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1. 发明授权

US4751288A Azo dyes containing 2-amino-3-cyano-5-formylthiophene derivatives as diazo components and substituted aniline compounds as coupling components 失效
标题翻译：含有2-氨基-3-氰基-5-甲酰基噻吩衍生物作为重氮组分的偶氮染料和取代的苯胺化合物作为偶联组分
公开(公告)号：US4751288A
公开(公告)日：1988-06-14
申请号：US843397
申请日：1986-03-24
申请人： Udo Bergmann , Erwin Hahn , Guenter Hansen , Helmut Reichelt
发明人： Udo Bergmann , Erwin Hahn , Guenter Hansen , Helmut Reichelt
IPC分类号： C09B29/09 , C09B29/00 , C09B29/033 , C09B29/08 , D06P1/18 , D06P3/54
CPC分类号： C09B29/0809 , C09B29/0059 , C09B29/0808 , Y10S534/02
摘要： The compounds of the formula I ##STR1## where R is unsubstituted or substituted phenyl or naphthyl, R.sup.1 and R.sup.2 are each unsubstituted or substituted alkyl, alkenyl or cycloalkyl, and one of the radicals may furthermore be hydrogen, R.sup.3 is hydrogen, methyl, methoxy, ethoxy or chlorine, and R.sup.4 is acylamino, are particularly useful for dyeing polyesters.
摘要翻译：其中R是未取代或取代的苯基或萘基，R 1和R 2各自为未取代或取代的烷基，链烯基或环烷基，并且其中一个基团可以是氢，R 3是氢，甲基，甲氧基，乙氧基或氯，R4为酰氨基，特别适用于染色聚酯。

2. 发明授权

US4820809A Heterocyclic azo dyes 失效
标题翻译：杂环偶氮染料
公开(公告)号：US4820809A
公开(公告)日：1989-04-11
申请号：US144648
申请日：1988-01-11
申请人： Udo Bergmann , Erwin Hahn , Guenter Hansen
发明人： Udo Bergmann , Erwin Hahn , Guenter Hansen
IPC分类号： C09B29/00 , C09B29/36
CPC分类号： C09B29/0059 , C09B29/3691
摘要： Novel compounds of the general formula I ##STR1## where X is hydrogen, nitro or unsubstituted or substituted alkyl, alkenyl, cycloalkyl, aryl or hetaryl, Y is cyano, nitro, alkanoyl, aroyl, alkylsulfonyl, arylsulfonyl, carboxyl, a carboxylic ester group or unsubstituted or substituted carbamyl, R is unsubstituted or substituted alkyl or aryl, R.sup.1 is hydrogen or R.sup.2, and R.sup.2 is unsubstituted or substituted alkyl, alkenyl, cycloalkyl, aralkyl or aryl, are useful for dyeing textile fibers, in particular polyesters.
摘要翻译：新的通式I的化合物其中X是氢，硝基或未取代或取代的烷基，烯基，环烷基，芳基或杂芳基，Y是氰基，硝基，烷酰基，芳酰基，烷基磺酰基，芳基磺酰基，羧基，羧酸酯基团或未取代或取代的氨基甲酰基，R是未取代或取代的烷基或芳基，R 1是氢或R 2，R 2是未取代的或取代的烷基，烯基，环烷基，芳烷基或芳基，可用于染色纺织纤维，特别是聚酯。

3. 发明授权

US4668775A .alpha.-methine substituted thiophene monoazo dye 失效
标题翻译： α-甲基取代噻吩单偶氮染料
公开(公告)号：US4668775A
公开(公告)日：1987-05-26
申请号：US758423
申请日：1985-07-24
申请人： Udo Bergmann , Erwin Hahn , Guenter Hansen
发明人： Udo Bergmann , Erwin Hahn , Guenter Hansen
IPC分类号： C09B56/16 , C09B29/033 , C09B29/09 , C09B29/095 , C09B29/36
CPC分类号： C09B56/16 , Y10S534/02
摘要： A compound of the formula: ##STR1## wherein K is a radical of a coupling component, R is a radical of a methylene-active compound, X is hydrogen or unsubstituted or substituted alkyl, aryl, or hetaryl and Y is cyano, nitro, alkanoyl, aroyl, alkylsulfonyl, arylsulfonyl, carboxyl, a carboxylic ester group or unsubstituted or substituted carbamyl. The present compound is useful for the dyeing of polyesters, nylons, cellulose esters and blends of polyesters and cellulose fibers.
摘要翻译：下式的化合物：其中K是偶联组分的基团，R是亚甲基活性化合物的基团，X是氢或未取代或取代的烷基，芳基或杂芳基，Y是氰基，硝基，烷酰基，芳酰基，烷基磺酰基，芳基磺酰基，羧基，羧酸酯基或未取代或取代的氨基甲酰基。本发明化合物可用于聚酯，尼龙，纤维素酯和聚酯和纤维素纤维的共混物的染色。

