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1. 发明授权

US08148312B2 Method of treating a substrate with stable bleaches with coloring agents 有权
标题翻译：用着色剂处理具有稳定漂白剂的底物的方法
公开(公告)号：US08148312B2
公开(公告)日：2012-04-03
申请号：US13237817
申请日：2011-09-20
申请人： Thomas W. Kaaret , Darin K. Griffith , Klein A. Rodrigues , William L. Smith
发明人： Thomas W. Kaaret , Darin K. Griffith , Klein A. Rodrigues , William L. Smith
IPC分类号： C11D3/02 , C11D3/37
CPC分类号： C08F2/18 , C08F8/44 , C08F212/08 , C08F220/06 , C08F2800/20 , C11D3/3757 , C11D3/3765 , C11D3/3956 , C11D3/42 , C08F2/44
摘要： The invention provides an aqueous bleaching solution for substrate treatment comprising a source of oxidant and a suspended polymer matrix having a plurality of optically functional particles associated with one or more copolymers present in the polymer matrix. The plurality of optically functional particles are associated with the copolymer during polymerization of at least one hydrophobic and at least one hydrophilic monomer so as to form a polymer matrix useful to impart an aqueous bleaching solution with optically functional properties providing a benefit to the solutions during storage, use and application to substrates for treatment. In accordance with various embodiments of the invention, the suspended polymer matrix forms a substantially stable dispersion of the optically functional particles in the aqueous bleaching solution, and provides compositions, methods and kits for employing aqueous bleaching solutions having optically functional properties that are maintained over substantially long storage times.
摘要翻译：本发明提供了用于底物处理的水性漂白溶液，其包括氧化剂源和悬浮聚合物基质，其具有与存在于聚合物基质中的一种或多种共聚物相关联的多个光学功能性颗粒。在至少一种疏水性和至少一种亲水性单体的聚合过程中，多种光学功能性颗粒与共聚物相关联，以便形成聚合物基质，其可用于赋予具有光学功能性质的水性漂白溶液以提供储存期间的溶液的益处，使用和应用于底物进行治疗。根据本发明的各种实施方案，悬浮聚合物基质形成水性漂白溶液中的光学功能性颗粒的基本上稳定的分散体，并且提供了使用具有光学功能特性的水性漂白溶液的组合物，方法和试剂盒，长存储时间。

2. 发明申请

US20080221005A1 Stable Bleaches With Coloring Agents 有权
标题翻译：稳定的漂白剂与着色剂
公开(公告)号：US20080221005A1
公开(公告)日：2008-09-11
申请号：US12013576
申请日：2008-01-14
申请人： Thomas W. Kaaret , Darin K. Griffith , Klein A. Rodrigues , William L. Smith
发明人： Thomas W. Kaaret , Darin K. Griffith , Klein A. Rodrigues , William L. Smith
IPC分类号： C11D3/02 , C11D3/37
CPC分类号： C08F2/18 , C08F8/44 , C08F212/08 , C08F220/06 , C08F2800/20 , C11D3/3757 , C11D3/3765 , C11D3/3956 , C11D3/42 , C08F2/44
摘要： The invention provides an aqueous bleaching solution for substrate treatment comprising a source of oxidant and a suspended polymer matrix having a plurality of optically functional particles associated with one or more copolymers present in the polymer matrix. The plurality of optically functional particles are associated with the copolymer during polymerization of at least one hydrophobic and at least one hydrophilic monomer so as to form a polymer matrix useful to impart an aqueous bleaching solution with optically functional properties providing a benefit to the solutions during storage, use and application to substrates for treatment. In accordance with various embodiments of the invention, the suspended polymer matrix forms a substantially stable dispersion of the optically functional particles in the aqueous bleaching solution, and provides compositions, methods and kits for employing aqueous bleaching solutions having optically functional properties that are maintained over substantially long storage times.
摘要翻译：本发明提供了用于底物处理的水性漂白溶液，其包括氧化剂源和悬浮聚合物基质，其具有与存在于聚合物基质中的一种或多种共聚物相关联的多个光学功能性颗粒。在至少一种疏水性和至少一种亲水性单体的聚合过程中，多种光学功能性颗粒与共聚物相关联，以便形成聚合物基质，其可用于赋予具有光学功能性质的水性漂白溶液以提供储存期间的溶液的益处，使用和应用于底物进行治疗。根据本发明的各种实施方案，悬浮聚合物基质形成水性漂白溶液中的光学功能性颗粒的基本上稳定的分散体，并且提供了使用具有光学功能特性的水性漂白溶液的组合物，方法和试剂盒，长存储时间。

