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1. 发明授权

US06927966B2 Conductive paste and laminated ceramic electronic component 有权
标题翻译：导电胶和层压陶瓷电子元件
公开(公告)号：US06927966B2
公开(公告)日：2005-08-09
申请号：US10351448
申请日：2003-01-27
申请人： Takaharu Miyazaki , Tsuyoshi Yamana
发明人： Takaharu Miyazaki , Tsuyoshi Yamana
IPC分类号： H01G4/12 , C04B35/49 , H01B1/22 , H01G4/008 , H01G4/232 , H01G4/30 , H05K1/09 , H01G4/06
CPC分类号： C04B35/49 , B32B18/00 , B32B38/145 , B32B2311/22 , C04B35/468 , C04B35/6281 , C04B35/62821 , C04B35/62823 , C04B2235/3206 , C04B2235/3208 , C04B2235/405 , C04B2235/79 , C04B2237/12 , C04B2237/346 , C04B2237/348 , C04B2237/405 , C04B2237/50 , C04B2237/704 , C04B2237/706 , H01G4/0085 , H05K1/092 , Y10T428/24917
摘要： A laminated ceramic electronic component, for example, monolithic ceramic capacitor, in which the delamination does not occur during baking and having superior thermal shock and moisture load resistance characteristics is provided. A conductive paste, used with advantage to form an internal electrode of the laminated ceramic electronic component, and a laminated ceramic electronic component using the conductive paste is provided. The conductive paste is composed of a conductive powder which is primarily Ni, an organic vehicle, a compound A containing at least one of Mg and Ca and which is an organic acid metal salt, oxide powder, metal organic complex salt and/or an alkoxide, and a compound B, having a hydrolyzable reactive group containing at least one of Ti and Zr, which adheres to the surface of the conductive powder.
摘要翻译：提供了层压陶瓷电子部件，例如，单片陶瓷电容器，其中在烘烤期间不发生分层并具有优异的耐热冲击和耐湿负荷特性。提供有利地形成层叠陶瓷电子部件的内部电极的导电性糊料和使用导电性糊料的层叠陶瓷电子部件。导电性糊料由主要为Ni的导电性粉末，有机载体，含有Mg和Ca中的至少一种的化合物A，作为有机酸金属盐，氧化物粉末，金属有机配盐和/或醇盐构成，以及具有含有Ti和Zr中的至少一种的可水解反应性基团的化合物B，其粘附到导电粉末的表面。

2. 发明授权

US06478882B2 Conductive paste and laminated ceramic electronic component using the same 有权
标题翻译：导电胶和层压陶瓷电子元件使用相同
公开(公告)号：US06478882B2
公开(公告)日：2002-11-12
申请号：US09893174
申请日：2001-06-27
申请人： Takaharu Miyazaki , Tsuyoshi Yamana
发明人： Takaharu Miyazaki , Tsuyoshi Yamana
IPC分类号： B23K35363
CPC分类号： H01G4/0085 , H05K1/092
摘要： A laminated ceramic electronic component, such as a laminated ceramic capacitor, having superior heat shock resistance and humidity loading resistance is provided, in which no delamination occurs during a firing step. A conductive paste advantageously used for forming internal electrodes and a laminated ceramic electronic component using the conductive paste are provided. The conductive paste is a conductive powder primarily composed of Ni; an organic vehicle; a compound A which is at least one of an organic acid metal salt, an organic metal complex salt and an alkoxide, and which contains at least one of Mg, Ca and Ba; and a hydrolyzed compound B containing at least one of Al and Si; wherein the hydrolyzed compound B is adhered to the surface of the conductive powder.
摘要翻译：提供了具有优异的耐热冲击性和耐湿负荷性的层压陶瓷电子部件，例如层压陶瓷电容器，其中在烧制步骤中不发生分层。提供有利地用于形成内部电极的导电浆料和使用导电浆料的层压陶瓷电子部件。导电膏是主要由Ni构成的导电粉末; 有机车辆化合物A，其为有机酸金属盐，有机金属络合盐和醇盐中的至少一种，并且含有Mg，Ca和Ba中的至少一种; 和含有Al和Si中的至少一种的水解化合物B; 其中水解化合物B粘附到导电粉末的表面。

