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1. 发明授权

US4704428A Silyl substituted cyclopentadiene, process for its production and synthetic resin and rubber mixtures containing it 失效
标题翻译：甲硅烷基取代的环戊二烯，其生产方法和含有它的合成树脂和橡胶混合物
公开(公告)号：US4704428A
公开(公告)日：1987-11-03
申请号：US933136
申请日：1986-11-21
申请人： Ulrich Deschler , Peter Panster , Peter Kleinschmit , Siegfried Wolff , Ewe-Hong Tan
发明人： Ulrich Deschler , Peter Panster , Peter Kleinschmit , Siegfried Wolff , Ewe-Hong Tan
IPC分类号： C08L21/00 , C07F7/18 , C08K5/00 , C08K5/5419 , C08K5/5425 , C08K9/06 , C08L1/00 , C08L7/00 , C08L23/00 , C08L27/00 , C08L33/00 , C08L33/02 , C08L101/00 , C08K3/36
CPC分类号： C07F7/1836 , C08K5/5419 , C08K9/06
摘要： The invention is directed to silylalkyl and silylaralkyl substituted cyclopentadienes which have a hydrolyzable group attached to the silicone atom, a process for their production and peroxide cross-linkable synthetic resin and rubber mixtures containing them.
摘要翻译：本发明涉及具有连接到硅氧烷原子的可水解基团的甲硅烷基烷基和甲硅烷基烷基取代的环戊二烯，其生产方法和可过氧化物可交联的合成树脂和含有它们的橡胶混合物。

2. 发明授权

US5049690A N,N'-disubstituted and N,N,N'-/N,N', N'-trisubstituted thioureas and method of their preparation (II) 失效
标题翻译： N，N'-二取代和N，N，N' - / N，N'，N'-三取代硫脲及其制备方法（II）
公开(公告)号：US5049690A
公开(公告)日：1991-09-17
申请号：US556544
申请日：1990-07-24
申请人： Ulrich Deschler , Peter Panster , Peter Kleinschmit
发明人： Ulrich Deschler , Peter Panster , Peter Kleinschmit
IPC分类号： C07F7/10 , C07F7/18
CPC分类号： C07F7/1836 , C07F7/182
摘要： N,N'-disubstituted or N,N,N'- or N,N',N'-trisubstituted thioureas with additional organyloxysilyl function and tertiary amine function of the general formula ##STR1## These compounds are prepared as follows: a) Aminoorganylsilanes of the general formula ##STR2## are reacted in an organic, inert solvent with carbon disulfide, b) The dithiocarbamates formed thereby having the general formula: ##STR3## are isolated and combined with at least the equimolar amount of an amino compound of the general formulaH.sub.2 N--(CH.sub.2).sub.n --NR.sup.3.sub.2, this mixture is heated until the reaction is completed and the desired product is subsequently isolated.
摘要翻译： N，N'-二取代的N，N，N'-或N，N'，N'-三取代的硫脲，具有另外的有机氧基甲硅烷基官能团和叔胺官能团，通式如下：a）氨基有机基硅烷通式[IMAGE]在有机惰性溶剂中与二硫化碳反应，b）由此形成的具有以下通式的二硫代氨基甲酸酯：分离并与至少等摩尔量的一般的氨基化合物（CH2）n-NR32，将该混合物加热至反应完成，随后分离所需产物。

3. 发明授权

US4645850A Silyl substituted cyclopentadiene, process for its production and synthetic resin and rubber mixtures containing it 失效
标题翻译：甲硅烷基取代的环戊二烯，其生产方法和含有它的合成树脂和橡胶混合物
公开(公告)号：US4645850A
公开(公告)日：1987-02-24
申请号：US756088
申请日：1985-07-17
申请人： Ulrich Deschler , Peter Panster , Peter Kleinschmit , Siegfried Wolff , Ewe-Hong Tan
发明人： Ulrich Deschler , Peter Panster , Peter Kleinschmit , Siegfried Wolff , Ewe-Hong Tan
IPC分类号： C08L21/00 , C07F7/18 , C08K5/00 , C08K5/5419 , C08K5/5425 , C08K9/06 , C08L1/00 , C08L7/00 , C08L23/00 , C08L27/00 , C08L33/00 , C08L33/02 , C08L101/00 , C07F7/08
CPC分类号： C07F7/1836 , C08K5/5419 , C08K9/06
摘要： The invention is directed to silyl alkyl and silylaralkyl substituted cyclopentadienes which have a hydrolyzable group attached to the silicon atom, a process for their production and peroxide cross-linkable synthetic resin and rubber mixtures containing them.
摘要翻译：本发明涉及具有与硅原子连接的可水解基团的甲硅烷基烷基和甲硅烷基烷基取代的环戊二烯，其生产方法和可过氧化物可交联的合成树脂和含有它们的橡胶混合物。