3. 发明授权

US5792218A N-alkyl ammonium acetonitrile activators in dense gas cleaning and method 失效
标题翻译： N-烷基铵乙腈活化剂在致密气体清洗和方法中
公开(公告)号：US5792218A
公开(公告)日：1998-08-11
申请号：US758541
申请日：1996-11-29
申请人： Vincent E. Alvarez , James W. Arbogast , James E. Deline , Lafayette D. Foland , Thomas W. Kaaret , Kevin A. Klotter , Michael J. Petrin , William L. Smith , Alfred G. Zielske , James D. Mitchell
发明人： Vincent E. Alvarez , James W. Arbogast , James E. Deline , Lafayette D. Foland , Thomas W. Kaaret , Kevin A. Klotter , Michael J. Petrin , William L. Smith , Alfred G. Zielske , James D. Mitchell
IPC分类号： C07D295/14 , C01B13/02 , C07D295/02 , C07D295/15 , C11D1/62 , C11D3/28 , C11D3/386 , C11D3/39 , C11D3/395 , C11D3/42 , C11D7/54 , C11D17/00 , D06L3/02 , H04B7/06 , C01B15/00
CPC分类号： C07D295/15 , C11D3/02 , C11D3/3925 , C11D3/3947 , D06L3/021 , D06L3/026
摘要： Nitrile activators, such as N-alkyl ammonium acetonitrile activators, are combined with a source of active oxygen as cleaning and bleaching compositions. Preferred activator embodiments of the invention include salts of N-methyl morpholinium acetonitrile, N-butyl morpholinium acetonitrile, N-hexyl morpholinium acetonitrile, and N-octyl morpholinium acetonitrile. A particularly preferred activator embodiment is an N-methyl morpholinium acetonitrile salt. The nitrile and active oxygen react to form a bleaching agent which is applied to a stain on an article. The treated stain is contacted with dense gas so as to provide substantially non-aqueous stain removal. One embodiment is a composition in which the nitrile and active oxygen are disposed in the dense carbon dioxide.
摘要翻译：腈活化剂如N-烷基铵乙腈活化剂与活性氧源一起作为清洁和漂白组合物。本发明优选的活化剂实例包括N-甲基吗啉鎓乙腈，N-丁基吗啉鎓乙腈，N-己基吗啉鎓乙腈和N-辛基吗啉鎓乙腈的盐。特别优选的活化剂实施方案是N-甲基吗啉乙腈盐。腈和活性氧反应形成漂白剂，将其用于制品上的污渍。处理的污渍与致密气体接触，以提供基本上非水性污渍去除。一个实施方案是其中将腈和活性氧设置在致密二氧化碳中的组合物。

