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    • 2. 发明授权
    • Low surface energy polyisocyanates and their use in one-or two-component
coating compositions
    • 低表面能多异氰酸酯及其在单组分或双组分涂料组合物中的用途
    • US5747629A
    • 1998-05-05
    • US764891
    • 1996-12-16
    • Philip E. YeskeWilliam E. SlackEdward P. Squiller
    • Philip E. YeskeWilliam E. SlackEdward P. Squiller
    • C08G18/02C08G18/73C08G18/77C08G18/78C08G18/79C08G18/80C09D175/04C08G18/28
    • C08G18/8087C08G18/773C08G18/7837
    • The present invention relates to polyisocyanate adducts containing allophanate groups, fluorine and optionally isocyanurate groups that are prepared by reacting compounds a) which i) are substantially free of hydroxyl groups and isocyanate groups, ii) have an average of at least two urethane groups per molecule and iii) contain 0 to 50% by weight of fluorine, based on the weight of the polyisocyanate adducts, with an excess quantity, based on the equivalents of urethane groups, of polyisocyanates b), which optionally contain fluorine, to form polyisocyanate adducts and optionally removing at least a portion of the unreacted excess polyisocyanates b), provided that compounds a) and polyisocyanates b) contain a total of at least 0.001% by weight, of fluorine, based on the weight of the polyisocyanate adducts. The present invention also relates to a process for preparing these polyisocyanates adducts, to blends of the polyisocyanate adducts with other polyisocyanates that do not contain fluorine and to the use of the polyisocyanate adducts or polyisocyanate blends, optionally in blocked form, in one- or two-component coating compositions.
    • 本发明涉及通过使i)基本上不含羟基和异氰酸酯基的化合物a)制备的含有脲基甲酸酯基团,氟和任选的异氰脲酸酯基团的多异氰酸酯加合物,ii)每个分子平均具有至少两个氨基甲酸酯基团 和iii)基于多异氰酸酯加合物的重量,含有0至50重量%的氟,基于氨基甲酸酯基的当量,任选地含有氟的多异氰酸酯b),以形成多异氰酸酯加合物和 任选地除去至少一部分未反应的过量多异氰酸酯b),条件是化合物a)和多异氰酸酯b)基于聚异氰酸酯加合物的重量含有总共至少0.001重量%的氟。 本发明还涉及一种制备这些多异氰酸酯加成物的方法,多异氰酸酯加合物与不含氟的其它多异氰酸酯的共混物以及任选地以封闭形式在一或二个中使用的多异氰酸酯加合物或多异氰酸酯共混物 - 组分涂料组合物。
    • 3. 发明授权
    • Pure, in particular catalyst-free polyurethanes
    • 纯的,特别是无催化剂的聚氨酯
    • US5374704A
    • 1994-12-20
    • US166760
    • 1993-12-14
    • Hanns-Peter MullerRolf DheinHerbert HuglHeinz Pudleiner
    • Hanns-Peter MullerRolf DheinHerbert HuglHeinz Pudleiner
    • A61L24/00A61L27/00A61L27/18A61L29/00A61L29/06A61L31/06B65D65/38C08G18/08C08G18/10C08G18/44C08G18/73C08G18/75C08G18/77C08J5/18
    • C08G18/773A61L27/18A61L29/06A61L31/06C08G18/10C08G18/44C08G18/75
    • The present invention is directed to pure polyurethanes which are biocompatible. These pure polyurethanes comprise the reaction product of:a) a pre-adduct containing NCO groups and comprising the reaction product ofi) a diisocyanate selected from the group consisting of aliphatic diisocyanates, cycloaliphatic diisocyanates, and mixtures thereof, withii) a macrodiol having a molecular weight of from 500 to 10,000 wherein said components i) and ii) reacted at temperatures of from 90.degree.-150.degree. C.; withb) a chain extender having a molecular weight of from 62 to 400 and being selected from the group consisting of aliphatic diols, cycloaliphatic diols, and mixtures thereof, and optionally,c) additional diisocyanate selected from the group consisting of aliphatic diisocyanates, cycloaliphatic diisocyanates, and mixtures thereof,wherein said component c), when added, is added either simultaneously with component b) or separately from component b), the quantities of components a)i), a)ii), and c) being such that the molar ratio of diisocyanate to macrodiol is from 1.5:1 to 22:1, and the reaction of components a) and b) and optionally component c) is conducted at temperatures of from 90.degree. to 230.degree. C., with the proviso that the reaction conditions are maintained until said polyurethane has a melt viscosity of at least 2500 mPa.s at 120.degree. C.