3. 发明授权

US06320738B1 Monolithic ceramic electronic component and method for making the same 有权
标题翻译：单片陶瓷电子元件及其制作方法
公开(公告)号：US06320738B1
公开(公告)日：2001-11-20
申请号：US09699550
申请日：2000-10-30
申请人： Tsuyoshi Yamana , Takaharu Miyazaki
发明人： Tsuyoshi Yamana , Takaharu Miyazaki
IPC分类号： H01G406
CPC分类号： H01L41/083 , H01C1/14 , H01C7/008 , H01C7/18 , H01G4/30 , H01L41/187 , Y10T29/43
摘要： A monolithic ceramic electronic component has a ceramic element including a plurality of ceramic layers and a plurality of internal electrode layers. Each internal electrode layer is disposed between two adjacent ceramic layers. The roughness of the interface between each internal electrode layer and each ceramic layer is about 200 nm or less, and the incidence of pores in the ceramic layer is about 1% or less by area at a polished cut cross-section. The monolithic ceramic electronic component can be a monolithic ceramic capacitor, a monolithic ceramic varistor, a monolithic ceramic piezoelectric component or a monolithic substrate.
摘要翻译：单片陶瓷电子部件具有包括多个陶瓷层和多个内部电极层的陶瓷元件。每个内部电极层设置在两个相邻的陶瓷层之间。每个内部电极层和每个陶瓷层之间的界面的粗糙度为约200nm或更小，并且在抛光切割横截面处，陶瓷层中的孔的发生率为面积的约1％或更小。单片陶瓷电子部件可以是单片陶瓷电容器，单片陶瓷压敏电阻器，单片陶瓷压电元件或单片基板。

4. 发明授权

US06849145B2 Method of producing ceramic green sheet and method of manufacturing multilayer ceramic electronic part 有权
标题翻译：陶瓷生片的制造方法和多层陶瓷电子部件的制造方法
公开(公告)号：US06849145B2
公开(公告)日：2005-02-01
申请号：US10448118
申请日：2003-05-30
申请人： Tsuyoshi Yamana , Takaharu Miyazaki
发明人： Tsuyoshi Yamana , Takaharu Miyazaki
IPC分类号： H01C7/00 , H01C7/18 , H01C17/065 , H01G4/12 , H01G4/30 , B32B31/26 , B28B11/08
CPC分类号： H01G4/30 , H01C7/003 , H01C7/18 , H01C17/06506 , H01G4/12
摘要： A ceramic green sheet having good surface roughness and few pinhole defects even when producing a thin ceramic green sheet is stably produced, to permit efficiently and securely manufacturing a multilayer ceramic electronic part in which deterioration of its life due to unevenness of interfaces between internal electrodes and ceramic layers and the occurrence of structural defects, such as delamination, bending of an electrode portion, etc, in a multilayer thin film to be suppressed. A dry sheet obtained by forming ceramic slurry to a sheet on a carrier film is smoothed by pressing using a plate press, a hydrostatic press or a calender roll under predetermined temperature and pressure conditions to improve the surface smoothness of the ceramic green sheet independently of the particle diameter of the ceramic and its dispersibility. An electrode paste is coated in a predetermine pattern on the thus-produced ceramic green sheet to form a sheet provided with an electrode. A plurality of the sheets provided with electrodes are laminated, and the burned to produce a multilayer ceramic electronic part.
摘要翻译：稳定地生产具有良好的表面粗糙度和较少的针孔缺陷的陶瓷生片，即使制造薄的陶瓷生片也能有效且可靠地制造多层陶瓷电子部件，其中由于内部电极之间的界面的不均匀性而使其寿命降低陶瓷层，以及在要抑制的多层薄膜中发生结构缺陷，如分层，电极部分的弯曲等。通过在预定的温度和压力条件下使用压片机，静液压机或压光辊压制，将通过在载体膜上的片材形成陶瓷浆料而获得的干燥片材平滑化，以提高陶瓷生片材的表面平滑度，陶瓷的粒径及其分散性。在如此制备的陶瓷生片上以预定图案涂覆电极糊，以形成设置有电极的片。层叠多个设有电极的片材，烧成多层陶瓷电子部件。