4. 发明授权

US4405330A Navy disperse dye mixtures 失效
标题翻译：海军分散染料混合物
公开(公告)号：US4405330A
公开(公告)日：1983-09-20
申请号：US433393
申请日：1982-10-08
申请人： Udo Bergmann , Helmut Degen , Guenter Hansen , Reinhold Krallmann , Wolf-Dieter Kermer
发明人： Udo Bergmann , Helmut Degen , Guenter Hansen , Reinhold Krallmann , Wolf-Dieter Kermer
IPC分类号： C09B29/08 , C09B67/22 , D06P3/54 , D06P1/04
CPC分类号： C09B67/0051 , C09B29/081 , C09B29/0813 , Y10S534/01 , Y10S8/922
摘要： Navy mixtures which contain dyes of the formula I ##STR1## where X is chlorine or bromine,Y is hydrogen, methoxy or ethoxy andR is N(C.sub.2 H.sub.5).sub.2, N(CH.sub.2 CH.dbd.CH.sub.2).sub.2 or N(C.sub.2 H.sub.4 OCOCH.sub.3).sub.2,the mixtures being composed of 10-70% of dyes with Y.dbd.H and R=N(C.sub.2 H.sub.5).sub.2, 5-40% of dyes with Y=OCH.sub.3 or OC.sub.2 H.sub.5 and R.dbd.N(CH.sub.2 --CH.dbd.CH.sub.2).sub.2 and 5-80% of dyes with Y=OCH.sub.3 or OC.sub.2 H.sub.5 and R=N(C.sub.2 H.sub.4 OCOCH.sub.3).sub.2.The novel mixtures have excellent tinctorial properties and give very fast dyeings on synthetic polyesters.
摘要翻译：含有式I的染料的海军混合物，其中X是氯或溴，Y是氢，甲氧基或乙氧基，R是N（C2H5）2，N（CH2CH = CH2）2或N（C2H4OCOCH3）2，该混合物由10-70％的具有Y = H和R = N（C 2 H 5）2的染料组成，5-40％的具有Y = OCH 3或OC 2 H 5和R = N（CH 2 -CH 2 CH 2）2和5 -80％的具有Y = OCH 3或OC 2 H 5和R = N（C 2 H 4 OCOCH 3）的染料。新型混合物具有优异的着色性能，并在合成聚酯上产生非常快的染色。

