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1. 发明授权

US07998239B1 Alloy nanoparticle synthesis using ionizing radiation 有权
标题翻译：使用电离辐射的合金纳米颗粒合成
公开(公告)号：US07998239B1
公开(公告)日：2011-08-16
申请号：US12620633
申请日：2009-11-18
申请人： Tina M. Nenoff , Dana A. Powers , Zhenyuan Zhang
发明人： Tina M. Nenoff , Dana A. Powers , Zhenyuan Zhang
IPC分类号： B22F9/24
CPC分类号： B22F9/24 , B22F1/0018 , B22F2999/00 , B82Y30/00 , B22F2202/11
摘要： A method of forming stable nanoparticles comprising substantially uniform alloys of metals. A high dose of ionizing radiation is used to generate high concentrations of solvated electrons and optionally radical reducing species that rapidly reduce a mixture of metal ion source species to form alloy nanoparticles. The method can make uniform alloy nanoparticles from normally immiscible metals by overcoming the thermodynamic limitations that would preferentially produce core-shell nanoparticles.
摘要翻译：形成稳定的纳米颗粒的方法，其包括基本上均匀的金属合金。高剂量的电离辐射用于产生高浓度的溶剂化电子和任选的自由基还原物质，其迅速减少金属离子源物质的混合物形成合金纳米颗粒。该方法可以通过克服优先产生核 - 壳纳米颗粒的热力学限制来制备来自正常不混溶金属的均匀合金纳米颗粒。

2. 发明授权

US06482380B1 Silicotitanate molecular sieve and condensed phases 有权
标题翻译：硅酸钛分子筛和冷凝相
公开(公告)号：US06482380B1
公开(公告)日：2002-11-19
申请号：US09717034
申请日：2000-11-22
申请人： Tina M. Nenoff , May D. Nyman
发明人： Tina M. Nenoff , May D. Nyman
IPC分类号： C01B3332
CPC分类号： G21F9/12 , B01J39/10 , B01J39/14 , C01B33/32 , C02F2101/006 , C02F2101/20
摘要： A new microporous crystalline molecular sieve material having the formula Cs3TiSi3O95•3H2O and its hydrothermally condensed phase, Cs2TiSi6O15, are disclosed. The microporous material can adsorb divalent ions of radionuclides or other industrial metals such as chromium, nickel, lead, copper, cobalt, zinc, cadmium, barium, and mercury, from aqueous or hydrocarbon solutions. The adsorbed metal ions can be leached out for recovery purposes or the microporous material can be hydrothermally condensed to a radiation resistant, structurally and chemically stable phase which can serve as a storage waste form for radionuclides.
摘要翻译：公开了具有式Cs 3 TiSi 3 O 95·3H 2 O及其水热缩相的新型微孔结晶分子筛材料Cs 2 TiSi 6 O 15。微孔材料可以从水溶液或烃溶液中吸附放射性核素或其他工业金属如铬，镍，铅，铜，钴，锌，镉，钡和汞的二价离子。吸附的金属离子可以被浸出以用于回收目的，或者微孔材料可以被水热冷凝成耐辐射，结构和化学稳定的相，其可以用作放射性核素的储存废物形式。

3. 发明授权

US07041616B1 Enhanced selectivity of zeolites by controlled carbon deposition 有权
标题翻译：通过控制碳沉积提高沸石的选择性
公开(公告)号：US07041616B1
公开(公告)日：2006-05-09
申请号：US10414184
申请日：2003-04-14
申请人： Tina M. Nenoff , Steven G. Thoma , Mutlu Kartin
发明人： Tina M. Nenoff , Steven G. Thoma , Mutlu Kartin
IPC分类号： B01J29/06
CPC分类号： B01J20/3408 , B01J20/186 , B01J20/28097 , B01J20/324 , B01J29/60 , B01J29/90 , B01J37/084 , C07C7/144 , Y02P20/584 , C07C9/14 , C07C9/18
摘要： A method for carbonizing a zeolite comprises depositing a carbon coating on the zeolite pores by flowing an inert carrier gas stream containing isoprene through a regenerated zeolite at elevated temperature. The carbonized zeolite is useful for the separation of light hydrocarbon mixtures due to size exclusion and the differential adsorption properties of the carbonized zeolite.
摘要翻译：用于碳化沸石的方法包括通过在高温下使含有异戊二烯的惰性载气流通过再生沸石使沉积碳沸石孔。碳化沸石可用于轻质烃混合物的分离，这是由于尺寸排除和碳化沸石的不同吸附特性。

