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1. 发明授权

US5071443A Blue azo dyestuff mixture for strong blue color on hydrophobic fibers 失效
标题翻译：蓝色AZO DYESTUFF混合物用于强力蓝色染料在疏水纤维上
公开(公告)号：US5071443A
公开(公告)日：1991-12-10
申请号：US487858
申请日：1990-03-05
申请人： Ulrich Buhler , Hubert Kruse , Manfred Hahnke , Margareta Boos , Reinhard Kuhn
发明人： Ulrich Buhler , Hubert Kruse , Manfred Hahnke , Margareta Boos , Reinhard Kuhn
IPC分类号： C09B67/22 , D06P1/18
CPC分类号： C09B67/0051 , Y10S8/921 , Y10S8/922 , Y10S8/924
摘要： The dyestuff mixture contains at least one dyestuff of the formula I ##STR1## and at least one dyestuff of the formula II ##STR2## wherein X and Y denote chlorine or bromine,R.sup.1 and R.sup.5 denote methyl or ethyl,R.sup.2 and R.sup.6 denote methyl, ethyl, n-propyl or i-propyl andR.sup.3, R.sup.4, R.sup.7 and R.sup.8 denote, for example, C.sub.1 - to C.sub.11 -alkyl, in the weight ratio of I:II=(5 to 95):(95 to 5), and is, for example, outstandingly suitable for dyeing synthetic fibres.
摘要翻译：染料混合物含有至少一种式I（I）的染料和至少一种式II的染料（II），其中X和Y表示氯或溴，R 1和R 5表示甲基或乙基， R2和R6表示甲基，乙基，正丙基或异丙基，R 3，R 4，R 7和R 8表示例如C 1至C 11烷基，其重量比为I：II =（5至95）：（95〜5），例如非常适合染色合成纤维。

2. 发明授权

US4851012A Mixtures of blue disperse monoazo dyestuffs 失效
标题翻译：蓝色分散单偶氮染料的混合物
公开(公告)号：US4851012A
公开(公告)日：1989-07-25
申请号：US151010
申请日：1988-02-01
申请人： Ulrich Buhler , Hubert Kruse , Reinhard Kuhn , Margareta Boos
发明人： Ulrich Buhler , Hubert Kruse , Reinhard Kuhn , Margareta Boos
IPC分类号： C09B67/22
CPC分类号： C09B67/0051 , Y10S8/921 , Y10S8/922 , Y10S8/924
摘要： A mixture of monoazo dyestuffs which contains one or more dyestuffs of the formula I ##STR1## and one or more dyestuffs of the formula II ##STR2## wherein R.sup.1 and R.sup.2 independently of one another each denote linear or branched alkyl with 1 to 6 carbon atoms, R denotes linear or branched alkyl with 1 to 5 carbon atoms and Hal denotes chloro or bromo, are outstandingly suitable for dyeing and printing hydrophobic materials.
摘要翻译：含有一种或多种式I（I）的染料和一种或多种式II（II）的染料的单偶氮染料混合物，其中R1和R2彼此独立地表示直链或支链烷基具有1至6个碳原子，R表示具有1至5个碳原子的直链或支链烷基，Hal表示氯或溴，非常适用于染色和印刷疏水性材料。