4. 发明授权

US4507490A Process for the production of sulfur containing organosilicon compounds 失效
标题翻译：含硫有机硅化合物生产工艺
公开(公告)号：US4507490A
公开(公告)日：1985-03-26
申请号：US593308
申请日：1984-03-26
申请人： Peter Panster , Rudolf Michel , Peter Kleinschmit , Ulrich Deschler
发明人： Peter Panster , Rudolf Michel , Peter Kleinschmit , Ulrich Deschler
IPC分类号： C07F7/08 , C07F7/18
CPC分类号： C07F7/182 , C07F7/1892
摘要： The invention is directed to a process for the production of sulfur containing organosilicon compounds by reaction of an oligosulfide obtained in the reaction solution from a hydrogen sulfide an alkali metal and sulfur with a haloalkylsilane.
摘要翻译：本发明涉及一种生产含硫有机硅化合物的方法，该方法是将反应溶液中得到的硫化氢与碱金属和硫与卤代烷基硅烷的反应制得。

5. 发明授权

US5061773A Aminoalkyl-substituted organopolysiloxane thiourea derivatives and methods of preparation and use thereof 失效
标题翻译：氨基烷基取代的有机聚硅氧烷硫脲衍生物及其制备和使用方法
公开(公告)号：US5061773A
公开(公告)日：1991-10-29
申请号：US558867
申请日：1990-07-30
申请人： Peter Panster , Ulrich Deschler , Peter Kleinschmit
发明人： Peter Panster , Ulrich Deschler , Peter Kleinschmit
IPC分类号： C02F1/62 , B01J20/26 , C02F1/28 , C08G77/28 , C08G77/48 , C08G77/54 , C08G77/58
CPC分类号： C02F1/285 , B01J20/26 , C08G77/28 , C08G77/54 , C08G77/58
摘要： Aminoalkyl-substituted organopolysiloxane thioureas are disclosed which consist of the units ##STR1## whereby R.sup.1 stands for a group ##STR2## R.sup.5 is an alkylene grouping, R.sup.2 is equal to R.sup.1 or H, R.sup.3 is equal to R.sup.1 or H or a group (CH.sub.2).sub.n --N(R.sup.6).sub.2 (III) (in which n=1-6, R.sup.6 =H or an alkyl group with C.sub.1 -C.sub.5) and R.sup.4 =H or a group of the formula (III), whereby (I) contains at most 2 (III) groups and at most 2 (III) groups and the free valances of the oxygen atoms sitting on the silicon atom are saturated by silicon atoms of other (III) groups, optionally with the insertion of cross-linking agents containing Si, Ti or Zr. The compounds can be random copolycondensates, block copolycondensates or mixed copolycondensates in relation to the optionally present cross-linking agents. In addition, various methods of preparing the compounds are indicated. The compounds can be used especially for the removal of dissolved metals from aqueous or organic phases.
摘要翻译：（I）单元组成的氨基烷基取代的有机聚硅氧烷硫脲，其中R1代表一个基团（II）R5是亚烷基，R2等于R1或H，R3等于R1或 H或基团（CH 2）n N（R 6）2（III）（其中n = 1-6，R 6 = H或具有C 1 -C 5的烷基）和R 4 = H或式（III）的基团，其中（I）含有至多2个（III）基团和至多2个（III）基团，并且位于硅原子上的氧原子的游离价数被其它（III）基团的硅原子饱和，任选地插入含有Si，Ti或Zr的交联剂。所述化合物可以是无规共聚缩合物，相对于任选存在的交联剂阻断共聚缩聚物或混合的共缩聚物。另外，表示了制备化合物的各种方法。该化合物特别用于从水相或有机相中除去溶解的金属。

