公开(公告)日：1999-02-16
申请号：US7477
申请日：1998-01-15
申请人： Jacob I. Emert , Joseph V. Cusumano , David C. Dankworth , William D. Diana , William B. Eckstrom , Keith R. Gorda , Antonio Gutierrez , Jon E. Stanat , Warren A. Thaler , Stephen Zushma
发明人： Jacob I. Emert , Joseph V. Cusumano , David C. Dankworth , William D. Diana , William B. Eckstrom , Keith R. Gorda , Antonio Gutierrez , Jon E. Stanat , Warren A. Thaler , Stephen Zushma
IPC分类号： C10M159/12 , C08F8/00 , C08F8/32 , C10L1/2383 , C10L1/30 , C10L10/00 , C10M129/93 , C10M129/95 , C10M133/56
CPC分类号： C10M133/56 , C08F8/14 , C08F8/32 , C10L1/2383 , C10L1/303 , C10L10/04 , C10M129/93 , C10M129/95 , C10M2207/125 , C10M2207/129 , C10M2207/281 , C10M2207/282 , C10M2207/283 , C10M2207/286 , C10M2215/04 , C10M2215/26 , C10M2217/046 , C10M2217/06
摘要： A Koch functionalized product, which is the reaction product of at least one hydrocarbon with carbon monoxide and a nucleophilic trapping agent, is derivatized with a heavy polyamine and a second amine. The hydrocarbon is a hydrocarbon compound or a hydrocarbon polymer. A heavy polyamine is a mixture of polyamines containing small amounts of lower polyamine oligomers such as tetraethylene pentamine and pentaethylenehexamine and containing primarily oligomers with more than 6 nitrogens and more extensive branching. Rubber seals embrittlement is reduced or minimized.
摘要翻译：作为至少一种烃与一氧化碳和亲核捕集剂的反应产物的Koch官能化产物用重多胺和第二胺衍生化。烃是烃化合物或烃聚合物。重多胺是含有少量下述多胺低聚物如四亚乙基五胺和五亚乙基六胺的多胺的混合物，并且主要含有具有超过6个氮和更广泛支化的低聚物。橡胶密封件脆化减少或最小化。

7. 发明授权

US5691422A Saturated polyolefins having terminal aldehyde or hydroxy substituents and derivatives thereof 失效
标题翻译：具有末端醛或羟基取代基的饱和聚烯烃及其衍生物
公开(公告)号：US5691422A
公开(公告)日：1997-11-25
申请号：US662835
申请日：1996-06-12
申请人： Jacob Emert , Istvan T. Horvath , Richard H. Schlosberg , Warren A. Thaler , David A. Young , Stephen Zushma
发明人： Jacob Emert , Istvan T. Horvath , Richard H. Schlosberg , Warren A. Thaler , David A. Young , Stephen Zushma
IPC分类号： C08F8/00 , C08F8/32 , C08F210/16 , C08F210/18 , C10L1/198 , C10L1/22 , C10L1/238 , C10L1/2383 , C10L1/2387 , C10L10/00 , C10M133/54 , C10M133/58
CPC分类号： C10M133/58 , C08F210/18 , C08F8/00 , C08F8/32 , C10L1/198 , C10L1/238 , C10L1/2383 , C10L1/2387 , C10L10/18 , C10M133/54 , C08F210/16 , C10M2215/04 , C10M2215/042 , C10M2215/22 , C10M2215/221 , C10M2215/225 , C10M2215/226 , C10M2215/26 , C10M2215/30 , C10M2217/046 , C10M2217/06
摘要： A saturated polymer having a terminal aldehyde or hydroxy substituent which may be used directly or in a derivative form as a dispersant for both fuel and lubricating oil compositions, wherein the saturated polymer has a M.sub.n of about 300 to 10,000, and is derived from a polyolefin which is derived from a monomer of the formula H.sub.2 C.dbd.CHR.sup.4, wherein R.sup.4 is hydrogen or a straight or branched chain alkyl radical, and wherein the polyolefin has at least about 30% terminal vinylidene unsaturation. Particularly desirable amine derivatives can be formed by either a single step aminomethylation process or a two step hydroformylation and reductive amination process.
摘要翻译：具有末端醛或羟基取代基的饱和聚合物，其可以直接或以衍生形式用作燃料和润滑油组合物的分散剂，其中饱和聚合物的Mn为约300至10,000，并且衍生自聚烯烃其衍生自式H2C = CHR4的单体，其中R4是氢或直链或支链烷基，并且其中聚烯烃具有至少约30％的末端亚乙烯基不饱和键。特别理想的胺衍生物可以通过单步氨基甲基化方法或两步加氢甲酰化和还原胺化方法形成。