5. 发明授权

US4764600A Isothiazolylazo dyes having aminophenyl and aminonaphthyl components 失效
标题翻译：具有氨基苯基氨基萘基组分的异噻唑基偶氮染料
公开(公告)号：US4764600A
公开(公告)日：1988-08-16
申请号：US460793
申请日：1983-01-25
申请人： Udo Bergmann , Johannes P. Dix , Guenter Hansen , Ernst Schefczik , Guenther Seybold
发明人： Udo Bergmann , Johannes P. Dix , Guenter Hansen , Ernst Schefczik , Guenther Seybold
IPC分类号： C09B29/039 , C09B29/00 , C09B29/06 , C09B29/08 , C09B29/095 , C09B29/042 , C09B29/09 , D06P1/18 , D06P3/54
CPC分类号： C09B29/0847 , C09B29/0081 , C09B29/06 , C09B29/0813 , C09B29/083 , C09B29/095 , Y10S534/02
摘要： An isothiazolylazo dye of the formula I ##STR1## wherein R is an alkyl group or unsubstituted aryl or substituted aryl group selected from the group consisting of ##STR2## and K is a radical of the formula ##STR3## where B is C.sub.1 -C.sub.4 alkyl or a substituted amino radical selected from the group consisting of ##STR4## R.sup.1 is hydrogen, methyl, methoxy or ethoxy, R.sup.2 and R.sup.3 independently of one another are each unsubstituted C.sub.1 -C.sub.4 alkyl or substituted alkyl groups selected from the group of C.sub.1 -C.sub.4 alkyls which are substituted by chlorine, bromine, cyano, hydroxyl, C.sub.1 -C.sub.4 -alkoxy, benzyloxy, phenoxy, phenyl, C.sub.1 -C.sub.4 -alkylcarbonyloxy which is unsubstituted or substituted by C.sub.1 -C.sub.4 -alkoxy, phenoxy or phenyl, phenycarbonyloxy which is unsubstituted or substituted by chlorine, bromine, methoxy, ethoxy, methyl or ethyl, oxycarbonyl, C.sub.1 -C.sub.4 -alkoxycarbonyl, C.sub.1 -C.sub.4 -alkoxycarbonyloxy, carbamyl, phenalkyloxycarbonyloxy, phenoxyalkyloxycarbonyloxy, C.sub.1 -C.sub.4 -alkoxyalkoxycarbonyloxy, phenylaminocarbonyloxy which is unsubstituted or substituted by chlorine, methoxy or methyl, C.sub.1 -C.sub.4 -alkoxyalkoxycarbonyl, phenylalkyloxycarbonyl or C.sub.1 -C.sub.4 -alkylaminocarbonyloxy which is unsubstituted or substituted by C.sub.1 -C.sub.4 -alkyl, C.sub.1 -C.sub.4 -alkoxy, chlorine or bromine; or R.sup.3 is hydrogen, R.sup.4 is a radical of the formula --A--OCO--Y--R, Z is hydrogen or methyl, X is hydrogen, methyl, methoxy, chlorine or an acylamino radical selected from the group consisting of A is C.sub.2 - or C.sub.3 -alkylene and Y is --O-- or --NH--. The dyes are very useful for dyeing cellulose esters and synthetic polyesters; the dyeings obtained are from yellow to blue, and very fast.
摘要翻译：式I的异噻唑基偶氮染料其中R为烷基或未取代的芳基或取代的芳基，所述芳基选自由下列组成的组：K IMAGE> TR＆lt; IMAGE＆gt;和K是式 > + TR 其中B是C1-C4烷基或选自由下列组成的组的取代的氨基：R 1是氢，甲基，甲氧基或乙氧基，R 2和R 3彼此独立地各自是未取代的 C 1 -C 4烷基或取代的烷基，其选自被氯，溴，氰基，羟基，C 1 -C 4 - 烷氧基，苄氧基，苯氧基，苯基，未被取代的C 1 -C 4 - 烷基羰基氧基取代的C 1 -C 4烷基被C 1 -C 4 - 烷氧基，苯氧基或苯基取代，未被取代或被氯，溴，甲氧基，乙氧基，甲基或乙基，氧羰基，C 1 -C 4 - 烷氧基羰基，C 1 -C 4烷氧基羰基氧基，氨基甲酰基，苯氧基羰基氧基，苯氧基羰基氧基，C 1 -C 4 - 烷氧基烷氧基羰基氧基未取代或被氯，甲氧基或甲基取代的苯氨基羰基氧基，未被取代或被C 1 -C 4 - 烷氧基，氯或溴取代的C 1 -C 4 - 烷氧基烷氧基羰基，苯基烷氧基羰基或C 1 -C 4烷基氨基羰氧基; 或R 3是氢，R 4是式-A-OCO-YR的基团，Z是氢或甲基，X是氢，甲基，甲氧基，氯或选自NHCHO，NHCOCH 3，NHCOC 2 H 5， NHCO芳基，NHCOCH2芳基，A是C2-或C3-亚烷基，Y是-O-或-NH-。染料对染色纤维素酯和合成聚酯是非常有用的; 得到的染色从黄色到蓝色，非常快。

