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1. 发明授权

US5302708A Water-soluble phthalocyanine dyes 失效
标题翻译：水溶性酞菁染料
公开(公告)号：US5302708A
公开(公告)日：1994-04-12
申请号：US926589
申请日：1992-08-06
申请人： Thomas Beck , Werner H. Russ , Hartmut Springer , Marcus Banfer
发明人： Thomas Beck , Werner H. Russ , Hartmut Springer , Marcus Banfer
IPC分类号： C09B62/517 , D06P3/24 , D06P3/66 , C07F15/04 , C09B47/30
CPC分类号： C09B62/517
摘要： Phthalocyanine dyes, in particular copper phthalocyanine and nickel phthalocyanine dyes which contain one or more groups of the formula given and defined below ##STR1## or one or more carboxy groups or both groups and which furthermore can contain one or more sulfo groups, customary sulfonamide groups and/or groups of the formula given and defined below ##STR2## dye hydroxy- and/or carboxamide-containing materials, in particular fiber materials, such as cellulose fiber materials, wool and polyamide fibers, in fast, predominantly green hues of high color strength.In the formulae: R is hydrogen or a lower substituted or unsubstituted aliphatic radical, A is an aromatic carbocyclic or aromatic heterocyclic radical or an alkylene radical, which may be interrupted by 1 or 2 hetero groups, X is a direct bond or a divalent organic bridging member or together with the group --N(R)-- forms the divalent radical of a saturated heterocycle containing two N atoms, Y, in the case where A is an aromatic radical, is a direct bond or a carbamoylalkylene group or a methylene, ethylene, methylamino or .beta.-cyanoethylamino group, or Y is lower alkylene, in which case the grouping --X--A-- must be a direct bond and m is 2, Z is a fiber-reactive group of the vinylsulfonyl series and m is the number 1 or 2.
摘要翻译：酞菁染料，特别是铜酞菁和镍酞菁染料，其含有一个或多个下式给出和定义的基团（* CHEMICAL STRUCTURE *）或一个或多个羧基或两个基团，并且还可以含有一个或多个磺基，常规磺酰胺基团和/或下面给出和定义的式（*化学结构*）染料含羟基和/或羧酰胺的材料，特别是纤维材料，如纤维素纤维材料，羊毛和聚酰胺纤维，在快速，主要是高色强度的绿色色调。在下式中：R是氢或低级取代或未取代的脂族基团，A是芳族碳环或芳族杂环基或亚烷基，其可以被1或2个杂基间隔，X是直接键或二价有机桥连成员或与基团-N（R）一起形成含有两个N原子的饱和杂环的二价基团，在A为芳族基团的情况下为直链或氨基甲酰基亚烷基或亚甲基，乙烯，甲基氨基或（β） - 氰乙基氨基，或Y为低级亚烷基，在这种情况下，分组-XA-必须是直接键，m为2，Z为乙烯基磺酰基系列的纤维反应性基团，m为数字1或2。

2. 发明授权

US5256776A Water-soluble phthalocyanine dyestuffs, processes for their preparation and their use 失效
公开(公告)号：US5256776A
公开(公告)日：1993-10-26
申请号：US936138
申请日：1992-08-27
申请人： Thomas Beck , Werner H. Russ , Hartmut Springer , Marcus Banfer
发明人： Thomas Beck , Werner H. Russ , Hartmut Springer , Marcus Banfer
IPC分类号： C07D487/22 , C09B62/44 , C09B62/517 , C09B62/016 , D06P1/38 , D06P3/10 , D06P3/66
CPC分类号： C09B62/517 , C09B62/4418
摘要： Water-soluble phthalocyanine dyestuffs, processes for their preparation and their use Phthalocyanine dyestuffs, in particular copper phthalocyanine and nickel phthalocyanine dyestuffs, which contain one or more groups of the formula define below ##STR1## or one or more carboxy groups, or both groups, and which furthermore can have one or more sulfo groups, customary sulfonamide groups and/or groups of the general formula defined below ##STR2## dye materials containing hydroxy and/or carboxamide groups, in particular fiber materials, such as, for example, cellulose fiber materials, wool and polyamide fibers, in deep-colored, fast, mainly green shades. In the formulae:R.sup.1 and R.sup.2 are both, independently of one another, hydrogen or a lower optionally substituted aliphatic radical, G is lower alkylene, or is phenylene, which can be substituted by lower alkyl, lower alkoxy, halogen, sulfo, carboxy and/or nitro, or the grouping --N(R.sup.1)--G--N(R.sup.2)-- forms the bivalent radical of a saturated heterocyclic ring, W is halogen, lower alkoxy, aryloxy, sulfo, phenylsulfonyl, lower alkylsulfonyl or an optionally substituted amino group, or is a radical of the formula --N(R.sup.3)--A--(Y--Z).sub.m, where R.sup.3, A, Y, Z and m have the meaning given below, A is an aromatic carbocyclic or aromatic heterocyclic radical or an alkylene radical, which can be interrupted by 1 or 2 hetero groups, or is an alkylenephenylene radical or the bivalent radical of a saturated heterocyclic ring containing two N atoms, Y, in the case where A is an aromatic radical, is a direct bond or a carbamoyl-alkylene group or a methylene, ethylene, methylamino or .beta.-cyanoethyl-amino group, or Y is lower alkylene, and in this case A necessarily is a direct bond and m is 2, Z is a fiber-reactive group of the vinylsulfone series, m is the number 1 or 2 and R.sup.3 is hydrogen or lower alkyl.