4. 发明授权

US08642527B2 Oxidizing bleach composition 有权
标题翻译：氧化漂白剂组合物
公开(公告)号：US08642527B2
公开(公告)日：2014-02-04
申请号：US11764621
申请日：2007-06-18
申请人： Gregory van Buskirk , Scott Cumberland , Thomas W. Kaaret , William L. Smith
发明人： Gregory van Buskirk , Scott Cumberland , Thomas W. Kaaret , William L. Smith
IPC分类号： C11D7/60
CPC分类号： C11D3/3953 , A01N59/00 , B82Y30/00 , C11D3/1213 , C11D3/3956 , C11D7/20 , C11D11/0047 , C11D17/06
摘要： The invention provides an aqueous bleaching solution for substrate treatment. The aqueous bleaching solution features a source of oxidant and a plurality of optically functional nanoparticles. The optically functional nanoparticles are nanoparticles in the range of about 0.1 nanometers to about 400 nanometers in size. The aqueous bleaching solution may optionally include one or more an oxidant-stable surfactants and optionally, one or more oxidant-stable polymers, and adjuncts. The optically functional nanoparticles are extremely stable in the aqueous bleaching solution and remain substantially suspended in the aqueous bleaching solution due to their extremely small size despite having an average density greater than that of the bleaching solution. The optically functional nanoparticles provide at least one optical functional benefit to the bleaching solution owing to their uniform and stable suspension throughout the solution, including such benefits as uniform light absorption, light and radiation scattering, fluorescent emission, phosphorescent emission, coloration, and visual aesthetic benefits and the like. Further, optically functional benefits include those benefits provided to a substrate or surface treated with the aqueous bleaching solutions whereby the optically functional property is transferred either temporarily or permanently to the substrate or surface following contact with bleaching solutions containing the optically functional nanoparticles.
摘要翻译：本发明提供了用于底物处理的水性漂白溶液。含水漂白溶液具有氧化剂源和多个光学功能纳米颗粒。光学功能纳米颗粒是尺寸在约0.1纳米至约400纳米范围内的纳米颗粒。含水漂白溶液可以任选地包括一种或多种氧化剂稳定的表面活性剂和任选的一种或多种氧化剂稳定的聚合物和助剂。光学功能性纳米粒子在水性漂白溶液中非常稳定，并且由于其极小的尺寸而保持基本上悬浮在含水漂白溶液中，尽管其平均密度大于漂白溶液的平均密度。光学功能纳米颗粒由于其在整个溶液中均匀稳定的悬浮液而对漂白溶液提供至少一种光学功能有益效果，包括均匀的光吸收，光和辐射散射，荧光发射，磷光发射，着色和视觉美学等优点利益等。此外，光学功能优点包括提供给用水性漂白溶液处理的底物或表面的那些益处，由此在与含有光学功能纳米颗粒的漂白溶液接触之后光学功能性质暂时或永久地转移到基底或表面。

5. 发明授权

US06297209B1 Sequesterants as hypochlorite bleach enhancers 失效
标题翻译：螯合剂作为次氯酸盐漂白剂增强剂
公开(公告)号：US06297209B1
公开(公告)日：2001-10-02
申请号：US08642981
申请日：1996-05-10
申请人： Thomas W. Kaaret , William L. Smith
发明人： Thomas W. Kaaret , William L. Smith
IPC分类号： C11D3395
CPC分类号： C11D3/3956 , C11D3/3765
摘要： Sequestering agents for use as a whitening and fabric strength enhancer for aqueous hypochlorite bleach compositions are provided. It was found that the sequesterants when used with hypochlorite in the presence of soluble heavy metal ions, particularly iron and manganese ions, provide significantly improved whitening and fabric protection. Most preferably, the sequesterants are selected from polyacrylic acid, a polyacrylic acid derivative, a copolymer of acrylic acid or methacrylic acid and a comonomer which is maleic acid or maleic anhydride and mixtures thereof. In one aspect, the sequesterants are employed in a method for laundering fabrics comprising: a) providing, in a wash liquor containing (i) at least about 40 ppb of iron cations or (ii) at least about 10 ppb of manganese cations, or (iii) the cations of both (i) and (ii), and a fabric piece; and b) adding either prior to, contemporaneously with, or after, the step of providing of said fabric piece to said wash liquor a hypochlorite composition which comprises one or more of said sequesterants. Preferably the sequesterant comprises at least 0.1 ppm by weight of said wash liquor and the hypochlorite composition is an alkali metal hypochlorite and said sequesterant has a molecular weight of between about 500 and 500,000 daltons.
摘要翻译：提供了用作次氯酸盐漂白剂组合物的增白剂和织物强度增强剂的螯合剂。已发现，在可溶性重金属离子，特别是铁和锰离子存在下，与次氯酸盐一起使用时，螯合剂可显着改善美白和织物保护。最优选地，螯合剂选自聚丙烯酸，聚丙烯酸衍生物，丙烯酸或甲基丙烯酸的共聚物和作为马来酸或马来酸酐的共聚单体及其混合物。一方面，螯合剂用于洗涤织物的方法中，包括：a）在含有（i）至少约40ppb的铁阳离子或（ii）至少约10ppb的锰阳离子的洗涤液中，或（iii）（i）和（ii）两者的阳离子和织物片; 和b）在向所述洗涤液提供包含一种或多种所述螯合剂的次氯酸盐组合物的步骤之前，同时或之后加入所述织物片的步骤。优选地，螯合剂包含至少0.1ppm重量的所述洗涤液，次氯酸盐组合物是碱金属次氯酸盐，所述螯合剂的分子量为约500至500,000道尔顿。