3. 再颁专利

USRE33908E Mixtures of blue mono-azo disperse dyestuffs and their use for dyeing polyester 失效
公开(公告)号：USRE33908E
公开(公告)日：1992-05-05
申请号：US658720
申请日：1991-02-19
申请人： Horst Tappe , Hubert Kruse , Reinhard Kuhn , Albert Bode , Margareta Boos
发明人： Horst Tappe , Hubert Kruse , Reinhard Kuhn , Albert Bode , Margareta Boos
IPC分类号： C09B29/01 , C09B29/085 , C09B67/22 , D06P1/18
CPC分类号： C09B67/0051 , C09B29/0003 , Y10S8/921 , Y10S8/922 , Y10S8/924
摘要： Synthetic fiber materials are effectively colored by dyeing or printing with a dyestuff mixture containing at least two separate dyestuffs (I) and (II) in a weight ratio of (I):(II) of from (20 to 99):(80 to 1) wherein:(I) is at least one dyestuff of the formula ##STR1## and (II) is at least one dyestuff of the formula ##STR2## in which X and Y are the same or different and each is independently chloro and bromo:R.sup.1 and R.sup.2 are the same or different and each independently denotes hydrogen, alkoxy having 1 to 4 carbon atoms, alkenyl having 3 or 4 carbon atoms, cyclohexyl, benzyl, chlorobenzyl, bromobenzyl, nitrobenzyl, cyanobenzyl, alkylbenzyl having 1 to 4 carbon atoms in the alkyl moiety, alkoxybenzyl having 1 to 4 alkoxy carbon atoms, alkyl having 1 to 11 carbon atoms, alkyl having 1 to 11 carbon atoms interrupted by 1 to 3 oxygen atoms or substituted alkyl having 1 to 11 carbon atoms wherein the substituent is one selected from the group consisting of chloro, bromo, cyano, phenyl, phenoxy, hydroxy, (C.sub.1 -to-C.sub.4 -alkyl)-carbonyloxy, (C.sub.1 -to-C.sub.4 -alkoxy)-carbonyl, phenylcarbonyloxy, (C.sub.3 -to-C.sub.5 -alkenyloxy)-carbonyloxy, (C.sub.1 -to-C.sub.4 -alkoxy)-carbonyloxy, phenoxycarbonyloxy, tetrahydrofurfuryl, (C.sub.1 -to-C.sub.4 -alkyl)-tetrahydrofurfuryl, tetrahydropyronyl and (C.sub.1 -to-C.sub.4 -alkyl)-tetrahydropyronyl;R.sup.3 and R.sup.4 are the same or different and each is independently methyl, ethyl, n-propyl or i-propyl;R.sup.5 and R.sup.6 are the same or different and each is independently one of the definitions of R.sup.1 and R.sup.2 excepting hydrogen.

4. 发明授权

US4678476A Mixtures of blue mono-azo disperse dyestuffs and their use for dyeing polyester 失效
标题翻译：蓝色单偶氮分散染料的混合物及其用于染色聚酯的用途
公开(公告)号：US4678476A
公开(公告)日：1987-07-07
申请号：US911746
申请日：1986-09-26
申请人： Horst Tappe , Hubert Kruse , Reinhard Kuhn , Albert Bode , Margareta Boos
发明人： Horst Tappe , Hubert Kruse , Reinhard Kuhn , Albert Bode , Margareta Boos
IPC分类号： C09B29/01 , C09B29/085 , C09B67/22 , D06P1/18 , C09B29/00 , D06P1/04
CPC分类号： C09B67/0051 , C09B29/0003 , Y10S8/921 , Y10S8/922 , Y10S8/924
摘要： Synthetic fiber materials are effectively colored by dyeing or printing with a dyestuff mixture containing at least two separate dyestuffs (I) and (II) in a weight ratio of (I):(II) of from (20 to 99):(80 to 1) wherein:(I) is at least one dyestuff of the formula ##STR1## and (II) is at least one dyestuff of the formula ##STR2## in which X and Y are the same or different and each is independently chloro and bromo:R.sup.1 and R.sup.2 are the same or different and each independently denotes hydrogen, alkoxy having 1 to 4 carbon atoms, alkenyl having 3 or 4 carbon atoms, cyclohexyl, benzyl, chlorobenzyl, bromobenzyl, nitrobenzyl, cyanobenzyl, alkylbenzyl having 1 to 4 carbon atoms in the alkyl moiety, alkoxybenzyl having 1 to 4 alkoxy carbon atoms, alkyl having 1 to 11 carbon atoms, alkyl having 1 to 11 carbon atoms interrupted by 1 to 3 oxygen atoms or substituted alkyl having 1 to 11 carbon atoms wherein the substituent is one selected from the group consisting of chloro, bromo, cyano, phenyl, phenoxy, hydroxy, (C.sub.1 -to-C.sub.4 -alkyl)-carbonyloxy, (C.sub.1 -to-C.sub.4 -alkoxy)-carbonyl, phenylcarbonyloxy, (C.sub.3 -to-C.sub.5 -alkenyloxy)-carbonyloxy, (C.sub.1 -to-C.sub.4 -alkoxy)-carbonyloxy, phenoxycarbonyloxy, tetrahydrofurfuryl, (C.sub.1 -to-C.sub.4 -alkyl)-tetrahydrofurfuryl, tetrahydrophyronyl and (C.sub.1 -to-C.sub.4 -alkyl)-tetrahydropyronyl;R.sup.3 and R.sup.4 are the same or different and each is independently methyl, ethyl, n-propyl or i-propyl;R.sup.5 and R.sup.6 are the same or different and each is independently one of the definitions of R.sup.1 and R.sup.2 excepting hydrogen.
摘要翻译：合成纤维材料通过用含有至少两种分开的染料（I）和（II）的染料混合物以（20〜99）:( 80〜（80〜 1）其中：（I）是至少一种式IMA的染料，（II）是至少一种式“IMAGE”的染料，其中X和Y相同或不同，并且各自独立地是氯和溴：R1和R2相同或不同，各自独立地表示氢，具有1-4个碳原子的烷氧基，具有3或4个碳原子的链烯基，环己基，苄基，氯苄基，溴苄基，硝基苄基，氰基苄基，具有1-4个碳原子的烷基苄基在烷基部分中，具有1-4个烷氧基碳原子的烷氧基苄基，具有1至11个碳原子的烷基，具有1至3个碳原子的1至11个碳原子的烷基或被取代的具有1至11个碳原子的烷基，其中取代基是1 选自氯，溴，氰基，苯基，杂环基羟基，（C 1 -C 4 - 烷基） - 羰基氧基，（C 1 -C 4 - 烷氧基） - 羰基，苯基羰氧基，（C 3 -C 5 - 烯氧基） - 羰基氧基，（C 1 -C 4 - ） - 羰基氧基，苯氧基羰基氧基，四氢糠基，（C 1 -C 4 - 烷基） - 四氢糠基，四氢化芴基和（C 1 -C 4烷基） - 四氢吡喃基; R 3和R 4相同或不同，各自独立地为甲基，乙基，正丙基或异丙基; R 5和R 6相同或不同，并且各自独立地是除氢之外的R 1和R 2的定义之一。

