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    • 1. 发明申请
    • MIXTURES OF ITACONIC ACID OR ITACONIC ACID DERIVATIVES AND PRIMARY AMINES FOR PRODUCING 1,3- AND 1,4-ALKYL METHYL PYRROLIDONES
    • 用于生产1,3-和1,4-亚烷基甲基吡咯烷酮的酸或酸性衍生物和主要胺的混合物
    • US20110251119A1
    • 2011-10-13
    • US13132785
    • 2009-11-24
    • Tobias WabnitzRolf PinkosKarl OttKatja Lamm
    • Tobias WabnitzRolf PinkosKarl OttKatja Lamm
    • C07D207/267C11D7/60C09K15/22B01F1/00C09K3/00
    • C07D207/267B01D53/1456B01D53/1493B01D2257/7022C07C57/13C09D9/005C11D3/28C11D7/3281
    • The present invention relates to a mixture comprising itaconic acid or an itaconic acid derivative and a primary amine of the formula (I) R—NH2  (I) where the molar ratio of primary amine to itaconic acid or the itaconic acid derivative is in the range from 0.5:1 to 20:1, wherein the mixture comprises 50 mole percent or less of 4-carboxypyrrolidones of the formula (II), derivatives of the 4-carboxypyrrolidones of the formula (II) and 4-carbamidopyrrolidones of the formula (III) based on the itaconic acid used or the itaconic acid derivative used and in which R is a linear or branched saturated aliphatic radical having 1 to 24 carbon atoms or a saturated cycloaliphatic radical having 3 to 24 carbon atoms.The invention further provides for the use of the inventive mixtures for preparing 1,3-alkylmethylpyrrolidones and/or 1,4-alkylmethylpyrrolidones, and also a process for preparing 1,3-alkylmethylpyrrolidones and/or 1,4-alkylmethylpyrrolidones.In addition, the present invention relates to mixtures comprising 1,3-alkylmethylpyrrolidones and/or 1,4-alkylmethylpyrrolidones and 1,3-alkylmethylpyrrolidines, where the proportion of 1,3-alkylmethylpyrrolidines is in the range from 10 to 10 000 ppm, and to mixtures comprising 1,3-alkylmethylpyrrolidone and 1,4-alkylmethylpyrrolidone, wherein the molar ratio of 1,3-alkylmethylpyrrolidone to 1,4-alkylmethylpyrrolidone is in the range from 1:1 to 10:1.
    • 本发明涉及包含衣康酸或衣康酸衍生物和伯胺与衣康酸衍生物的摩尔比在式(I)R-NH 2(I)中的伯胺的混合物, 其中所述混合物包含50摩尔%或更少的式(II)的4-羧基吡咯烷酮,式(II)的4-羧基吡咯烷酮的衍生物和式(III)的4-氨基甲酰基吡咯烷酮 ),其中R是具有1至24个碳原子的直链或支链饱和脂族基团或具有3至24个碳原子的饱和脂环族基团。 本发明进一步提供本发明混合物用于制备1,3-烷基甲基吡咯烷酮和/或1,4-烷基甲基吡咯烷酮的用途,以及制备1,3-烷基甲基吡咯烷酮和/或1,4-烷基甲基吡咯烷酮的方法。 此外,本发明涉及包含1,3-烷基甲基吡咯烷酮和/或1,4-烷基甲基吡咯烷酮和1,3-烷基甲基吡咯烷的混合物,其中1,3-烷基甲基吡咯烷的比例在10至10000ppm的范围内, 以及包含1,3-烷基甲基吡咯烷酮和1,4-烷基甲基吡咯烷酮的混合物,其中1,3-烷基甲基吡咯烷酮与1,4-烷基甲基吡咯烷酮的摩尔比在1:1至10:1的范围内。
    • 2. 发明授权
    • Mixtures of itaconic acid or itaconic acid derivatives and primary amines for producing 1,3- and 1,4-alkyl methyl pyrrolidones
    • 衣康酸或衣康酸衍生物和伯胺的混合物,用于制备1,3-和1,4-烷基甲基吡咯烷酮
    • US08796472B2
    • 2014-08-05
    • US13132785
    • 2009-11-24
    • Tobias WabnitzRolf PinkosKarl OttKatja Lamm
    • Tobias WabnitzRolf PinkosKarl OttKatja Lamm
    • C07D207/267B01D53/14
    • C07D207/267B01D53/1456B01D53/1493B01D2257/7022C07C57/13C09D9/005C11D3/28C11D7/3281
    • The present invention relates to a mixture comprising itaconic acid or an itaconic acid derivative and a primary amine of the formula (I) R—NH2  (I) where the molar ratio of primary amine to itaconic acid or the itaconic acid derivative is in the range from 0.5:1 to 20:1, wherein the mixture comprises 50 mole percent or less of 4-carboxypyrrolidones of the formula (II), derivatives of the 4-carboxypyrrolidones of the formula (II) and 4-carbamidopyrrolidones of the formula (III) based on the itaconic acid used or the itaconic acid derivative used and in which R is a linear or branched saturated aliphatic radical having 1 to 24 carbon atoms or a saturated cycloaliphatic radical having 3 to 24 carbon atoms. The invention further provides for the use of the inventive mixtures for preparing 1,3-alkylmethylpyrrolidones and/or 1,4-alkylmethylpyrrolidones, and also a process for preparing 1,3-alkylmethylpyrrolidones and/or 1,4-alkylmethylpyrrolidones.In addition, the present invention relates to mixtures comprising 1,3-alkylmethylpyrrolidones and/or 1,4-alkylmethylpyrrolidones and 1,3-alkylmethylpyrrolidines, where the proportion of 1,3-alkylmethylpyrrolidines is in the range from 10 to 10 000 ppm, and to mixtures comprising 1,3-alkylmethylpyrrolidone and 1,4-alkylmethylpyrrolidone, wherein the molar ratio of 1,3-alkylmethylpyrrolidone to 1,4-alkylmethylpyrrolidone is in the range from 1:1 to 10:1.