5. 发明授权

US06270906B1 Monolithic ceramic electronic component 有权
标题翻译：单片陶瓷电子元件
公开(公告)号：US06270906B1
公开(公告)日：2001-08-07
申请号：US09261511
申请日：1999-03-03
申请人： Takanori Nakamura , Tsuyoshi Yamana , Nobuyuki Wada , Takaharu Miyazaki
发明人： Takanori Nakamura , Tsuyoshi Yamana , Nobuyuki Wada , Takaharu Miyazaki
IPC分类号： H01G406
CPC分类号： H01G4/0085 , H01G4/30
摘要： A monolithic ceramic component has inner electrodes which are thin having a thickness of from about 0.2 &mgr;m to 0.7 min, and thereby, delamination is inhibited even though ceramic layers are thin, having a thickness up to about 3 &mgr;m. The mean particle size of the ceramic grains of the ceramic layers is up to 0.5 &mgr;m, so that the concavities and convexities at the interfaces between the inner electrodes and the ceramic layers can be reduced. Preferably, metal powder in a paste used to form the inner electrodes has a mean particle size of from about 10 to 200 nm, and thereby, the metal filling ratio and the smoothness of the inner electrodes can be enhanced, and the coverage can be improved.
摘要翻译：单片陶瓷部件具有厚度为约0.2μm至0.7min的薄的内部电极，因此即使陶瓷层较薄，具有高达约3μm的厚度，也会抑制分层。陶瓷层的陶瓷粒子的平均粒径可以达到0.5μm，从而可以减少内部电极和陶瓷层之间的界面处的凹凸。优选地，用于形成内部电极的糊料中的金属粉末具有约10至200nm的平均粒度，从而可以提高金属填充率和内部电极的平滑度，并且可以提高覆盖率。

6. 发明授权

US06673272B2 Conductive paste and laminated ceramic electronic component 有权
标题翻译：导电胶和层压陶瓷电子元件
公开(公告)号：US06673272B2
公开(公告)日：2004-01-06
申请号：US09899323
申请日：2001-07-05
申请人： Takaharu Miyazaki , Tsuyoshi Yamana
发明人： Takaharu Miyazaki , Tsuyoshi Yamana
IPC分类号： H01B106
CPC分类号： C04B35/49 , B32B18/00 , B32B38/145 , B32B2311/22 , C04B35/468 , C04B35/6281 , C04B35/62821 , C04B35/62823 , C04B2235/3206 , C04B2235/3208 , C04B2235/405 , C04B2235/79 , C04B2237/12 , C04B2237/346 , C04B2237/348 , C04B2237/405 , C04B2237/50 , C04B2237/704 , C04B2237/706 , H01G4/0085 , H05K1/092 , Y10T428/24917
摘要： A laminated ceramic electronic component, for example, monolithic ceramic capacitor, in which the delamination does not occur during baking and having superior thermal shock and moisture load resistance characteristics is provided. A conductive paste, used with advantage to form an internal electrode of the laminated ceramic electronic component, and a laminated ceramic electronic component using the conductive paste is provided. The conductive paste is composed of a conductive powder which is primarily Ni, an organic vehicle, a compound A containing at least one of Mg and Ca and which is an organic acid metal salt, oxide powder, metal organic complex salt and/or an alkoxide, and a compound B, having a hydrolyzable reactive group containing at least one of Ti and Zr, which adheres to the surface of the conductive powder.
摘要翻译：提供了层压陶瓷电子部件，例如，单片陶瓷电容器，其中在烘烤期间不发生分层并具有优异的耐热冲击和耐湿负荷特性。提供有利地形成层叠陶瓷电子部件的内部电极的导电性糊料和使用导电性糊料的层叠陶瓷电子部件。导电性糊料由主要为Ni的导电性粉末，有机载体，含有Mg和Ca中的至少一种的化合物A，作为有机酸金属盐，氧化物粉末，金属有机配盐和/或醇盐构成，以及具有含有Ti和Zr中的至少一种的可水解反应性基团的化合物B，其粘附到导电粉末的表面。