5. 发明授权

US5824117A Nitrobenzisothiazole azo dyestuff 失效
标题翻译：硝基苯并异噻唑偶氮染料
公开(公告)号：US5824117A
公开(公告)日：1998-10-20
申请号：US671574
申请日：1996-06-28
申请人： Ulrich Buhler , Jurgen Kuhlwein , Hubert Kruse
发明人： Ulrich Buhler , Jurgen Kuhlwein , Hubert Kruse
IPC分类号： C09B29/09 , C09B29/00 , C09B41/00 , C09B67/00 , C09B67/10 , C09B67/48 , D06P3/54
CPC分类号： C09B29/0081 , C09B41/001 , C09B67/0015 , C09B67/0029 , Y10S8/921 , Y10S8/922
摘要： The present invention relates to the dyestuff of the formula I ##STR1## modifications of this dyestuff which are stable during dyeing, processes for the preparation thereof and their use for dyeing and printing synthetic fiber materials.
摘要翻译：本发明涉及式I染料（I）染色中稳定的染料的修饰，其制备方法及其用于染色和印刷合成纤维材料的染料。

6. 发明授权

US5917121A Monoazo dyes which are stable under dyeing conditions, their preparation and their use 失效
标题翻译：在染色条件下稳定的单偶氮染料，其制备及其用途
公开(公告)号：US5917121A
公开(公告)日：1999-06-29
申请号：US913074
申请日：1997-09-05
申请人： Ulrich Buhler , Hubert Kruse , Heinz G. Zorn , Klaus-Wilfried Wanken
发明人： Ulrich Buhler , Hubert Kruse , Heinz G. Zorn , Klaus-Wilfried Wanken
IPC分类号： C09B41/00 , C09B67/00 , C09B67/10 , C09B67/38 , C09B67/48
CPC分类号： C09B67/0015 , C09B41/005 , C09B67/0029 , C09B67/008
摘要： The present invention relates to the .beta. and .gamma. modifications of the dye of the formula (I) ##STR1## as well as to a process for their preparation and their use for dyeing and printing textile materials of polyester and/or cellulose esters or blended fabrics of these materials and wool or cellulose.
摘要翻译： PCT No.PCT / EP96 / 00970 Sec。 371日期：1997年9月5日 102（e）1997年9月5日PCT PCT 1996年3月7日PCT公布。公开号WO96 / 29368 日期1996年9月26日本发明涉及式（I）染料的β和γ修饰以及其制备方法及其用于染色和印花聚酯和/或纤维素酯的纺织材料或这些材料的混合织物和羊毛或纤维素。

