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1. 发明授权

US06452045B1 Process for improving yields in a disproportionation reaction (high yield Henkel) 失效
标题翻译：改善歧化反应产率的方法（高产量汉高）
公开(公告)号：US06452045B1
公开(公告)日：2002-09-17
申请号：US09643518
申请日：2000-08-22
申请人： Thomas Fairchild Brownscombe , James Laurel Buechele , Donn Anthony DuBois , Susan Secor Pfrehm , William Larry King
发明人： Thomas Fairchild Brownscombe , James Laurel Buechele , Donn Anthony DuBois , Susan Secor Pfrehm , William Larry King
IPC分类号： C07C51347
CPC分类号： C08G63/189 , B01J23/002 , B01J23/06 , B01J23/44 , B01J23/80 , B01J27/232 , B01J37/088 , C07C51/02 , C07C51/15 , C07C51/265 , C07C51/412 , C07C51/416 , C07C51/42 , C07C51/43 , C07C51/47 , C07C51/487 , C07C63/36 , C07C63/15 , C07C63/16 , C07C63/38 , C07C63/26 , C07C63/24 , C07C63/307 , C07C63/04
摘要： Disclosed is a process for disproportionation of potassium naphthoate to the dipotassium salt of 2,6-NDA which gives reproducible improved yields of up to 40% which comprises: a) reacting naphthoic acid in the presence of excess base to produce a disproportionation feed comprising a finely dispersed disordered salt mixture of excess base salts and naphthoic acid salts, wherein the feed is prepared by the steps of: (1) Reacting naphthoic acid in the presence of excess base selected from the group consisting of carbonates and bicarbonates to form a salt; (2) Drying said salt mixture by a method which forms a highly mixed disordered salt mixture characterized by a differential scanning calorimeter(DSC) signature characterized by low melting peaks not previously observed in the salt; and b) Disproportionating said solid salts in the presence of a disproportionation catalyst to form the dipotassium salts of 2,6-NDA.
摘要翻译：公开了一种用于歧化萘甲酸钾至2,6-NDA的二钾盐的方法，其提供高达40％的可重现的提高的产率，其包括：a）在过量碱的存在下使萘甲酸反应以产生歧化进料，其包含精细分散的过量碱盐和萘甲酸盐的无序盐混合物，其中所述进料通过以下步骤制备：（1）在选自碳酸盐和碳酸氢盐的过量碱的存在下反应萘甲酸以形成盐; （2）通过形成高度混合的无序盐混合物的方法干燥所述盐混合物，所述混合物的特征在于差示扫描量热仪（DSC）特征，其特征在于以前在盐中未观察到低熔点峰; 和b）在歧化催化剂存在下使所述固体盐分解，形成2,6-NDA的二钾盐。

2. 发明授权

US06479699B2 Process for carboxylation of naphthoic acid to naphthalene dicarboxylic acid 失效
公开(公告)号：US06479699B2
公开(公告)日：2002-11-12
申请号：US09898890
申请日：2001-07-03
申请人： Thomas Fairchild Brownscombe , Donn Anthony DuBois , Susan Secor Pfrehm , William Larry King
发明人： Thomas Fairchild Brownscombe , Donn Anthony DuBois , Susan Secor Pfrehm , William Larry King
IPC分类号： C07C51347
CPC分类号： C08G63/189 , B01J23/002 , B01J23/44 , B01J23/80 , B01J37/088 , C07C51/02 , C07C51/15 , C07C51/265 , C07C51/412 , C07C51/416 , C07C51/42 , C07C51/43 , C07C51/47 , C07C51/487 , C07C63/26 , C07C63/24 , C07C63/15 , C07C63/38 , C07C63/16 , C07C63/36 , C07C63/307 , C07C63/04
摘要： Disclosed is a method for selective carboxylation of naphthoic acid, or other aromatic mono-acids to form primarily 2,3-naphthalene dicarboxylic acid (2,3-NDA) or other aromatic diacids which comprises reacting said aromatic mono-acid in the presence of one or more metal oxide catalysts, alone, or in combination, and in the presence of about 0.2 to 0.8 moles excess of base over aromatic mono-acid, at a temperature of about 380° C. to about 420° C., and, in a second step, disproportionating the product of said selective carboxylation at a temperature above about 420° C. to form a product with a greatly improved yield of 2,6-naphthalene dicarboxylic acid, or other aromatic dicarboxylic acid.