7. 发明授权

US06692598B1 Method of producing ceramic green sheet and method of manufacturing multilayer ceramic electronic part 有权
标题翻译：陶瓷生片的制造方法和多层陶瓷电子部件的制造方法
公开(公告)号：US06692598B1
公开(公告)日：2004-02-17
申请号：US09690788
申请日：2000-10-17
申请人： Tsuyoshi Yamana , Takaharu Miyazaki
发明人： Tsuyoshi Yamana , Takaharu Miyazaki
IPC分类号： B32B3126
CPC分类号： H01G4/30 , H01C7/003 , H01C7/18 , H01C17/06506 , H01G4/12
摘要： A ceramic green sheet having good surface roughness and few pinhole defects even when producing a thin ceramic green sheet is stably produced, to permit efficiently and securely manufacturing a multilayer ceramic electronic part in which deterioration of its life due to unevenness of interfaces between internal electrodes and ceramic layers and the occurrence of structural defects, such as delamination, bending of an electrode portion, etc., in a multilayer thin film to be suppressed. A dry sheet obtained by forming ceramic slurry to a sheet on a carrier film is smoothed by pressing using a plate press, a hydrostatic press or a calender roll under predetermined temperature and pressure conditions to improve the surface smoothness of the ceramic green sheet independently of the particle diameter of the ceramic and its dispersibility. An electrode paste is coated in a predetermine pattern on the thus-produced ceramic green sheet to form a sheet provided with an electrode. A plurality of the sheets provided with electrodes are laminated, and the burned to produce a multilayer ceramic electronic part.
摘要翻译：稳定地生产具有良好的表面粗糙度和较少的针孔缺陷的陶瓷生片，即使制造薄的陶瓷生片也能有效且可靠地制造多层陶瓷电子部件，其中由于内部电极和陶瓷层，以及要抑制的多层薄膜中出现结构缺陷，如分层，电极部分的弯曲等。通过在预定的温度和压力条件下使用压片机，静液压机或压光辊压制，将通过在载体膜上的片材形成陶瓷浆料而获得的干燥片材平滑化，以提高陶瓷生片材的表面平滑度，陶瓷的粒径及其分散性。在如此制备的陶瓷生片上以预定图案涂覆电极糊，以形成设置有电极的片。层叠多个设有电极的片材，烧成多层陶瓷电子部件。

8. 发明授权

US06442813B1 Method of producing a monolithic ceramic capacitor 失效
标题翻译：制造叠层陶瓷电容器的方法
公开(公告)号：US06442813B1
公开(公告)日：2002-09-03
申请号：US09058081
申请日：1998-04-09
申请人： Norihiko Sakamoto , Harunobu Sano , Takaharu Miyazaki
发明人： Norihiko Sakamoto , Harunobu Sano , Takaharu Miyazaki
IPC分类号： H01G907
CPC分类号： H01G4/30 , Y10T29/43 , Y10T29/435 , Y10T29/49126
摘要： A monolithic ceramic capacitor includes a plurality of dielectric ceramic layers, a plurality of inner electrodes formed between the dielectric ceramic layers in such a manner that one end of each inner electrode is exposed out of either end of the dielectric ceramic layers, and outer electrodes electrically connected with the exposed inner electrodes; in which the inner electrodes each are made of a base metal, and Si oxide layers or layers comprising an Si oxide and at lest one component that constitutes said dielectric ceramic layers and said inner electrodes are formed adjacent to the inner electrodes. The capacitor has excellent thermal impact resistance and wet load resistance characteristics. A producing method includes firing a green sheet laminate including a metal inner electrode at an oxygen partial pressure of about said equilibrium oxygen partial pressure of the metal to the metal oxide.
摘要翻译：单片陶瓷电容器包括多个电介质陶瓷层，多个内电极，形成在电介质陶瓷层之间，使每个内电极的一端从电介质陶瓷层的任一端露出，外电极电与暴露的内部电极连接; 其中内部电极各自由贱金属制成，并且包括Si氧化物的Si氧化物层或构成所述介电陶瓷层和所述内部电极的至少一个部件的Si形成在与内部电极相邻的位置。电容器具有优异的耐热冲击性和耐湿负载特性。一种制造方法包括以大约金属的平衡氧分压的氧分压与金属氧化物烧结包含金属内电极的生片层压体。