4. 发明授权

US06596254B1 Niobate-based octahedral molecular sieves 有权
标题翻译：铌酸盐基八面体分子筛
公开(公告)号：US06596254B1
公开(公告)日：2003-07-22
申请号：US09876903
申请日：2001-06-08
申请人： Tina M. Nenoff , May D. Nyman
发明人： Tina M. Nenoff , May D. Nyman
IPC分类号： C01G3300
CPC分类号： C01B37/00 , C01G33/006 , C01P2002/34 , C01P2002/77 , C01P2002/88 , C01P2006/60
摘要： Niobate-based octahedral molecular sieves having significant activity for multivalent cations and a method for synthesizing such sieves are disclosed. The sieves have a net negatively charged octahedral framework, comprising niobium, oxygen, and octahedrally coordinated lower valence transition metals. The framework can be charge balanced by the occluded alkali cation from the synthesis method. The alkali cation can be exchanged for other contaminant metal ions. The ion-exchanged niobate-based octahedral molecular sieve can be backexchanged in acidic solutions to yield a solution concentrated in the contaminant metal. Alternatively, the ion-exchanged niobate-based octahedral molecular sieve can be thermally converted to a durable perovskite phase waste form.
摘要翻译：公开了对于多价阳离子具有显着活性的铌酸盐基八面体分子筛和合成这种筛子的方法。筛子具有净负电荷的八面体框架，其包含铌，氧和八面体配位的低价过渡金属。该框架可以通过合成方法的闭塞碱性阳离子进行电荷平衡。碱性阳离子可以交换为其他污染金属离子。离子交换的铌酸盐基八面体分子筛可以在酸性溶液中反向交换，产生浓缩在污染金属中的溶液。或者，离子交换的铌酸酯基八面体分子筛可以热转化为耐用的钙钛矿相废物形式。

5. 发明授权

US06494326B1 Composite zeolite membranes 有权
标题翻译：复合沸石膜
公开(公告)号：US06494326B1
公开(公告)日：2002-12-17
申请号：US09596205
申请日：2000-06-15
申请人： Tina M. Nenoff , Steven G. Thoma , Carol S. Ashley , Scott T. Reed
发明人： Tina M. Nenoff , Steven G. Thoma , Carol S. Ashley , Scott T. Reed
IPC分类号： B01D7102
CPC分类号： B01D69/12 , B01D69/141 , B01D71/028 , B01D2323/12 , B01D2325/10 , B01J2229/64
摘要： A new class of composite zeolite membranes and synthesis techniques therefor has been invented. These membranes are essentially defect-free, and exhibit large levels of transmembrane flux and of chemical and isotopic selectivity.
摘要翻译：已经发明了一类新型复合沸石膜及其合成技术。这些膜基本上是无缺陷的，并且表现出大量的跨膜通量和化学和同位素选择性。

6. 发明授权

US08383021B1 Mixed-layered bismuth-oxygen-iodine materials for capture and waste disposal of radioactive iodine 有权
标题翻译：用于捕获和废物处理放射性碘的混合铋 - 氧碘物质
公开(公告)号：US08383021B1
公开(公告)日：2013-02-26
申请号：US12617051
申请日：2009-11-12
申请人： James L. Krumhansl , Tina M. Nenoff
发明人： James L. Krumhansl , Tina M. Nenoff
IPC分类号： C09K11/04 , C09K3/00 , G21F9/00
CPC分类号： G21F9/008 , C01G29/00 , C01P2002/22 , C01P2002/72 , C01P2002/77 , C01P2004/03 , C01P2004/82 , G21F9/16
摘要： Materials and methods of synthesizing mixed-layered bismuth oxy-iodine materials, which can be synthesized in the presence of aqueous radioactive iodine species found in caustic solutions (e.g. NaOH or KOH). This technology provides a one-step process for both iodine sequestration and storage from nuclear fuel cycles. It results in materials that will be durable for repository conditions much like those found in Waste Isolation Pilot Plant (WIPP) and estimated for Yucca Mountain (YMP). By controlled reactant concentrations, optimized compositions of these mixed-layered bismuth oxy-iodine inorganic materials are produced that have both a high iodine weight percentage and a low solubility in groundwater environments.
摘要翻译：合成混合层状铋氧碘物质的材料和方法，其可以在苛性碱溶液（例如NaOH或KOH）中存在的含水放射性碘物质的存在下合成。该技术为核燃料循环的碘储存和储存提供了一个一步的过程。它产生的材料对于非常类似于废弃物隔离试验工厂（WIPP）和估计为丝兰山（YMP）的储存条件而言将是耐用的。通过控制反应物浓度，生产这些混合层状铋氧 - 碘无机材料的优化组合物，其具有高碘重量百分比和在地下水环境中的低溶解度。