8. 发明授权

US5190797A Coating a substrate with an ionomer 失效
标题翻译：用离聚物涂覆基材
公开(公告)号：US5190797A
公开(公告)日：1993-03-02
申请号：US720042
申请日：1991-06-24
申请人： Warren A. Thaler , Cruise K. Jones , Evelyn N. Drake , Pacifico V. Manalastas , Edward N. Kresge
发明人： Warren A. Thaler , Cruise K. Jones , Evelyn N. Drake , Pacifico V. Manalastas , Edward N. Kresge
IPC分类号： B01J2/00 , B01J2/28 , C05G3/00
CPC分类号： B01J2/28 , B01J2/006 , C05G3/0029
摘要： The present invention relates to a process for the encapsulation of a solid substrate with a neutralized sulfonated polymer, which comprises the steps of: (a) forming a solution of a non-conjugated, diene polymer in a solvent selected from the group consisting of aliphatic, aromatic hydrocarbons and mixtures thereof; (b) contacting the solution of the unsaturated polymer with a sulfonating agent at a sufficient temperature and for a sufficient period of time to form a solution of a sulfonated polymer containing free acid; (c) forming a solution of a base selected from the group consisting of alkali metal hydroxides and mixtures thereof in a mixtrue of an aliphatic alcohol and a hydrocarbon, the hydrocarbon being selected from the group consisting of aliphatic and aromatic hydrocarbons and mixtures thereof; (d) adding the solution of base to the solution of sulfonated polymer in an amount sufficient to neutralize the polymer and the free acid, thereby forming a coating solution; (e) contacting the solid substrate with the coating solution while removing the solvent therefrom, thereby forming an encapsulated substrate. In a preferred embodiment, the solvent removed during step (e) is recovered and distilled to separate the solvent into at least two fractions, a fraction containing substantially hydrocarbon and an alcohol containing fraction. The separated solvents are then recycled to dissolve the polymer in step (a) and to dissolve the base in step (c).
摘要翻译：本发明涉及用中和的磺化聚合物包封固体基质的方法，其包括以下步骤：（a）在选自脂肪族的溶剂中的溶剂中形成非共轭二烯聚合物的溶液，芳族烃及其混合物; （b）在足够的温度下将不饱和聚合物的溶液与磺化剂接触足够的时间以形成含有游离酸的磺化聚合物的溶液; （c）在脂族醇和烃的混合物中形成选自碱金属氢氧化物及其混合物的碱的溶液，所述烃选自脂族和芳族烃及其混合物; （d）将碱溶液以足以中和聚合物和游离酸的量向磺化聚合物溶液中加入，从而形成涂布溶液; （e）将固体基质与涂布溶液接触，同时从其中除去溶剂，由此形成封装的基材。在优选的实施方案中，回收步骤（e）中除去的溶剂并蒸馏以将溶剂分离成至少两个馏分，基本上含有烃和含醇的馏分。然后将分离的溶剂再循环以在步骤（a）中溶解聚合物并在步骤（c）中溶解碱。

9. 发明授权

US5093003A Halogenated polyurethanes 失效
标题翻译：卤化聚氨酯
公开(公告)号：US5093003A
公开(公告)日：1992-03-03
申请号：US676777
申请日：1991-03-25
申请人： W. S. Winston Ho , Guido Sartori , Warren A. Thaler , Bruce H. Ballinger , David C. Dalrymple , Robert P. Mastondrea
发明人： W. S. Winston Ho , Guido Sartori , Warren A. Thaler , Bruce H. Ballinger , David C. Dalrymple , Robert P. Mastondrea
IPC分类号： B01D71/54 , B01D71/80 , C08G18/10 , C08G18/42 , C08G18/77
CPC分类号： C08G18/773 , B01D71/80 , C08G18/10 , C08G18/4238 , B01D71/48 , B01D71/54
摘要： A new copolymer composition comprising the soft segment of an aliphatic polyester and the hard segment of a highly halogenated polyurethane containing from 3 to 36 halogen atoms is disclosed. The new halogenated polyurethane copolymer membrane has high thermal stability, and good selectivity and permeability for separation of an aromatic/saturate mixture.
摘要翻译：公开了一种新的共聚物组合物，其包含脂族聚酯的软链段和含有3至36个卤素原子的高度卤化的聚氨酯的硬链段。新的卤化聚氨酯共聚物膜具有高的热稳定性，以及用于分离芳族/饱和物混合物的良好的选择性和渗透性。

10. 发明授权

US5051461A Novel pressure sensitive adhesives from diene-ethoxylated amine styrene sulfonate 失效
标题翻译：来自二烯 - 乙氧基化胺苯乙烯磺酸盐的新型压敏粘合剂
公开(公告)号：US5051461A
公开(公告)日：1991-09-24
申请号：US589284
申请日：1990-09-27
申请人： Pawan K. Agarwal , Warren A. Thaler
发明人： Pawan K. Agarwal , Warren A. Thaler
IPC分类号： C08F236/10 , C09J7/02 , C09J109/10
CPC分类号： C09J7/0214 , C08F236/10 , C09J109/10
摘要： This invention relates to emulsion type adhesive compositions which include a metal neutralized copolymer of a conjugated diene and an ethoxylated alkylamine salt of a styrene sulfonate, wherein the sulfonated copolymer has about 5 to about 125 meq. so sulfonate groups per 100 grams of the sulfonated copolymer, and less than about 300 parts by weight of a hydrocarbon resin of a petroleum or coal tar distillate, having about 5 to 6 carbon atoms, the hydrocarbon resin being composed of aliphatic dienes and monoolefins per 100 parts by weight of the neutralized sulfonated copolymer.
摘要翻译：本发明涉及乳液型粘合剂组合物，其包括共轭二烯的金属中和共聚物和苯乙烯磺酸盐的乙氧基化烷基胺盐，其中磺化共聚物具有约5至约125meq。因此每100克磺化共聚物的磺酸盐基团，以及小于约300重量份的具有约5至6个碳原子的石油或煤焦油馏出物的烃树脂，烃树脂由脂族二烯和单烯烃组成 100重量份中和的磺化共聚物。

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