3. 发明授权

US4757136A Water-soluble Azo compounds containing fiber-reactive groups and having a sulfo-naphthol coupling component with a triazinylamino substituent suitable as dyestuffs 失效
标题翻译：含有纤维反应性基团并具有磺基萘酚偶合组分的水溶性偶氮化合物，其具有适合作为染料的三嗪基氨基取代基
公开(公告)号：US4757136A
公开(公告)日：1988-07-12
申请号：US913534
申请日：1986-09-30
申请人： Hartmut Springer , Michael Kunze , Marcos Segal , Werner H. Russ
发明人： Hartmut Springer , Michael Kunze , Marcos Segal , Werner H. Russ
IPC分类号： C07D251/52 , C07D251/70 , C09B62/51 , D06P1/384 , D06P3/10 , D06P3/66
CPC分类号： C09B62/51
摘要： Water-soluble azo compounds having fiber-reactive dye properties conforming to the formula ##STR1## in which D denotes a benzene or naphthalene ring;R.sup.1 denotes hydrogen, alkyl, alkoxy, sulfo or carboxy;R.sup.2 denotes hydrogen, alkyl, alkoxy, sulfo, carboxy, substituted or unsubstituted aryl, hydroxy, nitro or halogen;R denotes hydrogen or substituted or unsubstituted alkyl;A denotes hydroxy, substituted or unsubstituted alkoxy or aryloxy, thio, substituted or unsubstituted alkylthioether or arylthioether or an optionally monosubstituted or disubstituted amino group having substituents from the aliphatic and aromatic and the acylamide series;B hydroxy, optionally substituted alkoxy or aryloxy, thio, optionally substituted alkylthioether or arylthioether or an optionally monosubstituted or disubstituted amino group having substituents from the aliphatic and aromatic and the acylamide series;M denotes hydrogen, alkali or alkaline earth;m denotes the number 1 or 2;n denotes the number 0 or 1;p denotes the number 0, 1 or 2;y denotes .beta.-thiosulfatoethyl, .beta.-phosphatoethyl, .beta.-chloroethyl, vinyl or .beta.-sulfatoethyl;the group --SO.sub.2 --Y is bonded to A or D or to both; or in which:A is chlorine or bromine,B is an optionally monosubstituted or disubstituted amino group having substituents from the aliphatic and aromatic and the acylamide series,m denotes the number 1 and the group --SO.sub.2 Y is bonded to D andD, R.sup.1, R.sup.2, R, M, n, p and Y have the above meanings.The new azo compounds dye fiber materials, such as wool and in particular cellulose, in strong and fast shades.
摘要翻译：具有符合式（1）＆lt; IMAGE＆gt;的式（1）的具有纤维反应性染料性质的水溶性偶氮化合物，其中D表示苯或萘环; R1表示氢，烷基，烷氧基，磺基或羧基; R 2表示氢，烷基，烷氧基，磺基，羧基，取代或未取代的芳基，羟基，硝基或卤素; R表示氢或取代或未取代的烷基; A表示羟基，取代或未取代的烷氧基或芳氧基，硫代，取代或未取代的烷基硫醚或芳基硫醚或任选具有脂族和芳族和酰基酰胺系列取代基的单取代或二取代的氨基; B羟基，任选取代的烷氧基或芳氧基，硫代，任选取代的烷基硫醚或芳硫醚或具有脂族和芳族和酰基酰胺系列取代基的任选单取代或二取代的氨基; M表示氢，碱或碱土; m表示数字1或2; n表示数字0或1; p表示数字0,1或2; y表示β-硫代硫代乙基，β-磷酰乙基，β-氯乙基，乙烯基或β-磺基乙基; 基团-SO 2 -Y键合到A或D或两者; 或其中：A为氯或溴，B为任选具有脂族和芳族和酰基酰胺系列取代基的单取代或二取代的氨基，m表示数1，基团-SO 2 Y与D键合，D， R2，R，M，n，p和Y具有上述含义。新的偶氮化合物染料纤维材料，如羊毛，特别是纤维素，具有强烈和快速的色调。