6. 发明授权

US4619992A 3-(.beta.-aminoethyl)-4-cyano-isothiazolylazo dyes 失效
标题翻译： 3-（β-氨基乙基）-4-氰基 - 异噻唑偶氮染料
公开(公告)号：US4619992A
公开(公告)日：1986-10-28
申请号：US710993
申请日：1985-03-12
申请人： Udo Bergmann , Johannes P. Dix , Guenter Hansen , Ernst Schefczik
发明人： Udo Bergmann , Johannes P. Dix , Guenter Hansen , Ernst Schefczik
IPC分类号： C09B29/042 , C09B29/00 , C09B29/36 , C09B29/039 , D06P1/18 , D06P3/54
CPC分类号： C09B29/0081
摘要： A compound of the formula: ##STR1## where R is hydrogen, C.sub.1 -C.sub.4 -alkyl, phenyl, chlorophenyl, methylphenyl, methoxyphenyl or nitrophenyl; R.sup.1 is allyl, C.sub.1 -C.sub.8 -alkyl, C.sub.1 -C.sub.8 -alkyl substituted by C.sub.1 -C.sub.8 -alkoxy, phenoxy, phenyl or C.sub.1 -C.sub.8 -alkanoyloxy, cyclopentyl, cyclohexyl, methylcyclohexyl, norbornyl, phenyl or phenyl substituted by chlorine, methyl or alkoxy; R.sup.2 is C.sub.1 -C.sub.10 -alkanoyl, C.sub.1 -C.sub.10 -alkanoyl substituted by alkoxy or phenoxy, cyclohexanoyl, benzoyl, benzoyl substituted by chlorine, methyl or methoxy, C.sub.1 -C.sub.8 -alkoxycarbonyl, aminocarbonyl, phenylaminocarbonyl, CH.sub.3 NHCO, C.sub.2 H.sub.5 NHCO, C.sub.3 H.sub.7 NHCO, C.sub.4 H.sub.9 NHCO, (CH.sub.3).sub.2 NCO, CH.sub.3 SO.sub.2, C.sub.6 H.sub.5 SO.sub.2 or p--CH.sub.3 --C.sub.6 H.sub.4 --SO.sub.2 ; or R.sup.1 and R.sup.2, together with the nitrogen atom, form a ring system, and K is a radical of a coupling component. The isothiazolylylazo compound of the invention is useful for the dyeing of the polyesters, nylon, and cellulose esters.
摘要翻译：其中R是氢，C 1 -C 4 - 烷基，苯基，氯苯基，甲基苯基，甲氧基苯基或硝基苯基的下式的化合物： R1是烯丙基，C1-C8-烷基，被C1-C8-烷氧基，苯氧基，苯基或C1-C8-烷酰氧基取代的C1-C8-烷基，环戊基，环己基，甲基环己基，降冰片基，苯基或被氯，甲基或烷氧基 R2是C1-C10烷酰基，被烷氧基或苯氧基取代的C1-C10烷酰基，环己酰基，苯甲酰基，被氯，甲基或甲氧基取代的苯甲酰基，C1-C8-烷氧基羰基，氨基羰基，苯基氨基羰基，CH3NHCO，C2H5NHCO，C3H7NHCO，C4H9NHCO，（CH3）2NCO，CH3SO2，C6H5SO2或对-CH3-C6H4-SO2; 或R 1和R 2与氮原子一起形成环系，K是偶合组分的基团。本发明的异噻唑立噻唑化合物可用于聚酯，尼龙和纤维素酯的染色。

