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1. 发明授权

US06841655B1 Surfactants 有权
标题翻译：表面活性剂
公开(公告)号：US06841655B1
公开(公告)日：2005-01-11
申请号：US10451149
申请日：2001-12-25
申请人： Tetsuya Gota , Kazushi Kobayashi , Kaoru Komiya , Masahide Tsuzuki , Takeaki Mizutari
发明人： Tetsuya Gota , Kazushi Kobayashi , Kaoru Komiya , Masahide Tsuzuki , Takeaki Mizutari
IPC分类号： B01F17/00 , B01F17/18 , B01F17/42 , C08F2/24 , C08F2/26 , C08F2/28 , C08F220/28 , C08G65/34
CPC分类号： C08F2/24 , B01F17/0021 , B01F17/0028 , B01F17/0035 , B01F17/0042 , B01F17/005 , B01F17/0057 , B01F17/0064 , C08F220/28
摘要： Disclosed are surfactants represented by the following formula (1): wherein R1 represents a branched aliphatic hydrocarbon group, a secondary aliphatic hydrocarbon group or a branched aliphatic acyl group, AO and AO′ each independently represents an oxyalkylene group having 2 to 4 carbon atoms, L represents a group represented by formula (2) to be described below, z stands for a number of from 1 to 10, X represents a hydrogen atom or an ionic hydrophilic group, m stands for a number of from 0 to 1,000, and n stands for a number of from 0 to 1,000. wherein R2 and R3 each independently represents a hydrogen atom or a methyl group, x stands for a number of from 0 to 12, and y stands for a number of 0 or 1. These surfactants do not contain any phenyl ether group considered to have significant effects on the environment, such as a nonylphenyl group, and have performance comparable with reactive surfactants containing one or more phenyl ether groups. Emulsifiers for emulsion polymerization, dispersants for dispersion polymerization and resin modifiers, all of which contain the surfactants, are also disclosed.
摘要翻译：公开了由下式（1）表示的表面活性剂：其中R 1表示支链脂族烃基，脂肪族脂族烃基或支链脂肪族酰基，AO和AO'各自独立地表示具有2〜4个碳原子的氧化烯基碳原子，L表示由下述式（2）表示的基团，z表示1至10的数，X表示氢原子或离子性亲水基团，m表示0至1,000的数，n表示0〜1,000的数。R 2和R 3各自独立地表示氢原子或甲基，x表示0〜12的数，y表示这些表面活性剂不包含被认为对环境具有显着影响的任何苯基醚基团，例如壬基苯基，并具有与含有一个或多个苯基醚基团的反应性表面活性剂相当的性能。还公开了用于乳液聚合的乳化剂，用于分散聚合的分散剂和树脂改性剂，所有这些都包含表面活性剂。

2. 发明授权

US5371159A Solution polymerization with reactive modifier 失效
标题翻译：溶液聚合反应性改性剂
公开(公告)号：US5371159A
公开(公告)日：1994-12-06
申请号：US12529
申请日：1993-02-02
申请人： Masahide Tsuzuki , Kaoru Komiya
发明人： Masahide Tsuzuki , Kaoru Komiya
IPC分类号： C08F16/26 , C08F16/30 , C08F30/02 , C08F290/06 , C08G65/28 , C08F216/20 , C08F228/00 , C08F230/02
CPC分类号： C08F16/26 , C08F16/30 , C08F290/062 , C08F30/02
摘要： An improved solution polymerization process is provided wherein vinyl monomers are polymerized in the presence of at least one reactive modifier which is a substituted alpha-olefin that incorporates at least three ether groups, is hydrophilic, and has a molecular weight of at least about 200. The modified vinyl polymers so produced are characterized by various improved physical properties including, in particular, electrical characteristics such as antistatic capacity.
摘要翻译：提供了一种改进的溶液聚合方法，其中乙烯基单体在至少一种反应性改性剂存在下聚合，所述反应性改性剂是引入至少三个醚基团的取代的α-烯烃，是亲水的，并且具有至少约200的分子量。如此制备的改性乙烯基聚合物的特征在于各种改进的物理性质，特别包括诸如抗静电能力的电特性。

