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1. 发明授权

US6046130A Catalyst and side-chain alkylation therewith 失效
标题翻译：催化剂和侧链烷基化
公开(公告)号：US6046130A
公开(公告)日：2000-04-04
申请号：US55673
申请日：1998-04-07
申请人： Thomas Narbeshuber , Georg Heinrich Grosch , Michael Trefzer , Eugen Gehrer , Michael Baier
发明人： Thomas Narbeshuber , Georg Heinrich Grosch , Michael Trefzer , Eugen Gehrer , Michael Baier
IPC分类号： B01J23/04 , B01J23/00 , B01J23/02 , B01J23/78 , B01J23/80 , B01J23/835 , B01J23/86 , B01J27/045 , B01J27/051 , B01J27/08 , C07B61/00 , C07C2/66 , C07C2/72 , C07C15/02 , B01J23/40 , B01J23/58 , B01J23/72
CPC分类号： B01J23/02 , B01J23/005 , C07C2/72 , C07C2523/04 , C07C2527/02 , C07C2527/057 , C07C2527/06 , Y10S502/524
摘要： The catalyst comprising at least one alkali metal on a spinel or inverse spinel as carrier may be doped with at least one compound of an alkali metal and/or alkaline earth metal, where the alkali metal/carrier ratio by weight is from 0.01 to 5 and, when a dopant is present, the dopant/carrier ratio by weight is from 0.01 to 5.The spinel therein has formula (I) and the inverse spinel has formula (II)AB.sub.2 X.sub.4 (I)B(AB)X.sub.4 (II)whereA is divalent metal,B is tri- or tetravalent metal,X is O, S, Se, halogen, pseudohalogen,the charges being balanced, and A preferably being selected from Mg, Cr, Fe, Zn, Mn, Co, Ni, Cu, Cd, Sn and mixtures thereof, and B being selected from Al, Ga, In, Fe, V, Cr, Ti, Pb, Mn, Co, Rh, Ni, Si and mixtures thereof, and X being O.
摘要翻译：包含在尖晶石或反尖晶石上的至少一种碱金属作为载体的催化剂可以掺杂有至少一种碱金属和/或碱土金属的化合物，其中碱金属/载体的重量比为0.01-5，和当掺杂剂存在时，掺杂剂/载体的重量比为0.01至5.其中尖晶石具有式（I），并且反尖晶石具有式（II）AB2X4（I）B（AB）X4（II）其中 A是二价金属，B是三价或四价金属，X是O，S，Se，卤素，假卤素，电荷平衡，A优选选自Mg，Cr，Fe，Zn，Mn，Co，Ni， Cu，Cd，Sn及其混合物，B选自Al，Ga，In，Fe，V，Cr，Ti，Pb，Mn，Co，Rh，Ni，Si及其混合物，X为O.

2. 发明授权

US06043189A Catalyst for side-chain alkylation 失效
标题翻译：侧链烷基化催化剂
公开(公告)号：US06043189A
公开(公告)日：2000-03-28
申请号：US151811
申请日：1998-09-14
申请人： Thomas Narbeshuber , Michael Trefzer , Eugen Gehrer
发明人： Thomas Narbeshuber , Michael Trefzer , Eugen Gehrer
IPC分类号： B01J23/04 , C07C2/54 , C07C2/72 , C07C5/25 , B01J23/02
CPC分类号： C07C2/72 , B01J23/04 , C07C2/54 , C07C5/2556 , C07C2521/06 , C07C2521/10 , C07C2523/04
摘要： The catalyst comprises at least one alkali metal on a doped carrier, where the doped carrier can be prepared from at least one zirconium and/or alkaline earth metal compound as carrier and at least one alkali metal compound as dopant and calcining the doped carrier at 350.degree. C. or below, the alkali metal/carrier ratio by weight being from 0.01 to 5 and the dopant/carrier ratio by weight being from 0.01 to 5.
摘要翻译：催化剂包含至少一种掺杂载体上的碱金属，其中掺杂载体可以由至少一种锆和/或碱土金属化合物作为载体和至少一种碱金属化合物作为掺杂剂制备，并在350℃煅烧掺杂载体 ℃以下，碱金属/载体比例为0.01〜5，掺杂剂/载体比例为0.01〜5。

