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    • 8. 发明授权
    • Joined body of aluminum nitride series ceramics, method of joining aluminum nitride series ceramics and joining agent
    • 氮化铝系列陶瓷的接合体,氮化铝系陶瓷的接合方法和接合剂
    • US06261708B1
    • 2001-07-17
    • US09013042
    • 1998-01-26
    • Tsuneaki OhashiTsutomu Imai
    • Tsuneaki OhashiTsutomu Imai
    • B32B516
    • C04B35/645C04B37/005C04B2235/6562C04B2235/658C04B2237/06C04B2237/064C04B2237/08C04B2237/10C04B2237/366C04B2237/708C04B2237/765Y10T403/479Y10T428/256
    • A novel method is provided for joining substrates made of aluminum nitride series ceramics to each other, which can perform the joining substantially without leaving an intervening third phase other than aluminum nitride series ceramics at the joining interface of the substrates. The method is performed, for example, by providing a joining agent 3 containing at least an aluminum nitride series ceramics and a flux between the substrates 1 and 2, heat treating the joining agent to eutectically melt the aluminum nitride series ceramics and the flux, then precipitating a reprecipitated phase of the aluminum nitride series ceramics at the joining interface of the substrates. Alternatively, the method is performed by providing a joining agent 3 containing at least an aluminum nitride series ceramics and a flux between the substrates 1 and 2, heating the joining agent to a temperature range T1 which is higher than the melting point of the flux, subsequently heating the joining agent to a temperature range T2 which is higher than the temperature range T1 to exit the components of the flux from the joining interface, ten precipitating the reprecipitated phase of the aluminum nitride series ceramics at the joining interface.
    • 提供了一种用于将由氮化铝系列陶瓷制成的衬底彼此接合的新方法,其可以在基板的接合界面处基本上不会留下除氮化铝系列陶瓷之外的中间第三相而进行接合。 该方法例如通过提供至少包含氮化铝系陶瓷的接合剂3和在基板1和2之间的焊剂,对接合剂进行热处理以使氮化铝系列陶瓷和焊剂共晶化,然后 在基板的接合界面处沉淀出氮化铝系陶瓷的再沉淀相。 或者,该方法通过提供至少包含氮化铝系陶瓷的接合剂3和在基板1和2之间的焊剂,将接合剂加热到高于焊剂的熔点的温度范围T1, 随后将接合剂加热到高于温度范围T1的温度范围T2以从接合界面离开焊剂的组分,在接合界面处使氮化铝系陶瓷的再沉淀相沉淀10次。
    • 9. 发明授权
    • Phosphate compounds, sintered bodies thereof and manufacture of the
sintered bodies
    • 磷酸盐化合物,其烧结体和烧结体的制造
    • US5128288A
    • 1992-07-07
    • US627412
    • 1990-12-14
    • Tsuneaki OhashiKeiji Matsuhiro
    • Tsuneaki OhashiKeiji Matsuhiro
    • C01B25/45C04B35/447
    • C04B35/447C01B25/45
    • A heat resistant, low expansion phosphate compound and sintered bodies thereof, having a composition of RZr.sub.4 P.sub.6 O.sub.24 (R is one or more cations of IIa group in the periodic table, such as Ba, Sr and Ca): an average thermal expansion coefficient between room temperature and 1,400.degree. C. of -10.about.+10.times.10.sup.-7 /.degree.C.; and having a high temperature type crystalline structure having R3c symmetry at room temperature. The sintered body of the invention can be manufactured by mixing and shaping starting materials, firing the resulting shaped body at 1,400.degree. C..about.1,700.degree. C. to provide a sintered body with a composition of RZr.sub.4 P.sub.6 O.sub.24 and then, keeping the obtained sintered body at a high temperature of not lower than a temperature of phase transition between a high temperature type and a low temperature type crystalline structure, followed by quenching.
    • 具有RZr4P6O24组成的耐热,低膨胀的磷酸盐化合物及其烧结体(R是周期表中的IIa族的一种或多种阳离子,例如Ba,Sr和Ca):室温下的平均热膨胀系数 和-100℃-10℃〜10℃/ 10℃。 并且在室温下具有R3c对称性的高温型晶体结构。 本发明的烧结体可以通过将原料混合和成形来制造,在1400℃的温度下烧结所得到的成型体,提供具有RZr4P6O24组成的烧结体,然后将得到的烧结体保持在 不低于高温型和低温型结晶结构之间的相变温度的高温,然后淬火。