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    • 1. 发明授权
    • Syntactic foam core incorporating honeycomb structure for composites
    • 含复合材料蜂窝结构的合成泡沫芯
    • US5773121A
    • 1998-06-30
    • US769792
    • 1996-12-19
    • Charles L. MeteerThomas E. Philipps
    • Charles L. MeteerThomas E. Philipps
    • B29C70/08B29C70/58B29C70/66B29D99/00B32B5/18B32B27/20B32B3/12B32B3/26B32B5/16B32B18/00
    • B29D99/001B29C70/086B29C70/58B29C70/66B32B27/20B32B5/18B29K2105/165Y10S493/966Y10T156/1003Y10T428/24157Y10T428/24165Y10T428/249972Y10T428/249974Y10T428/249986Y10T428/2996
    • A syntactic structural foam product in flat sheet form or curved three-dimensional form adaptable to such uses as a light weight structural core for composite laminates, is made of a mixture of hollow ceramic microspheres and dry resin powder, of either thermosetting or a high-temperature thermoplastic resin, distributed in the interstices of the mass of microspheres for integration of the mixture into desired form upon heating and cooling. The dry resin powder in another embodiment of the invention includes unexpanded expandable powder which will expand into microballoons in the confined spaces in which they reside and effect a bonding relation with surrounding particles upon supply of heat to the mixture. The foam product is produced by thoroughly intermixing and depositing the mixture as a layer over a surface having a release agent thereover within a dimension defined region. Heat is then supplied, with or without pressure, to the layer at a temperature and for a time period sufficient to effect a melting or softening of the resin powder. Thereafter the resin is cooled to a hardened condition to integrate the mixture into the product desired after which the product is withdrawn from the forming zone. The mixture in layer form can be reinforced with honeycomb structures and/or with elements such as glass or carbon fibers selectively included in the mixture for predeterminable physical properties.
    • 一种平板形式的复合结构泡沫产品或适用于复合层压材料的轻质结构芯的这种用途的弯曲三维形状由中空陶瓷微球和干燥树脂粉末的混合物制成, 分布在微球体的间隙中,用于在加热和冷却时将混合物整合成所需形式。 在本发明的另一个实施方案中的干燥树脂粉末包括未膨胀的可膨胀粉末,其将在它们所驻留的密闭空间中膨胀成微球,并在向混合物供应热量时与周围颗粒发生粘合关系。 泡沫产品通过将混合物作为层在其尺寸限定区域内具有脱模剂的表面上充分混合和沉积而制备。 然后在有或没有压力的情况下,在足以使树脂粉末熔化或软化的温度和时间内将热量提供给该层。 此后,将树脂冷却至硬化状态,以将混合物整合到所需的产品中,然后将产物从成形区取出。 层状混合物可以用蜂窝结构和/或选择性地包含在混合物中的元素例如玻璃或碳纤维来增强以获得预定的物理性能。
    • 2. 发明授权
    • Syntactic foam core material for composite structures
    • 用于复合结构的合成泡沫芯材料
    • US5888642A
    • 1999-03-30
    • US600850
    • 1996-02-13
    • Charles L. MeteerThomas E. Philipps
    • Charles L. MeteerThomas E. Philipps
    • C08J9/32B29C65/00B29C70/08B29C70/58B29C70/66B29D99/00B32B3/26B32B5/18B32B27/20C08J9/00
    • B29D99/001B29C70/086B29C70/58B29C70/66B32B27/20B32B5/18C08J9/0085C08J9/32B29K2105/165Y10T428/249933Y10T428/24994Y10T428/249972Y10T428/249974Y10T428/249986Y10T428/269
    • A syntactic structural foam product in flat sheet form or curved three-dimensional form adaptable to such uses as a light weight structural core for composite laminates, is made of a mixture of hollow ceramic microspheres and dry resin powder, of either thermosetting or a high-temperature thermoplastic resin, distributed in the interstices of the mass of microspheres for integration of the mixture into desired form upon heating and cooling. The dry resin powder in an other embodiment of the invention includes unexpanded expandable powder which will expand into microballoons in the confined spaces in which they reside and effect a bonding relation with surrounding particles upon supply of heat to the mixture. The foam product is produced by thoroughly intermixing and depositing the mixture as a layer over a surface having a release agent thereover within a dimension defined region and then supplying heat with or without pressure to the layer at a temperature and for a time period sufficient to effect a melting or softening of the resin powder and thereafter cooling the resin to a hardened condition to integrate the mixture into the product desired after which the product is withdrawn from the forming zone. Reinforcing elements such as glass or carbon fibers can be selectively included in the mixture for predeterminable desired physical and mechanical properties.
