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1. 发明申请

US20100210742A1 MICROPHASE-SEPARATED STRUCTURE MEMBRANE AND PROCESS FOR PRODUCING THE SAME 有权
标题翻译：微晶分离结构膜及其制造方法
公开(公告)号：US20100210742A1
公开(公告)日：2010-08-19
申请号：US12675955
申请日：2008-09-02
申请人： Tomokazu Iyoda , Sadayuki Asaoka , Yukimitsu Suzuki , Haruyuki Nakanishi , Shinichi Matsumoto , Hidekazu Arikawa
发明人： Tomokazu Iyoda , Sadayuki Asaoka , Yukimitsu Suzuki , Haruyuki Nakanishi , Shinichi Matsumoto , Hidekazu Arikawa
IPC分类号： C08J5/20
CPC分类号： C09D153/00 , C08F293/00 , C08F293/005 , C08F2438/01 , C08J5/2268 , C08J5/2287 , C08J9/26 , C08J2201/046 , C08J2333/14 , H01B1/122 , H01M8/1023 , H01M8/1058 , H01M2008/1095 , H01M2300/0082 , Y10T428/24504
摘要： Provided is a microphase-separated structure membrane including a block copolymer in which a hydrophilic polymer component and a hydrophobic polymer component are coupled to each other via a structural unit having a reactive group, an electron acceptor or electron donor, or a dye. In the microphase-separated structure membrane, a cylinder structure composed of the hydrophilic polymer component lies in a matrix composed of the hydrophobic polymer component and is oriented in the direction perpendicular to the membrane surface, and the structural unit having a reactive group, an electron acceptor or electron donor, or a dye lies between the matrix and the cylinder structure.
摘要翻译：提供了一种微相分离结构膜，其包括其中亲水性聚合物组分和疏水性聚合物组分通过具有反应性基团的结构单元，电子受体或电子给体或染料彼此偶联的嵌段共聚物。在微相分离结构膜中，由亲水性聚合物组分构成的圆筒结构位于由疏水性聚合物组分构成的基体中，并且在垂直于膜表面的方向上取向，并且具有反应性基团的结构单元，电子受体或电子给体，或染料位于基质和圆筒结构之间。

2. 发明授权

US08476322B2 Microphase-separated structure membrane and process for producing the same 有权
标题翻译：微分离分离结构膜及其制备方法
公开(公告)号：US08476322B2
公开(公告)日：2013-07-02
申请号：US12675955
申请日：2008-09-02
申请人： Tomokazu Iyoda , Sadayuki Asaoka , Yukimitsu Suzuki , Haruyuki Nakanishi , Shinichi Matsumoto , Hidekazu Arikawa
发明人： Tomokazu Iyoda , Sadayuki Asaoka , Yukimitsu Suzuki , Haruyuki Nakanishi , Shinichi Matsumoto , Hidekazu Arikawa
IPC分类号： C08J5/20
CPC分类号： C09D153/00 , C08F293/00 , C08F293/005 , C08F2438/01 , C08J5/2268 , C08J5/2287 , C08J9/26 , C08J2201/046 , C08J2333/14 , H01B1/122 , H01M8/1023 , H01M8/1058 , H01M2008/1095 , H01M2300/0082 , Y10T428/24504
摘要： Provided is a microphase-separated structure membrane including a block copolymer in which a hydrophilic polymer component and a hydrophobic polymer component are coupled to each other via a structural unit having a reactive group, an electron acceptor or electron donor, or a dye. In the microphase-separated structure membrane, a cylinder structure composed of the hydrophilic polymer component lies in a matrix composed of the hydrophobic polymer component and is oriented in the direction perpendicular to the membrane surface, and the structural unit having a reactive group, an electron acceptor or electron donor, or a dye lies between the matrix and the cylinder structure.
摘要翻译：提供了一种微相分离结构膜，其包括其中亲水性聚合物组分和疏水性聚合物组分通过具有反应性基团的结构单元，电子受体或电子给体或染料彼此偶联的嵌段共聚物。在微相分离结构膜中，由亲水性聚合物组分构成的圆筒结构位于由疏水性聚合物组分构成的基体中，并且在垂直于膜表面的方向上取向，并且具有反应性基团的结构单元，电子受体或电子给体，或染料位于基质和圆筒结构之间。