7. 发明授权

US5037962A .beta.-modification of 1-(2,4-dinitro-6-chloro-phenylazo)-2-propionylamino-4-N-ethylamino-5-(2- methoxy-ethoxy)benzene, its preparation and its use 失效
标题翻译： 1-（2,4-二硝基-6-氯 - 苯基偶氮）-2-丙酰基氨基-4-N-乙基氨基-5-（2-甲氧基 - 乙氧基）苯的β-改性，其制备及其用途
公开(公告)号：US5037962A
公开(公告)日：1991-08-06
申请号：US396329
申请日：1989-08-21
申请人： Hubert Kruse , Ulrich Buhler , Konrad Opitz , Willi Steckelberg
发明人： Hubert Kruse , Ulrich Buhler , Konrad Opitz , Willi Steckelberg
IPC分类号： C09B67/48 , C09B67/00 , C09B67/10 , D06P3/85
CPC分类号： C09B67/0015 , C09B67/0029
摘要： The .beta.-modification, which is stable under dyeing conditions, of the dyestuff of the formula ##STR1## is prepared by heating the .alpha.-modification, which is unstable under dyeing conditions, at temperatures of 60.degree. to 180.degree. C. and the .beta.-modification is useful in printing and dyeing fiber materials of cellulose esters, synthetic linear polyesters or mixed fabrics of the polyester fiber material with wool or viscose staple.
摘要翻译：通过在60℃至180℃的温度下加热在染色条件下不稳定的α-修饰，制备式“IMAGE”染料的染色条件下稳定的β-改性，改性可用于纤维素酯，合成线性聚酯或聚酯纤维材料与羊毛或粘胶短纤维的混合织物的纤维材料的印染。

8. 发明授权

US5902356A Textile dye preparations 失效
标题翻译：纺织染料制剂
公开(公告)号：US5902356A
公开(公告)日：1999-05-11
申请号：US887618
申请日：1997-07-03
申请人： Ulrich Buhler , Hubert Kruse , Rainer Az
发明人： Ulrich Buhler , Hubert Kruse , Rainer Az
IPC分类号： C09B67/38 , C09B67/40 , C09B67/46 , D06P1/16 , D06P1/613 , D06P1/62 , D06P1/651 , D06P1/653 , D06P1/46 , D06P3/85 , D06P3/854
CPC分类号： D06P1/65131 , C09B67/008 , C09B67/0086 , D06P1/613 , D06P1/6131 , D06P1/6136 , D06P1/621 , D06P1/65112 , D06P1/65125 , D06P1/653 , Y10S8/921 , Y10S8/922 , Y10S8/924
摘要： The present invention relates to liquid or pulverulent textile dye preparations including one or more dispersants based on an alkoxylated and carboxylic-esterified castor oil of the general formula I ##STR1## where A, X.sup.1, X.sup.2, Z.sup.1, Z.sup.2, Z.sup.3, n.sup.1 and n.sup.2 are each as defined in Claim 1.
摘要翻译：本发明涉及包含一种或多种基于通式I的烷氧基化和羧酸酯化蓖麻油的分散剂的液体或粉末纺织品染料，其中A，X1，X2，Z1，Z2，Z3，n1和n2各自为如权利要求1所述。