6. 发明授权

US5010203A Method of preparing organyloxysilyl 失效
标题翻译：制备有机硅氧烷基官能的环硫脲的方法
公开(公告)号：US5010203A
公开(公告)日：1991-04-23
申请号：US357723
申请日：1989-05-26
申请人： Ulrich Deschler , Peter Kleinschmit
发明人： Ulrich Deschler , Peter Kleinschmit
IPC分类号： C07F7/18
CPC分类号： C07F7/1892 , C07F7/1836
摘要： Novel cyclic N,N,N' and N,N,N',N'-substituted organyloxysilyl-functional silanes are prepared by reacting an aminopropyl silane with carbon disulfide and heating the dithiocarbamate.
摘要翻译：通过使氨基丙基硅烷与二硫化碳反应并加热二硫代氨基甲酸酯制备新的环状N，N，N'和N，N，N'，N'-取代的有机氧代甲硅烷基官能的硅烷。

7. 发明授权

US4623740A N,N'- and N,N',N'-substituted silylureas and process for their production 失效
标题翻译： N，N'-和N，N'，N'-取代的甲硅烷基脲及其制备方法
公开(公告)号：US4623740A
公开(公告)日：1986-11-18
申请号：US750272
申请日：1985-07-01
申请人： Ulrich Deschler , Wolfgang Buder , Peter Kleinschmit , Rudolf Michel
发明人： Ulrich Deschler , Wolfgang Buder , Peter Kleinschmit , Rudolf Michel
IPC分类号： C07F7/18 , C07F7/10
CPC分类号： C07F7/182
摘要： The invention is directed to N,N' and N,N',N'-substituted silylureas and a process for their production in which in a single step process there are reacted a halogenoalkylsilane or a halogenbenzylsilane with a primary or secondary amine and an alkali cyanate in equimolar amounts.
摘要翻译：本发明涉及N，N'和N，N'，N'-取代的甲硅烷基脲及其制备方法，其中在单步骤中使卤代烷基硅烷或卤代苄基硅烷与伯胺或仲胺和碱反应氰酸酯等摩尔量。

8. 发明授权

US5019637A Organopolysiloxane urea derivatives and organopolysiloxane thiourea derivatives, methods of their preparation and use 失效
标题翻译：有机聚硅氧烷脲衍生物和有机聚硅氧烷硫脲衍生物，其制备方法及用途
公开(公告)号：US5019637A
公开(公告)日：1991-05-28
申请号：US431219
申请日：1989-11-03
申请人： Peter Panster , Ulrich Deschler
发明人： Peter Panster , Ulrich Deschler
IPC分类号： B01J20/26 , B01J20/22 , C08G77/42 , C08G77/44 , C08G77/48 , C08G77/54 , C08G77/58
CPC分类号： B01J20/22 , C08G77/54 , C08G77/58
摘要： The invention is relative to optionally cross-linked organopolysiloxane urea derivatives and thiourea derivatives consisting of: ##STR1## wherein X stands for 0 or S andR.sup.1 is a group of the formula: ##STR2## in which R.sup.5 is alkylene with 1 to 10 C atoms or cycloalkylene with 5 to 8 C atoms or a group of the formula: ##STR3## with n=1-6 (on the nitrogen)m=0-6 (on the silicon), wherein R.sup.2 has the same meaning as R.sup.1 or stands for H, R.sup.3 and R.sup.4 have the same meaning as R.sup.1 or stands for H or alkyl with 1 to 5 C atoms. At least two but at the most three groups according to formula (2) are bound to the units according to formula (1). The free valances of the oxygen atoms bound to the silicon atom are saturated by silicon atoms of further groups of formula (2) with the optional inclusion of cross-linking agents. In addition, preparative methods for the products and a use for the removal of dissolved metals from liquid phases are indicated.
摘要翻译：本发明相对于任选的交联的有机聚硅氧烷脲衍生物和硫脲衍生物，其由以下组成：其中X代表0或S，R1是下式的基团：其中R5是具有1至10个C原子的亚烷基或具有5至8个碳原子的亚环烷基或具有n = 1-6（在氮上）m = 0-6（在硅上的下式的基团：），其中R2具有与R 1相同的含义或代表H，R 3和R 4具有与R 1相同的含义或代表H或具有1至5个C原子的烷基。根据式（2），至少两个但最多三个基团与根据式（1）的单元结合。与硅原子结合的氧原子的自由价数由另外的式（2）基团的硅原子饱和，任选地包含交联剂。此外，还指出了产品的制备方法和用于从液相中除去溶解的金属的用途。