7. 发明授权

US4547566A Copper, cobalt, nickel and iron complexes of disazo dyes 失效
标题翻译：铜，钴，镍和铁配合物的双偶氮染料
公开(公告)号：US4547566A
公开(公告)日：1985-10-15
申请号：US478101
申请日：1983-03-23
申请人： Udo Bergmann , Guenter Hansen , Georg Zeidler
发明人： Udo Bergmann , Guenter Hansen , Georg Zeidler
IPC分类号： C09B31/00 , C09B33/02 , C09B33/24 , C09B45/24 , C09B45/26 , C09B45/30 , C09B45/32
CPC分类号： C09B45/24 , C09B33/02 , C09B33/24
摘要： Compounds which in the form of the free acid are of the general formula I ##STR1## where A is a radical of the formula ##STR2## the radicals Y independently of one another are each hydroxyl or amino, X is hydrogen, hydroxysulfonyl or a radical of the formulaD--N.dbd.N--,R is a radical of 1-aminonaphthalene-4-, -5-, -6-, -7- or -8-monosulfonic acid or of 1-aminonaphthalene-3,6-, -3,7-, -3,8-, -4,7-, or -4,8-disulfonic acid, or a Cu, Fe, Ni, Co, Mn or Cr complex thereof, and D is phenyl which is unsubstituted or substituted by methyl, methoxy, ethoxy, nitro, chlorine, bromine or sulfo, or is sulfo-substituted naphthyl. These compounds are preferably used for dyeing leather.
摘要翻译：游离酸形式的化合物具有通式I，其中A是下式的基团，其中Y独立地为羟基或氨基，X为氢，羟基磺酰基或式DN = N-的基团，R是1-氨基萘-4-，5-，6-，7-或8-单磺酸或1-氨基萘-3,6 - ，-3,7-，-3,8-，-4,7-或-4,8-二磺酸，或其Cu，Fe，Ni，Co，Mn或Cr络合物，D为苯基，被甲基，甲氧基，乙氧基，硝基，氯，溴或磺基取代或被磺基取代的萘基取代。这些化合物优选用于染色皮革。

8. 发明授权

US4537597A Navy blue mixtures of disperse mono-azo dyes for cellulose acetate 失效
标题翻译：用于醋酸纤维素的分散单偶氮染料的海蓝色混合物
公开(公告)号：US4537597A
公开(公告)日：1985-08-27
申请号：US611536
申请日：1984-05-17
申请人： Udo Bergmann , Helmut Degen , Guenter Hansen , Reinhold Krallmann , Hans Weber
发明人： Udo Bergmann , Helmut Degen , Guenter Hansen , Reinhold Krallmann , Hans Weber
IPC分类号： C09B29/08 , C09B67/22 , D06P1/04
CPC分类号： C09B67/0051 , C09B29/0807 , Y10S534/01 , Y10S8/921
摘要： Mixtures of dyes of the formula I ##STR1## where X is chlorine or bromine, Z is hydrogen, methyl, ethyl, C.sub.1 -C.sub.4 -alkoxy or acetylamino, R is C.sub.1 -C.sub.4 -alkyl, R.sup.1 and R.sup.2 independently of one another are each allyl or methallyl or are each C.sub.1 -C.sub.6 -alkyl which is unsubstituted or substituted by hydroxyl, C.sub.1 -C.sub.4 -alkoxy or alkanoyloxy, or R.sup.1 and R.sup.2 together with the nitrogen atom are morpholino or tetra-, penta- or hexamethyleneimino, and one of the radicals R.sup.1 and R.sup.2 may furthermore be hydrogen.
摘要翻译：式I的染料的混合物，其中X是氯或溴，Z是氢，甲基，乙基，C1-C4-烷氧基或乙酰氨基，R是C1-C4烷基，R1和R2彼此独立地是每个烯丙基或甲代烯丙基或各自为未取代或被羟基，C 1 -C 4 - 烷氧基或烷酰氧基取代的C 1 -C 6 - 烷基，或者R 1和R 2与氮原子一起为吗啉代或四 - ，五 - 或六亚甲基亚氨基，基团R 1和R 2还可以是氢。