9. 发明授权

US5174791A Process for dyeing and printing blend fabrics of polyester and natural fibre materials with disperse dye and polyether-polyester to inhibit soilins with disperse dye 失效
标题翻译：用分散染料和聚醚多元素对聚酯和自然纤维材料进行染色和印染的方法，用分散的染料抑制土壤
公开(公告)号：US5174791A
公开(公告)日：1992-12-29
申请号：US741473
申请日：1991-08-05
申请人： Ulrich Buhler , Klaus Hofmann , Hubert Kruse , Jurgen Kuhlwein , Willi Steckelberg
发明人： Ulrich Buhler , Klaus Hofmann , Hubert Kruse , Jurgen Kuhlwein , Willi Steckelberg
IPC分类号： C09B67/46 , D06P1/52 , D06P1/613 , D06P1/62 , D06P1/651 , D06P3/82
CPC分类号： D06P3/8238 , C09B67/0085 , D06P1/5271 , D06P1/6136 , D06P1/623 , D06P1/65125
摘要： Process for dyeing and printing blended fabrics made from polyester and natural fibre materials, characterized in that the dye baths, padding liquors or printing pastes contain compounds of general formula (I). Dye preparations containing one or more compounds of general formula (I).
摘要翻译： PCT No.PCT / EP90 / 00112 Sec。 371日期：1991年8月5日 102（e）日期1991年8月5日PCT 1990年1月20日PCT PCT。出版物WO90 / 09478 日期1990年8月23日。由聚酯和天然纤维材料制成的染色和印花混纺织物的方法，其特征在于染浴，填充液或印刷浆含有通式（I）的化合物。含有一种或多种通式（I）化合物的染料制剂。

10. 发明授权

US5415669A Dye mixtures for the dyeing of textile hydrophobic fibre materials 失效
标题翻译：用于染色纺织疏水纤维材料的染料混合物
公开(公告)号：US5415669A
公开(公告)日：1995-05-16
申请号：US5269
申请日：1993-01-19
申请人： Ulrich Buhler , Hubert Kruse , Erwin Dietz
发明人： Ulrich Buhler , Hubert Kruse , Erwin Dietz
IPC分类号： C09B5/00 , C09B57/14 , C09B67/22 , D06P3/54 , D06P3/82 , C09B69/00
CPC分类号： D06P3/54 , C09B5/006 , C09B57/14 , C09B67/0034 , Y10S8/922
摘要： The present invention relates to mixtures of dyes of the general formula I ##STR1## in which R.sup.1 is hydrogen, halogen, (C.sub.1 -C.sub.4) -alkyl or (C.sub.1 -C.sub.4)-alkoxy;R.sup.2 is hydrogen, halogen, cyano, (C.sub.1 -C.sub.4)-alkyl, (C.sub.1 -C.sub.4)-alkoxy, (C.sub.1 -C.sub.4)-alkoxycarbonyl, (C.sub.1 -C.sub.4)-alkylcarbonyloxy or phenyl, which may be substituted or unsubstituted;R.sup.3 is hydrogen, (C.sub.1 -C.sub.4)-alkyl, (C.sub.1 -C.sub.4)-alkoxy or phenyl, which may be substituted or unsubstituted; andR.sup.4 is hydrogen, halogen, (C.sub.1 -C.sub.4)-alkoxy, phenylthio or phenoxy, which may be substituted or unsubstituted, to processes for their preparation and to the use of the dyes of the general formula I and their mixtures with one another for the dyeing and printing of textile hydrophobic synthetic fibre materials and blends thereof with natural fibre materials.
摘要翻译：本发明涉及通式Ⅰ的染料的混合物，其中R1是氢，卤素，（C1-C4） - 烷基或（C1-C4） - 烷氧基; R2是氢，卤素，氰基，（C1-C4） - 烷基，（C1-C4） - 烷氧基，（C1-C4） - 烷氧基羰基，（C1-C4） - 烷基羰氧基或苯基，其可以是取代或未取代的; R3是氢，（C1-C4） - 烷基，（C1-C4） - 烷氧基或苯基，其可以是取代或未取代的; 和R 4是氢，卤素，（C 1 -C 4） - 烷氧基，苯硫基或苯氧基，其可以被取代或未取代，用于其制备方法和使用通式I的染料及其彼此的混合物纺织疏水性合成纤维材料的染色和印花及其与天然纤维材料的共混物。

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