3. 发明授权

US06303833B1 Multi-metal cyanide complexes as catalysts and their use in preparing polyetherpolyols 有权
标题翻译：多金属氰化物络合物作为催化剂及其在制备聚醚多元醇中的应用
公开(公告)号：US06303833B1
公开(公告)日：2001-10-16
申请号：US09509515
申请日：2000-03-29
申请人： Georg Heinrich Grosch , Harald Larbig , Reinhard Lorenz , Dieter Junge , Eugen Gehrer , Ulrich Treuling
发明人： Georg Heinrich Grosch , Harald Larbig , Reinhard Lorenz , Dieter Junge , Eugen Gehrer , Ulrich Treuling
IPC分类号： C07C4311
CPC分类号： B01J27/26 , C08G65/2663
摘要： A crystalline multimetal cyanide complex of the formula (I) M1a[M2(CN)bL1c]d*e(M1fXg)*hL2′iH2O (I) where M1 is at least one element from the group consisting of Zn(II), Fe(II), Co(III), Ni(II), Mn(II), Co(II), Sn(II). Pb(II), Fe(III), Mo(IV), Mo(VI), Al(III), V(IV), V(V), Sr(II, W(IV), W(VI), Cu(II), and Cr(III), M2 is at least one element from the group consisting of Fe(II), Fe(III), Co(III), Cr(III), Mn(II), Mn(III), Ir(III), Rh(III), Ru(II), V(IV), V(V), Co(II) and Cr(II), L1 is at least one ligand from the group consisting of cyanide, carbonyl, cyanate, isocyanate, nitrile, thiocyanate and nitrosyl, X is a formate anion, an acetate anion or propionate anion, L2 is at least one water-miscible ligand from the group consisting of alcohols, aldehydes, ketones, ethers, polyethers, esters, urea derivatives, amides, nitriles and sulfides, a, b, c, d, e, f, g, h, i are integers, with a, b, c and d being chosen so that the electrical neutrality condition is satisfied, and f and g being chosen so that the electrical neutrality condition is satisfied, the X-ray diffiactogram of which shows reflections at particular d values, can be employed as catalyst.
摘要翻译：式（I）的结晶多金属氰化物络合物，其中M 1是由Zn（II），Fe（II），Co（III），Ni（II），Mn（II），Co（II）组成的组中的至少一种元素），Sn（II）。 Pb（II），Fe（III），Mo（IV），Mo（VI），Al（III），V（IV），V（V）（II），Fe（Ⅲ），Co（Ⅲ），Cr（Ⅲ），Mn（Ⅱ），Mn（Ⅲ）等元素中的至少一种元素，，Ir（III），Rh（III），Ru（II），V（IV），V（V），Co（II）和Cr（II），L1是至少一种由氰化物，羰基，氰酸酯，异氰酸酯，腈，硫氰酸酯和亚硝酰基，X是甲酸根阴离子，乙酸根阴离子或丙酸根阴离子，L2是至少一种与醇，醛，酮，醚，聚醚，酯，尿素衍生物，酰胺，腈和硫化物，a，b，c，d，e，f，g，h，i是整数，其中选择a，b，c和d，使得满足电中性条件，被选择为使得电中性条件满足，其X射线衍射图示出特定d值的反射可用作催化剂。

4. 发明授权

US06384154B1 Preparation of halogen-free, reactive polyisobutene 失效
标题翻译：无卤素，反应性聚异丁烯的制备
公开(公告)号：US06384154B1
公开(公告)日：2002-05-07
申请号：US09744256
申请日：2001-01-31
申请人： Christoph Sigwart , Thomas Narbeshuber , Eugen Gehrer , Rolf Fischer , Ulrich Steinbrenner , Shelue Liang
发明人： Christoph Sigwart , Thomas Narbeshuber , Eugen Gehrer , Rolf Fischer , Ulrich Steinbrenner , Shelue Liang
IPC分类号： C08F11010
CPC分类号： C08F110/10 , C08F2/00 , C08F4/10 , C08F4/26 , C08F4/24 , C08F4/12 , C08F4/06 , C08F4/18 , C08F4/22
摘要： A process for preparing halogen-free, reactive polyisobutene having a terminal double bond content of more than 60 mol % and an average molecular weight Mn of 800-3000 dalton by cationic polymerization in the liquid phase of isobutene over an acidic, essentially halogen-free heterogeneous catalyst, where a) a hydrocarbon mixture of essentially C4-hydrocarbons comprising isobutene in an amount of from 10 to 80% by weight is used as the starting material and b) polymerization is carried out continuously at from −30 to 0° C. with average starting material residence times of one hour or less, where the temperature and the residence time are selected such that the isobutene conversion is less than 60% and, after separation from the resulting polyisobutene, the isobutene is either enriched in the partially converted hydrocarbon mixture and returned to the polymerization or passed to another isobutene reaction coupled with the polymerization.
摘要翻译：一种通过阳离子聚合在异丁烯液相中酸性，基本上不含卤素的方式制备末端双键含量大于60mol％，平均分子量Mn为800-3000道尔顿的无卤素的活性聚异丁烯的方法非均相催化剂，其中将基本上含有10-80重量％异丁烯的C 4烃的烃混合物用作原料，和b）在-30℃至0℃下连续进行聚合，平均起始材料停留时间为1小时或更短，其中选择温度和停留时间使得异丁烯转化率小于60％，并且在从所得聚异丁烯分离后，异丁烯富含部分转化的烃混合物，返回聚合反应或通过与聚合偶联的另一异丁烯反应。