3. 发明授权

US5990342A Surfactant, emulsifier for emulsion polymerization, dispersant for suspension polymerization and modifier for resin modification 失效
标题翻译：表面活性剂，乳液聚合乳化剂，悬浮聚合用分散剂和树脂改性改性剂
公开(公告)号：US5990342A
公开(公告)日：1999-11-23
申请号：US683776
申请日：1996-07-16
申请人： Masahide Tsuzuki , Kaoru Komiya
发明人： Masahide Tsuzuki , Kaoru Komiya
IPC分类号： B01F17/42 , B01F17/52 , C08F2/18 , C08F2/20 , C08F2/24 , C08F2/26 , C07C69/73 , C07C69/52
CPC分类号： C08F2/26
摘要： A surfactant, an emusifier for emulsion polymerization, a dispersant for suspension polymerization and a modifier for modification of resin properties are disclosed, each of these agents being comprised of a novel compound having a dibasic carboxyl group. The compound is represented by Formula (1)[X--O--(R.sup.1 O).sub.m --OC--R.sup.2 --COO].sub.y M (1)where M is a hydrogen atom, a metal atom or a quaternary nitrogen-containing group, y is equal to the valence of M, R.sup.1 is at least one hydrocarbon group, R.sup.2 is a moiety of a dibasic acid or a moiety of its anhydride, m is 0 or an integer of 1 to 1,000, and X is a hydrocarbon group having at least one polymerizable double bond of carbon--ncarbon which may contain an oxygen atom and a fluorine atom.
摘要翻译：公开了一种表面活性剂，用于乳液聚合的乳化剂，用于悬浮聚合的分散剂和用于改性树脂性质的改性剂，这些试剂均由具有二元羧基的新化合物组成。该化合物由式（1）[XO-（R1O）m-OC-R2-COO] yM（1）表示，其中M是氢原子，金属原子或含季氮的基团，y等于 M的价数，R 1是至少一个烃基，R 2是二元酸的部分或其酸酐的部分，m是0或1〜1000的整数，X是具有至少一个可聚合双键的烃基可以含有氧原子和氟原子的碳 - 碳的键。

4. 发明授权

US5929290A Compound and surfactant 失效
标题翻译：复合和表面活性剂
公开(公告)号：US5929290A
公开(公告)日：1999-07-27
申请号：US913856
申请日：1997-09-29
申请人： Kaoru Komiya , Hiromasa Kawamata , Shohei Umezawa
发明人： Kaoru Komiya , Hiromasa Kawamata , Shohei Umezawa
IPC分类号： C07C43/178 , C07C69/63 , C07C305/10 , C07F9/09 , C08G65/00 , C08G65/14 , C08G65/26 , C08G65/28 , C07C43/18
CPC分类号： C08G65/2639 , C07C305/10 , C07C43/178 , C07C69/63 , C07F9/091 , C08G65/007 , C08G65/14
摘要： A novel polymerizable surfactant represented by the general formula (1): ##STR1## (wherein, R.sup.1 represents a hydrogen atom or a methyl group, Rf represents a hydrocarbon group in which one or more hydrogen atoms are replaced by a fluorine atom or atoms, or an acyl group in which one or more hydrogen atoms are replaced by a fluorine atom or atoms, AO and AO' represent a group selected from an oxyalkylene group having 2-4 carbon atoms or a styrene oxide residue, m and m' are 0 or a number between 1 and 1,000, X represents a hydrogen atom or a hydrophilic group).
摘要翻译： PCT No.PCT / JP97 / 00186 Sec。 371日期：1997年9月29日 102（e）1997年9月29日PCT PCT 1997年1月28日PCT公布。 WO97 / 28111 PCT公开号日期：1997年8月7日由通式（1）表示的新型可聚合表面活性剂：（其中，R1表示氢原子或甲基，Rf表示其中一个或多个氢原子被氟原子代替的烃基或原子或其中一个或多个氢原子被氟原子或原子取代的酰基，AO和AO'表示选自具有2-4个碳原子的氧化烯基或氧化苯乙烯残基的基团，m和m' 为0或1至1,000之间的数，X表示氢原子或亲水基团）。