4. 发明授权

US4775746A Water-soluble monoazo compounds containing a fiber-reactive group of the vinylsulfone series and having a sulfonaphthol coupling component with a phenylaminotriazinylamino substituent, suitable as dyestuffs 失效
标题翻译：含有乙烯基砜系列的纤维反应性基团并且具有与苯基氨基三嗪基氨基取代基具有磺化苯偶合组分的适合作为染料的水溶性单偶氮化合物
公开(公告)号：US4775746A
公开(公告)日：1988-10-04
申请号：US913693
申请日：1986-09-30
申请人： Hartmut Springer , Michael Kunze , Marcos Segal , Werner H. Russ
发明人： Hartmut Springer , Michael Kunze , Marcos Segal , Werner H. Russ
IPC分类号： C07D251/52 , C07D251/70 , C09B62/51 , D06P1/384 , D06P3/10 , D06P3/66 , C09B62/507
CPC分类号： C09B62/51
摘要： Water-soluble azo compounds having fiber-reactive dye properties conforming to the formula ##STR1## in which D denotes a benzene or naphthalene ring;R.sup.1 denotes hydrogen, alkyl, alkoxy, sulfo or carboxy;R.sup.2 denotes hydrogen, alkyl, alkoxy, sulfo, carboxy, substituted or unsubstituted aryl, hydroxy, nitro or halogen;R denotes hydrogen or substituted or unsubstituted alkyl;A denotes hydroxy, substituted or unsubstituted alkoxy or aryloxy, thio, substituted or unsubstituted alkylthioether or arylthioether or an optionally mononsubstituted or disubstituted amino group having substituents from the aliphatic and aromatic and the acylamide series;B hydroxy, optionally substituted alkoxy or aryloxy, thio, optionally substituted alkylthioether or arylthioether or an optionally monosubstituted or disubstituted amino group having substituents from the aliphatic and aromatic and the acylamide series;M denotes hydrogen, alkali or alkaline earth;m denotes the number 1 or 2;n denotes the number 0 or 1;p denotes the number 0, 1 or 2;Y denotes .beta.-thiosulfatoethyl, .beta.-phosphatoethyl, .beta.-chloroethyl, vinyl or .beta.-sulfatoethyl;the group --SO.sub.2 --Y is bonded to A or D or to both; or in which:A is chlorine or bromine,B is an optionally monosubstituted or disubstituted amino group having substituents from the aliphatic and aromatic and the acylamide series,m denotes the number 1 and the group --SO.sub.2 Y is bonded to D andD, R.sup.1, R.sup.2, R, M, n, p and Y have the above meanings.The new azo compounds dye fiber materials, such as wool and in particular cellulose, in strong and fast shades.
摘要翻译：具有符合式（1）的纤维反应性染料性质的水溶性偶氮化合物，其中D表示苯或萘环; R1表示氢，烷基，烷氧基，磺基或羧基; R 2表示氢，烷基，烷氧基，磺基，羧基，取代或未取代的芳基，羟基，硝基或卤素; R表示氢或取代或未取代的烷基; A表示羟基，取代或未取代的烷氧基或芳氧基，硫代，取代或未取代的烷基硫醚或芳基硫醚或具有脂族和芳族和酰基酰胺系列取代基的任选单取代或二取代的氨基; B羟基，任选取代的烷氧基或芳氧基，硫代，任选取代的烷基硫醚或芳硫醚或具有脂族和芳族和酰基酰胺系列取代基的任选单取代或二取代的氨基; M表示氢，碱或碱土; m表示数字1或2; n表示数字0或1; p表示数字0,1或2; Y表示β-硫代硫代乙基，β-磷酰乙基，β-氯乙基，乙烯基或β-磺基乙基; 基团-SO 2 -Y键合到A或D或两者; 或其中：A为氯或溴，B为任选具有脂族和芳族和酰基酰胺系列取代基的单取代或二取代的氨基，m表示数1，基团-SO 2 Y与D键合，D， R2，R，M，n，p和Y具有上述含义。新的偶氮化合物染料纤维材料，如羊毛，特别是纤维素，具有强烈和快速的色调。