6. 发明授权

US5959104A N-alkyl ammonium acetonitrile bleach activators 失效
公开(公告)号：US5959104A
公开(公告)日：1999-09-28
申请号：US59607
申请日：1998-04-13
申请人： James W. Arbogast , James E. Deline , Lafayette D. Foland , Thomas W. Kaaret , Kevin A. Klotter , Michael J. Petrin , William L. Smith , Alfred G. Zielske
发明人： James W. Arbogast , James E. Deline , Lafayette D. Foland , Thomas W. Kaaret , Kevin A. Klotter , Michael J. Petrin , William L. Smith , Alfred G. Zielske
IPC分类号： C07D295/14 , C07D295/15 , C11D3/386 , C11D3/39 , C11D3/395 , C11D3/42 , C11D7/54 , D06L3/02 , H04B7/06 , C07D265/30 , C07D295/00 , C09K3/00
CPC分类号： C07D295/15 , C11D3/38618 , C11D3/3925 , C11D3/3947 , C11D3/42 , D06L3/021 , D06L3/026 , H04B7/0619
摘要： Bleaching compositions are provided that comprise a nitrile containing compound that has the nitrile bonded to a quaternary nitrogen through a methylene unit (where one or both of the normal hydrogens can be substituted), and two of the quaternary nitrogen bonds are part of a saturated ring. This saturated ring contains from two to eight atoms in addition to the quaternary nitrogen. A source of active oxygen will react with the nitrile for bleaching applications. Particularly preferred nitrile containing compounds are N-alkyl morpholinium acetonitrile salts.