5. 发明授权

US5994562A Preparation of N-alkenylcarboxamides 失效
标题翻译： N-链烯基酰胺的制备
公开(公告)号：US5994562A
公开(公告)日：1999-11-30
申请号：US229996
申请日：1999-01-14
申请人： Klaus Ebel , Matthias Eiermann , Thomas Narbeshuber , Eugen Gehrer
发明人： Klaus Ebel , Matthias Eiermann , Thomas Narbeshuber , Eugen Gehrer
IPC分类号： B01J29/06 , B01J29/08 , B01J29/40 , B01J29/86 , C07B61/00 , C07C231/12 , C07C233/02 , C07D207/26 , C07D207/267 , C07D207/12 , C07C233/18 , C07C235/08
CPC分类号： C07D207/267 , B01J29/061
摘要： In a process for preparing N-alkenylcarboxamides by dehydration of N-(2-hydroxyalkyl)carboxamides and/or diethers thereof in the presence of a catalyst, molecular sieves, in particular zeolites, are used as catalyst.
摘要翻译：在催化剂存在下，通过N-（2-羟基烷基）甲酰胺和/或其醚脱水制备N-链烯基酰胺的方法中，使用分子筛，特别是沸石作为催化剂。

6. 发明授权

US06441110B1 Method for producing halogen-free reactive polyisobutene 失效
标题翻译：生产无卤素的反应性聚异丁烯的方法
公开(公告)号：US06441110B1
公开(公告)日：2002-08-27
申请号：US09367194
申请日：1999-08-06
申请人： Christoph Sigwart , Thomas Narbeshuber , Karsten Eller , Manfred Barl , Rolf Fischer , Eugen Gehrer
发明人： Christoph Sigwart , Thomas Narbeshuber , Karsten Eller , Manfred Barl , Rolf Fischer , Eugen Gehrer
IPC分类号： C08F424
CPC分类号： C08F110/10 , C08F10/10 , C08F4/24 , C08F4/20 , C08F4/025
摘要： A process for preparing halogen-free, reactive polyisobutene having a terminal double bond content of more than 50 mol % and an average molecular weight Mn of 280-10000 dalton by the cationic polymerization in the liquid phase of isobutene or hydrocarbon mixtures comprising isobutene comprises polymerizing at from −30° C. to +40° C. in the presence of a heterogeneous polymerisation catalyst comprising one or more oxides of the elements of transition groups V and VI of the Periodic Table of the Elements or in the presence of a heterogeneous polymerization catalyst comprising one or more oxidic compounds of one or more elements of transition groups V and VI of the Periodic Table of the Elements supported on a non-zeolitic oxidic support material which is not an oxygen-containing zirconium compound, the catalyst not containing a technically effective amount of halogen.
摘要翻译：通过在异丁烯或包含异丁烯的烃混合物的液相中的阳离子聚合制备末端双键含量大于50mol％，平均分子量Mn为280-10000dalton的无卤活性聚异丁烯的方法包括聚合在-30℃至+ 40℃下，在包含元素周期表的过渡基团V和VI的元素的一种或多种氧化物的非均相聚合催化剂的存在下，或在非均相聚合催化剂包含负载在不是含氧锆化合物的非沸石氧化载体材料上的元素周期表的一个或多个过渡基团V和VI元素的一种或多种氧化化合物，该催化剂不含技术上有效量的卤素。