7. 发明授权

US07566429B2 Catalytic reactive separation system for energy-efficient production of cumene 失效
标题翻译：催化反应分离系统，用于能量生产异丙苯
公开(公告)号：US07566429B2
公开(公告)日：2009-07-28
申请号：US11152997
申请日：2005-06-14
申请人： Genoveva Buelna , Tina M. Nenoff
发明人： Genoveva Buelna , Tina M. Nenoff
IPC分类号： B01J8/02 , C07C2/66
CPC分类号： B01D3/009 , B01J8/025 , B01J2208/00256 , B01J2208/00274 , B01J2208/00522 , B01J2219/30207 , B01J2219/30433 , C07C2/66 , Y02P20/127 , Y02P20/52 , Y02P20/57 , Y10S203/06 , C07C15/085
摘要： The present invention relates to an atmospheric pressure, reactive separation column packed with a solid acid zeolite catalyst for producing cumene from the reaction of benzene with propylene. Use of this un-pressurized column, where simultaneous reaction and partial separation occur during cumene production, allow separation of un-reacted, excess benzene from other products as they form. This high-yielding, energy-efficient system allows for one-step processing of cumene, with reduced need for product purification. Reacting propylene and benzene in the presence of beta zeolite catalysts generated a selectivity greater than 85% for catalytic separation reactions at a reaction temperature of 115 degrees C and at ambient pressure. Simultaneously, up to 76% of un-reacted benzene was separated from the product; which could be recycled back to the reactor for re-use.
摘要翻译：本发明涉及一种装有固体酸沸石催化剂的大气压反应性分离塔，用于从苯与丙烯反应制备异丙基苯。使用这种未加压的柱，其中在异丙基苯生产期间发生同时的反应和部分分离，允许在其形成时将未反应的过量苯与其它产物分离。这种高产能，高能效的系统可以对枯烯进行一步加工，减少对产品净化的需求。在β沸石催化剂存在下反应丙烯和苯，在115℃的反应温度和环境压力下，催化分离反应的选择性大于85％。同时，高达76％的未反应的苯与产物分离; 其可以被再循环回到反应器中以供重复使用。

8. 发明授权

US07119245B1 Synthesis of an un-supported, high-flow ZSM-22 zeolite membrane 有权
标题翻译：合成未支撑的高流动性ZSM-22沸石膜
公开(公告)号：US07119245B1
公开(公告)日：2006-10-10
申请号：US10280252
申请日：2002-10-25
申请人： Steven G. Thoma , Tina M. Nenoff
发明人： Steven G. Thoma , Tina M. Nenoff
IPC分类号： B01J21/00 , B01J29/00 , C07C7/00
CPC分类号： B01J29/7042 , B01D67/0046 , B01D67/0051 , B01D67/0076 , B01D67/0093 , B01D71/028 , B01D2323/08 , B01D2323/10 , B01D2323/12 , B01D2325/10 , B01J35/065 , B01J37/0009 , B01J2229/183 , C01B39/48 , C07C5/2708 , C07C2529/70 , C07C11/09
摘要： Novel methods for synthesizing wholly un-supported, high-flow catalytic membranes consisting of 100% crystalline ZSM-22 crystals with no binder phase, having sufficient porosity to allow high Weight Hourly Space Velocities of feedstock to pass through without generating back pressure. The ZSM-22 membranes perform favorably to existing bulk ZSM-22 catalysts (e.g., via 1-butene conversion and selectivity). The method of membrane synthesis, based on Vapor Phase Transport, allows free-standing, binder-less membranes to be fabricated in varied geometries and sizes so that membranes can be tailor-made for particular geometries applications. The ZSM-22 precursor gel may be consolidated into a semi-cohesive body prior to vapor phase crystallization, for example, by uniaxial pressing. These crystalline membranes may be modified by ion exchange, pore ion exchange, framework exchange, synthesis modification techniques to incorporate other elements into the framework, such as K, H, Mg, Zn, V, Ga, and Pt.
摘要翻译：用于合成完全不支撑的高流动催化膜的新方法，该膜由100％不含粘结相的ZSM-22晶体组成，具有足够的孔隙率，以允许原料的高重量小时空间速度通过而不产生背压。 ZSM-22膜对现有的体积ZSM-22催化剂（例如通过1-丁烯转化和选择性）有利地起作用。基于蒸气相运输的膜合成方法允许以不同的几何尺寸和尺寸制造独立的无粘合剂膜，以便可以针对特定几何应用定制膜。 ZSM-22前体凝胶可以在气相结晶之前固化成半凝聚体，例如通过单轴压制。这些结晶膜可以通过离子交换，孔离子交换，框架交换，合成修饰技术来修饰，以将其它元素掺入框架中，例如K，H，Mg，Zn，V，Ga和Pt。