3. 发明授权

US06441224B1 Process for carboxylation of naphthoic acid to naphthalene dicarboxylic acid 失效
标题翻译：将萘甲酸羧化为萘二甲酸的方法
公开(公告)号：US06441224B1
公开(公告)日：2002-08-27
申请号：US09643353
申请日：2000-08-22
申请人： Thomas Fairchild Brownscombe , Donn Anthony DuBois , Susan Secor Pfrehm , William Larry King
发明人： Thomas Fairchild Brownscombe , Donn Anthony DuBois , Susan Secor Pfrehm , William Larry King
IPC分类号： C07C51347
CPC分类号： C08G63/189 , B01J23/002 , B01J23/44 , B01J23/80 , B01J23/83 , B01J27/232 , B01J37/088 , C07C51/02 , C07C51/15 , C07C51/265 , C07C51/412 , C07C51/416 , C07C51/42 , C07C51/43 , C07C51/47 , C07C51/487 , C07C63/16 , C07C63/36 , C07C63/24 , C07C63/26 , C07C63/15 , C07C63/38 , C07C63/307 , C07C63/04
摘要： Disclosed is a method for selective carboxylation of naphthoic acid, or other aromatic mono-acids to form primarily 2,3-naphthalene dicarboxylic acid (2,3-NDA) or other aromatic diacids which comprises reacting said aromatic mono-acid in the presence of one or more metal oxide catalysts, alone, or in combination, and in the presence of about 0.2 to 0.8 moles excess of base over aromatic mono-acid, at a temperature of about 380° C. to about 420° C., and, in a second step, disproportionating the product of said selective carboxylation at a temperature above about 420° C. to form a product with a greatly improved yield of 2,6-naphthalene dicarboxylic acid, or other aromatic dicarboxylic acid.
摘要翻译：公开了一种用于选择性羧化萘甲酸或其它芳族单酸以主要形成2,3-萘二羧酸（2,3-NDA）或其它芳族二酸的方法，其包括使所述芳族单酸在在约380℃至约420℃的温度下，单独或组合使用一种或多种金属氧化物催化剂，并且在相对于芳族单酸约0.2至0.8摩尔过量的碱存在下，在第二步中，在高于约420℃的温度下歧化所述选择性羧化的产物以形成2,6-萘二甲酸或其它芳族二羧酸的产率大大提高的产物。

4. 发明授权

US06448436B1 Integrated process for the production of 2, 6-naphthalene dicarboxylic acid 失效
标题翻译：用于生产2,6-萘二羧酸的综合工艺
公开(公告)号：US06448436B1
公开(公告)日：2002-09-10
申请号：US09644003
申请日：2000-08-22
申请人： Keith Michael Kreitman , Steve Edward Brewer , John Bernard Rodden , Robert Lawrence Blackbourn , Thomas Fairchild Brownscombe , James Laurel Buechele , Ye-Mon Chen , Zaida Diaz , Donn Anthony DuBois , Raymond Lawrence June , Brendan Dermot Murray , Michael Wayne Potter
发明人： Keith Michael Kreitman , Steve Edward Brewer , John Bernard Rodden , Robert Lawrence Blackbourn , Thomas Fairchild Brownscombe , James Laurel Buechele , Ye-Mon Chen , Zaida Diaz , Donn Anthony DuBois , Raymond Lawrence June , Brendan Dermot Murray , Michael Wayne Potter
IPC分类号： C07C51265
CPC分类号： C08G63/189 , B01J27/232 , C07C51/02 , C07C51/15 , C07C51/265 , C07C51/412 , C07C51/416 , C07C51/42 , C07C51/43 , C07C51/47 , C07C51/487 , Y02P20/125 , C07C63/16 , C07C63/36 , C07C63/24 , C07C63/38 , C07C63/26 , C07C63/15 , C07C63/307
摘要： Disclosed is an integrated process for producing 2,6-naphthalene dicarboxylicacid comprising oxidizing a methylnaphthalene feedstock, hydrodebrominating the crude naphthoic acid product under conditions different from any work known in the art, forming a potassium salt of the acid; disproportionating the potassium salt to produce 2,6 potassium salts of NDA; selectively precipitating K2NDA; selectively precipitating the monopotassium salt of 2,6 NDA(KHNDA); disproportionating the KHNDA into 2,6 NDA and K2NDA; further reacting the 2,6 NDA in a pipe reactor; and drying the product 2,6 NDA by conventional means or directly slurrying directly into a PEN process. The process can tolerate impurities in the economical methylnaphthalene feed and the resulting 2,6 NDA is of high quality with
摘要翻译：公开了一种用于生产2,6-萘二羧酸的综合方法，包括氧化甲基萘原料，在与本领域已知的任何工作不同的条件下氢化溴化粗萘甲酸产物，形成酸的钾盐; 歧化钾盐生成2,6-二硝基苯胺钾盐; 选择性沉淀K2NDA; 选择性沉淀2,6 NDA（KHNDA）的单钾盐; 将KHNDA分解为2,6 NDA和K2NDA; 进一步使2,6 NDA在管式反应器中反应; 并通过常规方法干燥产品2,6NDA或直接浆化成PEN方法。该方法可以耐受经济的甲基萘进料中的杂质，并且所得的2,6 NDA是高质量的，具有<50ppm的钾。

