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    • 10. 发明申请
    • MULTI-STEP PROCESS FOR FORMING A BARRIER FILM FOR USE IN COPPER LAYER FORMATION
    • 形成用于铜层形成的障壁膜的多步法
    • US20070178692A1
    • 2007-08-02
    • US11733673
    • 2007-04-10
    • Wilbur CatabayZhihai WangPing Li
    • Wilbur CatabayZhihai WangPing Li
    • H01L21/4763
    • H01L21/76843H01L21/2855H01L21/76844H01L21/76846H01L21/76855H01L21/76858H01L21/76859H01L21/76864H01L21/76871H01L21/76873H01L21/76874H01L23/53238H01L2924/0002H01L2924/00
    • Embodiments of the invention include a method for forming a copper interconnect having a bi-layer copper barrier layer. The method comprises the steps of providing a substrate in a processing chamber, the substrate having a low-K dielectric insulating layer and an opening in the insulating layer. A first barrier layer of tantalum/tantalum nitride is formed on the insulating layer and in the opening. A second barrier layer is formed on the first barrier layer. The second barrier layer consisting of a material selected from the group of palladium, chromium, tantalum, magnesium, and molybdenum. A copper seed layer is formed on the second barrier layer and a bulk copper layer is formed on the seed layer. The substrate is annealed and subject to further processing which can include planarization. Other embodiments include providing a substrate in a processing chamber and forming a copper seed layer on the substrate. The seed layer is implanted with barrier materials to form an implanted seed layer followed by bulk copper-containing layer formation. The substrate is annealed to form a final barrier layer. In a related embodiment the step of forming a seed layer is replaced with the steps of forming a first barrier layer on the substrate and forming a copper seed layer on the first barrier layer. After implantation of barrier material into the seed layer and bulk deposition of copper-containing material, the substrate is annealed to form a final barrier layer. In yet another related embodiment the step of forming a seed layer is replaced with the steps of forming a first barrier layer on the substrate and forming a second barrier layer on the first layer. A copper seed layer is formed on the second barrier layer. After implantation of barrier material into the seed layer and bulk deposition of copper-containing material, the substrate is annealed to form a final barrier layer.
    • 本发明的实施例包括一种形成具有双层铜阻挡层的铜互连的方法。 该方法包括以下步骤:在处理室中提供衬底,所述衬底具有低K电介质绝缘层和绝缘层中的开口。 在绝缘层和开口中形成钽/氮化钽的第一阻挡层。 在第一阻挡层上形成第二阻挡层。 第二阻挡层由选自钯,铬,钽,镁和钼的材料组成。 在第二阻挡层上形成铜籽晶层,在籽晶层上形成体铜层。 将衬底退火并进行可包括平坦化的进一步加工。 其他实施例包括在处理室中提供衬底并在衬底上形成铜籽晶层。 种子层被植入阻挡材料以形成植入的种子层,然后形成大块含铜层。 将衬底退火以形成最终的阻挡层。 在相关实施例中,形成种子层的步骤被替换为在衬底上形成第一阻挡层并在第一阻挡层上形成铜籽晶层的步骤。 在将阻挡材料植入种子层和含铜材料的大量沉积之后,将衬底退火以形成最终的阻挡层。 在另一相关实施例中,形成种子层的步骤被替换为在衬底上形成第一阻挡层并在第一层上形成第二阻挡层的步骤。 在第二阻挡层上形成铜籽晶层。 在将阻挡材料植入种子层和含铜材料的大量沉积之后,将衬底退火以形成最终的阻挡层。