5. 发明授权

US5055565A Water-soluble disazo compounds, containing a vinylsulfonyl or .beta.-chloroethylsulfonyl grouping bonded directly or via a methylene group or a lower alkyl amino group to a benzoylamino group, suitable as dyestuffs 失效
标题翻译：含有乙烯基磺酰基或（BETA）-CHOOROETHYLSULFONYL的水溶性异氰酸酯化合物直接或通过亚甲基或低级烷基氨基键合到苯甲酰氨基上，适合作为试剂
公开(公告)号：US5055565A
公开(公告)日：1991-10-08
申请号：US570033
申请日：1990-08-20
申请人： Hartmut Springer , Manfred Kuhn , Werner H. Russ , Ludwig Schlafer
发明人： Hartmut Springer , Manfred Kuhn , Werner H. Russ , Ludwig Schlafer
IPC分类号： C09B62/513
CPC分类号： C09B62/513
摘要： Compounds according to the general formula ##STR1## in which: D is phenyl, optionally substituted by sulfo, carboxy, alkyl, alkoxy, alkanoylamino and/or chlorine, at least by sulfo or carboxy, or is a sulfosubstituted naphthyl;E is 1,4-phenylene, substituted by alkyl, alkoxy, alkanoylamino, ureido and/or chlorine, or is 1,4-naphthylene optionally substituted by sulfo;K is 1,4-phenylene, substituted by alkyl, alkoxy, alkanoylamino, ureido and/or chlorine, or is a 1,4-naphthylene optionally substituted by sulfo;A is a direct bond or is methylene or is a bivalent amino, alkylamino or (.beta.-cyanoethyl)-amino group;Y is vinyl or .beta.-chloroethyl.These compounds are fiber-reactive and have dyestuff properties and dye hydroxy--and/or carboxamido-containing material, in particular fiber material such as wool and, in particular cellulose, in strong color-fast shades.
摘要翻译：根据通式DNN [（4）E（1）] NN + TR 的化合物，其中：D是任选被磺基，羧基，烷基，烷氧基，烷酰基氨基和/或氯取代的苯基，至少通过磺基或羧基，或是磺基取代的萘基; E是由烷基，烷氧基，烷酰基氨基，脲基和/或氯取代的1,4-亚苯基，或是任选被磺基取代的1,4-亚萘基; K是由烷基，烷氧基，烷酰基氨基，脲基和/或氯取代的1,4-亚苯基，或是任选被磺基取代的1,4-亚萘基; A是直接键或亚甲基或是二价氨基，烷基氨基或（β-氰基乙基） - 氨基; Y是乙烯基或β-氯乙基。这些化合物是纤维反应性的并且具有染料性质和染料含羟基和/或羧酰氨基的材料，特别是纤维材料如羊毛，特别是纤维素，具有强烈的快速色调。

