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1. 发明授权

US06452045B1 Process for improving yields in a disproportionation reaction (high yield Henkel) 失效
标题翻译：改善歧化反应产率的方法（高产量汉高）
公开(公告)号：US06452045B1
公开(公告)日：2002-09-17
申请号：US09643518
申请日：2000-08-22
申请人： Thomas Fairchild Brownscombe , James Laurel Buechele , Donn Anthony DuBois , Susan Secor Pfrehm , William Larry King
发明人： Thomas Fairchild Brownscombe , James Laurel Buechele , Donn Anthony DuBois , Susan Secor Pfrehm , William Larry King
IPC分类号： C07C51347
CPC分类号： C08G63/189 , B01J23/002 , B01J23/06 , B01J23/44 , B01J23/80 , B01J27/232 , B01J37/088 , C07C51/02 , C07C51/15 , C07C51/265 , C07C51/412 , C07C51/416 , C07C51/42 , C07C51/43 , C07C51/47 , C07C51/487 , C07C63/36 , C07C63/15 , C07C63/16 , C07C63/38 , C07C63/26 , C07C63/24 , C07C63/307 , C07C63/04
摘要： Disclosed is a process for disproportionation of potassium naphthoate to the dipotassium salt of 2,6-NDA which gives reproducible improved yields of up to 40% which comprises: a) reacting naphthoic acid in the presence of excess base to produce a disproportionation feed comprising a finely dispersed disordered salt mixture of excess base salts and naphthoic acid salts, wherein the feed is prepared by the steps of: (1) Reacting naphthoic acid in the presence of excess base selected from the group consisting of carbonates and bicarbonates to form a salt; (2) Drying said salt mixture by a method which forms a highly mixed disordered salt mixture characterized by a differential scanning calorimeter(DSC) signature characterized by low melting peaks not previously observed in the salt; and b) Disproportionating said solid salts in the presence of a disproportionation catalyst to form the dipotassium salts of 2,6-NDA.
摘要翻译：公开了一种用于歧化萘甲酸钾至2,6-NDA的二钾盐的方法，其提供高达40％的可重现的提高的产率，其包括：a）在过量碱的存在下使萘甲酸反应以产生歧化进料，其包含精细分散的过量碱盐和萘甲酸盐的无序盐混合物，其中所述进料通过以下步骤制备：（1）在选自碳酸盐和碳酸氢盐的过量碱的存在下反应萘甲酸以形成盐; （2）通过形成高度混合的无序盐混合物的方法干燥所述盐混合物，所述混合物的特征在于差示扫描量热仪（DSC）特征，其特征在于以前在盐中未观察到低熔点峰; 和b）在歧化催化剂存在下使所述固体盐分解，形成2,6-NDA的二钾盐。

2. 发明授权

US06479699B2 Process for carboxylation of naphthoic acid to naphthalene dicarboxylic acid 失效
公开(公告)号：US06479699B2
公开(公告)日：2002-11-12
申请号：US09898890
申请日：2001-07-03
申请人： Thomas Fairchild Brownscombe , Donn Anthony DuBois , Susan Secor Pfrehm , William Larry King
发明人： Thomas Fairchild Brownscombe , Donn Anthony DuBois , Susan Secor Pfrehm , William Larry King
IPC分类号： C07C51347
CPC分类号： C08G63/189 , B01J23/002 , B01J23/44 , B01J23/80 , B01J37/088 , C07C51/02 , C07C51/15 , C07C51/265 , C07C51/412 , C07C51/416 , C07C51/42 , C07C51/43 , C07C51/47 , C07C51/487 , C07C63/26 , C07C63/24 , C07C63/15 , C07C63/38 , C07C63/16 , C07C63/36 , C07C63/307 , C07C63/04
摘要： Disclosed is a method for selective carboxylation of naphthoic acid, or other aromatic mono-acids to form primarily 2,3-naphthalene dicarboxylic acid (2,3-NDA) or other aromatic diacids which comprises reacting said aromatic mono-acid in the presence of one or more metal oxide catalysts, alone, or in combination, and in the presence of about 0.2 to 0.8 moles excess of base over aromatic mono-acid, at a temperature of about 380° C. to about 420° C., and, in a second step, disproportionating the product of said selective carboxylation at a temperature above about 420° C. to form a product with a greatly improved yield of 2,6-naphthalene dicarboxylic acid, or other aromatic dicarboxylic acid.