9. 发明授权

US08262950B1 Low sintering temperature glass waste forms for sequestering radioactive iodine 有权
标题翻译：低烧结温度玻璃废物形式用于隔离放射性碘
公开(公告)号：US08262950B1
公开(公告)日：2012-09-11
申请号：US12727353
申请日：2010-03-19
申请人： Tina M. Nenoff , James L. Krumhansl , Terry J. Garino , Nathan W. Ockwig
发明人： Tina M. Nenoff , James L. Krumhansl , Terry J. Garino , Nathan W. Ockwig
IPC分类号： C09K11/04 , C09K3/00 , G21F9/00
CPC分类号： G21F9/305 , C03C14/004 , C03C2214/14 , C03C2214/34 , C09K11/04
摘要： Materials and methods of making low-sintering-temperature glass waste forms that sequester radioactive iodine in a strong and durable structure. First, the iodine is captured by an adsorbant, which forms an iodine-loaded material, e.g., AgI, AgI-zeolite, AgI-mordenite, Ag-silica aerogel, ZnI2, CuI, or Bi5O7I. Next, particles of the iodine-loaded material are mixed with powdered frits of low-sintering-temperature glasses (comprising various oxides of Si, B, Bi, Pb, and Zn), and then sintered at a relatively low temperature, ranging from 425° C. to 550° C. The sintering converts the mixed powders into a solid block of a glassy waste form, having low iodine leaching rates. The vitrified glassy waste form can contain as much as 60 wt % AgI. A preferred glass, having a sintering temperature of 500° C. (below the silver iodide sublimation temperature of 500° C.) was identified that contains oxides of boron, bismuth, and zinc, while containing essentially no lead or silicon.
摘要翻译：制造低烧结温度玻璃废物的材料和方法形成了强大耐用的结构中的放射性碘。首先，碘被吸附剂捕获，该吸附剂形成碘负载材料，例如AgI，AgI-沸石，Ag1-丝光沸石，Ag-二氧化硅气凝胶，ZnI 2，CuI或Bi 5 O 7。接下来，将负载碘的材料的颗粒与低烧结温度玻璃（包括各种Si，B，Bi，Pb和Zn的氧化物）的粉状玻璃料混合，然后在比较低的温度下从425 ℃至550℃。烧结将混合粉末转化为具有低碘浸出速率的玻璃状废物形式的固体块。玻璃化玻璃废物形式可含有多达60重量％的AgI。确定了烧结温度为500℃（低于碘化银升华温度为500℃）的玻璃，其含有硼，铋和锌的氧化物，同时基本上不含铅或硅。

10. 发明授权

US07122164B2 Niobate-based octahedral molecular sieves 有权
公开(公告)号：US07122164B2
公开(公告)日：2006-10-17
申请号：US10427249
申请日：2003-05-01
申请人： Tina M. Nenoff , May D. Nyman
发明人： Tina M. Nenoff , May D. Nyman
IPC分类号： C22B59/00 , C22B26/00 , C22B13/00 , C22B19/00 , C22B17/00 , C22B23/00 , C22B34/00
CPC分类号： C01B37/00 , C01G33/006 , C01P2002/34 , C01P2002/77 , C01P2002/88 , C01P2006/60
摘要： Niobate-based octahedral molecular sieves having significant activity for multivalent cations and a method for synthesizing such sieves are disclosed. The sieves have a net negatively charged octahedral framework, comprising niobium, oxygen, and octahedrally coordinated lower valence transition metals. The framework can be charge balanced by the occluded alkali cation from the synthesis method. The alkali cation can be exchanged for other contaminant metal ions. The ion-exchanged niobate-based octahedral molecular sieve can be backexchanged in acidic solutions to yield a solution concentrated in the contaminant metal. Alternatively, the ion-exchanged niobate-based octahedral molecular sieve can be thermally converted to a durable perovskite phase waste form.

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