    • 一种平板形式的复合结构泡沫产品或适用于复合层压材料的轻质结构芯的这种用途的弯曲三维形状由中空陶瓷微球和干燥树脂粉末的混合物制成, 分布在微球体的间隙中,用于在加热和冷却时将混合物整合成所需形式。 在本发明的另一个实施方案中,干燥的树脂粉末包括未膨胀的可膨胀粉末,其在它们所驻留的密闭空间中膨胀成微球,并且在向混合物供应热量时与周围颗粒发生粘合关系。 泡沫产品是通过将混合物作为层在其尺寸限定区域之间的具有脱模剂的表面上充分混合和沉积,然后在足以实现的温度和时间期间向该层供应有或没有压力的层 熔化或软化树脂粉末,然后将树脂冷却至硬化条件,以将混合物整合到所需的产品中,然后将产物从成形区域中取出。 加强元件如玻璃或碳纤维可以选择性地包括在混合物中以获得预定的所需物理和机械性能。
    • 3. 发明授权
    • Method of making syntactic foam core material
    • 制作复合泡沫芯材料的方法
    • US5846357A
    • 1998-12-08
    • US655083
    • 1996-06-03
    • Charles L. MeteerThomas E. Philipps
    • Charles L. MeteerThomas E. Philipps
    • B29C70/08B29C70/58B29C70/66B29D99/00B32B5/18B32B27/20C08J9/00C08J9/32B32B3/26
    • B29D99/001B29C70/086B29C70/58B29C70/66B32B27/20B32B5/18C08J9/0085C08J9/32B29K2105/165Y10S264/06Y10S264/07Y10T156/1043Y10T428/249972Y10T428/249974Y10T428/249986Y10T428/269Y10T442/653
    • A syntactic structural foam product in flat sheet form or curved three-dimensional form adaptable to such uses as a light weight structural core for composite laminates, is made of a mixture of hollow ceramic microspheres and dry resin powder, of either thermosetting or a high-temperature thermoplastic resin, distributed in the interstices of the mass of microspheres for integration of the mixture into desired form upon heating and cooling. Resin powder collected as a waste by-product from resin coating materials can be recycled in the production of the desired product. The foam product is produced by first intermixing the microspheres and powdered resin by physical agitation of the mixture and depositing the mixture as a layer over a surface having a release agent thereover within a dimension defining region between boundary members and then supplying heat with or without pressure to the layer at a temperature and for a time period sufficient to effect a melting of the resin powder and thereafter cooling the resin in a hardened condition to integrate the mixture into the product desired after which the product is withdrawn from the forming zone. Reinforcing elements such as glass or carbon fibers can be selectively included in the mixture for predeterminable desired physical and mechanical properties.
    • 一种平板形式的复合结构泡沫产品或适用于复合层压材料的轻质结构芯的这种用途的弯曲三维形状由中空陶瓷微球和干燥树脂粉末的混合物制成, 分布在微球体的间隙中,用于在加热和冷却时将混合物整合成所需形式。 从树脂涂料中作为废弃副产物收集的树脂粉末可以在所需产品的生产中循环使用。 泡沫产品通过首先将混合物物理搅拌混合并将混合物作为一层层叠在具有脱模剂的表面上,在边界部件之间的尺寸限定区域内,然后在有或没有压力的情况下供应热量 在足以使树脂粉末熔化的温度和时间段内向层中加热,然后在硬化条件下冷却树脂,以将混合物整合到所需的产物中,然后将产物从成形区中取出。 加强元件如玻璃或碳纤维可以选择性地包括在混合物中以获得预定的所需物理和机械性能。
    • 5. 发明授权
    • Moldable sound control composite and product
    • 成型声控综合产品
    • US4311751A
    • 1982-01-19
    • US114118
    • 1980-01-21
    • Walter H. BrueggemannCharles L. Meteer
    • Walter H. BrueggemannCharles L. Meteer
    • C04B26/14C08L63/00C04B43/00
    • C04B26/14Y10S260/46Y10T428/24942Y10T428/31511Y10T428/31938
    • A moldable sound control composite is disclosed combining in itself when molded damping, barrier performance, and structural strength for use within a predetermined environment temperature range. As such, the moldable composite is not applied to other structures to damp their sound generation, but forms by itself a complete structural member having not only desirable sound reducing properties but desirable strength properties as well. The composite comprises a blend of a primary non-viscoelastic organic polymeric resinous material intended to impart structural strength to the composite, a secondary viscoelastic organic polymeric resinous material to provide damping performance, and filler material adapted to densify the composite and impart barrier performance. Optionally, at least one of the primary and secondary resinous materials may be thermosetting. By virtue of the blend of all of these ingredients, the molded composite has a glass transitional temperature range generally corresponding to the predetermined environmental temperature range for which the composite is designed for use and a maximum loss factor, n, falling within that range.