    • 本发明涉及生物相容的纯聚氨酯。 这些纯聚氨酯包括以下物质的反应产物:a)含有NCO基团的预加合物,其包含i)选自脂族二异氰酸酯,脂环族二异氰酸酯及其混合物的二异氰酸酯的反应产物,ii)具有 分子量为500至10,000,其中所述组分i)和ii)在90-150℃的温度下反应; 其中b)分子量为62至400的扩链剂,并且选自脂族二醇,脂环族二醇及其混合物,以及任选地,c)另外的二异氰酸酯,其选自脂族二异氰酸酯,脂环族脂族 二异氰酸酯及其混合物,其中所述组分c)在加入时与组分b)同时加入或与组分b)分开加入,组分a)i),a)ii)和c)的数量使得 二异氰酸酯与大分子二醇的摩尔比为1.5:1至22:1,组分a)和b)和任选组分c)的反应在90℃至230℃的温度下进行,条件是 维持反应条件,直到所述聚氨酯在120℃下的熔体粘度为至少2500mPa.s。
    • 7. 发明授权
    • Process for producing information recording medium
    • 生产信息记录介质的方法
    • US5008128A
    • 1991-04-16
    • US304086
    • 1989-01-31
    • Takanori KudoHeigo Ishihara
    • Takanori KudoHeigo Ishihara
    • C08G18/50C08G18/70C08G18/77C08G18/80C08G65/325G11B5/72G11B5/84
    • C08G18/773C08G18/5015C08G18/701C08G18/8054C08G65/325G11B5/72G11B5/8408
    • A fluorine-containing isocyanate derivative, wherein the isocyano group of the fluorine-containing isocyanate is protected, a fluorine-containing polymer having at least one acylazido group, a process for producing an information recording medium by applying a lubricant comprising the fluorine-containing isocyanate derivative or the fluorine-containing polymer having at least one acylazido group to a magnetic layer formed on a substrate directly or through an underlayer, or to a protective layer formed on the magnetic layer, then reproducing or forming an isocyano group and subjecting the isocyano group to polymerization, thereby forming a fluorine-containing isocyanate polymer layer, an information recording medium produced according to the process and an apparatus for information recording, using the information recording medium are disclosed.The lubricant is resistant to water and no polymerization proceeds before the formation of a lubricant layer, and a lubricant layer without defects is obtained with the lubricant and an information recording medium with good sliding characteristics is obtained.
    • 含氟异氰酸酯的异氰酸酯被保护的含氟异氰酸酯衍生物,具有至少一个酰基叠氮基的含氟聚合物,通过涂布包含含氟异氰酸酯的润滑剂制造信息记录介质的方法 衍生物或具有至少一个酰基叠氮基的含氟聚合物直接或通过底层形成在基底上的磁性层或形成在磁性层上的保护层,然后再生或形成异氰基并使异氰基 进行聚合,从而形成含氟异氰酸酯聚合物层,使用该信息记录介质的根据该方法生产的信息记录介质和用于信息记录的装置。 润滑剂在形成润滑剂层之前是耐水性的并且不进行聚合,并且获得具有良好滑动特性的润滑剂和信息记录介质的无缺陷的润滑剂层。