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    • 6. 发明申请
    • PHOTO-LATENT TITANIUM CATALYSTS
    • 钛酸钡催化剂
    • US20120220685A1
    • 2012-08-30
    • US13395467
    • 2010-09-09
    • Tobias HintermannDidier BauerAntoine CarroyCaroline LordelotRachel Kohli Steck
    • Tobias HintermannDidier BauerAntoine CarroyCaroline LordelotRachel Kohli Steck
    • C08G18/32C09D11/10C09D175/04C08F4/76C09J175/04
    • B01J31/2234B01J31/0208B01J31/2213B01J31/2226B01J2231/34B01J2531/46C08G18/222C08G18/6216C08G18/792C09D175/04
    • The present invention provides a photolatent Ti-chelate catalyst formulation, comprising (i) at least one compound of the formula (I) wherein R1 is C1-C20alkyl or C2-C20alkyl which is interrupted by one or more non-consecutive O-atoms; Y is formula (II) or optionally substituted phenyl; Y1 is formula (III) or optionally substituted phenyl; Y2 is formula (IV) or optionally substituted phenyl; Y3 is formula (V) or optionally substituted phenyl; R2, R3, R4, R5, R6, R7, R8, R9, R10, R11, R12 and R13 independently of each other are hydrogen, halogen, optionally substituted C1-C20alkyl, or R2, R3, R4, R5, R6, R7, R8, R9, R10, R11, R12 and R13 independently of each other are optionally substituted C6-C14aryl, provided that only one of R2, R3, R4 is hydrogen and only one of R5, R6, R7 is hydrogen and only one of R8, R9, R10 is hydrogen and only one of R11, R12, R13 is hydrogen; and (ii) at least one chelate ligand compound of the formula IIa, IIb or IIc, wherein Y′ is formula (VI) or formula (VII); Y′1 is formula (VIII) or formula (IX); R′2, R′3, R′4, R′5, R′6 and R′7 independently of each other have on of the meanings as given for R2, R3, R4, R5, R6, R7, R8, R9, R10, R11, R12 and R13; and R′14, R′15 and R′16 independently of each other have on of the meanings as given for R14, R15 and R16.
    • 本发明提供了一种光催化剂钛螯合催化剂制剂,其包含(i)至少一种式(I)化合物,其中R 1是被一个或多个非连续O原子间隔的C 1 -C 20烷基或C 2 -C 20烷基; Y是式(II)或任选取代的苯基; Y1是式(III)或任选取代的苯基; Y2是式(IV)或任选取代的苯基; Y 3是式(V)或任选取代的苯基; R2,R3,R4,R5,R6,R7,R8,R9,R10,R11,R12和R13彼此独立地是氢,卤素,任选取代的C 1 -C 20烷基,或者R 2,R 3,R 4,R 5,R 6,R 7 R 8,R 9,R 10,R 11,R 12和R 13彼此独立地是任选取代的C 6 -C 14芳基,条件是R 2,R 3,R 4中只有一个是氢,并且R 5,R 6,R 7中只有一个是氢, R8,R9,R10是氢,R11,R12,R13中只有一个是氢; 和(ii)式IIa,IIb或IIc的至少一种螯合配体化合物,其中Y'为式(VI)或式(VII); Y'1是式(VIII)或式(IX); R'2,R'3,R'4,R'5,R'6和R'7彼此独立地具有对R2,R3,R4,R5,R6,R7,R8,R9给出的含义 ,R10,R11,R12和R13; 并且R 14,R'15和R 16彼此独立地具有对R 14,R 15和R 16给出的含义。