3. 发明申请

US20120116024A1 SELF-SUPPORTING THIN POLYMER FILM 审中-公开
标题翻译：自支撑薄聚合物薄膜
公开(公告)号：US20120116024A1
公开(公告)日：2012-05-10
申请号：US13322325
申请日：2010-02-25
申请人： Tomokazu Iyoda , Takashi Yamamoto , Sadayuki Asaoka , Tasuku Izutani
发明人： Tomokazu Iyoda , Takashi Yamamoto , Sadayuki Asaoka , Tasuku Izutani
IPC分类号： C08F220/10 , B29C59/16
CPC分类号： C08F20/26 , B01D67/0006 , B01D69/125 , B01D71/48 , B01D71/52 , B01D71/80 , B01D2323/00 , B01D2323/30 , B01D2323/345 , C08F220/26 , C08F293/005 , C08F2220/286 , C08J5/18 , C08F2220/302
摘要： [Object] To provide a self-supporting thin polymer membrane having a large surface area, a high strength, and a perpendicularly oriented cylindrical structure, and to provide a method of producing the membrane.[Solution] The self-supporting thin polymer membrane of the present invention is a self-supporting thin polymer membrane including a block copolymer in which a hydrophilic polymer component and a hydrophobic polymer component having a crosslinkable structure are linked to each other by covalent bonding, and in the self-supporting thin polymer membrane, the hydrophilic polymer component forms unidirectionally oriented cylinders, and the hydrophobic polymer component forms crosslinks. The self-supporting thin polymer membrane of the present invention does not have physical pores but allows a material to selectively permeate the cylindrical portions and can be therefore used as various permeable membranes, ultrafiltration membranes, and nanoreactors.
摘要翻译：提供具有大表面积，高强度和垂直取向的圆柱形结构的自支撑薄聚合物膜，并提供制造膜的方法。 [解决方案]本发明的自支撑薄膜聚合物膜是包含嵌段共聚物的自支撑薄聚合物膜，其中亲水性聚合物组分和具有可交联结构的疏水性聚合物组分通过共价键彼此连接，并且在自支撑薄聚合物膜中，亲水性聚合物组分形成单向取向的圆筒，并且疏水性聚合物组分形成交联。本发明的自支撑薄膜聚合物膜不具有物理孔隙，而是允许材料选择性地渗透圆筒部分，因此可用作各种渗透膜，超滤膜和纳米反应器。

4. 发明申请

US20080132676A1 Method for Producing Polypyridinium 有权
标题翻译：生产多吡啶的方法
公开(公告)号：US20080132676A1
公开(公告)日：2008-06-05
申请号：US10593176
申请日：2005-03-23
申请人： Tomokazu Iyoda , Kaori Kamata , Yukimitsu Suzuki , Masahiro Takeuchi
发明人： Tomokazu Iyoda , Kaori Kamata , Yukimitsu Suzuki , Masahiro Takeuchi
IPC分类号： C08G73/06
CPC分类号： C08G73/0627
摘要： A production method for polypyridinium having a narrow molecular weight distribution and a desired molecular weight is provided. Polypyridinium 3 having a narrow molecular weight distribution and a desired molecular weight is synthesized by allowing a pyridine derivative monomer 2 to polymerize on a polymerization initiator 1 such as a specially designed 4-halopyridinium and the like in the presence of a dissolution accelerating agent, such as tetrabutyl ammonium tetrafluoroborate, that dissolves the polymer formed in a solvent as in the chemical below. where Y represents an anion that dissolves in an organic solvent, X and Z represent halogen atoms, R represents hydrocarbon groups and the like and o is about 1 to 300.
摘要翻译：提供了具有窄分子量分布和所需分子量的聚吡啶鎓的制备方法。通过使吡啶衍生物单体2在诸如特殊设计的4-卤代吡啶鎓等的聚合引发剂1上聚合，在溶解促进剂存在下合成具有窄分子量分布和所需分子量的聚吡啶鎓3，作为四氟丁基铵四氟硼酸盐，其溶解如在下面的化学品中在溶剂中形成的聚合物。其中Y表示在有机溶剂中溶解的阴离子，X和Z表示卤素原子，R表示烃基等，o为约1至300。