6. 发明授权

US4740592A Water-soluble azo compounds containing fiber-reactive groups and having a sulfo-naphthal coupling component with a triazinylamino substituent suitable as dyestuffs 失效
标题翻译：含有纤维反应性基团并具有磺基 - 萘偶合组分的适用作为染料的三嗪基氨基取代基的水溶性偶氮化合物
公开(公告)号：US4740592A
公开(公告)日：1988-04-26
申请号：US913485
申请日：1986-09-30
申请人： Hartmut Springer , Michael Kunze , Marcos Segal , Werner H. Russ
发明人： Hartmut Springer , Michael Kunze , Marcos Segal , Werner H. Russ
IPC分类号： C07D251/52 , C07D251/70 , C09B62/51 , D06P1/384 , D06P3/10 , D06P3/66 , C09B62/507
CPC分类号： C09B62/51
摘要： Water soluble azo compounds having fiber-reactive dye properties conforming to the formula ##STR1## in which D denotes a benzene or naphthalene ring;R.sup.1 denotes hydrogen, alkyl, alkoxy, sulfo or carboxy;R.sup.2 denotes hydrogen, alkyl, alkoxy, sulfo, carboxy, substituted or unsubstituted aryl, hydroxy, nitro or halogen;R denotes hydrogen or substituted or unsubstituted alkyl;A denotes hydroxy, substituted or unsubstituted alkoxy or aryloxy, thio, substituted or unsubstituted alkylthioether or arylthioether or an optionally monosubstituted or disubstituted amino group having substituents from the aliphatic and aromatic and the acylamide series;B hydroxy, optionally substituted alkoxy or aryloxy, thio, optionally substituted alkylthioether or arylthioether or an optionally monosubstituted or disubstituted amino group having substituents from the aliphatic and aromatic and the acylamide series;M denotes hydrogen, alkali or alkaline earth;m denotes the number 1 or 2;n denotes the number 0 or 1;p denotes the number 0, 1 or 2;Y denotes .beta.-thiosulfatoethyl, .beta.-phosphatoethyl, .beta.-chloroethyl, vinyl or .beta.-sulfatoethyl; the group --SO.sub.2 --Y is bonded to A or D or to both; or in which:A is chlorine or bromine,B is an optionally monosubstituted or disubstituted amino group having substituents from the aliphatic and aromatic and the acylamide series,m denotes the number 1 and the group --SO.sub.2 Y is bonded to D andD, R.sup.1, R.sup.2, R, M, n, p and Y have the above meanings.The new azo compounds dye fiber materials, such as wool and in particular cellulose, in strong and fast shades.
摘要翻译：具有符合式（1）＆lt; IMAGE＆gt;的式（1）的具有纤维反应性染料性质的水溶性偶氮化合物，其中D表示苯或萘环; R1表示氢，烷基，烷氧基，磺基或羧基; R 2表示氢，烷基，烷氧基，磺基，羧基，取代或未取代的芳基，羟基，硝基或卤素; R表示氢或取代或未取代的烷基; A表示羟基，取代或未取代的烷氧基或芳氧基，硫代，取代或未取代的烷基硫醚或芳基硫醚或任选具有脂族和芳族和酰基酰胺系列取代基的单取代或二取代的氨基; B羟基，任选取代的烷氧基或芳氧基，硫代，任选取代的烷基硫醚或芳硫醚或具有脂族和芳族和酰基酰胺系列取代基的任选单取代或二取代的氨基; M表示氢，碱或碱土; m表示数字1或2; n表示数字0或1; p表示数字0,1或2; Y表示β-硫代硫代乙基，β-磷酰乙基，β-氯乙基，乙烯基或β-磺基乙基; 基团-SO 2 -Y键合到A或D或两者; 或其中：A为氯或溴，B为任选具有脂族和芳族和酰基酰胺系列取代基的单取代或二取代的氨基，m表示数1，基团-SO 2 Y与D键合，D， R2，R，M，n，p和Y具有上述含义。新的偶氮化合物染料纤维材料，如羊毛，特别是纤维素，具有强烈和快速的色调。

7. 发明授权

US5003053A Water-soluble monoazo compounds containing a p-aminophenylamino- and chloro- or fluoro-substituted triazinylamino group and a fiber-reactive group selected from the vinylsulfone series, suitable as dyestuffs 失效
公开(公告)号：US5003053A
公开(公告)日：1991-03-26
申请号：US497734
申请日：1990-03-19
申请人： Hartmut Springer , Walter Helmling , Ludwig Schlafer , Werner H. Russ
发明人： Hartmut Springer , Walter Helmling , Ludwig Schlafer , Werner H. Russ
IPC分类号： C09B62/44
CPC分类号： C09B62/4413
摘要： Water-soluble monoazo compounds of the general formula (1) which dye in fast, mainly red shades materials which contain carboxamide and/or hydroxy groups, preferably in the form of fibers, in particular cellulose fiber materials. ##STR1## in which: Y is .beta.-thiosulfatoethyl, .beta.-phosphatoethyl, .beta.-chloroethyl, vinyl or .beta.-sulfatoethyl,M is hydrogen, an alkali metal or an alkaline-earth metal,D is naphthyl which is substituted by sulfo and/or a group of the formula Y--SO.sub.2 --,or is one of the radicals ##STR2## in which M and Y have one of the above meanings, m is the number zero or 1, R.sup.1 is hydrogen, lower alkyl, lower alkoxy or carboxy, and R.sup.2 is hydrogen, lower alkyl, lower alkoxy, sulfo, carboxy, optionally substituted aryl, hydroxy, nitro or halogen,n is the number zero or 1,R is hydrogen or optionally substituted lower alkyl,R* is hydrogen or optionally substituted lower alkyl,X is fluorine or chlorine,B is a group of the formula ##STR3## in which R.sup.3 is hydrogen or optionally substituted lower alkyl or aryl, R.sup.4 is hydrogen, optionally substituted alkyl having 1 to 8 carbon atoms or cycloalkyl having 5 to 8 carbon atoms and optionally having 1 to 3 methyl groups and/or one amino, lower alkanoylamino or benzoylamino group as substituents, or is the phenyl radical which may be substituted by sulfo, carboxy, halogen, lower alkyl, lower alkoxy, nitro, a group of the formula --SO.sub.2 --Y' (where Y' has one of the meanings of Y or is .beta.-hydroxyethyl), lower alkylamino, lower dialkylamino, lower alkanoylamino and/or benzoylamino, or is naphthyl radical, which may be substituted by sulfo and/or a group of the formula --SO.sub.2 --Y', and R.sup.5 has one of the meanings specified for R.sup.4, or R.sup.4 and R.sup.5, together with the nitrogen atom and one, two or three lower alkylene radicals and, if appropriate, one or two further heteroatoms, form a lower heterocyclic radical.