3. 发明授权

US06441224B1 Process for carboxylation of naphthoic acid to naphthalene dicarboxylic acid 失效
标题翻译：将萘甲酸羧化为萘二甲酸的方法
公开(公告)号：US06441224B1
公开(公告)日：2002-08-27
申请号：US09643353
申请日：2000-08-22
申请人： Thomas Fairchild Brownscombe , Donn Anthony DuBois , Susan Secor Pfrehm , William Larry King
发明人： Thomas Fairchild Brownscombe , Donn Anthony DuBois , Susan Secor Pfrehm , William Larry King
IPC分类号： C07C51347
CPC分类号： C08G63/189 , B01J23/002 , B01J23/44 , B01J23/80 , B01J23/83 , B01J27/232 , B01J37/088 , C07C51/02 , C07C51/15 , C07C51/265 , C07C51/412 , C07C51/416 , C07C51/42 , C07C51/43 , C07C51/47 , C07C51/487 , C07C63/16 , C07C63/36 , C07C63/24 , C07C63/26 , C07C63/15 , C07C63/38 , C07C63/307 , C07C63/04
摘要： Disclosed is a method for selective carboxylation of naphthoic acid, or other aromatic mono-acids to form primarily 2,3-naphthalene dicarboxylic acid (2,3-NDA) or other aromatic diacids which comprises reacting said aromatic mono-acid in the presence of one or more metal oxide catalysts, alone, or in combination, and in the presence of about 0.2 to 0.8 moles excess of base over aromatic mono-acid, at a temperature of about 380° C. to about 420° C., and, in a second step, disproportionating the product of said selective carboxylation at a temperature above about 420° C. to form a product with a greatly improved yield of 2,6-naphthalene dicarboxylic acid, or other aromatic dicarboxylic acid.
摘要翻译：公开了一种用于选择性羧化萘甲酸或其它芳族单酸以主要形成2,3-萘二羧酸（2,3-NDA）或其它芳族二酸的方法，其包括使所述芳族单酸在在约380℃至约420℃的温度下，单独或组合使用一种或多种金属氧化物催化剂，并且在相对于芳族单酸约0.2至0.8摩尔过量的碱存在下，在第二步中，在高于约420℃的温度下歧化所述选择性羧化的产物以形成2,6-萘二甲酸或其它芳族二羧酸的产率大大提高的产物。

4. 发明授权

US06448436B1 Integrated process for the production of 2, 6-naphthalene dicarboxylic acid 失效
标题翻译：用于生产2,6-萘二羧酸的综合工艺
公开(公告)号：US06448436B1
公开(公告)日：2002-09-10
申请号：US09644003
申请日：2000-08-22
申请人： Keith Michael Kreitman , Steve Edward Brewer , John Bernard Rodden , Robert Lawrence Blackbourn , Thomas Fairchild Brownscombe , James Laurel Buechele , Ye-Mon Chen , Zaida Diaz , Donn Anthony DuBois , Raymond Lawrence June , Brendan Dermot Murray , Michael Wayne Potter
发明人： Keith Michael Kreitman , Steve Edward Brewer , John Bernard Rodden , Robert Lawrence Blackbourn , Thomas Fairchild Brownscombe , James Laurel Buechele , Ye-Mon Chen , Zaida Diaz , Donn Anthony DuBois , Raymond Lawrence June , Brendan Dermot Murray , Michael Wayne Potter
IPC分类号： C07C51265
CPC分类号： C08G63/189 , B01J27/232 , C07C51/02 , C07C51/15 , C07C51/265 , C07C51/412 , C07C51/416 , C07C51/42 , C07C51/43 , C07C51/47 , C07C51/487 , Y02P20/125 , C07C63/16 , C07C63/36 , C07C63/24 , C07C63/38 , C07C63/26 , C07C63/15 , C07C63/307
摘要： Disclosed is an integrated process for producing 2,6-naphthalene dicarboxylicacid comprising oxidizing a methylnaphthalene feedstock, hydrodebrominating the crude naphthoic acid product under conditions different from any work known in the art, forming a potassium salt of the acid; disproportionating the potassium salt to produce 2,6 potassium salts of NDA; selectively precipitating K2NDA; selectively precipitating the monopotassium salt of 2,6 NDA(KHNDA); disproportionating the KHNDA into 2,6 NDA and K2NDA; further reacting the 2,6 NDA in a pipe reactor; and drying the product 2,6 NDA by conventional means or directly slurrying directly into a PEN process. The process can tolerate impurities in the economical methylnaphthalene feed and the resulting 2,6 NDA is of high quality with
摘要翻译：公开了一种用于生产2,6-萘二羧酸的综合方法，包括氧化甲基萘原料，在与本领域已知的任何工作不同的条件下氢化溴化粗萘甲酸产物，形成酸的钾盐; 歧化钾盐生成2,6-二硝基苯胺钾盐; 选择性沉淀K2NDA; 选择性沉淀2,6 NDA（KHNDA）的单钾盐; 将KHNDA分解为2,6 NDA和K2NDA; 进一步使2,6 NDA在管式反应器中反应; 并通过常规方法干燥产品2,6NDA或直接浆化成PEN方法。该方法可以耐受经济的甲基萘进料中的杂质，并且所得的2,6 NDA是高质量的，具有<50ppm的钾。