    • 本发明涉及包含衣康酸或衣康酸衍生物和伯胺与衣康酸衍生物的摩尔比在式(I)R-NH 2(I)中的伯胺的混合物, 其中所述混合物包含50摩尔%或更少的式(II)的4-羧基吡咯烷酮,式(II)的4-羧基吡咯烷酮的衍生物和式(III)的4-氨基甲酰基吡咯烷酮 ),其中R是具有1至24个碳原子的直链或支链饱和脂族基团或具有3至24个碳原子的饱和脂环族基团。 本发明进一步提供本发明混合物用于制备1,3-烷基甲基吡咯烷酮和/或1,4-烷基甲基吡咯烷酮的用途,以及制备1,3-烷基甲基吡咯烷酮和/或1,4-烷基甲基吡咯烷酮的方法。 此外,本发明涉及包含1,3-烷基甲基吡咯烷酮和/或1,4-烷基甲基吡咯烷酮和1,3-烷基甲基吡咯烷的混合物,其中1,3-烷基甲基吡咯烷的比例在10至10000ppm的范围内, 以及包含1,3-烷基甲基吡咯烷酮和1,4-烷基甲基吡咯烷酮的混合物,其中1,3-烷基甲基吡咯烷酮与1,4-烷基甲基吡咯烷酮的摩尔比在1:1至10:1的范围内。
    • 10. 发明授权
    • Device for recognising the angular position of a rotating part
    • 用于识别旋转部件的角位置的装置
    • US5497748A
    • 1996-03-12
    • US211729
    • 1994-04-11
    • Karl OttErwin SchmuckImmanuel KrauterJoerg Fuchs
    • Karl OttErwin SchmuckImmanuel KrauterJoerg Fuchs
    • G01B21/22F02D35/00F02D41/34F02D45/00F02P7/06G01D5/12G01D5/244G01D5/245G01D5/249G01P3/48F02D41/00
    • F02D41/009F02P7/061F02D41/0097
    • A device for recognizing the angular position of a rotating part is described in which the rotating part is a pick-up disc (14) provided with a multiplicity of regular angle marks (11) and a distinguishable reference mark (12), which is formed, for example, by two missing angle marks (11). The number of angle marks is (n-2), where n is a number which is divisible by as many numbers as possible corresponding to different numbers of cylinders and, for example, is 36. The voltage sequence generated in the sensor (15) is analyzed in the control unit (19), unambiguous cylinder recognition being obtained after the recognition of the reference mark (12) by comparison with a camshaft signal. The analysis of the voltage sequence also supplies the rotational speed and flanks, which can be predetermined, of the pulse sequence used for ignition and/or injection control.
    • PCT No.PCT / DE92 / 00805 Sec。 371日期1994年04月11日 102(e)日期1994年4月11日PCT提交1992年9月19日PCT公布。 公开号WO93 / 07449 描述了一种用于识别旋转部分的角位置的装置,其中旋转部分是具有多个规则角标记(11)的拾取盘(14)和可区分的参考标记 (12),其例如由两个缺失角标记(11)形成。 角度标记的数量是(n-2),其中n是可对应于不同数量的气缸的尽可能多的数字,并且例如是36的传感器(15)中产生的电压序列, 在控制单元(19)中进行分析,通过与凸轮轴信号进行比较,在识别出参考标记(12)之后获得明确的气缸识别。 电压序列的分析还提供用于点火和/或喷射控制的脉冲序列的旋转速度和侧面,其可以是预定的。