    • 公开了一种可模制声音控制复合材料,当其在预定环境温度范围内使用时,本身组合成型阻尼,阻隔性能和结构强度。 因此,可模塑复合材料不适用于其它结构以阻尼它们的声音产生,而是本身形成一个完整的结构构件,它具有不仅理想的减声性能,而且具有所需的强度特性。 复合材料包括旨在赋予复合材料结构强度的初级非粘弹性有机聚合物树脂材料的共混物,以提供阻尼性能的次级粘弹性有机聚合物树脂材料和适于致密化复合材料并赋予阻隔性能的填料材料。 任选地,初级和次级树脂材料中的至少一种可以是热固性的。 由于所有这些成分的共混,模塑复合材料具有通常对应于复合材料设计使用的预定环境温度范围和落在该范围内的最大损耗因子n的玻璃化转变温度范围。
    • 6. 发明授权
    • Moldable sound control composite
    • 可模塑声控组合
    • US4237176A
    • 1980-12-02
    • US690796
    • 1976-05-27
    • Walter H. BrueggemannCharles L. Meteer
    • Walter H. BrueggemannCharles L. Meteer
    • B32B27/08C04B26/18C08J3/00C08K3/00C08L1/00C08L7/00C08L21/00C08L23/00C08L27/00C08L33/00C08L33/02C08L67/00C08L67/02C08L77/00C08L101/00C04B43/00
    • C08L67/02C04B26/18C08K3/0033C08L77/00Y10T428/24942Y10T428/31786Y10T428/31794
    • A moldable sound control composite is disclosed combining in itself when molded damping, barrier performance, and structural strength for use within a predetermined environment temperature range. As such, the moldable composite is not applied to other structures to damp their sound generation, but forms by itself a complete structural member having not only desirable sound reducing properties but desirable strength properties as well. The composite comprises a blend of a primary non-viscoelastic organic polymeric resinuous material intended to impart structural strength to the composite, a secondary viscoelastic organic polymeric resinuous material to provide damping performance, and filler material adapted to densify the composite and impart barrier performance. Optionally, at least one of the primary and secondary resinuous materials may be thermosetting. By virtue of the blend of all of these ingredients, the molded composite has a glass transitional temperature range generally corresponding to the predetermined environmental temprature range for which the composite is designed for use and a maximum loss factor, n, falling within that range.
    • 公开了一种可模制声音控制复合材料,当其在预定环境温度范围内使用时,本身组合成型阻尼,阻隔性能和结构强度。 因此,可模塑复合材料不适用于其它结构以阻尼它们的声音产生,而是本身形成一个完整的结构构件,它具有不仅理想的减声性能,而且具有所需的强度特性。 复合材料包括旨在赋予复合材料结构强度的初级非粘弹性有机聚合物树脂材料,提供阻尼性能的次级粘弹性有机聚合树脂材料和适于致密复合材料并赋予阻隔性能的填充材料的混合物。 任选地,初级和次级树脂材料中的至少一种可以是热固性的。 由于所有这些成分的共混物,模塑复合材料具有通常对应于复合材料设计使用的预定环境温度范围和落在该范围内的最大损耗因子n的玻璃化转变温度范围。