8. 发明授权

US4906736A Copper complex formazan compounds containing a phenylaminotriazinylamino group with a fiber-reactive group of the vinylsulfone series and an alkyl amino substituent in the phenyl moiety suitable as fiber-reactive dyestuffs 失效
标题翻译：含有乙烯基砜系列的纤维反应性基团的苯基氨基三嗪基氨基和适合作为纤维反应性染料的苯基部分中的烷基氨基取代基的铜络合甲an化合物
公开(公告)号：US4906736A
公开(公告)日：1990-03-06
申请号：US159188
申请日：1988-02-23
申请人： Gunther Schwaiger , Hartmut Springer , Werner H. Russ
发明人： Gunther Schwaiger , Hartmut Springer , Werner H. Russ
IPC分类号： C09B62/503 , C09B62/44 , D06P3/24 , D06P3/66
CPC分类号： C09B62/4407
摘要： Water-soluble copper complex formazan compounds which conform to the general formula (1) below and have useful fiber-reactive dye properties and dye carboxamido- and/or hydroxy-containing material, in particular cellulose fibers, in fast blue shades. ##STR1## in which: M is hydrogen or a salt-forming metal atom,k, m and n each denote the number zero, 1 or 2, the sum (k+m+n) being equal to 1 to 4,A is a benzene or napththalene ring which additionally can contain the fiber-reactive group --NH--Q and further substituents,B is a benzene or naphthalene ring which additionally contains the fiber-reactive group --NH--Q and further substituents,D is substituted or unsubstituted alkylene of 1 to 8 carbon atoms or is a benzene or naphthalene ring having optionally additional substituents or is a heterocyclic radical,X is a sulfo group or an oxy or carbonyloxy group,r is the number 1 or 2,Q is a radical of the formula (2) ##STR2## in which Y is halogen, Z is vinyl or a .beta.-substituted ethyl,G is the thio or an amino group --N(R)-- where R is equal to hydrogen or to low, substituted or unsubstituted alkyl or a group --K--W.sub.p defined hereinafter, K is alkylene or arylene or arylene-alkylene or alkylene-arylene whose arylene and alkylene radicals can be substituted and/or interrupted by a hetero group, W is a water-solubilizing group and p is the number 1, 2 or 3,the group --NH--Q is bonded to an aromatic carbon atom of A or B or D or to an aliphatic carbon atom of D or of a substituent on A or B, in the case of r=2, however, not simultaneously to A, B or D.
摘要翻译：符合以下通式（1）的水溶性铜络合物甲an化合物，具有有用的纤维反应性染料性质，并具有染料甲酰胺基和/或羟基的材料，特别是纤维素纤维，具有快速的蓝色色调。其中：M是氢或成盐金属原子，k，m和n分别表示数字零，1或2，总和（k + m + n）等于在图1至图4中，A是苯或萘环，其另外可以含有纤维反应性基团-NH-Q和另外的取代基，B是另外含有纤维反应性基团-NH-Q的苯或萘环， D为1至8个碳原子的取代或未取代的亚烷基，或具有任选另外的取代基的苯或萘环，或为杂环基，X为磺基或氧基或羰氧基，r为数1或2， Q是式（2）的基团，其中Y是卤素，Z是乙烯基或β-取代的乙基，G是硫基或氨基-N（R） - ，其中R等于氢或低级取代或未取代的烷基或下文定义的基团-K-Wp，K是亚芳基和亚芳基或亚芳基或亚芳基 - 亚烷基或亚烷基 - 亚芳基亚烷基可以被杂基取代和/或中断，W是水溶性基团，p是数字1,2或3，基团-NH-Q键合到A或B的芳族碳原子上，或 D或D的脂族碳原子或A或B上的取代基，在r = 2的情况下，然而，不能同时对A，B或D。