7. 发明授权

US5817871A Preparation of amines 失效
标题翻译：胺的制备
公开(公告)号：US5817871A
公开(公告)日：1998-10-06
申请号：US921769
申请日：1997-08-15
申请人： Uwe Dingerdissen , Gunter Lauth , Andreas Henne , Peter Stops , Karsten Eller , Eugen Gehrer
发明人： Uwe Dingerdissen , Gunter Lauth , Andreas Henne , Peter Stops , Karsten Eller , Eugen Gehrer
IPC分类号： B01J27/18 , B01J27/182 , B01J27/185 , B01J27/188 , C07B61/00 , C07C209/60 , C07C211/03 , C07C211/05 , C07C211/06 , C07C211/07 , C07C211/08 , C07C211/35
CPC分类号： C07C211/35 , C07C209/60 , C07C211/07 , C07C2101/08
摘要： A process for preparing an amine by catalytic reaction of an olefin with ammonia or a primary or secondary amine by contacting a mixture of the reactants in a reactor at 200.degree. to 400.degree. C. and an elevated pressure up to 700 bar in the presence of a catalyst consisting essentially of an X-ray amorphous (non-crystalline) mesoporous catalyst, some of which may have a microporous non-crystalline content. The catalyst has the composition a MO.sub.2 * b Q.sub.2 O.sub.3 * c P.sub.2 O.sub.5 where Q is at least one of the trivalent elements aluminum, boron, chromium, iron or gallium, and M is at least one of the tetravalent elements silicon, titanium or germanium. The molar ratio of a:b is from 0.5:1 to 1000:1 and the molar ratio of c:b is from 0 to 2:1. As prepared and used in the process, this non-crystalline catalyst has a specific BET surface area of from 200 to 1000 m.sup.2 /g.
摘要翻译：通过使烯烃与氨或伯胺或仲胺进行催化反应来制备胺的方法，该方法是将反应物的混合物在200-400℃的反应器和高达700巴的升高的压力下反应，主要由X射线无定形（非结晶）介孔催化剂组成的催化剂，其中一些可能具有微孔非晶体含量。催化剂具有以下组成：MO2 * b Q2O3 * c P2O5其中Q是三价元素铝，硼，铬，铁或镓中的至少一种，M是四价元素硅，钛或锗中的至少一种。 a:b的摩尔比为0.5:1-1000:1，c:b的摩尔比为0-2:1。在该方法中制备和使用时，该非结晶催化剂的BET比表面积为200-1000m2 / g。

8. 发明授权

US06284704B1 Preparation of a basic catalyst avoiding high temperatures 失效
公开(公告)号：US06284704B1
公开(公告)日：2001-09-04
申请号：US09407284
申请日：1999-09-29
申请人： Ulrich Steinbrenner , Eugen Gehrer
发明人： Ulrich Steinbrenner , Eugen Gehrer
IPC分类号： B01J2302
CPC分类号： C07C2/72 , B01J23/04 , C07C2523/02 , C07C2523/04 , C07C2523/06 , C07C2523/08 , C07C2523/14 , C07C2523/18 , C07C2523/50 , C07C2523/52
摘要： A catalyst comprising at least one alkali metal and at least one metallic or semimetallic promoter selected from the group consisting of Ca, Sr, Ba, Ag, Au, Zn, Cd, Hg, In, Tl, Sn, As, Sb and Bi, on a support which may be doped with one or more compounds of an alkali metal and/or alkaline earth metal, where the alkali metal/support ratio by weight is from 0.01 to 5, the promoter/alkali metal ratio by weight is from 0.0001 to 5 and, when a dopant is present, the dopant/support ratio by weight is from 0.01 to 5.

9. 发明授权

US5714430A Mixtures containing fine metallic silver particles on a neutral to basic non-zeolite carrier oxide 失效
标题翻译：在中性至碱性非沸石载体氧化物上含有细金属银颗粒的混合物
公开(公告)号：US5714430A
公开(公告)日：1998-02-03
申请号：US499828
申请日：1995-07-10
申请人： Eugen Gehrer , Richard Thoma , Giorgio Greening , John-Bryan Speakman
发明人： Eugen Gehrer , Richard Thoma , Giorgio Greening , John-Bryan Speakman
IPC分类号： A01N25/08 , A01N59/16 , C08K9/12 , D01F1/10 , D06M11/00 , D06M11/79 , B01J23/50 , A01N25/34
CPC分类号： C08K9/12 , A01N59/16
摘要： Mixtures which contain silver with a particle diameter of from 0.001 to 5 .mu.m on a neutral or basic non-zeolite carrier oxide of elements of group IIa, IIIa, IIb, IIIb of the Periodic Table of the Elements, of the lanthanides or mixtures thereof, and a process for preparing these mixtures and antibiotic compositions which comprise these mixtures are described.
摘要翻译：在元素周期表IIa，IIIa，IIb，IIIb族元素的中性或碱性非沸石载体氧化物上含有粒径为0.001-5μm的银的混合物或其混合物，以及制备这些混合物的方法和包含这些混合物的抗生素组合物。