5. 发明授权

US5977398A Viscosity conditioner 失效
标题翻译：粘度调节剂
公开(公告)号：US5977398A
公开(公告)日：1999-11-02
申请号：US701768
申请日：1996-08-26
申请人： Kaoru Komiya
发明人： Kaoru Komiya
IPC分类号： C09K3/00 , C08G18/28 , C08G18/48 , C08G65/32 , C09D7/00 , C07C271/08 , C07C217/10 , C07C271/26 , C08K5/205
CPC分类号： C09D5/024 , C08G18/283 , C09D7/002 , C08L75/08
摘要： A viscosity conditioner is disclosed which is comprised of a compound represented by the following formula ##STR1## where R.sup.1 to R.sup.3 each are hydrocarbyl groups which may be identical or different, m ranges from 2 to 4, and n ranges from 1 to 1,000. The specified viscosity conditioner is by nature non-ionic and excellent in leveling.
摘要翻译：公开了一种粘度调节剂，其由下式表示的化合物组成，其中R 1至R 3各自为可相同或不同的烃基，m为2至4，n为1至1,000。特定的粘度调节剂本质上是非离子的，并且在流平方面是优异的。

6. 发明授权

US5753731A Viscosity conditioner and emulsion and emulsion paint compositions 失效
标题翻译：粘度调节剂和乳液和乳液漆组合物
公开(公告)号：US5753731A
公开(公告)日：1998-05-19
申请号：US706347
申请日：1996-08-30
申请人： Toyotaro Yoshioka , Kaoru Komiya
发明人： Toyotaro Yoshioka , Kaoru Komiya
IPC分类号： C08G18/28 , C09D7/00 , C08K5/205 , B01J13/00 , C07C269/02 , C07C271/10
CPC分类号： C09D5/024 , C08G18/283 , C09D7/002 , C08L75/08 , Y10S526/932
摘要： A viscosity conditioner is disclosed which comprises a compound structured to have a group of the following formula (1) ##STR1## where R is a hydrocarbyl group, R' is a branched or secondary hydrocarbyl group, and n ranges from 1 to 500. The specified viscosity conditioner is conducive to reduced temperature dependence and hence constant viscosity in a certain range suited for all environmental conditions and good coatability at all seasons. Also disclosed are an emulsion composition and an emulsion paint composition, each of which include of the viscosity conditioner.
摘要翻译：公开了一种粘度调节剂，其包含具有下式（1）的基团的化合物：其中R是烃基，R'是支链或仲烃基，n的范围从1到特定的粘度调节剂有利于降低温度依赖性，因此有利于在适合所有环境条件的一定范围内的恒定粘度和在所有季节具有良好的涂布性。还公开了乳液组合物和乳液漆组合物，其中每一种都包括粘度调节剂。