9. 发明授权

US5835339A Monolithic ceramic capacitor 失效
标题翻译：单片陶瓷电容器
公开(公告)号：US5835339A
公开(公告)日：1998-11-10
申请号：US901221
申请日：1997-07-24
申请人： Norihiko Sakamoto , Harunobu Sano , Takaharu Miyazaki
发明人： Norihiko Sakamoto , Harunobu Sano , Takaharu Miyazaki
IPC分类号： C04B35/46 , H01B3/00 , H01B3/12 , H01G4/12 , H01G4/30 , H01G4/005 , H01G4/06
CPC分类号： H01G4/30
摘要： A monolithic ceramic capacitor and producing method thereof are disclosed. The ceramic capacitor has a plurality of dielectric ceramic layers, a plurality of inner electrodes formed between the dielectric ceramic layers in such a manner that one end of each inner electrode is exposed out of either end of the dielectric ceramic layers, and outer electrodes electrically connected with the exposed inner electrodes; in which the inner electrodes each are made of a base metal, and Si oxide layers or layers comprising an Si oxide and at least one component that constitutes said dielectric ceramic layers and said inner electrodes are formed adjacent to the inner electrodes. The capacitor has excellent thermal impact resistance and wet load resistance characteristics.
摘要翻译：公开了一种叠层陶瓷电容器及其制造方法。陶瓷电容器具有多个电介质陶瓷层，多个内电极，形成在电介质陶瓷层之间，使得每个内电极的一端从电介质陶瓷层的任一端露出，外电极电连接与暴露的内部电极; 其中内部电极各自由贱金属制成，并且包括Si氧化物和构成所述电介质陶瓷层和所述内部电极的至少一个部件的Si氧化物层或层形成为与内部电极相邻。电容器具有优异的耐热冲击性和耐湿负载特性。

10. 发明授权

US5308706A Heat reflecting sandwich plate 失效
标题翻译：热反射夹心板
公开(公告)号：US5308706A
公开(公告)日：1994-05-03
申请号：US6173
申请日：1993-01-15
申请人： Jun Kawaguchi , Tatsuya Hyodo , Takaharu Miyazaki
发明人： Jun Kawaguchi , Tatsuya Hyodo , Takaharu Miyazaki
IPC分类号： B32B17/10 , C03C17/36 , G02B5/20 , B32B15/04 , B32B17/06
CPC分类号： C03C17/3613 , B32B17/10174 , C03C17/36 , C03C17/3642 , C03C17/366 , C03C17/3681 , G02B5/208 , Y10S428/925 , Y10T428/12549 , Y10T428/12569 , Y10T428/12597 , Y10T428/3163
摘要： Disclosed herein is a heat reflecting sandwich plate made up of a first and a second transparent plates bonded together with a transparent resin film. The first transparent plate is coated on the inside thereof with a heat reflecting film which is a laminate composed of two metal oxide layers, with a noble metal layer intervening between them. The noble metal layer has a sheet resistance of 4-10 ohms/square. The first and second metal oxide layers have thicknesses controlled such that their ratio is in the range of 1.1 to 1.6. The heat reflecting sandwich plate produces reflected rays which have a chromaticness specified by -1.ltoreq.a.ltoreq.1 and -1.ltoreq.b.ltoreq.1, where a and b denote the chromaticness indices of Hunter's color specification system, and has a visible light reflectivity lower than 10%. Because of these characteristic properties, the heat reflecting sandwich plate has high strength and safety, exhibits outstanding heat reflecting performance, and assumes almost no color and looks good despite its comparatively high visible light transmittance.
摘要翻译：本发明公开了一种由透明树脂膜结合在一起的第一透明板和第二透明板构成的热反射夹层板。第一透明板在其内部涂覆有热反射膜，该热反射膜是由两个金属氧化物层组成的层压体，并且介于它们之间的贵金属层。贵金属层的薄层电阻为4-10欧姆/平方。第一和第二金属氧化物层具有控制的厚度，使得它们的比例在1.1至1.6的范围内。热反射夹心板产生具有由-1

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