9. 发明授权

US5073644A Method of preparing pure 3-butenyl triorganooxysilanes, the intermediate products 3,4-dichlorobutyl triorgano-oxysilanes and use of the final products 失效
标题翻译：中间产品3,4-二氯丁基三异氰酸酯和最终产物的使用制备三丁基三异氰酸酯的方法
公开(公告)号：US5073644A
公开(公告)日：1991-12-17
申请号：US375923
申请日：1989-07-06
申请人： Ulrich Deschler , Peter Kleinschmit , Siegfried Wolff , Ewe-Hong Tan
发明人： Ulrich Deschler , Peter Kleinschmit , Siegfried Wolff , Ewe-Hong Tan
IPC分类号： C07F7/18 , C08K5/00 , C08K5/5425
CPC分类号： C07F7/1892 , C07F7/1836 , C07F7/188 , C08K5/5425
摘要： A method of preparing pure 3-butenyl triorgano oxysilanes, the intermediate products 3,4-dichlorobutyl triorgano oxysilanes and the use of the final products in rubber mixtures reinforced with silicic acid and vulcanizable with peroxides. 3,4-dichlorobutene-1 and trichlorosilane are used as initial products.
摘要翻译：制备纯3-丁烯基三有机基氧基硅烷的方法，中间体产物3,4-二氯丁基三有机氧基硅烷，并使用最终产物在用硅酸增强并用过氧化物硫化的橡胶混合物中。 3,4-二氯丁烯-1和三氯硅烷用作初始产品。

10. 发明授权

US4837322A Mixtures of sulfurous triazine compounds 失效
标题翻译：亚硫酸三嗪化合物的混合物
公开(公告)号：US4837322A
公开(公告)日：1989-06-06
申请号：US89895
申请日：1987-08-27
申请人： Ulrich Deschler , Georg Hellwig , Rudolf Michel , Peter Kleinschmit , Siegfried Wolff
发明人： Ulrich Deschler , Georg Hellwig , Rudolf Michel , Peter Kleinschmit , Siegfried Wolff
IPC分类号： C07D251/52 , C08K5/34 , C08K5/378 , C08L21/00
CPC分类号： C07D251/52 , C08K5/378
摘要： Mixtures of sulfurous triazine compounds and methods of preparing these compounds with the general formula ##STR1## in which R.sup.1, R.sup.2 =H,R.sup.2 =benzyl,R.sup.2, R.sup.3, R.sup.4 =C.sub.1 -C.sub.8 -alkyl, allyl, C.sub.3 -C.sub.8 cycloalkyl, the latter unsubstituted or substituted with 1-3 methyl groups, 2-hydroxyethyl, 3-hydroxypropyl, 2-hydroxypropyl orR.sup.3 and R.sup.4 (together): C.sub.4 -C.sub.6 -alkylene, --(CH.sub.2 --CHX).sub.2 Y withX=H, CH.sub.3, Y=O,S,S.sub.a : Polysulfide chain with 2-10 S atoms (i.e. 2.ltoreq.a.ltoreq.10), in which the individual polysulfides are present in such concentrations that the statistical average value of "a" is a whole or fractional numerical value in the range from 2 to 5., characterized in that a triazine compound of the general formula ##STR2## in which R.sup.1, R.sup.2, R.sup.3, R.sup.4 have the meanings indicated above is reacted with an ammonium polysulfide or alkali polysulfide and dissolved in a protic polar solvent, especially water, at a temperature of 80.degree. to 140.degree. C.
摘要翻译：亚硫基三嗪化合物的混合物和制备这些具有通式Ⅰ的化合物的方法，其中R1，R2 = H，R2 =苄基，R2，R3，R4 = C1-C8-烷基，烯丙基，C3-C8环烷基，未取代或被1-3个甲基取代的后者，2-羟基乙基，3-羟丙基，2-羟基丙基或R 3和R 4（一起）：C 4 -C 6亚烷基， - （CH 2 -CHX）2 Y，X = CH 3，Y = O，S，Sa：具有2-10个S原子的多硫链（即2

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