5. 发明授权

US07985829B2 Method for producing polypyridinium 有权
标题翻译：生产聚吡啶的方法
公开(公告)号：US07985829B2
公开(公告)日：2011-07-26
申请号：US10593176
申请日：2005-03-23
申请人： Tomokazu Iyoda , Kaori Kamata , Yukimitsu Suzuki
发明人： Tomokazu Iyoda , Kaori Kamata , Yukimitsu Suzuki
IPC分类号： C08G73/06 , C08G73/00
CPC分类号： C08G73/0627
摘要： A production method for polypyridinium having a narrow molecular weight distribution and a desired molecular weight is provided. Polypyridinium 3 having a narrow molecular weight distribution and a desired molecular weight is synthesized by allowing a pyridine derivative monomer 2 to polymerize on a polymerization initiator 1 such as a specially designed 4-halopyridinium and the like in the presence of a dissolution accelerating agent, such as tetrabutyl ammonium tetrafluoroborate, that dissolves the polymer formed in a solvent as in the chemical below. where Y represents an anion that dissolves in an organic solvent, X and Z represent halogen atoms, R represents hydrocarbon groups and the like and o is about 1 to 300.
摘要翻译：提供了具有窄分子量分布和所需分子量的聚吡啶鎓的制备方法。通过使吡啶衍生物单体2在诸如特殊设计的4-卤代吡啶鎓等的聚合引发剂1上聚合，在溶解促进剂存在下合成具有窄分子量分布和所需分子量的聚吡啶鎓3，作为四氟丁基铵四氟硼酸盐，其溶解如在下面的化学品中在溶剂中形成的聚合物。其中Y表示在有机溶剂中溶解的阴离子，X和Z表示卤素原子，R表示烃基等，o为约1至300。

6. 发明授权

US07327074B2 Illuminating devices employing titanium dioxide photocatalysts 失效
标题翻译：使用二氧化钛光催化剂的照明装置
公开(公告)号：US07327074B2
公开(公告)日：2008-02-05
申请号：US11605374
申请日：2006-11-29
申请人： Akira Fujishima , Kazuhito Hashimoto , Tomokazu Iyoda , Shigemichi Fukayama , Tetsuo Yoshimoto , Tokuyoshi Saitoh
发明人： Akira Fujishima , Kazuhito Hashimoto , Tomokazu Iyoda , Shigemichi Fukayama , Tetsuo Yoshimoto , Tokuyoshi Saitoh
IPC分类号： H01J61/40 , F21V9/00
CPC分类号： A61L9/205 , B01D2255/20707 , B01D2255/802 , B01J21/06 , B01J21/063 , B01J21/066 , B01J35/002 , B01J35/004 , B01J37/0244 , C03C17/2456 , C03C17/256 , C03C17/3417 , C03C2217/212 , C03C2217/71 , H01J61/35 , H01J61/42
摘要： An illuminating device is made from a transparent hollow envelope that encloses a filler gas. The envelope has inner and outer surfaces. The illuminating device has a coating of a fluorescent material deposited on the inner surface of the transparent envelope where the fluorescent material emits light having a visible component and an ultraviolet component; and a titanium dioxide film having first and second opposing surfaces where the first surface of the titanium dioxide film is formed on the outer surface of the transparent envelope. A light transmittance of the titanium dioxide film is at least 50% for light having a wavelength of 550 nm, and the light transmitted from the fluorescent material through the transparent envelope and the first surface of the titanium dioxide film to the second surface thereof causes photocatalytic activity to be generated on the second surface of the titanium dioxide film.
摘要翻译：照明装置由包围填充气体的透明中空外壳制成。信封具有内表面和外表面。照明装置具有沉积在透明外壳的内表面上的荧光材料的涂层，其中荧光材料发射具有可见成分和紫外分量的光; 以及具有第一和第二相对表面的二氧化钛膜，其中二氧化钛膜的第一表面形成在透明外壳的外表面上。对于波长为550nm的光，二氧化钛膜的透光率为至少50％，并且从荧光材料通过透明外壳和二氧化钛膜的第一表面向其第二表面透射的光引起光催化在二氧化钛膜的第二表面上产生的活性。