5. 发明授权

US06448437B1 Disproportionation catalyst 失效
标题翻译：歧化催化剂
公开(公告)号：US06448437B1
公开(公告)日：2002-09-10
申请号：US09643398
申请日：2000-08-22
申请人： Donn Anthony DuBois , Brendan Dermot Murray
发明人： Donn Anthony DuBois , Brendan Dermot Murray
IPC分类号： C02C51347
CPC分类号： C08G63/189 , B01J23/002 , B01J23/80 , B01J23/83 , B01J27/232 , B01J37/088 , B01J2523/00 , C07C51/02 , C07C51/15 , C07C51/265 , C07C51/412 , C07C51/416 , C07C51/42 , C07C51/43 , C07C51/47 , C07C51/487 , C07C63/38 , C07C63/15 , C07C63/16 , C07C63/36 , C07C63/24 , C07C63/26 , C07C63/307 , B01J2523/17 , B01J2523/27 , B01J2523/48
摘要： Disclosed are halide-free catalyst compositions for the disproportionation/isomerization of aromatic carboxylic acid salts. In one embodiment the catalyst comprises a mixed catalyst of compounds of copper, zinc, and zirconium; and, in a second embodiment, the catalyst comprises a copper compound treated with a base, optionally used with a promoter. Both halide-free catalysts provide advantages with respect to metallurgic problems, as well as good stability, activity and selectivity, and the later is faster kinetically at lower temperatures.
摘要翻译：公开了用于芳族羧酸盐的歧化/异构化的无卤化物催化剂组合物。在一个实施方案中，催化剂包含铜，锌和锆化合物的混合催化剂; 并且在第二实施方案中，催化剂包含用碱处理的铜化合物，任选与启动子一起使用。无卤化物催化剂在冶金问题方面提供优点，以及良好的稳定性，活性和选择性，并且在较低温度下动力学更快。

6. 发明授权

US06420490B1 Telechelic polymers are produced by ozonation degradation of diene polymers 失效
标题翻译：通过二烯聚合物的臭氧化降解产生远端聚合物
公开(公告)号：US06420490B1
公开(公告)日：2002-07-16
申请号：US09448664
申请日：1999-11-24
申请人： Donn Anthony DuBois
发明人： Donn Anthony DuBois
IPC分类号： C08F832
CPC分类号： C08F8/32 , C08C19/04 , C08F8/04 , C08F8/06
摘要： A low molecular weight, telechelic polymer containing polar internal functionality is produced by (a) treating a copolymer of a polar alpha olefin and a conjugated diene with ozone to degrade the copolymer and form polymer segments which have aldehyde or ketone groups on the chain ends, wherein the copolymer has a random distribution of predominantly 1,4-diene double bonds and the pendant functional groups of the polar alpha olefin are stable to ozone, and (b) further reacting the aldehyde or ketone end groups to provide terminal functionality. The terminal functionality which can be provided includes carboxylic acid groups, primary hydroxyl groups, and amide groups.
摘要翻译：通过（a）用臭氧处理极性α-烯烃和共轭二烯的共聚物来降解共聚物并形成在链端具有醛基或酮基的聚合物链段，从而产生含有极性内部官能团的低分子量遥爪聚合物，其中所述共聚物具有主要为1,4-二烯双键的无规分布，并且极性α-烯烃的侧链官能团对臭氧是稳定的，和（b）使醛或酮端基进一步反应以提供末端官能团。可以提供的末端官能团包括羧酸基团，伯羟基基团和酰胺基团。

7. 发明授权

US06316112B1 Fluoro-functional polyethylene-polysiloxane block copolymers 有权
标题翻译：氟官能聚乙烯 - 聚硅氧烷嵌段共聚物
公开(公告)号：US06316112B1
公开(公告)日：2001-11-13
申请号：US09442221
申请日：1999-11-17
申请人： Donn Anthony DuBois , Jeffrey George Southwick , Ronald James Hoxmeier , John Allen
发明人： Donn Anthony DuBois , Jeffrey George Southwick , Ronald James Hoxmeier , John Allen
IPC分类号： B82B2728
CPC分类号： C08G77/42 , C08G77/24 , C09D183/10 , Y10T428/1457 , Y10T428/31663 , Y10T428/31913
摘要： This invention relates to anionically polymerized block copolymers comprised of at least one block of polyethylene and at least one block of a polymerized cyclic siloxane monomer wherein said cyclic siloxane monomer contains at least one functional group containing a fluorocarbon substituent, e.g., 2,4,6-tris(3,3,3-trifluoropropyl)-1,3,5-trimethylcyclotrisiloxane. The fluoro-functionality may instead be introduced into the polymer by using said siloxane monomer to end cap the polymer. These copolymers can be used in extruded release coating films prepared by blending the copolymer with a film grade polymer. They can also be used to modify surface adhesion, promote flow in polymer processing or coat a polymeric surface to impart properties such as a barrier to water vapor transmission, or solvent resistance.
摘要翻译：本发明涉及由至少一个聚乙烯嵌段和至少一个聚合的环状硅氧烷单体嵌段组成的阴离子聚合的嵌段共聚物，其中所述环状硅氧烷单体含有至少一个含氟碳取代基的官能团，例如2,4,6 （3,3,3-三氟丙基）-1,3,5-三甲基环三硅氧烷。可以通过使用所述硅氧烷单体将聚合物封端而将氟官能度引入聚合物。这些共聚物可用于通过将共聚物与膜级聚合物共混制备的挤出脱模涂膜中。它们还可以用于改变表面粘附性，促进聚合物加工中的流动或涂覆聚合物表面以赋予诸如阻隔水蒸汽透过性或耐溶剂性的性能。

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