7. 发明授权

US5888419A Granular N-alkyl ammonium acetontrile compositions 失效
标题翻译：颗粒状N-烷基铵乙腈组合物
公开(公告)号：US5888419A
公开(公告)日：1999-03-30
申请号：US758539
申请日：1996-11-29
申请人： Victor M. Casella , Ulrich Brockel , Clement K. Choy , James E. Deline , Lafayette D. Foland , Susan P. Huestis , Kevin A. Klotter , Sarah A. Perkins , David Peterson , Michael J. Petrin , Martin J. Phillippi , William P. Sibert , Michael Schonherr , Hans Peter Seelmann-Eggebert , William L. Smith , Alfred G. Zielske , Thomas W. Kaaret
发明人： Victor M. Casella , Ulrich Brockel , Clement K. Choy , James E. Deline , Lafayette D. Foland , Susan P. Huestis , Kevin A. Klotter , Sarah A. Perkins , David Peterson , Michael J. Petrin , Martin J. Phillippi , William P. Sibert , Michael Schonherr , Hans Peter Seelmann-Eggebert , William L. Smith , Alfred G. Zielske , Thomas W. Kaaret
IPC分类号： C07D295/14 , C07D295/15 , C11D3/12 , C11D3/28 , C11D3/386 , C11D3/39 , C11D3/395 , C11D3/42 , C11D7/54 , C11D17/06 , D06L3/02 , H04B7/06 , C09K3/00 , B27N5/00 , C01B15/10
CPC分类号： C07D295/15 , C11D17/06 , C11D3/3925 , C11D3/3935 , D06L3/021 , D06L3/026
摘要： Granules are provided that are useful for oxidizing applications when the granules are dissolved in the presence of an active oxygen source. These granules include a salt having the structure of Formula I ##STR1## wherein A is a saturated ring formed by a plurality of atoms in addition to the N.sub.1 atom, the saturated ring atoms including at least one carbon atom and at least one of O, S, and N atoms, the substituent R.sub.1 bound to the N.sub.1 atom of the Formula I structure including either (a) a C.sub.1-24 alkyl or alkoxylated alkyl where the alkoxy is C.sub.2-4, (b) a C.sub.4-24 cycloalkyl, (c) a C.sub.7-24 alkaryl, (d) a repeating or nonrepeating alkoxy or alkoxylated alcohol, where the alkoxy unit is C.sub.2-4, or (e) --CR.sub.2 R.sub.3 C.tbd.N where R.sub.2 and R.sub.3 are each H, a C.sub.1-24 alkyl, cycloalkyl, or alkaryl, or a repeating or nonrepeating alkoxyl or alkoxylated alcohol where the alkoxy unit is C.sub.2-4, the R.sub.2 and R.sub.3 substituents being each H, a C.sub.1-24 alkyl, cycloalkyl, or alkaryl, or a repeating or nonrepeating alkoxyl or alkoxylated alcohol where the alkoxy unit is C.sub.2-4, Z is in the range of 0 to 10, and wherein Y is a counterion. The salt is carried by, coated with, or admixed with a solid particulate such as silica gel, silicic acid, silicate, aluminum oxide, clay, aluminum silicate, or mixtures thereof.
摘要翻译：当颗粒在活性氧源的存在下溶解时，提供可用于氧化应用的颗粒。这些颗粒包括具有式I结构的盐，其中A是除N1原子之外由多个原子形成的饱和环，饱和环原子包括至少一个碳原子和至少一个碳原子 O，S和N原子，与式I结构的N1原子结合的取代基R1包括（a）C1-24烷基或烷氧基为烷氧基的烷基，其中烷氧基为C2-4，（b）C4-24环烷基，（c）C7-24烷芳基，（d）重复或非重复烷氧基或烷氧基化醇，其中烷氧基单元为C 2-4，或（e）-CR 2 R 3 C 3 N N其中R 2和R 3各自为H， 24烷基，环烷基或烷芳基，或重复或非重复烷氧基或烷氧基化醇，其中烷氧基单元为C 2-4，R 2和R 3取代基各为H，C 1-4烷基，环烷基或烷芳基，或重复或非重复烷氧基或烷氧基化醇，其中烷氧基单元为C 2-4，Z在0至10的范围内，并且其中Y为抗衡离子。盐与硅胶，硅酸，硅酸盐，氧化铝，粘土，硅酸铝或其混合物等固体颗粒携带，涂覆或混合。

8. 发明申请

US20120009279A1 METHOD OF TREATING A SUBSTRATE WITH STABLE BLEACHES WITH COLORING AGENTS 有权
标题翻译：用着色剂处理具有稳定漂白剂的基材的方法
公开(公告)号：US20120009279A1
公开(公告)日：2012-01-12
申请号：US13237817
申请日：2011-09-20
申请人： Thomas W. Kaaret , Darin K. Griffith , Klein A. Rodrigues , William L. Smith
发明人： Thomas W. Kaaret , Darin K. Griffith , Klein A. Rodrigues , William L. Smith
IPC分类号： D06L3/08 , A01N59/00 , A01P1/00 , A61L2/18 , B08B3/00 , D06L1/16 , C11D3/60 , B82Y99/00
CPC分类号： C08F2/18 , C08F8/44 , C08F212/08 , C08F220/06 , C08F2800/20 , C11D3/3757 , C11D3/3765 , C11D3/3956 , C11D3/42 , C08F2/44
摘要： The invention provides an aqueous bleaching solution for substrate treatment comprising a source of oxidant and a suspended polymer matrix having a plurality of optically functional particles associated with one or more copolymers present in the polymer matrix. The plurality of optically functional particles are associated with the copolymer during polymerization of at least one hydrophobic and at least one hydrophilic monomer so as to form a polymer matrix useful to impart an aqueous bleaching solution with optically functional properties providing a benefit to the solutions during storage, use and application to substrates for treatment. In accordance with various embodiments of the invention, the suspended polymer matrix forms a substantially stable dispersion of the optically functional particles in the aqueous bleaching solution, and provides compositions, methods and kits for employing aqueous bleaching solutions having optically functional properties that are maintained over substantially long storage times.
摘要翻译：本发明提供了用于底物处理的水性漂白溶液，其包括氧化剂源和悬浮聚合物基质，其具有与存在于聚合物基质中的一种或多种共聚物相关联的多个光学功能性颗粒。在至少一种疏水性和至少一种亲水性单体的聚合过程中，多种光学功能性颗粒与共聚物相关联，以便形成聚合物基质，其可用于赋予具有光学功能性质的水性漂白溶液以提供储存期间的溶液的益处，使用和应用于底物进行治疗。根据本发明的各种实施方案，悬浮聚合物基质形成水性漂白溶液中的光学功能性颗粒的基本上稳定的分散体，并且提供了使用具有光学功能特性的水性漂白溶液的组合物，方法和试剂盒，长存储时间。