9. 发明授权

US5290922A Disazo compounds containing a cyanoamidotriazinyl radical as a bridging member (middle component) and fiber-reactive groups of the vinylsulfone series, suitable as dyestuffs 失效
标题翻译：含有氰基酰氨基三嗪基作为桥连构件（中间成分）的双偶氮化合物和乙烯基砜系列的纤维反应性基团，适合作为染料
公开(公告)号：US5290922A
公开(公告)日：1994-03-01
申请号：US958368
申请日：1992-12-30
申请人： Hartmut Springer , Rolf Gleibner
发明人： Hartmut Springer , Rolf Gleibner
IPC分类号： C09B62/44 , C09B62/513 , D06P1/384
CPC分类号： C09B62/513 , C09B62/4411
摘要： Disazo compounds which possess fiber-reactive groups and have useful dye properties and are capable of dyeing hydroxyl- and/or carboxamido-containing materials, in particular fiber materials, such as cellulose fibers and natural and synthetic polyamide, such as wool, in strong, fast shades. They conform to the formula ##STR1## wherein the substituents are as defined in the specification.
摘要翻译： PCT No.PCT / EP91 / 01208 Sec。一九九二年十二月三十日 102（e）1992年12月30日PCT PCT 1991年6月27日PCT公布。第WO92 / 01021号公报日期：1992年1月23日。具有纤维反应性基团并具有有用染料性能并且能够染色含羟基和/或羧酰氨基的材料，特别是纤维材料如纤维素纤维和天然和合成聚酰胺的双偶氮化合物，如羊毛，强力，快速的色调。它们符合式（*化学结构*），其中取代基如说明书中所定义。

10. 发明授权

US5166338A Water-soluble fiber-reactive dyes and preparation and use thereof 失效
标题翻译：水溶性纤维活性染料及其制备及应用
公开(公告)号：US5166338A
公开(公告)日：1992-11-24
申请号：US654873
申请日：1991-02-13
申请人： Holger M. Buch , Josef Geisenberger , Hartmut Springer
发明人： Holger M. Buch , Josef Geisenberger , Hartmut Springer
IPC分类号： C09B62/503
CPC分类号： C09B62/503
摘要： Anthraquinone, phthalocyanine, formazan, azomethine, dioxazine, phenazine, triphenylmethane, xanthene, thioxanthone, nitroaryl, naphthoquinone, pyrenequinone and perylenetetracarbimide dyes which contain one or two groups of the general formula ##STR1## where Y is vinyl or an ethyl group which contains in a .beta.-position a substituent which is eliminable by means of alkali to form a vinyl group, and W is a direct bond or a group of the general formula ##STR2## where M is a hydrogen atom or an alkali metal and n is zero, 1 or 2. The dyes have very good fiber-reactive properties and are advantageously suitable for dyeing carboxamino- and/or hydroxy-containing material, for example wool, in particular cellulose fiber materials; on these materials they produce strong fast shades in a high degree of fixation.
摘要翻译：蒽醌，酞菁，甲an，偶氮甲碱，二恶嗪，吩嗪，三苯甲烷，呫吨，噻吨酮，硝基芳基，萘醌，芘醌和苝醌四酰亚胺染料，其含有一个或两个通式为“IMAGE”的基团，其中Y是乙烯基或含有 β位，可通过碱可以除去形成乙烯基的取代基，W是直接键或通式为“IMAGE”的基团，其中M是氢原子或碱金属，n是0，染料具有非常好的纤维反应性，并且有利地适用于染色含羧基氨基和/或羟基的材料，例如羊毛，特别是纤维素纤维材料; 在这些材料上，它们在高度的固定下产生强烈的快速色调。

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