5. 发明授权

US06355834B1 Process for making an aromatic diacid in one step using a single catalyst system 失效
标题翻译：使用单一催化剂体系在一个步骤中制备芳族二酸的方法
公开(公告)号：US06355834B1
公开(公告)日：2002-03-12
申请号：US09644228
申请日：2000-08-22
申请人： Thomas Fairchild Brownscombe , Susan Secor Pfrehm , William Larry King
发明人： Thomas Fairchild Brownscombe , Susan Secor Pfrehm , William Larry King
IPC分类号： C07C5116
CPC分类号： C07C51/265 , C07C63/38
摘要： Disclosed is a process for manufacturing an aromatic diacid in one step with a single catalyst system which comprises: a) Introducing into a reactor an aromatic hydrocarbon containing the number of rings desired in the product diacid with one or more alkyl groups attached to the rings; b) Reacting said aromatic hydrocarbon in the presence of an oxidant supply and a single catalyst system comprising at least one catalyst selected from Group IB, IIB, VB, or VIIB of the Periodic Table, in a reaction medium capable of stabilizing the aromatic acids formed against further oxidation to water and CO2, or decarboxylation to aromatic hydrocarbons, and also capable of allowing the isomerization of the acids so formed to the desired diacids; and c) Reacting said hydrocarbon feed with said oxidant in the presence of said catalyst system until a desired amount of said feed is oxidized to carboxylic acids and isomerized to the desired diacid product.
摘要翻译：公开了一种用单一催化剂体系制备芳族二酸的方法，该方法包括：a）向反应器中引入含有产物二酸中期望的数目的环的芳族烃与一个或多个连接到环上的烷基; b）在氧化剂供应和包含至少一种选自元素周期表IB，IIB，VB或VIIB族的催化剂的催化剂体系的存在下，在能够稳定形成的芳族酸的反应介质中使所述芳烃反应防止进一步氧化成水和二氧化碳，或对芳烃脱碳，并且还能够使所形成的酸异构化成所需的二酸; 和c）在所述催化剂体系的存在下，用所述氧化剂使所述烃进料反应，直到所需量的所述进料被氧化成羧酸并异构化为所需的二酸产物。

6. 发明授权

US06316665B1 Process for producing diacids by carboxylation of phenolic compounds 失效
标题翻译：通过酚化合物的羧化生产二酸的方法
公开(公告)号：US06316665B1
公开(公告)日：2001-11-13
申请号：US09643519
申请日：2000-08-22
申请人： Thomas Fairchild Brownscombe , Garo Vaporciyan , Narayana Mysore , Susan Secor Pfrehm
发明人： Thomas Fairchild Brownscombe , Garo Vaporciyan , Narayana Mysore , Susan Secor Pfrehm
IPC分类号： C07C6300
CPC分类号： C07C51/15 , C07C63/28 , C07C63/26 , C07C63/38
摘要： An oxidation free process for converting a hydroxy substituted aromatic to an aromatic diacid which comprises reacting a hydroxy substituted aromatic with excess basic salt in the presence of carbon dioxide at disproportionation/isomerization reaction conditions.
摘要翻译：用于将羟基取代的芳族转化成芳族二酸的无氧化方法，其包括在歧化/异构化反应条件下在二氧化碳存在下使羟基取代的芳族化合物与过量的碱式盐反应。

7. 发明申请

US20100018902A1 METHODS FOR PRODUCING A TOTAL PRODUCT AT SELECTED TEMPERATURES 审中-公开
标题翻译：在选择温度下生产总产品的方法
公开(公告)号：US20100018902A1
公开(公告)日：2010-01-28
申请号：US12570961
申请日：2009-09-30
申请人： Thomas Fairchild Brownscombe , Scott Lee Wellington , Eswarachandra Kumar Paruchuri , Weijian Mo , William Douglas Gillespie , Chen Elizabeth Ramachandran , Susan Secor Pfrehm , David William Wallace
发明人： Thomas Fairchild Brownscombe , Scott Lee Wellington , Eswarachandra Kumar Paruchuri , Weijian Mo , William Douglas Gillespie , Chen Elizabeth Ramachandran , Susan Secor Pfrehm , David William Wallace
IPC分类号： C10G31/00
CPC分类号： C10G45/00 , C10G65/04 , C10L1/04
摘要： Method of producing a total product are described. A method includes providing a feed and a supported inorganic salt catalyst to a contacting zone. Contact of the supported inorganic salt catalyst with the feed in the presence of a hydrogen source and steam in the contacting zone at a temperature of at most 1000° C. and a total operating pressure of at most 4 MPa produces the total product.
摘要翻译：描述了生产总产品的方法。一种方法包括向接触区提供进料和负载的无机盐催化剂。在氢气源和蒸汽存在下，在最高1000℃的温度和最高4MPa的总操作压力下，在接触区域中负载的无机盐催化剂与进料的接触产生总产物。