10. 发明授权

US5585496A Catalytic preparation of condensation products of formaldehyde 失效
标题翻译：催化制备甲醛缩合产物
公开(公告)号：US5585496A
公开(公告)日：1996-12-17
申请号：US570557
申请日：1995-12-11
申请人： Joaquim H. Teles , Johann-Peter Melder , Eugen Gehrer , Wolfgang Harder , Klaus Ebel , Carsten Groening , Regina Meyer
发明人： Joaquim H. Teles , Johann-Peter Melder , Eugen Gehrer , Wolfgang Harder , Klaus Ebel , Carsten Groening , Regina Meyer
IPC分类号： B01J31/02 , C07B61/00 , C07C45/75 , C07C47/19 , C07C49/17 , C07D249/08 , C07D249/10 , C07D249/12 , C07D249/14 , C07D471/06
CPC分类号： C07C45/75
摘要： A process for the catalytical preparation of condensation products of formaldehyde, in which formaldehyde or a formaldehyde-forming compound is caused to undergo reaction using a catalyst which has been produced, in the presence of an auxiliary base, from a triazolium salt of formula I ##STR1## in which R.sup.1 and R.sup.3 are the same or different and stand for aliphatic groups having from 1 to 30 carbon atoms, optionally substituted aryl groups, optionally substituted aralkyl groups, and/or optionally substituted heteroaryl groups,R.sup.2 represents hydrogen, the hydroxymethylene group --CH.sub.2 OH or the hydroxy-hydroxymethylene-methylidyne group --CH(OH)(CH.sub.2 OH), andR.sup.4 denotes hydrogen, a halogen atom, a nitro or cyano group, an aliphatic group having from 1 to 30 carbon atoms, an optionally substituted aryl group, an optionally substituted aralkyl group, an optionally substituted heteroaryl group, an alkoxy group --OR.sup.5, a thioether group --SR.sup.6, an amino group --NR.sup.7 R.sup.8, an acyl group--COR.sup.9 or an ester group --COOR.sup.10, where R.sup.5, R.sup.6, R.sup.7, R.sup.8, and R.sup.9 stand for radicals such as those stated above for R.sup.1, and R.sup.10 is a C.sub.1 -C.sub.10 alkyl group or an optionally substituted aryl or aralkyl group, orR.sup.3 and R.sup.4 together form a C.sub.3 -C.sub.5 alkylene or C.sub.3 -C.sub.5 alkenylene group or a C.sub.6 -C.sub.14 alkylene group, or a C.sub.7 -C.sub.14 aralkylene or C.sub.8 -C.sub.14 aralkenylene bridging member, andA is the equivalent of an anion having one or more negative charges for electrical neutralization of the charge on the triazolium cation.
摘要翻译：催化制备甲醛缩合产物的方法，其中使甲醛或形成甲醛的化合物在辅助碱存在下由式I的三唑鎓盐生产的催化剂进行反应，（I）其中R1和R3相同或不同，代表具有1至30个碳原子的脂族基团，任选取代的芳基，任选取代的芳烷基和/或任选取代的杂芳基，R 2表示氢，羟基亚甲基-CH 2 OH或羟基 - 羟基亚甲基 - 亚甲基基团-CH（OH）（CH 2 OH），R 4表示氢，卤素原子，硝基或氰基，具有1至30个碳原子的脂族基团，取代的芳基，任选取代的芳烷基，任选取代的杂芳基，烷氧基-OR 5，硫醚基-SR 6，氨基-NR 7 R 8，酰基-C COR 9或酯gr 其中R 5，R 6，R 7，R 8和R 9分别代表上述R 1的基团，R 10是C 1 -C 10烷基或任意取代的芳基或芳烷基，或者R 3和R 4一起形成 C3-C5亚烷基或C3-C5亚烯基或C6-C14亚烷基，或C7-C14亚芳基或C8-C14芳亚烷基桥连元件，A相当于具有一个或多个负电荷用于电中和的阴离子的三唑鎓阳离子的电荷。

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