7. 发明授权

US5534643A Surface-treating agent for metal can and method for treating metal cansurface 失效
标题翻译：金属表面处理剂及金属罐表面处理方法
公开(公告)号：US5534643A
公开(公告)日：1996-07-09
申请号：US186516
申请日：1994-01-26
申请人： Syunichi Endou , Satoshi Miyamoto , Kaoru Komiya , Naomi Koishikawa
发明人： Syunichi Endou , Satoshi Miyamoto , Kaoru Komiya , Naomi Koishikawa
IPC分类号： C10M105/40 , C10M173/02 , C10N30/06 , C10N40/24 , C07C57/00
CPC分类号： C10M173/02 , C10M105/40 , C10M2201/02 , C10M2207/287 , C10M2207/288 , C10M2207/289 , C10N2240/00 , C10N2240/22 , C10N2240/30 , C10N2240/50 , C10N2240/52 , C10N2240/54 , C10N2240/56 , C10N2240/58 , C10N2240/60 , C10N2240/66 , C10N2250/02
摘要： The invention provides a surface-treating agent for a metal can, which diminishes friction on an outside surface of the can without giving a bad influence on attachability of paint, lacquer and the like and shows high safety to the human body. Furthermore, the invention provides a method for treating a metal can surface with said surface-treating agent. The surface-treating agent for a metal can is characterized by containing an ester compound between a polyglycerol and fatty acid(s) as an essential component. To diminish a friction coefficient of the metal can surface, the surface-treating agent is brought into contact with the metal can surface.
摘要翻译：本发明提供了一种用于金属罐的表面处理剂，其减少了罐的外表面上的摩擦，而不会对涂料，漆等的附着性产生不良影响，并且对人体具有高安全性。此外，本发明提供了用所述表面处理剂处理金属罐表面的方法。金属罐用表面处理剂的特征在于，在聚甘油和脂肪酸之间含有酯化合物作为必需成分。为了减小金属罐表面的摩擦系数，表面处理剂与金属罐表面接触。

8. 发明授权

US5372743A Surfactant composition, degreasing composition and degreasing bath 失效
标题翻译：表面活性剂组成，脱脂组成和脱脂浴
公开(公告)号：US5372743A
公开(公告)日：1994-12-13
申请号：US103322
申请日：1993-08-09
申请人： Satoshi Miyamoto , Isao Kawasaki , Kaoru Komiya
发明人： Satoshi Miyamoto , Isao Kawasaki , Kaoru Komiya
IPC分类号： C11D1/72 , C11D1/78 , C11D1/825 , C23G1/14 , C11D3/36 , C07F9/09
CPC分类号： C11D1/825 , C23G1/14 , C11D1/72 , C11D1/78
摘要： The degreasing composition comprises a surfactant composition comprising a compound (a) represented by the general formula (1):R.sup.1 O(AO).sub.n H (1)wherein R.sup.1 is a substituted or unsubstituted hydrocarbon group having 6 or more carbon atoms; A is at least one group selected from the group consisting of an ethylene group, a propylene group, a butylene group and a styrene group, provided that an ethylene group in A is 5 mol or more per 1 mol of R.sup.1, and that the ethylene group is 50 mol % or more per 100 mol % of said A; and n is an integer of 5-50;a compound (b1) represented by the general formula (2): ##STR1## wherein R.sup.2 is a substituted or unsubstituted hydrocarbon group having 6 or more carbon atoms, E is an ethylene group, and n is an integer of 1-20; and a compound (b2) represented by the general formula (3): ##STR2## wherein R.sup.2, E and n are the same as in the formula (2); a weight ratio of compound (a)/(compound (b1)+compound (b2)) being 10/90-95/5, and a weight ratio of compound (b2)/compound (b1) being 20/80 or more, and further comprising an alkali builder in a weight ratio [(compound (a)+compound (b1)+compound (b2))/alkali builder] of 1:0.1-1:2,000.
摘要翻译：脱脂组合物包含含有通式（1）表示的化合物（a）的表面活性剂组合物：R1O（AO）nH（1）其中R1是具有6个或更多个碳原子的取代或未取代的烃基; A是选自亚乙基，亚丙基，亚丁基和苯乙烯基团中的至少一个基团，条件是每1摩尔R1中A中的亚乙基为5摩尔或更多，并且乙烯所述A为100摩尔％为50摩尔％以上; n为5-50的整数; 由通式（2）表示的化合物（b1）：其中R2是取代或未取代的具有6个或更多个碳原子的烃基，E是亚乙基，n是1-20的整数 ; 和由通式（3）表示的化合物（b2）：其中R2，E和n与式（2）中相同; 化合物（a）/（化合物（b1）+化合物（b2））的重量比为10 / 90-95 / 5，化合物（b2）/化合物（b1）的重量比为20/80以上，并且还包含重量比为[（化合物（a）+化合物（b1）+化合物（b2））/碱性助洗剂]的碱助洗剂为1:0.1-1:2000。

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