9. 发明授权

US07008600B2 Disinfecting article and cleaning composition with extended stability 有权
标题翻译：具有延长稳定性的消毒品和清洁剂组合物
公开(公告)号：US07008600B2
公开(公告)日：2006-03-07
申请号：US10870093
申请日：2004-06-16
申请人： George Katsigras , Surinder Bains , Lily Cheng , Thomas W. Kaaret , William L. Smith
发明人： George Katsigras , Surinder Bains , Lily Cheng , Thomas W. Kaaret , William L. Smith
IPC分类号： A61L2/00 , A01N59/08
CPC分类号： A61L2/238 , A01N59/00 , A61L2/18 , A61L2/232 , A61L2/26 , A61L2202/182 , A61L2202/26 , B08B1/00 , C11D3/3956 , C11D3/48 , C11D17/049 , Y10T428/24826 , A01N25/34 , A01N25/10 , A01N2300/00
摘要： The present invention relates to a disinfecting article, a sealable housing system for disinfecting articles, and a disinfecting composition comprising a hypohalite composition and a surfactant, for cleaning and disinfecting surfaces, with improved stability and extended efficacy for cleaning and disinfecting surfaces with residues such as foods, dirt, microorganisms and many other common contaminates. The disinfecting article is preferably a wipe that is comprised of high denier fibers and stored in a sealable housing system to ensure the stability of the substrate in the hypohalite releasing solution.
摘要翻译：本发明涉及消毒制品，用于消毒制品的可密封外壳系统，以及包含次卤酸盐组合物和表面活性剂的消毒组合物，用于清洁和消毒表面，具有改进的稳定性和延长的清洁和消毒表面的功效，其中残留物例如食物，污垢，微生物和许多其他常见污染物。消毒制品优选是由高旦数纤维构成的擦拭物并且存储在可密封的外壳系统中，以确保底物在次卤酸盐释放溶液中的稳定性。

10. 发明授权

US5741437A N-alkyl ammonium acetonitrile bleach activators 失效
公开(公告)号：US5741437A
公开(公告)日：1998-04-21
申请号：US720602
申请日：1996-10-01
申请人： James W. Arbogast , James E. Deline , Lafayette D. Foland , Thomas W. Kaaret , Kevin A. Klotter , Michael J. Petrin , William L. Smith , Alfred G. Zielske
发明人： James W. Arbogast , James E. Deline , Lafayette D. Foland , Thomas W. Kaaret , Kevin A. Klotter , Michael J. Petrin , William L. Smith , Alfred G. Zielske
IPC分类号： C07D295/14 , C07D295/15 , C11D3/386 , C11D3/39 , C11D3/395 , C11D3/42 , C11D7/54 , D06L3/02 , H04B7/06 , C09K3/00 , C01B15/10
CPC分类号： C07D295/15 , C11D3/38618 , C11D3/3925 , C11D3/3947 , C11D3/42 , D06L3/021 , D06L3/026 , H04B7/0619
摘要： Bleaching compositions are provided that comprise a nitrile containing compound that has the nitrile bonded to a quaternary nitrogen through a methylene unit (where one or both of the normal hydrogens can be substituted), and two of the quaternary nitrogen bonds are part of a saturated ring. This saturated ring contains from two to eight atoms in addition to the quaternary nitrogen. A source of active oxygen will react with the nitrile for bleaching applications. Particularly preferred nitrile containing compounds are N-alkyl morpholinium acetonitrile salts.

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