8. 发明授权

US07625481B2 Systems and methods of producing a crude product 失效
标题翻译：生产粗产品的系统和方法
公开(公告)号：US07625481B2
公开(公告)日：2009-12-01
申请号：US12169975
申请日：2008-07-09
申请人： Scott Lee Wellington , Thomas Fairchild Brownscombe
发明人： Scott Lee Wellington , Thomas Fairchild Brownscombe
IPC分类号： C10G47/02 , C10G47/00
CPC分类号： C10G45/00 , C10G65/04 , C10L1/04 , Y02P20/142
摘要： Contact of a crude feed with a hydrogen source in the presence of an inorganic salt catalyst produces a total product that includes a crude product. The crude feed has a residue content of at least 0.2 grams of residue per gram of crude feed. The inorganic salt catalyst comprises alkali metals, alkaline earth metals, or mixtures thereof. The crude product is a liquid mixture at 25° C. and 0.101 MPa. One or more properties of the crude product may be changed by at least 10% relative to the respective properties of the crude feed.
摘要翻译：在无机盐催化剂存在下，粗制原料与氢源的接触产生包括粗产物的总产物。原油原料每克原油原料的残留物含量至少为0.2克。无机盐催化剂包括碱金属，碱土金属或其混合物。粗产物是在25℃和0.101MPa下的液体混合物。原油产品的一种或多种性质相对于原油原料的各自特性可以改变至少10％。

9. 发明授权

US08070936B2 Systems and methods of producing a crude product 失效
标题翻译：生产粗产品的系统和方法
公开(公告)号：US08070936B2
公开(公告)日：2011-12-06
申请号：US12360205
申请日：2009-01-27
申请人： Scott Lee Wellington , Thomas Fairchild Brownscombe , Stanley Nemec Milam
发明人： Scott Lee Wellington , Thomas Fairchild Brownscombe , Stanley Nemec Milam
IPC分类号： C10G47/02
CPC分类号： C10G45/00 , C10G65/04 , C10L1/04 , Y02P20/142
摘要： Contact of a crude feed with one or more catalysts containing a transition metal sulfide produces a total product that includes a crude product. The crude feed has a residue content of at least 0.2 grams of residue per gram of crude feed. The crude product is a liquid mixture at 25° C. and 0.101 MPa. One or more properties of the crude product may be changed by at least 10% relative to the respective properties of the crude feed. In some embodiments, gas is produced during contact with one or more catalysts and the crude feed.
摘要翻译：原油原料与含有过渡金属硫化物的一种或多种催化剂的接触产生包括粗产物的总产物。原油原料每克原油原料的残留物含量至少为0.2克。粗产物是在25℃和0.101MPa下的液体混合物。原油产品的一种或多种性质相对于原油原料的各自特性可以改变至少10％。在一些实施方案中，在与一种或多种催化剂和原油原料接触期间产生气体。

10. 发明授权

US07959797B2 Systems and methods of producing a crude product 有权
公开(公告)号：US07959797B2
公开(公告)日：2011-06-14
申请号：US12360223
申请日：2009-01-27
申请人： Scott Lee Wellington , Thomas Fairchild Brownscombe , Stanley Nemec Milam
发明人： Scott Lee Wellington , Thomas Fairchild Brownscombe , Stanley Nemec Milam
IPC分类号： C10G45/00
CPC分类号： C10G45/00 , C10G65/04 , C10L1/04 , Y02P20/142
摘要： Contact of a crude feed with one or more catalysts containing a transition metal sulfide produces a total product that includes a crude product. The crude feed has a residue content of at least 0.2 grams of residue per gram of crude feed. The crude product is a liquid mixture at 25° C. and 0.101 MPa. One or more properties of the crude product may be changed by at least 10% relative to the respective properties of the crude feed. In some embodiments, gas is produced during contact with one or more catalysts and the crude feed.

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