7. 发明授权

US07157840B2 Illuminating devices employing titanium dioxide photocatalysts 有权
标题翻译：使用二氧化钛光催化剂的照明装置
公开(公告)号：US07157840B2
公开(公告)日：2007-01-02
申请号：US10327042
申请日：2002-12-24
申请人： Akira Fujishima , Kazuhito Hashimoto , Tomokazu Iyoda , Shigemichi Fukayama , Tetsuo Yoshimoto , Tokuyoshi Saitoh
发明人： Akira Fujishima , Kazuhito Hashimoto , Tomokazu Iyoda , Shigemichi Fukayama , Tetsuo Yoshimoto , Tokuyoshi Saitoh
IPC分类号： H01J63/04
CPC分类号： A61L9/205 , B01D2255/20707 , B01D2255/802 , B01J21/06 , B01J21/063 , B01J21/066 , B01J35/002 , B01J35/004 , B01J37/0244 , C03C17/2456 , C03C17/256 , C03C17/3417 , C03C2217/212 , C03C2217/71 , H01J61/35 , H01J61/42
摘要： An illuminating device is made from a transparent hollow envelope that encloses a filler gas. The envelope has inner and outer surfaces. The illuminating device has a coating of a fluorescent material deposited on the inner surface of the transparent envelope where the fluorescent material emits light having a visible component and an ultraviolet component; and a titanium dioxide film having first and second opposing surfaces where the first surface of the titanium dioxide film is formed on the outer surface of the transparent envelope. A light transmittance of the titanium dioxide film is at least 50% for light having a wavelength of 550 nm, and the light transmitted from the fluorescent material through the transparent envelope and the first surface of the titanium dioxide film to the second surface thereof causes photocatalytic activity to be generated on the second surface of the titanium dioxide film.
摘要翻译：照明装置由包围填充气体的透明中空外壳制成。信封具有内表面和外表面。照明装置具有沉积在透明外壳的内表面上的荧光材料的涂层，其中荧光材料发射具有可见成分和紫外分量的光; 以及具有第一和第二相对表面的二氧化钛膜，其中二氧化钛膜的第一表面形成在透明外壳的外表面上。对于波长为550nm的光，二氧化钛膜的透光率为至少50％，并且从荧光材料通过透明外壳和二氧化钛膜的第一表面向其第二表面透射的光引起光催化在二氧化钛膜的第二表面上产生的活性。

8. 发明申请

US20090117335A1 Method for Producing a Nanoporous Substrate 失效
标题翻译：生产纳米多孔基材的方法
公开(公告)号：US20090117335A1
公开(公告)日：2009-05-07
申请号：US12093343
申请日：2006-11-14
申请人： Tomokazu Iyoda , Kaori Kamata , Ryoko Watanabe
发明人： Tomokazu Iyoda , Kaori Kamata , Ryoko Watanabe
IPC分类号： B32B3/26 , B31D3/00
CPC分类号： H01L21/3086 , H01L21/0337 , Y10S438/942 , Y10S438/947 , Y10S977/888 , Y10S977/892 , Y10S977/895 , Y10T428/24504
摘要： Nanoporous substrate with fine pores having a diameter from 3 to 40 nm arranged with less than 60 nm periodicity is prepared by a method comprising the steps of coating amphipathic block copolymer on a substrate, forming a film containing hydrophilic cylinders aligned perpendicularly to the surface of the film on a substrate, and immersing the substrate into a solution containing an etchant.
摘要翻译：通过包括以下步骤的方法制备直径为3至40nm的具有小于60nm周期的直径的细孔的纳米多孔基材，所述方法包括以下步骤：将两亲嵌段共聚物涂布在基材上，形成含有垂直于将基板浸渍在含有蚀刻剂的溶液中。