9. 发明授权

US4491543A Dis-, tris-, and tetrakisazo compounds containing resorcinol, sulfonylamino, and two or three sulfonic acid groups 失效
标题翻译：含有间苯二酚，磺酰基氨基和两个或三个磺酸基的二 - ，三 - 和四偶氮化合物
公开(公告)号：US4491543A
公开(公告)日：1985-01-01
申请号：US380711
申请日：1982-05-21
申请人： Udo Bergmann , Guenter Hansen , Dietrich Lach , Michael Thomas , Georg Zeidler
发明人： Udo Bergmann , Guenter Hansen , Dietrich Lach , Michael Thomas , Georg Zeidler
IPC分类号： C09B33/02 , C09B33/00 , C09B33/04 , C09B45/04 , C09B45/24 , C09B45/32 , C09B33/044 , C09B33/22 , C09B33/30 , C09B33/32
CPC分类号： C09B45/24 , C09B33/00
摘要： The present invention discloses substituted phenyl di and trisazo dyes free of reactive groups having two or three sulfonic acid groups, of the general formula: ##STR1## wherein D.sup.1 is ##STR2## Z is hydrogen or D.sup.4 --N.dbd.N--; D.sup.2 is phenyl substituted by hydroxyl, hydroxysulfonyl, chlorine or nitro, or is naphthyl substituted by hydroxy, hydroxysulfonyl or nitro, X, independently of one another, are hydroxyl or amino, D.sup.3 is phenyl which is substituted by hydroxysulfonyl, chlorine, bromine, methyl, methoxy, ethoxy, nitro, phenylamino, sulfophenylamino or nitrosulfophenylamino, or is naphthyl which is substituted by hydroxysulfonyl; D.sup.4 is phenyl which is unsubstituted or substituted by methyl, ethyl, methoxy, ethoxy, chlorine, bromine, nitro, sulfamoyl or hydroxysulfonyl, or is naphthyl which is substituted by hydroxysulfonyl; and R.sup.2 is methyl, ethyl or allyl; the rings B and E may additionally be substituted by methyl, ethyl, methoxy, ethoxy, chlorine, bromine or hydroxysulfonyl, with the proviso that D.sup.2 has a hydroxyl group ortho to the azo bond; or the iron, manganese, cobalt, chromium, nickel or copper complexes of this dye. These compounds, particularly in the form of their metal complexes are suitable for dyeing nitrogen-containing fibers such as wool, and preferably, leather. The present dyes yield very fast brown hues, in particular on retanned leather.
摘要翻译：本发明公开了不具有两个或三个磺酸基团的反应性基团的取代苯基二和三偶氮染料，其通式如下：其中D1是氢或D4-N = N-; D2是由羟基，羟基磺酰基，氯或硝基取代的苯基，或被羟基，羟基磺酰基或硝基取代的萘基，X彼此独立地是羟基或氨基，D3是被羟基磺酰基，氯，溴，甲基，甲氧基，乙氧基，硝基，苯基氨基，磺基苯基氨基或亚硝基磺基苯基氨基，或被被羟基磺酰基取代的萘基; D4是未取代或被甲基，乙基，甲氧基，乙氧基，氯，溴，硝基，氨磺酰基或羟基磺酰基取代的苯基，或被羟基磺酰基取代的萘基; 和R2是甲基，乙基或烯丙基; 环B和E可以另外被甲基，乙基，甲氧基，乙氧基，氯，溴或羟基磺酰基取代，条件是D2具有与偶氮键邻位的羟基; 或该染料的铁，锰，钴，铬，镍或铜络合物。这些化合物，特别是其金属络合物的形式，适用于染色含氮纤维如羊毛，优选皮革。本染料产生非常快的棕色色调，特别是在鞣革上。

10. 发明授权

US4960874A Isothiazolylazo dyes having aminophenyl and aminonaphthyl components 失效
标题翻译：具有氨基苯基和氨基萘基组分的异噻唑基偶氮染料
公开(公告)号：US4960874A
公开(公告)日：1990-10-02
申请号：US214502
申请日：1988-07-01
申请人： Udo Bergmann , Johannes D. Dix , Guenter Hansen , Ernst Schefczik , Guenther Seybold
发明人： Udo Bergmann , Johannes D. Dix , Guenter Hansen , Ernst Schefczik , Guenther Seybold
IPC分类号： C09B29/039 , C09B29/00 , C09B29/06 , C09B29/08 , C09B29/095
CPC分类号： C09B29/0847 , C09B29/0081 , C09B29/06 , C09B29/0813 , C09B29/083 , C09B29/095 , Y10S534/02
摘要： Compounds of the general formula I ##STR1## where R is alkyl or unsubstituted or substituted aryl and K is a radical of the formula ##STR2## B is C.sub.1 -C.sub.4 -alkyl or substituted amino, R.sup.1 is hydrogen, methyl, methoxy or ethoxy, R.sup.2 and R.sup.3 independently of one another are each unsubstituted or substituted alkyl, R.sup.3 may furthermore be hydrogen, R.sup.4 is a radical of the formula --A--OCO--Y--R, Z is hydrogen or methyl, X is hydrogen, methyl, methoxy, chlorine or acylamino, A is C.sub.2 - or C.sub.3 -alkylene and Y is --O-- or --NH--, are very useful for dyeing cellulose esters and synthetic polyesters.

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