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    • 9. 发明授权
    • Gas-phase growth process
    • 气相生长过程
    • US4702936A
    • 1987-10-27
    • US778004
    • 1985-09-20
    • Kazuo MaedaNoboru TokumasuToshihiko Fukuyama
    • Kazuo MaedaNoboru TokumasuToshihiko Fukuyama
    • C23C16/30C23C16/34C23C16/40C23C16/48C30B25/02B05D3/06
    • C23C16/482C23C16/308C23C16/345C23C16/401C23C16/402C30B25/02
    • A gas-phase growth process for forming a film of SiO.sub.2 Si.sub.3 N.sub.4 or Si.sub.x O.sub.y N.sub.z, which comprises reacting a mixture of an organic or inorganic silane with one or more reaction gases comprising O.sub.2, N.sub.2 O, NO.sub.2 NO, CO.sub.2 CO and NH.sub.3, with the proviso that the mixture of inorganic silane and O.sub.2 is excluded as a reaction gas combination of the present invention. The process comprises feeding a reaction gas into a reaction chamber which is kept at a reaction temperature below 500.degree. C., and subjecting the surface of a substrate chamber which is placed in the reaction chamber to UV irradiation. This irradiation excites the reaction gas, which allows a low-temperature gas-phase growth to proceed. The photo-excitation occurs selectively only at UV-irradiated sections, so that a film growth may occur selectively on the substrate surface within the range of UV irradiation. The optional use of a suitable mask allows a film of a prescribed pattern to be formed on the substrate surface.
    • 一种用于形成SiO 2 + L,Si 3 N 4或SixO y N z的膜的气相生长方法,其包括将有机或无机硅烷的混合物与一种或多种包含O 2,N 2 O,NO 2 + L,NO,CO 2 + L的反应气体 ,CO和NH 3,条件是排除无机硅烷和O 2的混合物作为本发明的反应气体组合。 该方法包括将反应气体进料到保持在低于500℃的反应温度的反应室中,并将放置在反应室中的基板室的表面进行紫外线照射。 该照射激发反应气体,这允许进行低温气相生长。 光激发仅在UV照射部分选择性地发生,从而在UV照射的范围内,可以在衬底表面上选择性地发生膜生长。 可选地使用合适的掩模允许在基板表面上形成规定图案的膜。
    • 10. 发明授权
    • Film forming method and semiconductor device manufacturing method
    • 成膜方法和半导体器件的制造方法
    • US6110814A
    • 2000-08-29
    • US330052
    • 1999-06-11
    • Noboru TokumasuKazuo Maeda
    • Noboru TokumasuKazuo Maeda
    • H01L21/31C23C16/40C23C16/56H01L21/3105H01L21/316H01L21/768H01L21/4763
    • H01L21/76819C23C16/401C23C16/56H01L21/31051
    • The present invention relates to a film forming method for forming a planarized interlayer insulating film to cover wiring layers, etc. of a semiconductor integrated circuit device. The method includes the steps of forming on a substrate 206, a phosphorus-containing insulating film 45a containing P.sub.2 O.sub.3 by using a film forming gas in which an oxidizing. gas is added into a gas mixture including a phosphorus-containing compound, which has III valence phosphorus and in which oxygen is bonded to at least one bond of the III valence phosphorus, and silicon-containing compound, or by using the film forming gas from which the oxidizing gas removed, heating the phosphorus-containing insulating film 45a while applying acceleration to the insulating film 45a to fluidize the insulating film and thus planarize a surface of the insulating film 45b while the insulating film 45a has a predetermined viscosity, and heating further the insulating film 45b after the surface of the insulating film 45b has been planarized, to sublimate P.sub.2 O.sub.3 in the insulating film 45b and thus solidify the insulating film 45b.
    • 本发明涉及一种用于形成半导体集成电路器件的布线层等的平坦化层间绝缘膜的成膜方法。 该方法包括以下步骤:通过使用其中进行氧化的成膜气体,在基板206上形成含有P 2 O 3的含磷绝缘膜45a。 将气体加入到含有III价态的磷的含磷化合物的气体混合物中,其中氧与III价态的磷的至少一个键结合,并且含硅化合物,或者通过使用成膜气体从 除去氧化气体,同时加热含磷绝缘膜45a,同时对绝缘膜45a施加加速度,使绝缘膜流化,从而使绝缘膜45b的表面平坦化,同时绝缘膜45a具有预定的粘度,并进一步加热 绝缘膜45b的表面之后的绝缘膜45b被平坦化,以使绝缘膜45b中的P2O3升华,从而固化绝缘膜45b。