9. 发明授权

US09074227B2 Helical fine structure, method for producing the same, and electric-wave shield or absorber using the helical fine structure 有权
标题翻译：螺旋精细结构，其制造方法以及使用螺旋状精细结构的电波屏蔽或吸收体
公开(公告)号：US09074227B2
公开(公告)日：2015-07-07
申请号：US13262024
申请日：2010-04-19
申请人： Tomokazu Iyoda , Kaori Ito , Atsushi Yamada
发明人： Tomokazu Iyoda , Kaori Ito , Atsushi Yamada
IPC分类号： C12N13/00 , C12N1/00 , C12N1/12 , A01H1/02 , C12P1/04 , H05K9/00
CPC分类号： C12P1/04 , C12N1/12 , H05K9/0081 , H05K9/009 , Y10T428/2924 , Y10T428/2925
摘要： A helical fine structure of the present invention is characterized by including: a phytoplankton having a helical shape and selected from a group of cyanobacteria called Spirulina; and a surface modification layer formed on the phytoplankton. The surface modification layer includes at least one metal plating layer. Thereby, the helical fine structure can be utilized as an electric-wave shield or an absorber. Moreover, a method for producing the helical fine structure is characterized in that a prestep of a step of forming the surface modification layer on the phytoplankton having a helical shape includes a washing step with an organic solvent to remove an outer membrane from a surface of the phytoplankton.
摘要翻译：本发明的螺旋细微结构的特征在于包括：具有螺旋形状并选自称为螺旋藻的一组蓝细菌的浮游植物; 以及形成在浮游植物上的表面改性层。表面改性层包括至少一个金属镀层。由此，螺旋状微细结构可以用作电波屏蔽或吸收体。此外，螺旋状微细结构的制造方法的特征在于，在具有螺旋形状的浮游植物上形成表面改性层的步骤的一个步骤包括用有机溶剂洗涤步骤以从外部膜的表面除去外部膜浮游植物

10. 发明授权

US6117568A Cyanochromium-complex-based magnetic material 失效
标题翻译：基于氰基铬络合物的磁性材料
公开(公告)号：US6117568A
公开(公告)日：2000-09-12
申请号：US913167
申请日：1997-10-30
申请人： Kazuhito Hashimoto , Akira Fujishima , Osamu Sato , Tomokazu Iyoda
发明人： Kazuhito Hashimoto , Akira Fujishima , Osamu Sato , Tomokazu Iyoda
IPC分类号： C25D9/00 , H01F10/00 , H01F41/26 , H01F10/08
CPC分类号： H01F41/26 , C25D9/00 , H01F10/005
摘要： The invention provides a novel cyanochromium-complex-based magnetic material formed on an electrode, which is excellent in magnetic properties and of which magnetic properties are reversibly controllable, by impressing a reduction potential which electrochemically reduces Cr.sup.3+ into Cr.sup.2+ in a solution containing at least [Cr(CN).sub.6 ].sup.3- and Cr.sup.3+.
摘要翻译： PCT No.PCT / JP96 / 00577 Sec。 371 1997年10月30日第 102（e）1997年10月30日PCT 1996年3月8日PCT公布。公开号WO96 / 28831 日期1996年9月19日本发明提供了一种形成在电极上的新颖的基于氰基铬络合物的磁性材料，其磁性能优异，磁性能可逆地控制，通过在电化学方法中减少Cr3 +的还原电位，至少含有[Cr（CN）6] 3-和Cr3 +的溶液。

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